ADHYAY Batch ISOMERISM LECTURE -1

Isomerism
nee

Iso-name

mers- constituents

Isomerism
H
Mean ↓
structural Isomerium
steroisomeriem
conformational
①'chain isomerism v Geometrical
① also known
*

as lotamers.
②
Position isomerism &
optical
③
functional isomerism-

④ Meta merism

⑤
Tautomerism

⑥
Ring
chain isomerism.
structural isomerism -
-Those molecules whose
empirical formula is

but structural is structural

formula different
same are called
isomers.

D C one
way
- -

aidentical- Iway.
c
< c s
-
-

identical
way
( c- c
<y c
a
- - -

I
(n - c-c c c

sways
-
-

c -c -
c

1
25 + c-c-
- -
C

ways.
c - - - c 3

C
I
c -
C -
C

↓
 123456

I
C6 5
-
c -c
c
position isomers

S
- -
- -

-in which have

some
difference

I
12345
E
c -c
- - -

↳ position of
the

sands which mastiment called

are

have
difference in
parent,c-c-c- ↳23
-- C
5
position isomers.
chain.

I
I ->

Chain
~ C sways

is here
I position

I -How manyways captionalang skeleton.

some
We
we

DBENDU (c+ 1)
(N)
=
-

& structural isomers? X

Calax--
of
c
no c -c c -
- -

-
DBE (4+1) -(170)
=

0
=

c -c-
-

2
↓
- -
c - 2. C
- c -c -c -

b
c -c -
c - x
C
I ~ X
2 I
c -c -
->
- -
- C
c -c
-

4
-
-
I
1:calculate the
no structural isomers CSHC
of of
-
--
c - 3
->
25 c -c
- -

-- -

---C I ↳
I
C

I - - I
- c -
C
--

↓ 8
=

⑭
R :calculate the
no structural
of Junula
-
- homers
of C6H13Br.
the
-

structural
1:calculate the
no
of isomers
of formula
the C6HIO.

DBE (64) (10) 0. (nH2n+2O

= -
=

ne

--- -
functional
·somers
-
-
alcohol ether.
Co- alcohols -

- ~v
CGH13-01
-

c -c-c- c-c
-
c ->
③ position isomers

L
->

Chain -- -- -
irmes
c -c
-

c -
c
-

c -> 5 -
position
↓
--
c -c -c
-
c -
-
4) -
pention isomers

L
↓-
Gain C

c
-
- k -
-
c -
~
c
->
B
↓
-
alcohol
-

-
-

c -

↓ ↓ --
-
Co-other (R-O-R1 Cuttm+1- 0 -Cuttr +1
*0,1,2--
is
=
22-0-24

I
3
0 23
3c c
- -
- -

I
-

chan
-

-
-

->

-
- -
-
-

) - chan

p-e -q
-

" ~ - -

-C --- C - 3
- v W -

- -
- - 4

↓
E
- I
I -> -

c C C
8
-
=

↓
- -
-

carizi
e -

c- -> 2
c -c -

--
2
--
-
-

4
↓ -

Total ether 4 =
8+3
+
15
=

alcoho
Total
Joisomerism:
* These
compounds whose

emperical formula is same but the structural

formula
is
having
two
differenttypes offunctional
group
functional
all called isomers.

alcohol ethers. ROM R 0 R

eg.
-
-

O O

k
aldehydes
a ketones R
- -
H R -
-
R
6

aid & esters. R-CH2--OH R 1

-
o-R

by
thou
meism:Thisisomerism
is shown

functional groups
hold
which can two
different
alkyl groups of functional
on either side
the the

grouf
I ⑧

R -
0
-
R2 R - -
-
R
R -
NA-R
CHy-O-CH2-CH2-CH3
I
CH
meta
Cz-O-
-
mers
-
- CH5-CH2-0-CH2-CHS ↓
position isomers.

* position isomers
regarded
ketones an as as well as metamers.
 ⑧
Y
> I 4 It
se stee
2

↓ -
3

Calculate structural
having empirical
isomers
: the
no
of
formula as C5H1002 ↑

functi o nal
x

calboxylic aids]-
L homers.
DBE (5+1)
= -

(102)
↳ enters,

zargic "
O

ads:- CGHq-d-on
~ -

④
]
-
(n c - -

- -

↓
es:-
O

R-I-o-R
---
..
O
--
Il
>
- Cr -

c
-
-

C3 c -c -
c -
2

I
-

-
Il
2
-
c -

0 D
-

C3 -"
0
~v Il
c -c -
c
:* - -
0

ca-k
- -o
-

k
Y 1 0 25 -

-
-
-
-

↳
calculate the
no structural
A as C5H10.
isomers
having empirical formula
DBE=(5+ 1) -

(E) I =

either
IIbond or
ling.
enes:5
-

c
cc1 +

2
-
-

ccc c -
③
k
C
I *
--- C - 0
- -

↓ -
5

ringanylic:.....
;
e

* It ↑ position

-
I
- -
& I-ring chain isomers.

<]
/ ↑
M
--
IIT JEE

calculate the
that

the
log cycliccompounds for
as
↳

CGH6 + DBE (41)

=
-
(6/2)
3 2
5
=
-
=

-
-

⑤ -
I
cycle
+ 1* bond or

ang
I &
↓ I

bicycle compounds.
⑭ Calculate the
total structural
formula formed by
oC6112.
no

empirical famula
I
including cyclic acyleic
&

I
Both

1:calculate of alkynes Jared by

total
the Colic

DBE (64) (102) 3

-

= =

26 -
-
-
cc c

..
c-c- -c

c -

"I C
- - cca

-
I
c -
-
- ①
d

cx
c -c -

c -

d d
-
-