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SYNOPSIS
A Thermal Expansion of Liquids V2 V1
Introduction: a app / 0C
V1 (t2 t1 )
Liquids do not have a shape of their own. They
assume the shape of the container. V2 V1[1 app (t )]
Linear and superficial expansions have no Relation between r and a :
meaning for liquids. The coefficient of real expansion of a liquid is
As liquids possess definite volume, they equal to the sum of coefficient of apparent
experience volume expansion only. expansion of the liquid and coefficient of volume
Coefficient Of Real Expansion( r ): expansion of the vessel.
The actual expansion of the liquid is called real
or absolute expansion of liquid. = r app vessel app 3vessel
The real expansion of liquid depends on If r vessel , the level of liquid in the vessel
a) Initial volume of liquid
rises.
b) Rise in temperature
c) Nature of liquid If r vessel , the level of liquid in the vessel
The real increase in volume per unit original remains stationary.
volume per 10C rise in temperature is called If real vessel , the level of liquid in the vessel
coefficient of real expansion
will fall.
V2 V1 If the same liquid is heated in two vessels X and
r real /0 C
V1 (t 2 t1 ) Y then r = ax+3x = ay+3y
d d d d Immersed in Liquid:
t C , then r d t r d t
0 0 t or 0 t / C0 When a body is immersed in a liquid its weight
t 0
decreases.
If d1 and d2 are densities of liquid at t1 0 C and The apparent weight of the body, W=V(d-s) g.
d1 d 2 0
where d= density of solid
t 2 C ,then r d t d t / C s= density of liquid
0
1 2 2 1
V= volume of solid .
The temperature at which the density of liquid is
When temperature is increased, density of the
x 0 liquid decreases more than that of solid. Hence
x% less than that at 00 C is (100 x) C apparent weight of solid immersed in liquid
r
increases.
The temperature at which the density becomes
If d1 and d 2 are densities of a liquid at t1C
x% of the density at 00 C is 100 x 0C and t 2 C respectively and volumes of solid body
x r
The temperature at which the density of liquid is at t1C and t 2 C are v1 and v 2 then
F2 v 2 d 2
Volume of Unoccupied space
F1 v1 d1
remains smae at all Temperatures:
When a liquid is taken in a container and heated, F2 1 s t 2 t1
the unoccupied volume over the liquid remains
F1 1 r t 2 t1
constant at all temperatures, if Vc c Vl l
v2 d2 1
where Vc and Vl are the volumes of the container 1 s t 2 t1 and
v1 d1 1 r t 2 t1
and the liquid respectively.
c and l are the coefficient of volume expansion F1
1 r s t 2 t1
of container and coefficient of real expansion of F2
the liquid. Where r is coefficient of real expansion of liquid,
The coefficient of real expansion of mercury is
s is coeffcient of volume expansion of solid.
seven times that of glass approximately. Therefore
for the unoccupied volume over liquid in a glass Since,
vessel to remain constant at all temperatures is F1 1 r t 2 t1
Vl 1 F2 1 s t 2 t1
Vc 7
1 r t 2 t1 1 s t 2 t1
Volume of Liquid Expelled:
2
A container of volume Vc at temperature t10 C is 1 s t 2 t1 r t 2 t1 r s t 2 t1
completely filled with a liquid. If the container is F1
1 r s t 2 t1
heated to t2 0 C , then volume of liquid overflown F2
is Vl (V2 )l (V2 )c ( l c )Vc (t2 t1 )
Apparent Weight of a Solid
t
s r 2
2
t1 0 .
34 Narayana IIT/PMT Academy
JEE MAINS HEAT AND THERMODYNAMICS
A body floats in a liquid at t1C with x1 % of its The experiment with Hope’s apparatus
volume is submerged in a liquid. If liquid is heated establishes that water has maximum density at
to t 2 C then the same body floats with x 2 % 40C.
of its volume submerged in the liquid. Dilatometer is a convenient apparatus to study
the anomalous expansion of water.
x2 x1 0
r / C
x1 t2 t1 In cold countries during winter water at the
surface in ponds, lakes and rivers begin to freeze.
Since up thrust = vdg
But the temperature of bottom layers will be at
v1d1g v 2 d 2g 40 C. Hence the survival of aquatic plants and
x1 x2 animals is possible due to anomalous behaviour
vd1g vd 2g of water.
100 100
d1 x 2 In winter, water in the lumps of clay cools from
1 r t 2 t1 40C to 00 C and expands resulting in the breaking
d 2 x1
of lumps
x2 x1 0 In winter season cold countries radiators of
r / C
x1 t2 t1 automobiles may burst when water in them
Anamolous Expansion of Water: solidifies. Hence liquids like ethyl alcohol or
Liquids, in general expand in volume with rise of ethylene glycol are added to water to prevent
temperature. solidification.
Pure water when heated contracts from 00 C to The mud walls having moisture embedded in
3.980 C (40 C) and expands from 40C onwards.
them, crack and break down in winter due to
It is called anamolous expansion of water.
anomalous expansion of water.
Water has negative expansion coefficient in the
range at 00 C to 40 C and positive expansion Water expands on solidification and hence floats
coefficient above 40 C. on water.
At 40 C water occupies minimum volume and
Water carrying pipes burst in winter, as water
hence density becomes maximum (1gm /cc).
expands on cooling from 40 Cto 00C.
The anomalous behaviour of water has been
explained on the assumption that there are three
types of water molecules. They are
a) H2 O b) H 2O 2 c) H 2O 3
0
The density of water increases from 0 Cto 4 C 0
and decreases with rise in temperature from 40C H2O , H 2O 2 and H 2O 3 molecules have
different volumes per unit mass and are mixed in
different proportions at different temperatures.
So water has maximum density at 4C due to
greater proportions of higher types.
14. A small stone is inside a ice block which 20. Two identical tumblers are filled fully with
floats in water. When the ice fully melts the water at a certain temperature. One of the
level water tumblers is warmed up and the other cooled
1) increases down. But it is observed that the water
2) decreases overflows from both the tumblers. The
3) does not change temperature at which they are fully filled is
1) 4K 2) 277K 3) 2770C 4) -2770C
4) first decreases and then increases
21. Water at 40C is filled to the brim of 2 beakers.
15. Water in closed rectangular tube with left
A boy perfomed an experiment ‘A’ of heating
arm vertically placed above the arc lamp is
and ‘B’ of cooling. The observation was
heated
1) Water level in ‘B’ went down and in ‘A’ water
1) Water will begin to circulate in anticlockwise flowed out.
direction. 2) Water flowed out in both the cases.
2) Water will begin to circulate in clockwise 3) Water flowed out in ‘B’ and water level went
direction. down in ‘A’.
3) Water will not circulate but heats up 4)Water level went down in both cases.
4) Water will oscillate in clockwise and anticlock 22. The surface of water in a lake is just going
wise directions. to freeze. Then the temperature of water of
16. The apparent coefficient of expansion of a the bottom of the lake is
liquid depends upon 1) 4 K 2) 2770C 3) 277K 4) 1000C
1) the nature of the liquid 23. Water has maximum density at
2) the scale of temperature 1) 00C 2) 40C 3) 250C 4) 370C
3) mass of the liquid 24. A Sealed glass jar is full of water. When it is
4) pressure of the liquid kept in a freezing mixture, it is broken
because
17. A glass is full of water at 40 C when it is (a)
1) Water expands from 40C to 00C
cooled (b) heated then, which one of the 2) Ice expands while melting
following is correct 3) Water expands due to freezing
1) water level decreases, increases 4) Ice expands since its temperature falls below
2) water level increases, decreases 00 C
3) water level decreases, decreases 25. A sealed glass jar is full of water. When its
4) water over flow in both cases temperature is decreased to 00C.
18. The top of a lake is frozen when the air in 1) The glass jar remains as it is with ice.
contact with the lake surface is at 50 C the 2) The glass jar remains as it is with water.
temerature of water in contact with the 3) The glass jar contains half the amount of ice
bottom of the lake will be mixed with water.
4) The glass jar breaks due to the formation of
1) 50 C 2) 40 C 3) 0 0 C 4) 40 C ice.
19. A metal sphere is suspended in water at
KEY
0 0 C by a thread when water is heated to
CONCEPTUAL
40 C the tension in the thread 1.2 2.2 3.1 4.2 5.3
1) Decreases 6.4 7.3 8.3 9.1 10.3
2) Increases 11.1 12.3 13.2 14.2 15.2
3) Remains same 16.1 17.4 18.2 19.1 20.2
4) First increases and then decreases 21.2 22.3 23. 2 24.1 25.4
Narayana IIT/PMT Academy 37
HEAT AND THERMODYNAMICS JEE
JEEMAINS
MAINS
HINTS f1 f 2 f1 f 2
3. f t f t 4.
2 1 1 2 f 2 t1 f 1 t 2
LEVEL-II
2. If g (apparent) of a liquid in a vessel is 76%
V of g (real) of that liquid, the coefficient of
1. app linear expansion of the vessel is
V1 (t2 t1 )
1. 8% of g (real) 2. 16% of g (real)
3 V V 3. 24% of g (real) 4. 25.3% of g (real)
V V V
4 2 2 3. A uniform pressure P is exerted on all sides
2. r x 31 ; r 2 x 3 2 of a solid cube at temperature t0 C. By what
amount should the temperature of the cube
Solve gr
be raised in order to bring its volume back
97 to the original value before the pressure was
3. weight of body = Vd 0 g
100 Liquidsat C applied, if the bulk modulus is B and volume
coefficient is g?
= Vd Liquidsat 0t g
P P
97 d1 1) 2)
1 rt B B
100 d 0
4. Weight of the body = 0.98VdL4g = VdLtg B 1
3) 4)
P BP
d4
[1 r (t 4)] 4. If d1 and d2 are the densities of a liquid at t10
dt
d1
5. R a 3 g C and t20 C, then d is (g = coefficient of
2
l2 l1 real expansion)
6. 3
l1 t ,
1 t1 1 t1
7. R a g 1. 2.
1 t 2 1 t 2
1 t 2 1 t 2
8. R a g 3. 4.
1 t1 1 t1
2. A metal ball suspended from a spring 7. Apparent expansion of a liquid depends upon
balance is immersed in water at 4C . If the 1) Nature of liquid 2) Nature of vessel
temperature of water is changed the reading 3) Temperature rise 4) Scale of temperature
in the balance 8. List - I List - II
(a) may decreases (b) increases a. Temperature of water e.273 K
(c) may remains same
at the bottom of a lake
1) only (c) is true 2) (b) is true
3) (a) & (c) are true 4) (b) & (c) are true b. r of water is - ve f. 277 K
3. When a liquid in a vessel is heated, its level between
continuosly rises. Then
c. r of water is positive g. above 277 K
1) R is ve g 0
d. Temperature of water h. 273K and
2) R is ve g is ve just below ice layer in 277 K
3) R A 4) R g a Lake
4. Identify the correct statement from the 1) a- g, b-h, c-e, d-f 2) a-h, b-e, c-f, d-g
following: 3) a-e, b-f, c-g, d-h 4) a-f, b-h, c-g, d-e
1) Liquids have two coefficient of expansions as 9. LIST -I LIST -II
they do not have definite shape and size. a) App. expansion e) Nature of vessel
2) The apparent expansion of liquid may be equal and liqied
to zero. b) Real expansion f) Nature of liquid
3) The expansion of liquids is less than the solids. c) ga g) Nature of
4) The real expansion of liquids depends on the
Vessel&liquid
nature of material of the container.
5. Identify the correct statements from the and temperature
following: d) gr h) Nature of
a) The apparent expansion of liquid depends on liquid&temp.
the expansion of material of the container 1) a-e, b-f, c-g, d-h 2) a-f, b-g, c-h, d-e
b)The real expansion of the liquids depends on 3) a-g, b-h,c-e, d-f. 4) a-h, b-e, c-f, d-g.
the density of the liquid. 10. LIST -I LIST - II
c)The expansion of liquid with respect to the
container is called the apparent expansion. m1
a) Mass of liquid expelled e) 1 t
1) Only a & b are true 2) Only b & c are true
3) a,b & c are true 4) Only a & c are true on heating
6. A liquid of coefficient of real expansion is
partly filled in a vessel of coefficient of linear d1 d 2
b)Corrected Barometric f) d t
expansion /3. When the system is heated, 2
then. height
a) The volume of space above liquid remains
same. a m1t
b) The level of liquid relative to vessel remains c) Coefficient of real g) 1 t
a
same. expansion of liquid
c) The fraction of volume of liquid in vessel
remains same. d) Mass of liquid h) h0 1 ( r )t
1) Only (a) is correct remaining on heating
2)Only (b) & (c) are correct 1) a-g, b-h, c-f, d-e 2) a-h, b-e, c-g, d-h
3)Only ( c) is true 4) All are true 3) a-e, b-f, c-g, d-h. 4) a-f,b-g, c-h, d-e
42 Narayana IIT/PMT Academy
JEE MAINS HEAT AND THERMODYNAMICS