DPP # 2

ONLY ONE OPTION CORRECT TYPE

1. In a given process for an ideal gas, w = 0 and q < 0 then for the gas :
(A) Temperature will decrease (B) Volume will increases
(C) Pressure will remains constant (D) Temperature will increase

2. Two mole of an ideal gas is heated at constant pressure of one atmosphere from 27ºC to 127ºC.
If Cv, m = 20 + 10–2 T JK–1 mol–1, then q and U for the process are respectively :
(A) 6362.8 J, 4700 J (B) 3037.2 J, 4700 J
(C) 7062.8, 5400 J (D) 3181.4 J, 2350 J

3. The increase in internal energy of 1 kg of water at 100°C when it is converted into steam at the
same temperature and at 1 atm (100 k Pa) will be [The density of water and steam are 1000
kg/m3 & 0.6 kg/m3 respectively. The latent heat of vapourisation of water is 2.25 × 106 J/kg.]
(A) 2.08 × 106 J (B) 4 × 107 J (C) 3.27 × 108 J (D) 5 × 109 J

4. The work done in the isothermal reversible expansion of argon gas at 27°C from 4 L to 16 L
was equal to 4200 cal. What is the amount for Argon subjected to such an expansion?
(Atomic weight Ar = 40, ln 4 = 1.4)
(A) 5.0 g (B) 20.0 g (C) 200.0 g (D) 48.1 g

5. 1 mole of an ideal gas is allowed to expand reversibly and isothermally at 300 K from 1.25 dm3
to 2.5 dm3. Work done by the system will be
Given : R = 8.3 JK–1mol–1, ln2 = 0.7
(A) 1743 J (B) –1743 J (C) 1728.8 J (D) –1728.8 J

6. Calculate the work done in Joules when 1.0 mole of N2H4 decomposed against a pressure of 1.0
atm at 27°C
3N2H4(g)  4NH3(g) + N2(g)
(A) –4988.4 (B) –9976.8 (C) 9976.8 (D) 4988.4

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 1
Online Partner UNACADEMY
 ONE OR MORE THAN ONE OPTION CORRECT TYPE
7. During the isothermal expansion of an ideal gas :
(A) The internal energy remains unaffected (B) The temperature remains constant
(C) The enthalpy remains unaffected (D) The enthalpy increases

8. U must be zero for :

(A) Cyclic process (B) Isothermal ideal gas expansion
(C) Isothermal real gas expansion (D) Isothermal change in physical state

9. Which of the following are incorrect:

(A) Work done by the surrounding in case of infinite stage expansion is more than single stage
expansion
(B) Irreversible work is always greater than reversible work, (with sign)
(C) On an ideal gas in case of single stage expansion and compression system as well as
surrounding are restored back to their original states
(D) If a gas in thermodynamic equilibrium is taken from state A to state B, by four successive
single stage expansions. Then we can plot 4 points on the P-V indicator diagram.

INTEGER/SUBJECTIVE
10. Calculate the U (in Joule) for 1 mole ideal diatomic gas undergoing for the process A to B as
shown in diagram : ( 1 L-atm = 100 J)

A
2

P
(atm)

1 B
1 4
V(L)

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 2
Online Partner UNACADEMY