SEMS Academy

Chemistry (TEST -13)

Test Session-2020
Name: Class: 2nd Year, Time: 1.Hrs, Marks:, Date:
Q No. 1 2 3 4 Total
Marks 30
Q: 1. Tick the correct option. 10x1 = 10
Q.1 Four possible options have been given. Tick () mark the correct option. (10)

i) The carbon atom of a carbonyl group is:

(a) sp hybridized (b) sp2 hybridized (c) sp3 hybridized (d) none of these

ii) Formalin is:

(a) 10% solution of formaldehyde in water (b) 20% solution of formaldehyde in water

(c) 40% solution of formaldehyde in water (d) 60% solution of formaldehyde in water

iii) Which of the following reagents will react with both aldehydes and ketones?
(a) Grignard (b) Tollen’s reagent (c) Fehling’s reagent (d) Benedict’s reagent

iv) Cannizzaro’s reaction is not given by:

(a) Formaldehyde (b) Acetaldehyde (c) Benzaldehyde (d) Trimethylacetaldehyde

v) Which of the following compounds will not give iodoform teat on treatment with I 2 /NaOH
(a) Acetaldehyde (b) Acetone (c) Butanone (d) 3-Pentanone

vi) Acetone reacts with HCN to form a cyanohydrin. It is an example of:

(a) Electrophilic addition (b) Electrophilic substitution

(c) Nucleophilic addition (d) Nucleophilic substitution

vii) Ketones are prepared by the oxidation of:

(a) Primary alcohol (b) secondary alcohol (c) Tertiary alcohol (d) None of these

viii) A carbonyl group can be reduced to alkane by

(a) WURTZ reaction (b) Kolbe’s reaction (c) Clemmenson’s reaction (d) None
Section –I 8x2= 16

I. Outline Tollens test and give its application also.

II. Convert i) into methanol ii)Ethanal into ethanol.
III. Give prepation of following from acetaldehyde i)lactic acid ii)Acetal
IV. Give mechanism of acid catalysed reaction of carbonyl compounds.
V. What is condensation reaction?Give one example.
VI. Discus the oxidation of aldehydes.
VII. Distinguish between 2-butanone and 3-pentanone;
VIII. What is the effect of heat on calcium acetate?
IX. What is formalin?Give composition
X. Give reaction of acetaldehyde and ketone with 2,4-DNPH
Long
(a) Describe the mechanism of aldol condensation .why the formaldehyee does not give this test.
(b) Give addition of sodium bisulphite with carbonyl compounds and mention its application.