CA71 Service Instructions 02-2005 - E

valid from:
Software version 5.5

SV 02/2005
51513447
StamoLys CA 71
AM/NO/PH/MN/FE/CR/CU/HY/SI
Analyzer for
Photometric Measurement
Operating and Service Instructions
Endress+Hauser 1
1 Safety instructions ...............................................................................................................................................6
1.1 Designated use.......................................................................................................................................................6

1.2 Installation, commissioning and operation ...........................................................................................................6
1.3 Operational safety..................................................................................................................................................6
1.4 Return ....................................................................................................................................................................7
1.5 Notes on safety conventions and icons .................................................................................................................7
2 Safety instructions reagents .................................................................................................................................8
2.1 First aid provisions ................................................................................................................................................8

2.1.1 Ammonia Analyzer Reagent AM1 ( CAY140VxxAAE 1 ).............................................................................8
2.1.2 Ammonia Analyzer Reagent AM2 ( CAY140VxxAAE 2 ).............................................................................9
2.1.3 Nitrate Analyzer Reagent NI1 .......................................................................................................................9
2.1.4 Phosphate Analyzer Molybdenum blue Reagent PH1 ( CAY240VxxAAE 1 )...............................................9
2.1.5 Phosphate Analyzer Molybdenum blue Reagent PH2 ( CAY240VxxAAE 2 )...............................................9
2.1.6 Phosphate Analyzer Molybdate Vanadate Reagent PH1 ( CAY243VxxAAE ) ............................................10
2.1.7 Silicate Reagent SI1 ( CAY640VxxAAE 1 ) ................................................................................................10
2.1.8 Silicate Reagent SI2 ( CAY640VxxAAE 2 ) .................................................................................................10
2.1.9 Silicate Reagent SI3 ( CAY640VxxAAE 3 ) .................................................................................................10
2.1.10 Silicate Cleaner ( CAY641VxxAAE ) ...........................................................................................................10
2.1.11 Reagent FE1 ( for iron CAY840VxxAAE )..................................................................................................11
2.1.12 Reagent MN1 ( for manganes CAY843VxxAAE 1 )...................................................................................11
2.1.13 Reagent MN2 ( for manganese CAY843VxxAAE 2 ) .................................................................................11
2.1.14 Reagent MN3 ( for manganese CAY843VxxAAE 3 ) .................................................................................11
2.1.15 Cleaner for manganese ( CAY844VxxAAE ) ...............................................................................................11
2.1.16 Reagent CR1 ( for chromate VI CAY846VxxAAE 1 )..................................................................................11
2.1.17 Reagent CR2 ( for chromate VI CAY846VxxAAE 2 )..................................................................................12
2.1.18 Reagent CU1 ( for copper CAY850VxxAAE 1 ) ..........................................................................................12
2.1.19 Reagent CU2 ( for copper CAY850VxxAAE 2 ) ..........................................................................................12
2.2 Life / shelf time reagents ....................................................................................................................................13
2.3 Check of the reagents by optical check...............................................................................................................14
2.4 Proofing of correct feeding sample and reagent..................................................................................................16
2.4.1 CA71AM-B and C........................................................................................................................................16
2.4.2 CA71PH-C ...................................................................................................................................................16
3 Identification.....................................................................................................................................................18
3.1 Device designation ..............................................................................................................................................18

3.2 Nameplate............................................................................................................................................................18
3.3 Product structure.................................................................................................................................................18
3.3.1 Structure and function.................................................................................................................................18
3.3.2 Measuring ranges.........................................................................................................................................19
3.4 Scope of delivery outlet left side .........................................................................................................................20
3.5 Certificates and approvals ...................................................................................................................................20
4 The measuring and evaluation unit ....................................................................................................................21
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4.1 Local operation ....................................................................................................................................................22
4.2 Hardware .............................................................................................................................................................22
5 Basics of measurement ......................................................................................................................................24
5.1 Functional principles of colorimetry ...................................................................................................................24

5.1.1 Measuring methods Analyzer ......................................................................................................................25
5.2 Instrument functions ...........................................................................................................................................27
5.3 Measurement cycle..............................................................................................................................................28
5.4 The „blind“ / "frequency offset “ .......................................................................................................................30
5.5 “ Calibration“ ......................................................................................................................................................30
5.6 Measurement of the sample ................................................................................................................................30
6 Installation ........................................................................................................................................................31
6.1 Incoming acceptance, transport, storage.............................................................................................................31

6.2 Installation conditions .........................................................................................................................................31
6.2.1 Dimensions ..................................................................................................................................................31
6.3 Installation examples...........................................................................................................................................33
6.3.1 CAT 430 or customer-specific ultra filtration and two CA 71 analyzers ...................................................33
6.3.2 CAT 411, CAT 430 and two CA 71 analyzers (two-channel version) .......................................................34
6.3.3 CAT 430, CA 71 analyzer and CNS70, container installation ...................................................................35
6.4 Installation and commissioning instructions.......................................................................................................37
6.4.1 Start-up Checklist ........................................................................................................................................38
6.4.2 Connection of sample line...........................................................................................................................40
6.5 Structure and nomenclature................................................................................................................................42
6.6 Spare parts for the sample and reagent transport ...............................................................................................43
7 Wiring ..............................................................................................................................................................45
7.1 Installation electrical connection ........................................................................................................................45

7.2 Quick wiring guide..............................................................................................................................................45
7.3 Wiring plan, internal ...........................................................................................................................................49
7.4 Signal connections...............................................................................................................................................50
7.5 Switching contacts...............................................................................................................................................51
7.6 External start of the CA71 ..................................................................................................................................52
7.6.1 Triggered by SPS ..........................................................................................................................................52
7.6.2 Triggered by potential free relay .................................................................................................................52
7.7 Post-connection check.........................................................................................................................................53
8 Operation .........................................................................................................................................................56
8.1 Operation and commissioning ............................................................................................................................56

8.2 Display and operating elements ..........................................................................................................................56
8.3 Local operation ....................................................................................................................................................56
8.3.1 Main menu...................................................................................................................................................57
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8.3.1.1 Overview menu structure....................................................................................................................57
8.3.2 Menu "AUTO MEASURING" ......................................................................................................................58
8.3.3 Menu "PARAMETER ENTRY".....................................................................................................................59
8.3.4 Menu "CONFIGURATION" ........................................................................................................................61
8.3.4.1 Calibration............................................................................................................................................63
8.3.4.2 Offset calibration (reagent blind value / 0 measurement)..................................................................65
8.3.5 Submenu, .....................................................................................................................................................67
8.3.5.1 Standard values / Datas of internal calibration curve .........................................................................71
8.3.6 Menu "LANGUAGE"...................................................................................................................................75
8.3.7 Menu "ERROR DISPLAY"............................................................................................................................75
8.3.8 Menu "SERVICE" ........................................................................................................................................76
8.3.9 Menu(s) "DATA STORAGE (1/2)" .............................................................................................................79
8.3.10 "DATA STORAGE-Calibration factor datas" ...............................................................................................79
8.3.11 Factory settings ............................................................................................................................................80
8.3.12 Factory settings 115V/50Hz steppmotor and Reagent filling time ............................................................85
8.3.13 Factory settings 115V/60Hz steppmotor and Reagent filling time ............................................................85
9 Service and replacement....................................................................................................................................87
9.1 Service Checklist CA 71......................................................................................................................................87

9.2 Service software AnaWin ....................................................................................................................................89
Detection of disturbances by reaction course.............................................................................................................92
9.2.1.1 Interferences ........................................................................................................................................92
9.2.1.2 Air bubbles ...........................................................................................................................................94
9.3 Replacement of the reagents ...............................................................................................................................95
9.4 Exchange of valve channel complete: .................................................................................................................96
9.5 Upgrade or change CA71 from one channel to a two channel version, valve set .............................................98
9.6 Sample collecting vessel with or without level control ....................................................................................100
9.7 Cleaning of pump heads....................................................................................................................................102
9.8 Contact pressure and correct sample and reagent transportation ....................................................................103
9.9 Exchange of the pump hoses.............................................................................................................................106
9.9.1 Pump hose combinations...........................................................................................................................108
9.9.2 Maintenance and service kit CAV740 ......................................................................................................109
9.10 Exchange of the valve hoses..............................................................................................................................110
9.11 Exchange of static mixer ...................................................................................................................................111
9.12 Phometer and Photometercuvette.....................................................................................................................112
9.13 Photometer-construction standard cuvette.......................................................................................................114
9.14 Photometer-construction 5 cm cuvette.............................................................................................................116
9.15 Exchange Photometer .......................................................................................................................................117
9.16 Exchange EPROM..............................................................................................................................................118
9.17 Adjustment analog output with Potentiometer.................................................................................................120
9.18 Installation of a second analog output...............................................................................................................121
9.19 Replacement or installation 2-channel valve board:........................................................................................122
9.20 Instructions for service kits CA71 CPU module + eprom ................................................................................124
9.21 Exchange of pump motor/ motor combinations...............................................................................................125
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9.22 Extension of measuring range by dilution ........................................................................................................126
9.22.1 Dilutions by means of sample pump with different hoses ........................................................................129
9.22.2 Sample Volume per minute .......................................................................................................................130
9.23 Extension of measuring range by changing the speed of step motor ...............................................................131
10 Error tracing and trouble-shooting.................................................................................................................. 135
10.1 Trouble-shooting instructions ...........................................................................................................................135

10.2 System errors / process errors ..........................................................................................................................135
10.3 Chemical interferences .....................................................................................................................................142
10.3.1 Interference for Ammonium measurement ..............................................................................................142
10.3.2 Interference for chlorine measurement ....................................................................................................142
10.3.3 Interference for chromate measurement ..................................................................................................143
10.3.4 Interference for copper measurement.......................................................................................................143
10.3.5 Interference for manganese measurement................................................................................................144
10.3.6 Interference for nitrite measurement........................................................................................................144
10.3.7 Interference for phosphate measurement .................................................................................................144
10.3.8 Interference for silicate measurement ......................................................................................................145
11 Circuit plans .................................................................................................................................................. 146
12 General Laboratory instructions ..................................................................................................................... 163
12.1 Basics .................................................................................................................................................................163

12.2 Sample Dilution Techniques .............................................................................................................................164
12.3 Correcting for Volume Additions ......................................................................................................................164
12.4 Using Pipets and Graduated Cylinders..............................................................................................................165
12.5 Using volumetric pipets.....................................................................................................................................165
12.6 Using the TenSette Pipet...................................................................................................................................166
12.7 Interferences......................................................................................................................................................168
12.8 Standard addition...............................................................................................................................................168
13 Conversation tables chemical formulas ........................................................................................................... 170
14 Copy sheets ................................................................................................................................................... 172
11.1 Telefax reagents order....................................................................................................................................172

11.2 Fax order maintenance parts.............................................................................................................................178
11.3 Maintenance plan Analyzer no. ................... ...................................................................................................180
11.3.1 Maintenance plan dilution modul .............................................................................................................181
11.3.2 Maintenance plan ultra filtration...............................................................................................................181
11.3.3 Stamolys-Analyzer......................................................................................................................................182
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1 Safety instructions
1.1 Designated use
The analyzer CA 71 is a compact analysis system for photometric measurement.

It is especially designed for the monitoring of ammonium, nitrite and phosphate in sewage treatment plants.
Manganese, iron, chromium VI and copper in industrial, drinking- or softdrink water applications. Silicate
and hydrazine in power plant application.
Any other use than the one described here compromises the safety of persons and the entire measuring
system and is, therefore, not permitted.
The manufacturer is not liable for damage caused by improper or non-designated use.
1.2 Installation, commissioning and operation
Please note the following items:

• Installation, electrical connection, commissioning, operation and maintenance of the measuring system
must only be carried out by trained technical personnel.
• The technical personnel must be authorised for the specified activities by the system operator. Technical
personnel must have read and understood these Operating Instructions
• and must adhere to them.
• Before commissioning the entire measuring point, check all the connections for correctness. Ensure that
electrical cables and hose connections are not damaged.
• Do not operate damaged products and secure them against unintentional commissioning. Mark the
damaged product as being defective.
• Measuring point faults may only be rectified by authorised and specially trained personnel.
• If faults can not be rectified, the products must be taken out of service and secured against unintentional
commissioning.
• Repairs not described in these Operating Instructions may only be carried out at the manufacturer’s or by
the Endress+Hauser service organisation.
1.3 Operational safety
The analyzer has been designed and tested according to the state of the art and left the factory in perfect
functioning order.
Relevant regulations and European standards have been met.
As the user, you are responsible for complying with the following safety conditions:
• Installation instructions
• Local prevailing standards and regulations.
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1.4 Return
If the analyzer has to be repaired, please return it cleaned to the Endress+Hauser sales centre responsible.
Please use the original packaging, if possible.
Please enclose the completed Dangerous Goods sheet (copy the second last page of these Operating
instructions) with the packaging and also the shipping documents.
1.5 Notes on safety conventions and icons
1 Warning!
This symbol alerts you to hazards. They can cause serious damage to the instrument or
to persons if ignored.
* Caution!
This symbol alerts you to possible faults which could arise from incorrect operation.
They could cause damage to the instrument if ignored.
Note!
This symbol indicates important items of information.
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2 Safety instructions reagents
1 Warning!
After eye-contact carefully wash with water and contact a doctor. At work wear appropriate safety clothes,
safety gloves and goggles / face protection. In case of accident or indisposition immediately consult a doctor
While operation with reagents, the safety data sheets must be considered without fail!
While removing hoses, splashing danger exists.
Never add water to the reagents. Add reagents with sulphuric acid, strong heat develops with splashing
danger.
Each manipulation at the reagent pump tubes requires pulling the reagent tubes at the cans from the
connection board, in order to prevent soiling of the reagents.
Pay attention
¾ Refer to the safety data sheets when handling reagents.
¾ Wear protective clothing, protective gloves and protective goggles when handling reagents. If you have
an accident or you feel unwell, consult a physician immediately.
¾ If reagents come into contact with the eyes, carefully rinse with copious amounts of water with the
eyelid open. If reagents come into contact with the skin, carefully rinse with copious amounts of water.
Consult a physician immediately!
¾ Rinse bottles, flasks, zylinders, pipetes with destilled water directly after using them.
¾ If bottles, flasks, zylinders, pipetes are not dry, rinse them with the solution that should be filled in.
¾ The less operation steps the less the mistakes.
¾ The larger the employed volumes the less the mistakes.
¾ Cuvette tests wich uses less than 0,2 ml sample are not recommendable.
¾ The statistical safety via correctness of a value increase with the number of the analyses
¾ Bottles, flasks, zylinders with applied solutions must become labeled with contents, concentration and
date of manufacturer.
¾ As dilution water is always distilled and/or DE-ionized water to employ
2.1 First aid provisions
2.1.1 Ammonia Analyzer Reagent AM1 ( CAY140VxxAAE 1 )

Hazardous ingredients: Sodium salicylate, Nitroprussid sodium
After inhaling: provide fresh air.

After skin contact: Wash with plenty of water. Remove contaminated clothes.
After eye contact: At opened eyelid wash with plenty of water. Consult an eye-doctor.
After swallowing: Drink lots of water, try to vomit, consult a doctor.
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2.1.2 Ammonia Analyzer Reagent AM2 ( CAY140VxxAAE 2 )
Hazardous ingredients: Sodium hydroxide
After inhaling: Provide fresh air, contact a doctor

After skin contact: wash with plenty of water. Swab with polyethylenglycol 400. Immediately remove
contaminated clothes.
After eye contact: with opened eyelid flush eyes carefully with sufficient water (at least 10 min). Contact a
doctor immediately.
After swallowing: drink plenty of water, avoid vomiting (perforation risk). Contact a doctor immediately. No
neutralization attempts.
2.1.3 Nitrate Analyzer Reagent NI1

Hazardous ingredients: Sulfuric acid
After inhaling: provide fresh air, consult a doctor

After skin contact: wash with sufficient water. Swab with polyethlenglycol 400. Remove contaminated
clothes immediately.
After eye-contact: with opened eyelid wash carefully with water (at least 10 min) Immediately call an eye-
doctor.
After swallowing: Drink plenty of water, do not vomit (danger of perforation )
Immediately contact a doctor. No neutralization attempts.
2.1.4 Phosphate Analyzer Molybdenum blue Reagent PH1 ( CAY240VxxAAE 1 )

Hazardous ingredients: none
2.1.5 Phosphate Analyzer Molybdenum blue Reagent PH2 ( CAY240VxxAAE 2 )

After inhaling: provide fresh air, consult a doctor

After skin contact: wash with sufficient water. Swab with polyethlenglycol 400. Remove contaminated
clothes immediately.
After eye-contact: with opened eyelid wash carefully with water (at least 10 min) Immediately call an eye-
doctor.
After swallowing: Drink plenty of water, do not vomit (danger of perforation ). Immediately contact a doctor.
No neutralization attempts.
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2.1.6 Phosphate Analyzer Molybdate Vanadate Reagent PH1 ( CAY243VxxAAE )
After inhaling: Provide fresh air. If necessary, effect a resuscitation. Contact a doctor
After skin contact: Wash with plenty of water. Remove contaminated clothes. Immediately contact a doctor.
After eye contact: With opened eyelid flush eyes carefully with sufficient water. Contact a doctor.
After swallowing: Do not vomit. Drink 1-2 glasses of water. Contact a doctor immediately. An unconscious
person may never be given anything through the mouth.
2.1.7 Silicate Reagent SI1 ( CAY640VxxAAE 1 )

Hazardous ingredients: Sulfuric acid, molybdic acid, sodium hydrogensulphate
General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may
even occur after several hours; therefore medical observation for at least 48 hours after the accident.
After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult
doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly. Immediately rinse with
water.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing: Drink plenty of water and provide fresh air. Call for a doctor immediately.

Hazardous ingredients: citric acid
General information: No special measures required.

After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Generally the product does not irritate the skin.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: If symptoms persist consult doctor.

Hazardous ingredients: compound one 2-amino-2-methylpropanol.

Hazardous ingredients: compund two disodium disulphite
General information: Symptoms of poisoning may even occur after several hours; therefore medical
observation
for at least 48 hours after the accident.
After swallowing: Call for a doctor immediately
2.1.10 Silicate Cleaner ( CAY641VxxAAE )

Hazardous ingredients: ammonia
After inhalation: In case of unconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
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After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a
doctor.
2.1.11 Reagent FE1 ( for iron CAY840VxxAAE )

Hazardous ingredients: thioglycolic acid and ammonium mercaptoacetate
General information: Immediately remove any clothing soiled by the product.

Remove breathing equipment only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation: Supply fresh air or oxygen; call for doctor. In case of unconsciousness place patient stably in
side position for transportation.
After swallowing: Do not induce vomiting; call for medical help immediately. Drink plenty of water and
provide fresh air. Call for a doctor immediately.
2.1.12 Reagent MN1 ( for manganes CAY843VxxAAE 1 )

Hazardous ingredients: acetic acid
General information: Immediately remove any clothing soiled by the product.

After swallowing: Drink plenty of water and provide fresh air. Call for a doctor immediately.
2.1.13 Reagent MN2 ( for manganese CAY843VxxAAE 2 )

2.1.14 Reagent MN3 ( for manganese CAY843VxxAAE 3 )

2.1.15 Cleaner for manganese ( CAY844VxxAAE )

Hazardous ingredients: citric acid

2.1.16 Reagent CR1 ( for chromate VI CAY846VxxAAE 1 )

Hazardous ingredients: sulphuric acid
doctor.
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2.1.17 Reagent CR2 ( for chromate VI CAY846VxxAAE 2 )
Hazardous ingredients: compound 1 propan-2-ol and dimethyl sulfoxide
doctor.
Hazardous ingredients: compound 2 none
2.1.18 Reagent CU1 ( for copper CAY850VxxAAE 1 )

Hazardous ingredients: ammonia
doctor.
2.1.19 Reagent CU2 ( for copper CAY850VxxAAE 2 )

Hazardous ingredients: ethanol

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2.2 Life / shelf time reagents
Order code activ inactiv

Ammonium CA7xAM CAY140 3 month at 20 °C 1 year
Phosphate CA7xPH-A/C CAY240 3 month at 20 °C 1 year
CA7xPH-B/D CAY243 1 year
Manganese CA7xMN CAY843 3 month at 20 °C 1 year
Iron CA7xFE CAY840 1 year
Chromate CA7xCR CAY846 1 year
Copper CA7xCU CAY850 3 month at 20 °C 1 year
Nitrite CA7xNO CAY343 3 month at 20 °C 1 year
Nitrate CA70NI CAY340 6 weeks at 20 °C
Aluminium CA70AL CAY940 1 year
CA71AL CAY939 6 weeks 12 weeks
Silicate CA70SI CAY640 1 year
CA71SI CAY643 3 month at 20 °C 1 year
Hardness CA70HA CAY743 1 year
CA71HA CAY 749 3 month at 20 °C 1 year
Hydrazine CA7xHY CAY540 6 weeks at 20 °C 1 year
Chlorine CA7xCL-A/C CAY543 4 weeks at 20 °C 1 year
CA7xCL-B/D CAY546 4 weeks at 20 °C 1 year
Note!
The date of manufacture is registered on each bottle behind the print batch number.
The storage of the chemicals should happen in a cool dark area. If the temperatures should amount to higher
than 25 °C, then the reagents before use are to be examined by means of visual inspection.
At higher temperatures during the enterprise than 25 to 30 °C the calibration interval must be set on all 6 h,
so that changes of chemistry are considered automatically.
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2.3 Check of the reagents by optical check
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Parameter designation of chemical Appearance if okay Appearance if no more okay
AM1 yellowish tawny or black

Ammonium
AM2 colorless with chlorine smell without chlorine smell
PH1 colorless or weakly yellow strongly yellow
Phosphate blue
PH2 cololess blue
Phosphate yellow PH1 yellow yellow with precipitation
MN1 colorless
Manganese MN2 colorless
MN3 easily green
Iron FE1 yellow yellow with precipitation
CR1 colorless
Chromate
CR2 colorless orange
CU1 colorless
Copper
CU2 colorless
Nitrite NO1 colorless pink
Nitrate NI1 colorless tawny or violette
AL1 orange red
Aluminium AL2 colorless
AL3 colorless
SI1 colorless
Silicate SI2 colorless
SI3 yelowish brownish with precipitation
HA1 red
Hardness
HA2 colorless
Hydrazine HY1 easily yellowish
CL1 colorless
Chlorine
CL2 colorless pink
2.4 Proofing of correct feeding sample and reagent.
In some analyser there is a need to check the correct mixture sample and reagent. It has an direct input for
the correct measurement:
It is the same for different modifications 115/230 V 50/60 Hz.
2.4.1 CA71AM-B and C
Check in the service menue feeding:
Mixture:
Sample Reagent 1 Reagent 2
1 : 4 : 4
2.4.2 CA71PH-C
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in the standard running in the servive menu feeding pump 1 or 2 for 1 minute
Sample pump 5.7 ml

Reagent pump Reagent 1 1.8 ml
Reagent 2 1.8 ml
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3 Identification
3.1 Device designation
3.2 Nameplate
Compare the order code on the nameplate (at the analyzer) with the product structure
(see below) and your order.
3.3 Product structure
3.3.1 Structure and function
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3.3.2 Measuring ranges
CA71AM- Stamlys CA71 Ammonium

A Measuring range: 0,1-5 mg/l NH4-N
B Measuring range: 0,2-15 mg/l NH4-N
C Measuring range: 0,5-100 mg/l NH4-N
D Measuring range: 1-500 µg/l NH4-N
CA71PH- Stamlys CA71 Phosphate

A Measuring range: 0,05-2,5 mg/l PO4-P (blue)
B Measuring range: 0,5-20 mg/l PO4-P (yellow)
C Measuring range: 0,1-25,0 mg/l PO4-P (blue)
D Measuring range: 0,5-50 mg/l PO4-P (yellow)
CA71NO- STAMOLYS CA71 NO Nitrit

A Measuring range: 10 - 500 µg/l NO2-N
B Measuring range: 0.1 - 1.0 mg/l NO2-N
C Measuring range: 0.2 - 3 mg/l NO2-N
CA71FE- StamoLys CA71FE Iron

A Measuring range: 10 - 500 µg/l Fe
B Measuring range: 0.05 - 2 mg/l Fe
C Measuring range: 0,1 - 5 mg/l Fe
CA71CR- StamoLys CA71CR Chromate

A Measuring range: 0.1 - 2,5 mg/l Cr VI
B Measuring range: 0.2 -5 mg/l Cr VI
CA71MN- StamoLys CA71MN Manganese

A Measuring range: 1 - 150 µg/l Mn
B Measuring range: 10 - 2000 µg/l Mn
CA71CU- StamoLys CA71Cu Copper

A Measuring range: 0.1 - 2 mg/l Cu
B Measuring range: 0.2 - 5 mg/l Cu
CA71HY- StamoLys CA71HY Hydrazine

A Measuring range: 1 - 500 µg/l N2H4
CA71AL- StamoLys CA71AL Aluminium

A Measuring range: 10 - 1000 µg/l Al
CA71SI- StamoLys CA71SI Silicate

A Measuring range: 1 -200 µg/l Si
B Measuring range: 20 -5000 µg/l Si
The measuring system will be delivered as a ready for use compact device in a splash water protected
stainless steel case and consists of the following main parts:
• the analyzer (peristaltic pumps, mixer) with probe collector (optional) and a thermostatic photometer,
working at 1 or 2 wavelengths
• the measuring and evaluation unit with digital display and text menu control for configuration, parameter
entry and diagnosis, automatic periodic calibration and data logger for 1024 values
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3.4 Scope of delivery outlet left side
The scope of delivery comprises:

• an analyzer with mains plug
• a cleaning injector
• a tin of silicone spray
• a Nopren hose, length 2.5 m (8.2 ft), ID 1.6 mm (0.06")
• a C-flex hose, length 2.5 m (8.2 ft), ID 6.4 mm (0.25")
• a C-flex hose, length 2.5 m (8.2 ft), ID 3.2 mm (0.12")
• two hose fittings of each size:
– 1.6 x 1.6 mm (0.06 x 0.06")
– 1.6 x 3.2 mm (0.06 x 0.12")
– 6.4 x 3.2 mm (0.25 x 0.12")
• two T-hose fittings of each size:
– 1.6 x 1.6 x 1.6 mm (0.06 x 0.06 x 0.06")
– 3.2 x 3.2 x 3.2mm (0.12 x 0.12 x 0.12")
• an interference suppressor for the current output
• 4 edge covers
• a quality certificate
• Operating Instructions (english).
Note!
Reagents, please order separately.
If you have any questions, please contact your supplier or your responsible Endress+Hauser sales centre (see
back page of these Operating Instructions).
3.5 Certificates and approvals
Declaration of conformity
The product meets the legal requirements of the harmonised European standards.
Endress+Hauser confirms compliance with the standards by affixing the 4 symbol.
Quality certificate
Depending on the order code you receive a quality certificate.
With the certificate Endress+Hauser confirms compliance with all technical regulationsand the successful
testing individually for your product.
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4 The measuring and evaluation unit
The StamoLys analyzer is controlled by a 16-bit micro-controller and executes the following functions:
- measured value detection and processing

- menu guidance
- storage and administration of the user’s parameter
- storage of the measured values
- monitoring of the system.
All user’s parameters such as measuring range, limit values, time intervals and adjustment of output signals
are entered menu-controlled and filed in a battery-buffered memory.
The operation is done via 6 keys, which allow a horizontal and vertical movement through the menu.
During the measurement the numeric results are presented at the same time on an LCD-display and an LED-
display which can be read from larger distances.
LED’s integrated in the key area indicate diverse system- and output conditions.
Front view with description of positions
1 LED (measured value)

2 LC display (measured value and status)
3 Serial interface RS 232
4 Operating keys and control LEDs
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4.1 Local operation
The operating keys and the integrated indicator LEDs have the following functions:
4.2 Hardware
Stamolys family hardware setup

Hardware setup
Measuring and evaluation unit
Analysis unit
Reagent unit
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Membrane keypad
LED display LC main display with LEDs
RS 232
Measuring and evaluation unit

LED (measured value)
LC display (measured value and status)
Operating keys with status LED
Serial interface RS 232
Hardware setup analysis unit
Endress+Hauser 23
Hose pump: sample reagents
Photometer
Static
mixer
Inlet Outlet
Sample Cleaner / standard
valve valve
5 Basics of measurement
5.1 Functional principles of colorimetry
Basis of photo-metric measurements is Lambert-Beer law for the area of low concentrations.
Lambert-Beer law is considered only to monochromatics light (light of a single wavelength) and constant
exterior conditions like temperature and solvent. (Concentration max. 10-2 mol/l)
The following facts underlie this law:
The absorption of a parallel luminous beam by a solution of the substance to be examined is independent of
the intensity of the radiated light.
The absorption depends on the concentration of the analyte (colour intensity of the reaction product),
thickness of the photometer cuvette and extinction coeffizient
The extinctionscoeffizient is a size characteristic for every absorbing material. It is dependent on the
substance and wavelength, but independent on the concentration.
Measuring principle
Sample Reagent Colouring
Wavelength Absorption Residual light

Endress+Hauser 24
Analyzers determine measuring procedure the demanded chemical material on the bases of a test free of solid
by means of the Colorimetric. With the Colorimetric procedures reagents are added to the sample. The
reagents convert the seached substance (analyte) into a reaction product, which is specifically coloured. The
intensity of the color is a degree of the concentration of the searched material. To determinate the colour
intensity the reaction product is irradiated with and the light intensity is measured after the passage.
However, the decline of the light intensity takes place not about the whole wavelength spectrum, but is
limited to specific wavelengths. The measuring result is readable in the display directly and is available as a
current output signal and two border contacts.
Stamolys CA71 works by adaption of laboratory methods and form them into a fully automized on-line-
analysis process. For wastewater applications, a total of four parameters are available: ammonium, phosphate
and nitrite. The measuring processes are essentially selected in accordance to the DIN process in order to use
proven processes with known influencing values. For the determination of the orthophosphate, a
molybdenum vanadate method is available as well as the molybdenum blue method. This process enables an
economical analysis of even high phosphate concentrations and may be used especially for precipitant
batching.
For applications in drinking water and industrial use, analyzers for nitrite, iron, chlorine, silicate, manganese,
hardness, cupper, chromate, and aluminium are available with photometric method. Other parameters are in
preparation.
5.1.1 Measuring methods Analyzer
Aluminium ECR method for aluminium determination

Aluminium and eriochromium cyanine R form an orange dye.
The absorption is determined at a wavelength of 565 nm. The absorption intensity is
proportional to the aluminium concentration in the sample.
The reference wavelength is 880 nm.
Ammonium Indophenole blue method for ammonium determination acc. to ISO 11732
Sodium dichloric isocyanurate and sodium salicylate form a blue dye in conjunction with
ammonium.
The absorption is determined at a wavelength of 660 nm (AM A+B) resp. of 565 nm (AM
C). The absorption intensity is proportional to the ammonium concentration in the
sample.
Free chlorine DPD method as per DIN 38408 - Part 4
DPD (N,N -diethyl-p-phenylendiamine) together with hypochlorous acid and hypochlorite
ions forms a magenta dye. Here, the pH value is kept constant by an acetate buffer.
The absorption is measured at a wavelength of 555 nm. The absorption strength of the
lights proportional to the concentration of the free chlorine in the sample.
The reference measurement (only measuring range C, see product structure) is performed
at a wavelength of 880 nm.
Total chlorine As well as the DPD reagent, additional potassium iodide is added to the acetate-buffered
sample. Chloramines in the sample oxidise iodide to hypoiodite or hypoiodite acid, which
together with DPD form the magenta dye.
The absorption is measured at a wavelength of 555 nm. The absorption strength of the
light is proportional to the concentration of the total chlorine in the sample.
The reference measurement (only measuring range D, see product structure) is performed
at a wavelength of 880 nm.
Chromate Diphenyle carbacide method for chromate determination
Chromate and diphenyle carbacide form a chelate complex. The sample colour turns to
pink. With this method only Cr(VI) ions can be determined. Complex bonded chromate
can not be determined.
proportional to the chromate concentration in the sample.
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Copper Cuprizone method for copper determination
Under alkaline conditions cuprizone and Cu2+ form a blue complex.
With this method only Cu (II) ions can be determined. Complex bonded copper and Cu
(I) ions can not be determined.
proportional to the copper concentration in the sample.
Iron Ferrozine method for iron determination
In the presence of iron the reagent indicator turns the sample colour to violet .
proportional to the iron concentration in the sample.
Hardness Calmagnite method for total hardness determination
Calcium and magnesium and the reagent form a red dye.
proportional to the total hardness in the sample.
Hydrazine p-dimethyle aminobenzaldehyde method for hydrazine determination
In the presence of hydrazine the reagent indicator turns the sample colour to yellow.
proportional to the hydrazine concentration in the sample.
Manganese Leuco malachite method for manganese determination
In the presence of manganese the reagent indicator turns the sample colour to green-blue
.
proportional to the manganese concentration in the sample.
Nitrite Naphthylamine method for nitrite determination acc. to DIN 38405-D10
Under acidic conditions, nitrite ions diazotices sulphonamido, which forms a red dye in
conjunction with N-(1-naphthyl)-ethylenediamine.
proportional to the nitrite concentration in the sample.
Phosphate Molybdenum blue method for orthophosphate determination in deviation to DIN EN
1189 (versions PH-A and PH-C)
Molybdate ions and antimony ions form a blue dye in conjunction with phosphate.
The absorption is determined at a wavelength of 880 nm (PH-A) resp. of 660 nm (PH-C).
The absorption intensity is proportional to the orthophosphate concentration in the
sample.
Molybdate vanadate method for orthophosphate determination (versions PH-B and PH-D)
Vanadate ions and molybdate ions form a yellow dye in conjunction with phosphate.
proportional to the orthophosphate concentration in the sample.
Both methods will detect ortho-phosphate, but not other phosphorous components (Total
Phosphorous)
Silicate Heteropoly blue method for silicate determination
Under acidic conditions silicate and phosphate react with molybdate to form yellow
silicomolybdic and phosphomolybdic acid complexes. Addition of citric acid destroys the
phosphate complexes. Last step is the addition of an amino acid. It reduces the yellow
silicomolybdic complex to intensively blue silicomolybdic blue.
The absorption is determined at a wave length of 810 nm (SI-A) resp. of 880 nm (SI-B).
The absorption intensity is proportional to the silicate concentration in the sample.
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5.2 Instrument functions
• The use of similar determination methods allows for largely identical construction of all instruments,
which consequently allows the exchange of individual components between the different instrument
types. With the installation of the important components on an retractable measuring module user
friendliness is ensured: all components are easily accessible. In the event of instrument failure,
exchanging the retractable measuring module makes replacement intrumentation available without
extensive mounting procedures. Parameter too can be changed in this way.
• Next to the identical construction, the identical menu guided instrument operation is ensured. Faulty
operation are largely precluded with this concept. Fundamental entries are safeguarded with the use of a
code.
• Next to the conventional 4-20mA current output, the integrated data logger with data output Allows for
data processing on a PC over a digital interface.
• Despite the photometric measurement process, ultrafiltration is not required for the probe preparation.
Turbidity compensation, automatic cleaning of the instrument, suitable pipe cross sections and
appropriate probe entry permit for the use of alternative probe processing systems like microfiltration
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5.3 Measurement cycle
To create the measurement result reagents has to be added to the sample by operation of the peristaltic
pumps, the solution has to be mixed in the static mixer and the color of the reaction product has to be
measured in the photometer.
Measurement of the chemical substance in the sample, calibration and measurement of the influence of
reagents (blind) happens similar. The only difference is the liquid, that has to be measured.
Each measurement cycle starts with running of the sample pump in order to bring fresh liquid to the mixer
and photometer. Because of the optimisation of the measurement process, the intrinsic colouring of the probe
is detected before every measurement and can therefore also be compensated. It is only when the
relationship of intrinsic colouring of the probe to the colour reaction in the specific wave length range
becomes too large that counter measures have to be initiated. The result is stored internal (basis frequency).
After that, sample pump and reagent pump runs together in a specified ratio to transport the liquids through
the mixer into the photometer. Both pumps stop and the reaction take place in the photometer. The
photometer is designed as a thermostat controlled component in order to ensure reproducable conditions
thereby making it insensitive to fluctuations in temperature. With the heating of the photometer, reaction
times can be reduced substantially so that results of the analysis are available in short time. Long time
experiences in turbidity measurement led to the development of a dual ray photometer which can
compensate turbidity reliably up to approx. 100 FNU. When reaction is finished the color of reaction product
is measured (plateau frequency)
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Measurement cycle
6100 1. Measuring (color of the

sample)
r
mete basis frequency
p hoto
al of
6000 Sign
stabilizing mixing
flushing reaction period
5900
5800
5700
flushing
5600
2. measuring (color of solution)
plateau frequency
running of sample pump
5500
running of reagent pump

5400
time
The raw measurement value is calculated as follows:
basis frequency - plateau frequency = Raw value
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5.4 The „blind“ / "frequency offset “
Reagents (kind of manufacturing and basic chemicals will influence the measurment result of calibration and
measurement result of the sample.
Simililar to laboratory analysis a so-called „blind“ or frequency offset has to be realized for compensation of
the reagents influence. Instead of sample destilled water is connected to the sample inlet. The calibration of
frequency offset is started manually after each replacement of reagents. The result is calculated as follows:
basis frequency of offset measurement - plateau frequency of offset measurement

= frequency offset
and stored in an internal data storage.
5.5 “ Calibration“
Two pinch valves are used to allow automatic cleaning and calibration cycles. Aging of reagents and wear and
tear of pump hoses is compensated by automatic calibration. Calibration itself work in the same way as
sample measurement. Instead of sample a calibration solution with known concentration is measured by
switching the valves. The measurement result of calibration create a calibration factor (cf) wich is stored in
an internal data storage. Calibration factor is calculated as follows:
Basis frequency of calibration - plateau frequency of calibration - frequency offset

= actual calibration value
nominal calibration value ÷ actual calibration value = calibration factor.
and stored in an internal data storage.
5.6 Measurement of the sample
Measuring cycle of is similar to frequency offset measurement and calibration. Instead of destilled water or
standard solution the sample is sucked into the analyzer by switching the magnetic valves during the
operating of the pumps.
The actual measuring value is calculated as follows:
(Basis frequency of sample - plateau frequency of sample - frequency offset) x calibration factor = actual
measurement value.
The actual measurement value will be compared with the internal calibration curve to display the
concentration in the correct unit.
Internal calibration curve
mg/l
actual measurement value [Hz]

Endress+Hauser 30
6 Installation
6.1 Incoming acceptance, transport, storage

• Make sure the packaging is undamaged! Inform the supplier about damage to the packaging.
• Keep the damaged packaging until the matter has been settled.
• Make sure the contents are undamaged! Inform the supplier about damage to the delivery contents.
• Keep the damaged products until the matter has been settled.
• Check that the scope of delivery is complete and agrees with your order and the shipping documents.
• The packaging material used to store or to transport the product must provide shock
• protection and humidity protection. The original packaging offers the best protection.
• Also, keep to the approved ambient conditions (see "Technical data").
• If you have any questions, please contact your supplier or your Endress+Hauser
• sales centre responsible (see back page of this document).
6.2 Installation conditions
6.2.1 Dimensions
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6.3 Installation examples
6.3.1 CAT 430 or customer-specific ultra filtration and two CA 71 analyzers

• Permeate can contain air bubbles (CAT 430) or is free of bubbles (customer-supplied ultrafiltration)
• Distance between the analyzers as short as possible: sampling line between T-piece and the second
analyzer (Fig. 9, item 2) shorter than 1.5 m
• Cross-section of sampling line ID 3.2 - 4 mm
• only one sample receiver required
Note!
Ensure that there is always sufficient sample available for both analyzers. Observe this when selecting
maintenance intervals for CAT 430 and when setting the sample volume in the collecting vessel.
1 Sample from CAT 430

2 Sampling line
3 Sample receiver overflow
4 T-piece
5 Collecting vessel
51512089 KIT CA71 Sample vessel with level detection

51512088 KIT CA71 Sample vessel w/o level detection
51512096 KIT CA Y tube adapter 1.6*1.6*1.6 mm
51512099 KIT CA71 connection nipple sample vessel 10pcs
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6.3.2 CAT 411, CAT 430 and two CA 71 analyzers (two-channel version)
• Permeate not free of air bubbles
• Distance between the analyzers as short as possible: sampling line between T-piece and the second
analyzer (Fig. 10, item 5) shorter than 1.5 m
• Cross-section of sampling line ID- 4 mm
• one sample collector each (without level measurement) for CAT 411 or CAT 430
Note!
Ensure that there is always sufficient sample available for both analyzers. Observe this when selecting
maintenance intervals for CAT 411 and CAT 430.
1/2 Sample from CAT 430

3 sample vessel
4 sample overflow into drain
5 sample line
6 Y tube adapter
51512089 KIT CA71 Sample vessel with level detection

51512088 KIT CA71 Sample vessel w/o level detection
51512096 KIT CA Y tube adapter 1.6*1.6*1.6 mm
51512099 KIT CA71 connection nipple sample vessel 10pcs
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6.3.3 CAT 430, CA 71 analyzer and CNS70, container installation
Details see following

page
Endress+Hauser 35
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6.4 Installation and commissioning instructions
To install the analyzer at the intended location, proceed as follows:

Note!
Please do not install analyzer outdoor. Either in a temperated housing or a measuring house kept at a
moderate temperature.
1. Place the analyzer in position and secure it. For the installation dimensions, please see chapter 6.2.
Note!
A wall bracket is available as an option for mounting the analyzer ( Chap. “Accessories”).
2. Lay the drain pipe for the reaction products. Where possible, use fixed pipes (PVC or PE, internal diameter
¾ " with 3% incline).
3. Connect the sample transfer.
Note!
The sample can be obtained as follows:
– Directly or after a reversible flow filter or a cross current filter by means of a small pump (rating approx.
300 ml/min), suitable for clear media, e.g. in the discharge channel of a sewage treatment plant
– From a sedimentation tank or after microfiltration; this is practical for media containing flocculants, e.g. in
an activated sludge basin
– Sample conditioning using ultrafiltration for heavily soiled media, e.g. from the primary settling tank.
For questions regarding sample conditioning and its automation, please contact Endress+Hauser Service or
the Endress+Hauser Sales Centre responsible for your region.
4. Connect the tubes from canisters containing reagents, standard and cleaning agents to the following
nozzles: “
5. Tighten the pump hoses onto the sample pump and onto the reagent pump.
6. Set the pressure at the hose bed throttle valve (Chap ) such that sample and reagent are fed in without
bubbles.
This completes the installation process. Now carry out the installation check and proceed according to
chapters “Wiring”, “Operation and Commissioning”.
Note!
The start up checklist should be used in every case
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6.4.1 Start-up Checklist
Town:______________________________________________________________________
Order code:_______________________________________________________________________
Serial-No. Analyzer:___________________________________________________________
Serial-No. Photometer:________________________________________________________
Software-Version: ____________________________________________________________
Date: ______________________________________________________________________
Safety first! Pay attention to all safety hints for handling of chemicals, personal safety
equipment, electrical safety, working security.
Please follow list strictly top to bottom!
Electrical Start-up
◊ Ensure that the mains supply complies with the ratings specified on the nameplate
◊ Set electrical connections
◊ Press „M“ during switch-on the analyzer
◊ Connect a frequency meter at photometer output
Configuration
Remark datas into „settings CA71_en.doc“
◊ Check photometer dependent on type of analyzer
◊ Enter unit of measure dependent on instructions of user
◊ Check Calibration factor dependent on specification of analyzer
◊ Check Concentration-offset dependent on specification of analyzer
◊ Check Dilution dependent on specification of analyzer
◊ Enter Analog output dependent on instructions of user
◊ Check entry of special menu
◊ Enter Alarm values dependent on instructions of user
◊ Enter Error contact dependent on instructions of user
◊ Check currentl date/time
Parameter entry
Remark datas into „settings CA71_en.doc“
◊ Enter Measuring range start dependent on instructions of user
◊ Enter Measuring range end dependent on instructions of user
◊ Enter Alarm values dependent on instructions of user
◊ Enter 1. measuring dependent on instructions of user
◊ Enter Measuring interval dependent on instructions of user
◊ Enter 1. Calibration dependent on date of stat-up
◊ Enter Calibration interval dependent on instructions of user
◊ Enter Standard solution dependent on concentration of standard solution
◊ Enter 1. Flushing dependent on date/ time of first calibration
◊ Enter Flushing interval dependent on type of analyzer
◊ Enter Flushing hold on dependent on type of analyzer
Endress+Hauser 38
Tubes
◊ Route discharge line
◊ Clean pump heads and spray with silicone spray
◊ Check correctness of hoses and connection
◊ Attach the hose holder on the pumps
Working with destilled water

◊ Check pump rate and prsasure of hose holder
◊ Check leak proofness
Working with reagents

◊ Fill reagent, cleaning solution and standard tubes
◊ Calibrate offset (0 measurement) min. 2 times
◊ Measurement of standard solution at sample connector
◊ Connect sample feed
◊ Enter Delay to sample dependent on tube length of feed line
◊ Check Delay to sample
◊ Measurement of sample
◊ Check concentration of sample by laboratory value
Endress+Hauser 39
6.4.2 Connection of sample line
1 Ventilation
2 Sample inlet from sampling
3 Collecting vessel
4 Electrical connections
5 Analyzer sample inlet
* variable, freely adjustable dimensions
6 Sampling for analyzer
7 Analyzer outlet
8 Sample overflow
One-channel version
E+H Collecting vessel (at CA 71, with or without level measurement)
Connection hose ID 3.2 mm (0.13")
Customer collecting vessel
Connection hose ID 1.6 mm (0.06")
Max. distance from collecting vessel to analyzer 1 m (3.28 ft)
Max. height difference from collecting vessel to analyzer 0.5 m (1.64 ft)
Two-channel version
• In scope of delivery only a collecting vessel without level measurement
• Order a second collecting vessel seperately
• Only one collecting vessel can be mounted at housing
• Level measurement not available
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Adjusting of the level measurement (one-channel version only)
Adjust the conductive level measurement due to the number of connected analyzers.
1. In dependence of the application, mount the right adjusting pin or no adjusting pin
(Fig. 6 and Fig. 7, position 2).
2. Pull the marked pipe (position 3) downwards due to your application (1, 2 or 3
analyzers).
• After mounting, check that all connections are secure and leak-tight.
• Ensure that the hoses can not be removed without effort.
• Check all hoses for damage.
Endress+Hauser 41
6.5 Structure and nomenclature
Overview parts
A Sample input two channel version

B Standards and reagent canisters
C Collecting vessel sample
P Sample
R Cleaner canister
R1 Reagent 1 canister
R2 Reagent 2 canister
S Standard solution canister
The above diagram contains the components and spare parts for all versions. In the following sections you
can find the spare parts and the corresponding order number for your model using the item number.
Endress+Hauser 42
6.6 Spare parts for the sample and reagent transport
Numbers belong to sketch on page 39
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Maintenance and service kit CAV740
Quantity ORDER NO. order- Description

no.
CAV740-1A Maintenance kit CA 7X AL or PH, NO, MN, FE, HY, CR, CU
Aluminium, Phosphate, Nitrite, Manganese, Hydrazine, Copper,
Chromate-Analyser
- 1 sets pump tubings yellow/blue ( 12 pieces )
- 1 set pump tubings black/black (12 pieces)
- each 1 pack hose adapter Pos. 130, 131, 132, 133, 134
- 1,40 m hose made of C-Flex for pinchvalve
CAV740-2A Maintenance kit CA 7X for AM or HA
Ammonia-Analyser or Hardness-Analyser
- 2 sets pump tubings yellow/blue ( 12 piece )
CAV740-3A Maintenance kit CA 7X NI Nitrate-Analyser
- 1 set pump tubings yellow/yellow (12 pieces)
CAV740-4A Maintenance kit CA 7X SI or CL
Silicate, Chlorine-Analyser
- 1 sets pump tubings violette/white ( 12 pieces )
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7 Wiring
7.1 Installation electrical connection
Note!
To reach the terminal strip, you must swing out the analyser frame.
1. Loosen the two lower Allen screws SW 6 by 3 to 4 turns (Fig. 13, pos. 1).
2. Unscrew the two upper Allen screws until the analyser frame swings out. Thus you can reach
the terminal strip (pos. 2).
7.2 Quick wiring guide

1 Warning!
• Electrical connection must only be carried out by authorised skilled personnel.
• Skilled personnel must have read and understood these Operating Instructions and must adhere to them.
• Ensure before beginning the connection work that the power cable is not under voltage.
• Ensure before connection that the mains voltage corresponds with the voltage specified on the
nameplate.
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1) Brass screw with bolt top right in the connection compartment (marked with )
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Note!
• The terminal block for mains connection (terminals L, N, PE) is situated on the left of the main board on
the cooled version.
• Alarm values 1 and 2 do not need to be connected if the PLC sets its own alarm values at the analog
output.
• When using a sample conditioning system:
Connect terminals 57 and 53 on the CA 71 to the corresponding terminals on the sample conditioning
system. For the allocation of these terminals, please see the sample conditioning system operating
instructions.
• If there is a 24 V voltage at terminal 57, the analyzer will not begin measurement (sample not ready). To
start measurement, the voltage must stay at 0 V for at least 5 seconds. This can be used for external start
• The power supply line can be connected directly to the analyzer or via a main switch to the sample
conditioning system.
Screening of the analog outputs
The interference suppressor attenuates electromagnetic effects on control, power and signal lines.
After the connection of the data transfer cables clip the interference suppressor (in scope of delivery) on the
cable cores (not on the outer insulation of the cable!). Place the cable screen out of the interference
suppressor and connect it to PE (brass screw with bolt, top right in the connection compartment)
1 Cable screen (to PE )

2 Signal cable
3 Interference suppressor
4 Cable cores of the signal cable
Note!
With the two-channel version, place the cable cores of all cables (data cables to analog output 1 and to analog
output 2) through the interference suppressor.
Endress+Hauser 48
7.3 Wiring plan, internal
extern CA71 intern
L 1L
N 2N
PE 3 PE
3x 1mm² LiYCY 5x0,25
Oelflex 59 Status 5
61 fx 4
62 +17V 1 Photometer
63 -17V 3
64 0V 2
65 Screen 6
Oelflex 4x0,5
74 V3
74 V3 two channel
53 0V Switching
53 0V
Oelflex 2x0,5
66 LF Leckage
67 LF detection
4 PE gn/ge
5 L1 rt Synchromotor
6N ge
7 L2 bl
78 Br1/1 sw
ws/sw
ws/or
79 Br1/2 or Stepmotor
77 Br2/2 rt
ws/rt
ws/ge
76 Br2/1 ge
80 Screen
Oelflex 4x0,5
72 V1
73 V2
71 0V
71 0V
V2 V1
Calibration/Cleaning
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7.4 Signal connections
One channel version
Two channel version
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7.5 Switching contacts
One-channel version
Two-channel version
A = NO current configured
R = NC current configured
Note!
Condition fulfilled means:
• AV 1: concentration > Alarm value 1
• AV 2: concentration > Alarm value 2
• Fault: error occurred
Contacts AV 1, AV 2 and fault are only affected during automatic operation.
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7.6 External start of the CA71
7.6.1 Triggered by SPS

Connect 0V from the SPS with 0V of the analyser ( terminal 53 )
Signal output from the SPS connected with the input „No Sample“ of the analyser ( terminal 57 )
Output 57: „No Sample“

activ 24V
SPS CA7X
0V 53: 0V
7.6.2 Triggered by potential free relay

Connect contact connection from the relay ( NC ( normally closed ), if the analyser has to keep waiting in
alarm condition ( relay coil without voltage ); NO ( normally open ),if the analyser has to measure in alarm
condition ) with the 24V of the analyser ( terminal 54 )
Connect contact connection from the relay ( Common, tie point contact from one relay with change-over
contact ) with the input „No Sample“ of the analyser ( terminal 57 )
54: 24V
CA7X
57: No sample
Optional Normally open Optional Normally closed

contact: contact:
Instrument is not measuring Instrument is working if the
if the relay is active relay is active
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7.7 Post-connection check
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Current output simulation:
1. Hold both arrow keys down (see "Local operation, page 20) and connect the analyzer to the main power or
switch the main switch on (if available). Wait until the display "0 mA" appears.
2. Check on your PLC, PCS or you data logger whether the current value is the same.
3. Press the key. Browse to the next current values (4, 12, 20 mA, depending on the setting).
4. Check that the respective current values are also on your PLC, PCS or your data logger.
5. If the values are not there, check the terminal assignment for analog output 1 or 2.
Endress+Hauser 55
8 Operation
8.1 Operation and commissioning

The following chapters provide you with information on the analyzer’s operating elements and explain how
to make settings.
In chapter“Commissioning” you will find the procedure for initial start-up and for daily analyzer operation.
Please use start up checklist.
8.2 Display and operating elements
Fig.: CA 71 display and control panel
1 LED display (measured value)

2 LC display (measured value + status)
3 4 RS 232 serial interface
5 Operating keys with indicator LEDs
8.3 Local operation

The operating keys and the integrated indicator LEDs have the following functions: . .
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8.3.1 Main menu
8.3.1.1 Overview menu structure
AUTO MEASURING
E
calibration measuring flushing wait
⇓
PARAMETER ENTRY
E Measuring Measuring Alarm value Alarm value 1. measuring Measuring

range start range end 1 2 interval
1. calibration Calibration Standard 1. flushing Flushing Flushing hold

interval solution interval on
⇓
CONFIGURATION
E Code- Photometer Unit of Calibration Cf-memory Concentr.

number measure factor offset
dilution Delay to Analog- Alarm value Alarm value Error contact

sample output ** 1 2
act. date / Calibrate Frequency

time offset offset
⇓
LANGUAGE
E
German English French Danish etc.
⇓
Error display
E Error reports
⇓
SERVICE
E
Valve 1 Pump 1 Pump 2 Valve 2 Frequency
⇓ Mixture
DATA MEMORY
E
Meas. value output Clear data
Endress+Hauser 57
Submenu behind the analog output (service submenu)
Anolog output **
To proceed in the Config Menu until reaching ( 0-20mA / 4-20mA ); touching with 4 fingers (both hands) -
first „K“, then „E“, „CE“ and „M“ (all 4 together), lifting the first finger from „K“ and in a split second also
lifting from the 3 others.
Note
After changes in the Submenu in any case the Default setup in „Configuration“ must be done. (more details
in Chapter 8.3.5 submenu)
Access the main menu by holding down the M key until “AUTO MEASURING” is
displayed.
For the main menu options and information about them, please see the following table.
8.3.2 Menu "AUTO MEASURING"
The actions "calibration", "measuring" and "flushing" are triggered by time-control.

The settings for these actions are made in the "PARAMETER ENTRY" menu.
The respective action is displayed in the LC display. The most recently registered concentration value is
displayed until the end of the next measurement.
Otherwise, "wait" is displayed when
• the time of the first measurement has not yet been reached or
• the measuring interval has not yet expired.
Note!
"Measuring" flashes when the analyzer is ready for the next measurement but has not
yet received the enable signal from the sample collector or the sample conditioning unit.
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8.3.3 Menu "PARAMETER ENTRY"
Navigate through the main menu with the È key to the "PARAMETER ENTRY" option and press the E key,
to move forward within this sub-menu and the CE key, to return to the previous option. The settings can be
changed within the individual options with the arrow keys. With the M key, you can return to the main
menu at any time.
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1) All channels set to 0 means, the channel selection is provided by an external device. All channels set to 1
means, alterning beginning with channel 1.
Note!
• Calibration should be started manually after exchange of reagents, pump hoses, mixer or photometer, or
whenever a new frequency offset is set.
• Always synchronise calibration and flushing time.

• Carry out flushing with standard cleaning solution approx. 3-4 hours before the next calibration.
• Flushing with special cleaning solution (e.g. hydrochloric acid) has a lasting effect on calibration.
Therefore, carry out this cleaning after calibration.
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8.3.4 Menu "CONFIGURATION"
Note
Concentration-offset : can be used for adjustment of the measuring values whenever they allways differs in
the same direction with nearly the same value from the laboratory measurement.
Dilution: can be used for adjustment of the measuring values whenever they allways differs in the same
direction in the same ratio from the laboratory measurement.
Delay to sample, please do not calculated the shortest time to transfer the sample from the collecting vessel to
the mixer. The shortest time is the time which is programmed in the software. Please change for Silcate from
80 to 120 sec. 80 sec are to short to flush and clean the cuvette from the old sample.
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Note
Some settings of this menu affect the defaults in the "PARAMETER ENTRY" menu. In view of this, complete
the "CONFIGURATION" menu first during initial start-up.
Navigate through the main menu with theÈ key to the "CONFIGURATION" option and press the E key, to
move forward within this sub-menu and the CE key, to return to the previous option. The settings can be
changed within the individual options with the È and Ç keys. With the M key, you can return to the main
menu at any time.
Calibrate offset: must be done at least after exchange parts in the instrument (reagents, pump hoses,
mixer etc.) . Instead of the sample connect destillated water to the sample line on valve 1.
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8.3.4.1 Calibration
Note
The calibration factor is the most important indicator for functionality of the analyzer
It should documentated at each service and asked at each customer call.
If calibration factor is at the normal value of the instrument it can be taken for granted, that the analyzer is
working properly, because the analyzer is able to detect the concentration of the standard properly.
Misfunction of the analyzer is than in most of the cases based on misfunction of the sample preparation, or
sample supply
Proceed as follows if you want to activate an immediate calibration (e.g. after you have replaced the
reagents).
Ensure that you have changed the reagents, filled the hoses again (no air bubbles) and the analyzer is in
measuring mode.
1. Hold M down until AUTO MEASURING appears.
2. Use È to move through the PARAMETER ENTRY menu and press E.
3. Use E to go to the "1st calibration" option.
4. Select the option with E
5. Now use the È or Ç and E keys to set a time which lies in the past.
6. Press E to accept the value and then press M twice to return to the main menu
7. Press E again. This takes you back to measuring mode.
The calibration is now carried out automatically.
* Caution!
After the calibration has finished, the analyzer automatically goes into measuring mode. The next calibration
will take place after the intervall is reached without checking the time of 1st calibration again.You now have
to set the time of the 1st calibration back into the future in order to align the calibration and rinsing times to
each other. The rinse must be performed 3-4 hours before the next calibration.
Proceed as described above to change the setting for the time of the 1st calibration. After changing to
measuring mode, the analyzer automatically begins measuring, rinsing and calibrating at the defined times.
Factors influencing the calibration factor

Curve with colored zero
Frequency Curve with frequency offset
Curve, high range standard
Curve, low range standard
Concentration
Aging of the reagents increase the calibration factor.

Æ maximum useful life when stored correctly: 6 weeks
Aging of the hoses increase the calibration factor.

Æ useful life dependent on
pressure of pump clip,
measuring interval,
cleaning of the pump head with alcohol
and use of silicon spray
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Where to set the Calibration point ?
Stamolys with a big range and high accuracy

Frequency Original Curve
Curve, Stamolys
Curve, most competitors
Concentration
Calibration with automatic self-monitoring
Relationship between concentration entered and concentration measured.
1. Variation factor <10% yes

of old value?
Calibration no Accept value
Calibration will automatically be repeated, no error message.
Variation factor <10%

2. yes
of old and previous
Calibration measured value? no Accept value
"Failed calibration" error is set, old calibration value is valid.
The calibraion factor can be edited manually with the arrow keys
Precision adjustment (3rd digit) : Press the 'E' key in addition to the arrow key
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8.3.4.2 Offset calibration (reagent blind value / 0 measurement)
In the menu Configuration go to the point Calibrate offset
In the case of de-mineralised water the reagent's own coloration will be determined.
The "frequency offset" is stated in Hz as a result.
Note
Calibrate (frequency) offset: must be done at least after exchange components in the instrument (reagents,
pump hoses, mixer etc. ) in order to eliminate their influences.
• Instead of the sample connect destillated water to the sample line on valve 1.
• Start offset calibration by pressing key K
• Wait until the measurement is finshed and the value is diplayed.
• Repeat offset calibration by using CE to go back in the menu
Calibration of frequency offset should be done at least twice. Note down the value of frequency offset after
each calibration to compare the values.
The displayed value can be manually changed with the arrow-keys. The average value of the detected values
can be added by that.
Note
A normal calibration must be performed after the final new frequency offset value.
Perm. values approx.:

NH4-N : 80 +/- 20 Hz
PO4-P : 0 +/- 10 Hz (Version A+C)
50 +/- 10 Hz (Version B+D)
NO2-N: 0 – 15 Hz
Mn: -10 – 10 Hz (Version A)
Mn: 10 – 20 Hz (Version B)
Cl2: 0 –10 Hz
Fe: 10 Hz +/- 10 Hz
Hy: 90 Hz +/- 10 Hz
Cu: 5 – 25 Hz
Cr: 20 –40 Hz
For ammonium and phosphate analyzer the offset should not change a lot. So a change from 70 to 197 Hz is
something where the reason has to be found out.
The following reasons are possible:
• destilled water is not ammoniumfree: check with laboratory photometer
• the reagents are spoiled with ammonium (could happen when the reagent pump clamp was opend and
the reagent cans where still connected to the tubes): Check by mixing 1ml of each reagent with 10ml of
destilled water. There should be no green color after 10 minutes
• the photometer is dirty: filling destilled water into the analyzer by connecting the destilled water to the
sample inlet and pump it long enough (min 5 minutes) with the sample pump. Checking the frequency
of the destilled water and compare it to the last frequency with destilled water. Should be nearly the
same, otherwise clean the photometer by sucking bleaching solution (sodium hypochlorite solution 10-
12%, available in pharmacy) into the photometer
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• the flushing time is not long enough in order to flush the reaction products out of the photometer it
should be at least 80s: Check by measuring the standard solution as sample twice and monitor the
frequency during the measurement. During the second measurement the frequency should be in the
same range as it was with destilled water (photometer is dirty) before the reagents are added. Otherwise
increase the flushing time
• the measuring intervall is more than 20 minutes and flushing after reaction is just 30 sec (default value)
reaction products still remains in the photometer and create a seond reaction, flushing is not satisfying by
that anymore.
• adjust the flushing after reaction (in the service submenue) to at least 60 sec.
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8.3.5 Submenu,
CA71 Software Version PA5.0: Parameters in Submenu
Version Nov 27, 2002
Access Coding:
To proceed in the Config Menu until reaching ( 0-20mA / 4-20mA ); touching with
4 fingers (both hands) - first „K“, then „E“, „CE“ and „M“ (all 4 together), lifting
the first finger from „K“ and in a split second also lifting from the 3 others.
Note
After changes in the Submenu in any case the Default setup in „Configuration“
must be done.
Parameters:
Note
Whenever one of these settings is changed make sure that they are documented properly!
Use form at page 169 or AnaWin for proper documentation
Standard values: Upload of the specific standard values ( Filling time, rpm (U/min.)., Reaction
time ) by pressing both arrows together.
Error mask: Here several errors can be suppressed for display.

The error will be there, but this setting is blocking the Dashes in display, no
error LED no settings of contact errors.
The analog output will stay on the last measuring value (w/o error) on hold and
will be updated with the next measuring value.
The following numbers have to be set for masking:
Errors Number
Wrong photometer device 4
No measuring signal 8
Dirty measuring device 16
Calibration not successful 32
Leak in the system 64
Sampler empty 128
Also combinations of errors can be masked.

Example: „Wrong meas. device“ ( 4 ) and „Dirty meas.Device“ ( 16 ): 4+16=20,
Number for masking = 20
Or
„“Calibration not successful“ ( 32 ), „Leak in the system“ ( 64 ) and „Sampler
empty“ (128):
32+64+128=224, Number for masking = 224
Usable range: 0-255
Standard ( Value for default ): 0
MB >= Defines the starting of the measuring range for the display.
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Measured value lower than this limit – the display will show 4 strokes.
Range: depending from the parameter,
Standard ( Value at default setup ): depending from parameter defined in
„CONFIGURATION"
MB max: Will fix the upper end of the analog output (20 mA meas. value).
Example: MB max 30 mg/l –N means that the upper range in the „Param.
Menu“ can be set only up to 30 mg/l –N.
ATTENTION: Only the analog output will be changed, the chemical possible
measuring range of the unit will not be influenced!!
Range: specific for the parameter,
Standard ( Value at default setup ): depending from parameter defined in
„CONFIGURATION"
Additional relay ( only in The configuration for this additional relay can be done in 2 ways:
2 channel version ): Channel 2: Display of the actual Measuring channel (channel 1 or channel 2)
Standard: Display measuring accomplished, i.e. on the end of each measuring
cycle the relay will be triggered for several seconds.
Range: Standard – Channel 2
Standard ( Value at default setup ): channel 2
Rinsing: Fixes the duration, the analyser will be rinsed with sample after measuring
(reaction time accomplished and display measuring value); for the 2 channel
version with the last sample measured.
Rinsing time set on 0 s, error „Sampling unit inactive“ („SEDI mode“).
Range: 0 – 300 s,
Recommandation: If measurement intervall will allow, set as high as possible.
This is a must with long measuring intervals >20 minutes
Standard ( Value at default setup ): depending from parameter fixed In
„CONFIGURATION". Typically at 30 s.
tfill: = filling time. Fixes the time, the analyser needs to mix sample and reagents and
to bring this mixture into the cuvette.
example.: tfill = 10 s, both pumps will turn together during 10 s.
Range: 5 – 60 s.
Standard ( Value at default setup ): depending from parameter set in
„CONFIGURATION".Default settings are based on the length of hose between
mixer and photometer, default setting of speed of step motor and pump hoses in
order to guarantee a proper filling of the photometer. Whenever one of the
parameters has been changed, changing of tfill might be necassary. Longer tfill is a
must, when length of hose has been „extended“, speed of photometer has been
slowed down or diameter of pump hoses has been lowered. Vice versa tfill can be
shorted in order to decrease consumption of reagents.
trea: = reaction time. Defines the time, the analyzer needs to get sample with reagents
completely reacted.
example.: trea = 60 s, after adding the reagents to the sample, the analyzer
willread the platea frequency after 60s to calculate the measuring result.
Range: 20 – 900 s,
Standard ( Value at default setup ): depending from parameter, Fixed in
„CONFIGURATION".
Extention might necassary when composition of the sample disturbs the reaction.
This can be the case when at the end of the reaction time the frequency still
drops for more than 1-2 Hz/sec.
Extended trea to the time until the frequency keeps stabil.
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trea 2: = reaction time 2. A second, additional reaction time is set, running before the
first rection time. After accomplishing the first reaction time (trea 2), a second
reagents addition will take place and the second reaction time is running.
To be used f.e. for silicate.
Range: 20 – 900 s,
Standard ( Value at default setup ): depending from parameter fixed in
„CONFIGURATION".
Air pumping ( only at Air pumping through the analyzer before pumping of the sample; this is
photometer type universal especially important at parameters with high concentration of sulfuric acid as part
): of the reagents ( Nitrate, Phosphate yellow ).
When selecting air pumping no cleaning solution can be connected to the
analyzer
Range: On – OFF
Standard ( Value at default setup ): with photometer type universal not possible.
SMO positioning ( only Position – view from front side – for the step motor
with photometer type Range: left ( NH4 ) - right ( PO4 )
universal ): Standard ( Value at default setup ): with photometer type universal not possible.
Rpm (U/min): = turning velocity of the step motor per minute. (rpm = rounds per minutes)
This value can be changed.
Range: 5 – 80 EPM.
Standard ( Value at default setup ): depending from the parameter set in
„CONFIGURATION".
If a change in the frequency from the power supply is needed from 50 to 60 Hz,
please change the rpm at 20 %. Example 10 to 12 rpm.
Together with the speed of the synchromotor and the used pump tubes the rpm
fixes the ratio of reagents and sample.
Increasing the amount of reagent can extended the measuring range but can as
well cause the danger of less accuracy.
Decreasing the amount of reagent can increase the accuracy of low concentration
but will decrease the measuring range.
After change the rpm checking if internal calibration curve is still valid ( by
measuring at least 3 different samples: 10 %, 50 %, 90 % of measuring range end
) and checking if tfill is still satisfying is a must.
If internal calibration curve is not valid anymor, please refer to page 118
Factor GlMwB ( k Stabilisation of the measured values.

floating mean ): The higher, the slower will be the display of measured values and frequencies at
fluctuations following jumps and concentration changes. This factor should be
changed only in very special conditions.
Range: 1 – 10, 1 means the measured value is displayed directly, without
modifications.
Standard ( Value at default setup ): 1
Mode: The format of the memory will be fixed.

The data storing can be done as concentration values ( Meas. Mode ), or as raw
values ( 2 frequency values – base line and plateau ) ( lab calibration ).
Range: Measuring mode – Lab calibration
Standard ( Value at default setup ): Measuring mode
Change to raw values is helpfull to check repeatability of the measurement, or
when a customized internal calibration curve has to be set (please refer to page
118). Variation of the basis frequency can be a signal of too short „delay to
sample“. Variation of the plateau value can be a signal of too short tfill, too short
trea, wear and tear of pump hoses, aged reagents etc.
After finishing service please set to „measuring mode“ again.
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Standard values: Frequency reference curve is registered depending from photometer type and
measuring range. (internal calibration curve )The curve is represented by pairs of
concentration / frequency ( different numbers of pairs per curve possible ).
This curve should not be modified. The factory calibration creates a basic curve
which is specific for each photometer; is curve is in the memory, on the end of
the submenu.
ATTENTION!! Reset to get the standard values will overwrite (cancel!) the factory
calibration values and a standard set of values will be set for the concerned
parameter.
Range: The values pairs with max. 10 concentration values and the
corresponding frequencies,
Standard ( Value at default setup ): specific for the parameter
Changing might be necassary whenever pump hose diameter or ratio of
reagents/sample (speed of step motor) has been changed or the behavior of the
sample do not allow to work with the existing curve.
If change is necessary please refer to page 118 ff
Calculation of response time:

response time = delay to sample + tfill + t reac + rinsing
In order to get a better flushing effect during "delay to sample and rinsing, the pump will not work
continously but 3 sec. with 1 sec. stop.
For calculation of the time devide the entered time through 3 and add the result to the entered time:
Example: delay to sample : 180 Æ 240 sec total time consumption. Please refer to table consumption.
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8.3.5.1 Standard values / Datas of internal calibration curve
The signal strength is processed device-internally as a frequency.

The following table provides an overview of the standard calibration data
(frequency-offset = 0).
Note
Compare these values to your own data.
After changes in the CONFIGURATION menu and in case of software updates, you can check and, if
necessary, change the calibration data in the sub-menu.
Standard- Characteristic CA71 STAMOLYS (sheet 1):
Photometertype AM-A AM-B AM-C PH-A PH-B PH-C PH-D NI-A
übersprin
gen
Unit mg/l-N mg/l-N mg/l-N mg/l-P mg/l-P mg/l-P mg/l-P mg/l-N
Measuring range 0,1-5 0,2-15 0,2-100 0,05-2,5 0,5-20 0,05-25 0,5-50 0,2-20
Number of 10 10 10 10 10 10 10 10
calibration points
Concentration 1 0 0,0 0,0 0,00 0 0 0 0

Concentration 2 0,5 1,5 10,0 0,25 2 2,5 5 2
Concentration 3 1,0 3,0 20,0 0,50 4 5 10 4
Concentration 4 1,5 4,5 30,0 0,75 6 7,5 15 6
Concentration 5 2,0 6,0 40,0 1,00 8 10 20 8
Concentration 6 2,5 7,5 50,0 1,25 10 12,5 25 10
Concentration 7 3,0 9,0 60,0 1,50 12 15 30 12
Concentration 8 3,5 10,5 70,0 1,75 14 17,5 35 14
Concentration 9 4,0 12,0 80,0 2,00 16 20 40 16
Concentration 10 5,0 15,0 100,0 2,50 20 25 50 20
Delta f 1 [Hz] 0 0 0 0 0 0 0 0
Delta f 2 [Hz] 251 325 721 96 73 330 179
Delta f 3 [Hz] 515 679 1419 180 144 651 341
Delta f 4 [Hz] 831 972 2038 265 213 901 487
Delta f 5 [Hz] 1059 1320 2637 355 277 1149 620
Delta f 6 [Hz] 1319 1603 3037 430 341 1376 740
Delta f 7 [Hz] 1525 1840 3338 516 400 1543 841
Delta f 8 [Hz] 1741 2054 3441 568 459 1718 902
Delta f 9 [Hz] 1902 2342 3550 638 516 1795 928
Delta f 10 [Hz] 2308 2746 3834 798 622 1920 950
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Photometertype NI-B AL-A AL-B FE-A FE-B FE-C MN-A NO-A
übersprin
gen
Unit mg/l-N µg/l µg/l µg/l mg/l mg/l ug/l ug/l
Measuring range 1-50 10-300 50-1000 10-500 0,05-2 0,1-5 1-150 10-500
Number of 10 4 10 10 5 10 10 10
calibration points
Concentration 1 0 0 0 0 0 0 0 0
Concentration 2 5 100 100 50 0,5 0,5 15 50
Concentration 3 10 200 200 100 1 1 30 100
Concentration 4 15 300 300 150 1,5 1,5 45 150
Concentration 5 20 400 200 2 2 60 200
Concentration 6 25 500 250 2,5 75 250
Concentration 7 30 600 300 3 90 300
Concentration 8 35 700 350 3,5 105 350
Concentration 9 40 800 400 4 120 400
Concentration 10 50 1000 500 5 150 500
Delta f 1 [Hz] 0 0 0 0 0 0 0
Delta f 2 [Hz] 52 52 19 238 238 89 122
Delta f 3 [Hz] 125 125 44 492 492 229 242
Delta f 4 [Hz] 184 184 68 754 754 360 358
Delta f 5 [Hz] 255 92 1010 1010 515 465
Delta f 6 [Hz] 306 116 1251 628 582
Delta f 7 [Hz] 384 139 1477 816 685
Delta f 8 [Hz] 450 163 1693 999 793
Delta f 9 [Hz] 516 186 1920 1233 889
Delta f 10 [Hz] 643 232 2307 1772 1083
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Photometertype NO-B NO-C SI-A SI-B CU-A CU-B CR-A CR-B
Unit mg/l-N mg/l-N ppb ppb mg/l mg/l mg/l mg/l

Measuring range 0,1-1,0 0,2-3 1-200 100-5000 0,1-2 0,2-5 0,1-2,5 0,2-5
Number of 10 10 10 10 5 10 6 10
calibration points
Concentration 1 0 0 0 0 0,00 0,00 0,00 0,00

Concentration 2 0,1 0,3 20 100 0,50 0,50 0,50 0,50
Concentration 3 0,2 0,6 40 500 1,00 1,00 1,00 1,00
Concentration 4 0,3 0,9 60 1000 1,50 1,50 1,50 1,50
Concentration 5 0,4 1,2 80 1500 2,00 2,00 2,00 2,00
Concentration 6 0,5 1,5 100 2000 2,50 2,50 2,50
Concentration 7 0,6 1,8 120 2500 3,00 - 3,00
Concentration 8 0,7 2,1 140 3000 3,50 - 3,50
Concentration 9 0,8 2,4 160 4000 4,00 - 4,00
Concentration 10 1,0 3 200 5000 5,00 - 5,00
Delta f 1 [Hz] 0 0 0 0 0 0 0 0
Delta f 2 [Hz] 240 716 68 107 134 134 342 342
Delta f 3 [Hz] 471 1294 142 211 257 257 648 648
Delta f 4 [Hz] 693 1767 217 311 380 380 936 936
Delta f 5 [Hz] 894 2155 289 396 501 501 1193 1193
Delta f 6 [Hz] 1091 2429 369 515 633 1395 1395
Delta f 7 [Hz] 1275 2664 443 555 748 1630
Delta f 8 [Hz] 1423 2846 515 636 877 1799
Delta f 9 [Hz] 1595 2991 591 671 1000 1980
Delta f 10 [Hz] 1895 3225 742 858 1226 2275
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Photometertype HA-A HA-B HY-A MN-B CL-A/B CL-C/D
Unit mg/l mg/l µg/l µg/l mg/l mg/l l

Measuring range 0,2-10 0,8-80 1-500 10-2000 0,010- 0,10-
1,000 10,00
Number of 10 10 10 10 10 10
calibration points
Concentration 1 0 0 0 0 0 0
Concentration 2 1 10 50 200 0,100 1,00
Concentration 3 2 20 100 400 0,200 2,00
Concentration 4 3 30 150 600 0,300 3,00
Concentration 5 4 40 200 800 0,400 4,00
Concentration 6 5 50 250 1000 0,500 5,00
Concentration 7 6 60 300 1200 0,600 6,00
Concentration 8 7 70 350 1400 0,700 7,00
Concentration 9 8 80 400 1600 0,800 8,00
Concentration 10 10 100 500 2000 1,000 10,00
Delta f 1 [Hz] 0 0 0 0 0 0
Delta f 2 [Hz] 60 43 37 192 236 278
Delta f 3 [Hz] 126 86 81 428 422 487
Delta f 4 [Hz] 233 128 119 732 620 649
Delta f 5 [Hz] 286 164 153 1058 819 795
Delta f 6 [Hz] 355 184 195 1425 1023 924
Delta f 7 [Hz] 409 205 231 1683 1229 1019
Delta f 8 [Hz] 466 222 269 1817 1467 1115
Delta f 9 [Hz] 517 234 302 1876 1688 1203
Delta f 10 [Hz] 591 247 376 1948 2044 1350
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8.3.6 Menu "LANGUAGE"
{ XE "language, selection of" }
Navigate through the main menu with the È key to the "LANGUAGE" option and press the È key to select
your desired language. Pressing E accepts the desired language.
With the M key, you can return to the main menu at any time.
The following languages are available:
• Deutsch (german)
• English
• Français (french)
• Nederlands (dutch)
• Suomi (finish)
• Magyar (hungarian)
• Polski (polish)
• Italiano (italian)
8.3.7 Menu "ERROR DISPLAY"
Navigate through the main menu with the È key to the "ERROR DISPLAY" option and
press the E key to move forwards within this sub-menu and the CE key to return to the previous error
message.
With the M key you can return to the main menu at any time.
Note
This menu is a "Read-Only-Menu".
You can find the individual error messages, their meaning and solutions to problems on page 122 ff
If there is at least one error message, the signal output is set to "fault".
Causes of faults are requested for every measurement. If an error which occurred previously don't exist
anymore, it is automatically cancelled. If this should not happen automatically, error messages can be deleted
by switching the CA 71 off and back on again.
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8.3.8 Menu "SERVICE"
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Navigate through the main menu with the È key to the "SERVICE" option and press the E key to move
forward within this sub-menu and the CE key to return to the previous option. The settings can be changed
within the individual options with the Ç or È. With the M key, you can return to the main menu at any
time.
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8.3.9 Menu(s) "DATA STORAGE (1/2)"
Navigate through the main menu with the È key to the "DATA MEMORY (1/2)" option
and press the E key to move forward within this sub-menu and the CE key to return to
the previous option.
With the M key you can return to the main menu at any time.
Note
Two menus, "DATA MEMORY 1" and "DATA MEMORY 2", are only for the two channel version.
In the one channel version there is only one menu "DATA MEMORY".
8.3.10 "DATA STORAGE-Calibration factor datas"
Note
To enter this menu select the CONFIGURATION menu, browse to the "Calibration factor" option and press
the K key.
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8.3.11 Factory settings
Factory settings STAMOLYS (sheet 1):

Type of AM-A AM-B AM-C PH-A PH-B PH-C PH-D NI-A
photometer
Unit mg/l-N mg/l-N mg/l-N mg/l-P mg/l-P mg/l-P mg/l-P mg/l-N
Calibration factor 1,00 1,00 1,00 1,00 1,00 1,00 1,00 1,00
c-Offset 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00
Dilution 1,00 1,00 1,00 1,00 1,00 1,00 1,00 1,00
Sample delay[s] 80 80 80 80 80 80 80 80
Analog output 4-20 mA 4-20 mA 4-20 mA 4-20 mA 4-20 mA 4-20 mA 4-20 mA 4-20 mA
Alarm value GW1 normal normal normal normal normal normal normal normal
closed closed closed closed closed closed closed closed
Error contact normal normal normal normal normal normal normal normal
f-Offset [Hz] 0 0 0 0 0 0 0 0
Range start 0,00 0,0 0,0 0,00 0,0 0,0 0,0 0,0
Range end 5,00 15,0 100,0 2,50 20,0 25,0 50,0 20,0
Alarm value GW1 2,50 7,50 30,0 1,25 10,0 10,0 25,0 10,0
Alarm value GW2 5,00 15,0 50,0 2,50 20,0 25,0 50,0 20,0
1. Measurement Actual date of selecting default settings
Measuring interval 10 10 10 10 10 10 10 10
[min]
1. Calibration Actual date + 1 day of selecting default settings,8.00Uhr
Calib.intervall [h] 48 48 48 48 48 48 48 48
Calib. Solution 1,00 5,00 50,0 1,00 5,00 5,00 10,0 5,00
1. Flushing Actual date + 1 day of selecting default settings,6.00Uhr
Flush. Intervall [h] 48 48 48 48 0 48 0 0
Flushing hold on 60 60 60 60 1 60 1 1
[s]
R kenn in KOhm 1k8 1k8 3k0 1k1 2k4 1k1 2k4 2k4
Verfahrensablauf: AM AM AM PH-A PH-B PH-A PH-B NI
Note: Before the work alignment the current date and the current time are to be entered!
Default values submenu STAMOLYS:

Type of AM-A AM-B AM-C PH-A PH-B PH-C PH-D NI-A
photometer
Min. selectable mg/l, mg/l, mg/l, mg/l, mg/l, mg/l, mg/l, mg/l,
units mg/l-N mg/l-N mg/l-N mg/l-P mg/l-P mg/l-P mg/l-P mg/l-N
Errormask 0 0 0 0 0 0 0 0
MB>= 0,05 0,5 0,5 0,05 0,5 0,05 0,5 0,2
MB 5,00 15,0 100 2,50 20,0 25,0 50,0 20,0
Flush [s] 30 30 30 30 30 30 30 30
t fill [s] 11 11 11 16 16 16 16 12
t rea [s] 180 180 180 360 360 360 360 360
Faktor GlMwB 1 1 1 1 1 1 1 1
SMO U/min 20 5 5 8 10 8 10 6
Note: The default values for the secret menu are to be taken over before general factory setting, thus the
measuring range maximum input border „MB“ is in time set.
Endress+Hauser 80
Type of NI-B Al-A Al-B FE-A FE-B FE-C MN-A MN-B
photometer
Unit mg/l-N µg/l µg/l µg/l mg/l mg/l ug/l ug/l
Calibration factor 1,00 1,00 1,00 1,00 1,00 1,00 1,00 1,00
c-Offset 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00
Dilution 1,00 1,00 1,00 1,00 1,00 1,00 1,00 1,00
Sample delay[s] 80 80 80 80 80 80 80 80
Analog output 4-20 mA 4-20 mA 4-20 mA 4-20 mA 4-20 mA 4-20 mA 4-20 mA 4-20 mA
Error contact normal normal normal normal normal normal normal normal
f-Offset [Hz] 0 0 0 0 0 0 0 0
Range start 0 0 0 0 0,00 0,00 0 0

Range end 50,0 300 1000 500 2,00 5,00 150 2000
Alarm value GW1 25,0 150 500 250 1,00 2,50 50 1000
Alarm value GW2 50,0 300 1000 500 2,00 5,00 100 2000
Measuring interval 10 10 10 10 10 10 10 10
[min]
1. Calibration actual date + 1 day of selecting default settings, 8.00Uhr
Calib.intervall [h] 48 48 48 48 48 48 48 48
Calib. Solution 20,0 100 250 100 2,00 2,00 100 500
1. Flushing actual date + 1 day of selecting default settings, 6.00Uhr 28
Flush. Intervall [h] 0 0 0 0 0 0 48
Flushing hold on 1 1 1 1 1 1 60 60
[s]
R kenn in KOhm 2k4 3k0 3k0 3k0 3k0 3k0 3k0 3k0
Vefahrensablauf NI AM AM AM AM AM AM AM

Type of NI-B AL-A AL-B FE-A FE-B FE-B MN-A MN-B
photometer
Min. selectable mg/l, µg/l, µg/l, µg/l, mg/l, mg/l, µg/l, µg/l,
units mg/l-N ppb ppb ppb ppm ppm ppb ppb
Errormask 0 0 0 0 0 0 0 0
MB>= 1,0 10 50 10 0,05 0,05 1,0 10
MB 50,0 300 1000 500 2,00 2,00 150,0 2000
Flush [s] 30 30 30 30 30 30 30 30
t fill [s] 12 14 14 12 12 12 15 30
t rea [s] 360 60 60 60 60 60 300 90
Faktor GlMwB 1 1 1 1 1 1 1 1
SMO U/min 6 60 60 60 60 60 24 6
Note: The default values for the secret menu are to be taken over before general factory
setting, thus the measuring range maximum input border „MB“ is in time set.
Endress+Hauser 81
Type of NO-B NO-C SI-A SI-B CU-A CU-B

photometer
Unit µg/l-N mg/l-N mg/l-N µg/l µg/l mg/l mg/l

Calibration factor 1,00 1,00 1,00 1,00 1,00 1,00 1,00
c-Offset 0,00 0,00 0,00 0,00 0,00 0,00 0,00
Dilution 1,00 1,00 1,00 1,00 1,00 1,00 1,00
Sample delay[s] 80 80 80 160 80 80 80
Analog output 4-20mA 4-20mA 4-20mA 4-20mA 4-20mA 4-20mA 4-20mA
Alarm value GW1 normal normal normal normal normal normal normal
closed closed closed closed closed closed closed
Error contact normal normal normal normal normal normal normal
f-Offset [Hz] 0 0 0 0 0 0 0
Range start 0 0,00 0,00 0 0 0,00 0,00
Range end 500 1,00 3,00 200 5000 2,00 5,00
Alarm value GW1 250 0,50 1,50 100 2500 1,00 2,50
Alarm value GW2 500 1,00 3,00 200 5000 2,00 5,00
Measuring 10 10 10 10 10 10 10
interval [min]
Calib.intervall [h] 48
Calib. Solution 250 0,5 1,5 500 1000 1,00 2,00
1. Flushing actual date + 1 day of selecting default settings, 6.00Uhr

Flushing hold on 60 60 60 0 60 1 1
[s]
R kenn in KOhm 3k0
Verfahrensablauf AM AM AM SI PH-A AM AM

Type of NO-A NO-B NO-B SI-A SI-B CU-A CU-B
photometer
Min. selectable µg/l, µg/l- mg/l-N, mg/l-N, µg/l, ppb µg/l, ppb mg/l, ppm mg/l, ppm
units N mg/l mg/l
Errormask 0 0 0 0 0 0 0
MB>= 10 0,10 0,20 1 100 0,10 0,20
MB 500 1,00 3,00 200 5000 2,00 5,00
Flush [s] 30 30 30 30 30 30 30
t fill [s] 12 12 12 24 15 12 12
t rea [s] 120 120 120 90 120 120 120
t gvs [s] without 30
mixture filling on
t rea 2 [s] 240 240
Faktor GlMwB 1 1 1 1 1 1 1
SMO U/min 60 60 60 30 30 60 60
Note: The default values for the secret menu are to be taken over before general factory setting, thus the
measuring range maximum input border „MB“ is in time set.
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Endress+Hauser 83
factory settings STAMOLYS (Blatt 4):
Type of HA-A HA-B HY-A CR-A CR-B CL-A/B CL-C/D

photometer
Unit mg/l mg/l µg/l mg/l mg/l mg/l mg/l

Calibration factor 1,00 1,00 1,00 1,00 1,00 1,00 1,00
c-Offset 0,00 0,00 0,00 0,00 0,00 0,00 0,00
Dilution 1,00 1,00 1,00 1,00 1,00 1,00 1,00
Sample delay[s] 80 80 80 80 80 120 120
Analog output 4-20mA 4-20mA 4-20mA 4-20mA 4-20mA 4-20mA 4-20mA
Error contact normal normal normal normal normal normal normal
f-Offset [Hz] 0 0 0 0 0 0 0
Range start 0,00 0,0 0 0,00 0,00 0,000 0,00
Range end 10,0 80,0 500 2,50 5,00 1,000 10,00
Alarm value GW1 5,00 40,0 250 1,25 2,50 0,400 5,00
Alarm value GW2 10,0 80,0 500 2,50 5,00 1,000 10,00
Measuring interval 10 10 10 10 10 10 10
[min]
Calib.intervall [h] 48 48 48 48 48 0 0
Calib. Solution 5,00 40,0 400 1,00 2,00 0 0
1. Flushing actual date + 1 day of selecting default settings, 6.00Uhr48
Flushing hold on 60 60 1 1 1 60 60
[s]
R kenn in KOhm 3k0 3k0 2k4 3k0 3k0 3k0 3k0
Verfahrensablauf PH-B PH-B PH-A AM AM PH-A PH-A
Type of HA-A HA-B HY CR-A CR-B CL-A/B CL-C/D

photometer
Min. selectable mg/l, °fH, mg/l, °fH, µg/l, ppb mg/l, mg/l, mg/l, mg/l,
units °dH °dH ppm ppm ppm ppm
Errormask 0 0 0 0 0 0 0
MB>= 0,20 0,8 1,0 0,10 0,20 0,010 10,0
MB 10,0 80,0 500 2,50 5,00 1,000 10,00
Flush [s] 30 30 30 30 30 30 30
t fill [s] 12 12 16 12 12 20 20
t gvs [s] without 20 10
mixture filling o
t rea [s] 60 60 60 180 180 60 60
Factor GlMwB 1 1 1 1 1 1 1
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SMO U/min 20 10 12 60 60 60 30
Note: The default values for the secret menu are to be taken over before general factory
setting, thus the measuring range maximum input border „MB“ is in time set.
8.3.12 Factory settings 115V/50Hz steppmotor and Reagent filling time
50Hz instruments or 115V/50Hz instruments change in the submenu behind the analog
output Speed of the Steppmotor and the the filling time in following tabell.
Parameter Steppmotor U/min Reagent filling time tfüll

AM-A Standard 20 15
AM-B Standard 5 15
AM-C Standard 5 18
AM-D 15 60
AL 16 17
PH-A 8 25
PH-B 10 25
PH-C 14 25
PH D 15 25
CR-alle Standard 60 22
CU-alle Standard 50 22
FE-alle Standard 60 22
MN-A Standard 40 25
MN-B Standard 5 45
NO-alle Standard 60 22
SI-A 30 24
SI-B 30 15
HA-A 5 15
HA-B 40 10
HY-alle 48 20
CL-A Standard 60 20
CL-B 30 20
8.3.13 Factory settings 115V/60Hz steppmotor and Reagent filling time
60Hz instruments or 115V/60Hz instruments change in the submenu behind the analog
output Speed of the Steppmotor and the the filling time in following tabell.
Parameter Steppmotor U/min Reagent filling time tfüll

AM-A Standard 20 15
AM-B Standard 5 15
AM-C Standard 5 18
AM-D 18 40
AL 19 14
PH-A 10 25
PH-B 15 25
PH-C 17 25
PH-D 15 25
CR-alle Standard 60 22
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CU-alle Standard 50 22
FE-alle Standard 60 22
MN-A Standard 48 25
MN-B Standard 6 30
NO-alle Standard 60 22
SI-A 36 20
SI-B 36 13
HA-A 6 15
HA-B 48 10
HY-alle 58 17
CL-A Standard 60 15
CL-B 36 17
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9 Service and replacement
9.1 Service Checklist CA 71
Town: _____________________________________________________________________
Order code:_______________________________________________________________________
Serial-No. Analyzer:___________________________________________________________
Serial-No. Photometer: ________________________________________________________
Software-Version: ____________________________________________________________
Date: ______________________________________________________________________
Safety first! Pay attention to all safety hints for handling of chemicals, personal safety
equipment, electrical safety, working security.
Please follow list strictly top to bottom!
Preparatory work (general)

◊ Clear with user, if it is necessary to set analyzer out of control of ... e.g. precipitant dosage
◊ Note current measurement value and check for plausibility
◊ Visual inspection (Enclosure, hoses, pumps and valves, electronics, reagents)
◊ Connect labtop via RS232 and start software AnaWIN to store all frequency values
◊ Perform test measurement, note result and check for plausibility
Preparatory work (media and reagents contacted parts)

◊ Disconnect Analyzer from sample feed line
◊ Remove hoses from canisters and clean hoses outside
◊ Rinse hoses with destilled water in Service mode
◊ Empty hose system in Service mode
◊ Connect one-trip syringe to sample inlet, open hose clamp of sample pump and use one-trip syringe
to fill sample line with diluted cleaner P3-Ultrasil 130. Let cleaner act on hoses and continue later,
see „Cleaning“
Status of analyzer
◊ Check and note settings of analyzer, compare with factory settings of Analyzer
◊ Read out Data memory (use CAX Tool/AnaWIN and PC / Laptop)
◊ Read out Calibration factor data memory (use CAX Tool/AnaWIN and PC / Laptop)
◊ Check plausibility of calibration factors dependent on specifications of instrument
◊ Check wear and tear of pump hoses
◊ Check correctness of hoses and connections
◊ Check reagents (manufacturing date, aging, spoiling, contamination with sample,color, smell, filling
level)
◊ Check standard solution (manufacturing date, concentration, setting of analyzer)
Endress+Hauser 87
General function
◊ Check function of keys by using service menu
◊ Check display
◊ Check analog output by current putput simulation (Chapter 7.5.)
◊ Check error contact by e.g. short cutting leagage detector
◊ Check sample reservoir by filling with sample and empty it
◊ Check valves functionallity and wear and tear of valves hoses
◊ Check temperature of photometer (should be round about 40°C)
◊ Check electronic plug-in, cabinet inside and outside
Cleaning
◊ Continue hose cleaning startet before at „Preparatory work“. Push and pull one-trip syringe powerful
to flush sample hose system with diluted cleaner P3-Ultrasil 130
◊ Empty sample hose system
◊ Use one-trip syringe to flush sample hose system powerful with destilled water
◊ Note frequency value of destilled water dependent on specification of instrument
◊ Clean sample collecting vessel
◊ Clean pump head and grease it
◊ After finishing service: clean cabinet, clean window, clean and dry bottom of analyzer cabinet and
bottom of reagents cabinet
Replacement (if necessary or if part of maintenance)

◊ Replace pump hoses
◊ Replace hoses for sample, reagent, standard, cleaning solution and outlet
◊ Replace hose connections
◊ Replace mixer
◊ Replace photometer cuvette
Test operation with destilled or demineralized water

◊ Check pressure of hose holder and pump rate
◊ Check proofness (hoses, hose connections, valves)
◊ Check valve function (convey destilled water with air bubbles and check convey courses)
Test operation with reagents

(store all datas with AnaWIN)
◊ Set „Mode“ in submenu on lab calibration
◊ Fill reagent, cleaning solution and standard hoses with solutions
◊ Calibrate offset (zero measurement with destilled water as sample) min. 2 times
◊ Note frequency value of zero measurement
◊ Calibrate the analalyzer min. 2 times
◊ Set „Mode“ in submenu back to „Measuring mode“
◊ Note frequency value of calibration
◊ Connect sample feed line
◊ Check setting of „delay to sample“ and adapt if necessary
◊ Measure with original sample. Compare result with separate lab analysis
Endress+Hauser 88
9.2 Service software AnaWin
AnaWin is a Windows (Windows 98, Windows NT) based software for service of Analyzers CA 70 from V
3.9 and CA 71 from V 5.0
It can be downloaded on http://www.de.endress.com
Functions of AnaWin
• Graphic display and documentation of the reaction course
• Read out and documentation of the analyzer settings
• Read out and documentation of datastorage
Start screen
When starting the software please select at first in menu "Mode / settings" language and port.
The functions frequency control (display of the reaction course), Parameter (analyzer settings) and data
storage. Can be selected in menu "Mode" afterwards
Endress+Hauser 89
Screen Frequency control
The reaction course as well as the actual frequency and status are displayed on the screen. After the reaction
is finished additionally basis frequency (fB) and plateau frequency (fP) and there delta is shown in the right
corner of the screen.
Horizontal lines mark level of Basis and plateau frequency. Vertical lines mark end of status e.g. flushing
Storing of the values is NOT possible, Software bug. Unfortunally not able to be fixed.
Endress+Hauser 90
Screen Parameter
Start read out settings
Start read out calibration data storage
Parameter entry Standard values

(internal calibration curve)
Configuration
Service submenu
The different settings are sorted in different folders.
Screen data storage
Operation buttons:
• Get parameters
• Clear display
• Read data storage
• Read calibration
storage
Storing of the values is NOT possible, Software bug. Unfortunally not able to be fixed.
Please printout the values or note them into the form, page 169
Endress+Hauser 91
Detection of disturbances by reaction course
9.2.1.1 Interferences
The following graph will show a "normal" reaction course of Stamolys Phosphate Analyzer
Reaktionsverlauf PO4-P
6150
1. Measuring (colour of the

sample)
6100 mixing
flushing
stabilizing
6050
6000 reaction period

Hz
5950
5900
flushing
2. Measuring (colour of the
5850 solution)
5800
time
In comparism to the normal reaction, interfiring substances very often inhibit the reaction.
The reaction time is lowerd and not finished, when the selected reaction time of the analyzer is reached. The
frequency still drops down.
Endress+Hauser 92
Measurement disturbed by interferences
7300
7100 1. Measurement (colour of the

sample
6900
6700
Hz
6500
1. Measurement (colour of the
solution
6300
6100
1 31 61 91 121 151 181 211 241 271 301 331 361 391 421 451 481 511 541 571 601 631 661
time (3 sec / Division)
If interferences disturb the measurement it might help to increase the reaction time and use stabilized
sample as standard solution
A list of possible interferences you will find in chapter 10.3 Chemical interferences
Endress+Hauser 93
9.2.1.2 Air bubbles
Air bubbles will show frequency peaks in the reaction course
Disturbane by air bubbles
7150
air bubbles
7100
7050
7000
Hz
6950
6900
6850
6800
time
• Airbubbles can influence the ratio of reagent and sample during mixing phase.
• Airbubbles can influence the detection of basis Frequency or plateau frequency if airbubbles are in the
photometer during the detection.
Due to the fact, that this influences of airbubbles are not repeatable, unstable measurement values are the
result.
Tightness of the hose system has to be secured and air bubbles avoided
Endress+Hauser 94
9.3 Replacement of the reagents
1 Warning!
• There is a danger of crushing limbs at doors, inserts and pump heads.
• Refer to the warning instructions in the safety data sheets when handling reagents.
• Wear protective clothing, gloves and goggles.
• Make sure the workplace is well ventilated when you work with chlorine bleach. If you feel unwell,
consult a physician immediately.
• If reagents come into contact with the skin or eyes, carefully rinse with copious amounts of water and
consult a physician immediately.
• Never add water to reagents. Reagents containing acids may splash and heat may build up.
If you store the reagents correctly (in the dark, not over 20 °C) they will keep for min. 6 weeks from the date
of manufacture (batch number). When this period of time has expired, the reagents must be replaced. Shelf
life can be prolonged by keeping the reagents in a dark, cool storage place.
The reagents absolutely must be replaced when

• the reagents have been contaminated by sample
• the reagents are too old
• the reagents have been spoilt by incorrect storage conditions or environmental influences
To replace the reagents proceed as follows:

1. Carefully remove the hoses from the canisters and wipe them with a dry (paper) cloth. Wear protective
gloves when doing this.
2. Switch on the reagent pump for about 5 seconds.
3. Flush the reagent hose with plenty of distilled water ("SERVICE" operation).
4. Replace the reagent canister and feed the hoses into the new canister.
5. Fill the reagent hose with the new reagents ("SERVICE" operation)
6. Determine the reagent blind value ("CONFIGURATION" / "Frequency offset").
7. Then carry out a calibration ("PARAMETER ENTRY").
Endress+Hauser 95
9.4 Exchange of valve channel complete:
51512100 KIT CA71 valve complete (1 pc. for 1 channel version)

51512234 KIT CA71 valve set (2 pcs., for 2 channel version)
• Rinse system with water in the service menu and then emptie it.
• Remove power supply.
• Open Analyzer frame.
• Remove lines from terminal ( terminal 72 and 71 for valve 1 or terminal 73 and 71 for valve 2 ).
• Remove pump board.
• Remove valve board.
Schrauben Ventilhalteplatte
Screws valve board Pumpenplatte
Pump board
Schrauben Pumpenplatte
Ventil 1
Screws pump board
Valve 1
Ventil 2
Valve 2
• Unfix valve clip to remove valve coil.

• Place new valve plate in reverse sequence.
Valve 1: Sample in front and Standard or Cleaner in the back

Valve 2: Standard in front and Cleaner in the back
Endress+Hauser 96
* Caution!
To remove the hoses out of the valves please use the service menu to open the valve. Exchange without
opening might destroy the valve
In case of valve 1 hose for sample (P), in case of valve 2 hose for standard solution (S) is open.
To remove the hose connecting valve 1 to valve 2 switch in service menue valve 1 to S.
To remove the hose for cleaner (R) switch in service menue valve 2 to C.
Schlauch vorn im Ventil 1 eingelegt

Tubing in front of valve 1 Schlauch vorn im Ventil 2 eingelegt
Tubing in front of valve 2
R S
Schlauch hinten im Ventil 1eingelegt
Tubing at the rear of valve 1
Schlauch hinten im Ventil 2 eingelegt

Tubing at the rear of valve 2
Endress+Hauser 97
* Caution!
Remove all hoses from the bottles and put them into a water bottle. Operate pumps manually and flush the
hoses to remove all reagnets and cleaning solution from the hoses.
9.5 Upgrade or change CA71 from one channel to a two channel version, valve set
51512640 KIT CA 71 upgrade from 1 channel into 2 channel
Replacement 2-channel valve board:
• Rinse system with water in the service menu and then empty it.
• Remove line from terminal 74 and 53.
• Remove valve board.
• Place new valve board in reverse sequence.
First change from 1-channel to 2-channel:
• Rinse system with water in the service menu and then empty it.
* Caution!
¾ ! At first notice all settings.
¾ Remove power supply.
¾ Remove the black board in the front of the Analyzer.
¾ Place new valve board.
¾ Fix lines into terminal 74 and 53.
¾ Insert second analog output board.
¾ Remove old eprom and insert in the new 2-channel eprom.
¾ Switch on Analyzer and press FACTORY SETTING.
¾ Input all settings
Ventilhalteplatte 2- Kanal
2-channel board
Endress+Hauser 98
Endress+Hauser 99
9.6 Sample collecting vessel with or without level control
The sample collector is made to supply three Analyzer. For use with two or one Analyzer you have to modify
your sample vessel:
Collecting vessel without level measurement; order no. 51512088

Collecting vessel with level measurement (conductive); order no. 51512089
• Remove cover from the sample vessel.

• Remove black cover of the level detection.
• By using two Analyzer set screws M3x20 into threaded bolt.
• By using one Analyzer set screws M3x35 into threaded bolt.
• Shift overflow pipe ( see drawing ).
• Assemble sample vessel in reverse sequence.
• Assemble sample vessel at left side of the analyzer.
Connection of the sample vessel:

* Caution!
Only possible for 1- channel system.
• Connect the lines of the sample vessel as follows:

Black line into terminal 58
Yellow line into terminal 57
White line into terminal 54
Green line into terminal 53
Deckel 3 Analyzer 2 Analyzer 1 Analyzer

Probensammler
Cover
sample vessel
ENMET 12
M3x8
M3x20
M3x35
Zulauf
Inlet
To Analyzer
Überlauf
Overflow
Probensammler
Sample vessel
Endress+Hauser 100
Sample collecting vessel without level control.
Endress+Hauser 101
9.7 Cleaning of pump heads
The Pump head can be dismounted completely in unscrewing with hex-socked screw (Allen screw) 2 mm,
the position is not marked on the central axis!
(approx. 1 mm distance to the panel plate)
51512085 KIT CA71 head with rolls for peristaltic pump
The pump head can be cleaned as follows: In the service menu is started the appropriate pump, after one
clamped and from the pump head removed the hoses. The pump head is injected with silicone spray and
cleaned with running engine with a cloth through to press to the pump roles these in slightly. Roof pump
saddle and roles become, as well as the pump hose with silicone spray again injected and the hose again
inserted and the contact pressure examines.
Schlauchsattel
Halter Rollenkopf
Hose holder Holder pump head
Rollenkopf
Pump head
Endress+Hauser 102
9.8 Contact pressure and correct sample and reagent transportation
51512085 KIT CA71 head with rolls for peristaltic pump

51512086 KIT CA71 hose holder unit for pump
Schlauchsattel
Halter Rollenkopf
Hose holder
Holder pump head
Rollenkopf
Pump head
Flush hoses with water at first:

• remove hoses from reagent cans in order to avoid soiling of the reagents
• before setting analyser back to measuring mode make sure that the reagent pump hoses are filled
with reagent again.
Endress+Hauser 103
Sample or Sample or
reagents to reagents inlet
photometer
Insert the hose holder and connect hoses * Caution!
Check flow direction
Adjust plug pressure of the new hose holder with adjust screw until sample or reagent will deliver.
Pumping behavior at air and liquid is different, so pressure adjustment has to be done with liquid (destilled
water) filled hoses. Small air bubbles will help to see flow direction and speed.
Endress+Hauser 104
Inbus nut for adjust the pressure
Endress+Hauser 105
9.9 Exchange of the pump hoses
1 Warning!
When removing hoses from the hose nozzles, beware of reagent splashing.
For this reason, wear protective gloves and goggles.
The peristaltic pumps used for the CA 71 convey the medium in a combination of
vacuum and displacement pump. The pump rate is dependent on the elasticity of the
pump hoses. Elasticity decreases as mechanical stress increases and the pump rate
drops. Wear depends on mechanical stress (measuring interval, pump starting
pressure). Up to a certain degree, the wear-effect can be compensated by calibration.
If the impairment in elasticity is too great, the pump rate is no longer reproducible and
this leads to incorrect measurements. This is why it is necessary to replace the hoses.
Note!
The clamp action of the pump mechanism over a period of time will soften the tubing to the point that it will
collapse and obstruct liquid flow. This breackdown is accelerated at high temperatures. As a result, the
following replacement schedules, based on ambient operating temperature, are recommende:
a.) between 10 and 25 °C (50-77°F), replace at six-month intervals.

b.) between 25 and 40 °C (77-104°F), replace at three-month intervals.
pressed side
Inlet
To photometer
eased side
Life of the tubing can be extended by periodically adjusting the position of the tubing in the tube holder
assembly to establish new points of contact with the clamp rod. It can turn through the hose in the hose
cartridge to happen, i.e. the side of the hose eased so far is inserted now on the side of the pressure.
Note!
Please pay attention if the connections of sucking in and passing on sample and reagent must be exchanged,
too.
Endress+Hauser 106
To replace the hoses proceed as follows:
1. Flush the old hoses with water first and then empty them ("SERVICE").
2. Remove the reagent hoses from the reagent canisters, in order to prevent contamination of the reagents.
3. Remove the hoses from the connectors at the pump(s).
Latch high pressures

4. Press the hose holder down right and then take it out
5. Replace the new pump hoses in the reverse sequence of operations. It must be paid attention which is
introduced the hose routing to locking at the hose holder. Do not forget to reconnect the reagent hoses to the
canister.
Endress+Hauser 107
Owner for hose routing (Locking)
6. After installation, refill the hoses with sample, standard or cleaning agent
("SERVICE" menu). Before filling, be sure to close the clips on the reagent pump to
prevent contaminating the reagents.
7. Carry out a calibration ("PARAMETER ENTRY" menu).
1 Warning!
Ensure that you connect the new pump hoses to the correct connections at the mixer.
Note!
Sample must always meet reagent 1 first!
9.9.1 Pump hose combinations
Parameter Hose of the sample Pump hose of the reagent pump

Ammonium yellow / blue yellow / blue
Phosphate yellow / blue black / black
Chromate yellow / blue black / black
Nitrite yellow / blue black / black
Copper yellow / blue black / black
Manganese yellow / blue black / black
Iron yellow / blue black / black
Nitrate yellow / blue yellow / yellow
Silicate violett / white black / black
Chlorine violett / white black / black
Hardness yellow / blue yellow/blue
Endress+Hauser 108
9.9.2 Maintenance and service kit CAV740
Quantity ORDER NO. order-no. Description

Chromate-Analyser
CAV740-4A Maintenance kit CA 7X SI or CL
Silicate, Chlorine-Analyser
Endress+Hauser 109
9.10 Exchange of the valve hoses
The clamping action of the pinch valve mechanism over a period of time will soften the tubing to the point
that it will collapse and obstruct liquid flow. This breakdown is accelerated at high temperatures. As a result,
the following replacement schedules, based on ambient operating temperature, are recommende:
between 10 and 25 °C (50-77°F), replace at six-month intervals.

between 25 and 40 °C (77-104°F), replace at three-month intervals.
Life of the tubing can be extended by periodically adjusting the position of the tubing in the pinch valve
assembly to establish new points of contact with the clamp rod.
Note!
To remove the hoses out of the valves please use the service menu to open the valve. Exchange without
opening might destroy the valve
In case of valve 1 hose for sample (P), in case of valve 2 hose for standard solution (S) is open.
To remove the hose connecting valve 1 to valve 2 switch in service menue valve 1 to S.
To remove the hose for cleaner (R) switch in service menue valve 2 to C.
periodically adjust the position of the tubing up and down
Valve 1: Sample in front and Standard or Cleaner in the back

Valve 2: Standard in front and Cleaner in the back
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9.11 Exchange of static mixer
Mixing unit is a double spiral in PP material, the hose is Silicon rubber (biocompatible,
can be sterilized, resistent -75°C...+135°C), socalled C-Flex, connectors in PP.
Change necessary when spirales soft/dissolved
The Mixing Kit can be ordered:

51512101 KIT CA mixer module complete 2 pcs.
Photometergehäuse
Photometerbox
Mischerbaugruppe
Mixer
The mixing spirals can be dissolved by solvents contained in the samples; the measuring values will be
unstable, periodical check is recommended.
(The two spirals look like noodles, twisted into one another.)
¾ Rinse system with water in the service menu and then empty it.
¾ Remove cover from photometerbox.
¾ Remove the black hose at both side of the mixer.
¾ Remove the mixer from the plastic clip.
¾ Place new mixer in reverse sequence.
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9.12 Phometer and Photometercuvette
A change of the cuvette normally is needed for very high accuracy a new lab calibration curve.
Exchange of photometer cuvette is necessary, when chemical cleaning is not satisfying anymore. For check
fill the photometer with destilled water and compare the frequency to the origin frequency at deliver. The
frequency should be round about 6000 Hz.
Even cuvettes, which appear on a white background clear and clean can show burned places while viewing
in backlight neon lamp. They must be replaced, too
The photometer is opened with a Phillips screwdriver, the casing itself can be un-screwed with an Hex-
socket screw 3 mm key (2 screws).
Measuring is functional also with open leakage detector.

Additional cleaning possible with hypochlorite and 1-3% HCl.
Photometer Cuvette Order no.: 51505778
¾ Rinse system with water in the service menu and then empty it.
¾ Disconnect photometer lines from terminal 59, 61, 62, 63, 64, 65.
¾ Removet black tube from tube adapter.
¾ Remove cover from photometer.
¾ Unscrew the two hexagon socket screws and remove photometer.
¾ Place new photometer in reverse sequence.
* Caution!
¾ Wait min. 0,5 h warm up time before starting measurement
The photometer itself must be in vertical position, solution inlet from the bottom,
outlet on top; the photometer is fixed between casing door rubber plate and casing rubber.
The larger the angle from the vertical position, the higher the risk for bubbles on hold inside the cuvette =
wrong reading of absorption!
Cleaning of the etches of the boards with alcohol or spirit recommended.
Photometer CA71-xx
3
2
P 1
R S
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Photometer CA71-SI-A
3
2
P 1
R S
Leak detector
connection
Photometer
Mixer
In order to examine and renew the cuvette in the photometer, the four screws on the side are loosened,
where the flat cable is not.
Afterwards the photometer block can be pulled apart.
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Sending part Receiving part
* Caution!
Positioning of the 2 LEDs for measuring light and for background compensation.
9.13 Photometer-construction standard cuvette
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Reference -LED Measuring-LED
Heating
Glass- cuvette
Receiver
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9.14 Photometer-construction 5 cm cuvette
Measuring-LED glass-cuvette receiver
* Caution!
Never touch cuvette never with the fingers; wear cotton gloves. Light absorption very sensitive to salt traces
etc..
Note!
There can be several reasons for deposits.
Alcaline cleaning agent can show in CA71AM such white internal blocking of the cuvettes.
Also in CA71PH-A already after one week w/o cleaning a blue-tinged deposit will change the absorption
(calibration factor decreases).
Examples:
Note!
After each manipulation at the cuvette or exchange the validity of the internal calibration curve has to e
checked (please refer to „standard values“).
The hoses connected to the cuvette must be accured with cable straps in every case.
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9.15 Exchange Photometer
Please pay attention to the following warnings for your own safety!
Please pay attention to the operating instructions of your CA71!
1. How to use
The parts of this service kit are only to be used as spare parts for instruments of Stamolys CA71 family.
Any other use is not permitted.
2. Handling of electronic modules

Electronic modules are sensitive against electrostatic discharge (ESD).
Before you take a module from its ESD protective packing, discharge yourself e. g. on a protective
conductor. A permanent earth connection, e.g. with ESD wristlet is recommended.
3. Electric safety rules

- Switch off mains before working at the instrument's terminals or opening the housing.
- Protect mains switch against accidental reactivation.
- Make sure that the instrument is dead.
- Please pay attention: switching contacts of the instrument may be supplied from circuits other than the
instrument itself. Switch off these circuits as well!
4. Working on voltage-carrying installations

If working on voltage-carrying installation is unavoidable, it is only allowed for properly trained
electrotechnical personnel.
5. Feedback to the process

Before switching off an active instrument, consider the feedback to your process.
Observe your process if it is controlled by the instrument via the switching contacts, via a bus system or
via the signal output and a PCS.
6. Rinse system with water in the service menu and then empty it.
7. Disconnect photometer lines from terminal 59, 61, 62, 63, 64, 65.
8. Removet black tube from tube adapter.
9. Remove cover from photometer.
10. Unscrew the two hexagon socket screws and remove photometer.
11. Place new photometer in reverse sequence.
12. Warning ! Wait min. 0,5 h warm up time before starting measurement.
13. Hold M down until AUTO MEASURING appears.
14. Use È to move through the Config Menu and press E.
15. Select the correct photometer with the È.
16. Select the correct measuring unit with the È.
17. Now load the default settings press both arrow keys È together Ç and wait some seconds.
18. press the E key to reach the submenu behind the analog output.
19. To go inside the submenu ( 0-20mA / 4-20mA ); touching with 4 fingers (both hands) - first „K“, then
„E“, „CE“ and „M“ (all 4 together), lifting the first finger from „K“ and in a split second also lifting from the
3 others.
20. Use È to reach the default setting in the submenu.
21. Now load the default settings press both arrow keys È together Ç and wait some seconds.
22. Go to the standard values with È.
23. Load the standard vakues with pressing both arrow keys È together Ç and wait some seconds.
24. Introduce the datas from the table which you have seen with the photometer unit. Put them inside. At
first the values and after them the frequencies.
Example:
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mg/l-P Hz
0,0 0
1,0 151
2,0 288
3,0 449
4,0 560
5,0 683
6,0 797
7,0 928
8,0 1026
10,0 1156
25. If all the points are inside press the M.

26. The instrument will go back to the config menu to default settings.
27. Press both arrow keys a fourth timeÈ together Ç and wait some seconds. Now the instrument can work
with the correct settings specific for the photometer-
28. Press M key twice to return to the main menu and than press E to come back to auto measurement-
9.16 Exchange EPROM
* Caution!
Before changing the EPROM note down all settings (incl. settings of service submenu)
EPROM need to be changed for software upgrade (photometer!)
EPROM only to be changed with analyzer disconnect from power before!
Notch helps for orientation - receiving frame (cavity) has the notch on the same side.
(pin 1 ident!) (label will not help for orientation)
Type 27 C 1001
= to be ordered including the new software
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To change the EPROM, please lift carefully from both sides to avoid bending of contacts. (a screwdriver will
help) For better access lift off the large flat band cable from CPU board.
* Caution!
Static Sensitive Device!Handle only at Static Safe Work Stations
Note!
After change of EPROM the settings has to be checked and renewed if necessary
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9.17 Adjustment analog output with Potentiometer
Potentiometer Position for analog output.

The second analog output carries also the 2 Potentiometers on the relevant spots.
An adjustment and lacqering is done in production.
To check the analog output:: switch equipment off. During switching on again keep keys È and Ç pressed.
In the display Iout = 0 mA appears. By pressing the key M 4, 12 up to 20 mA will appear at display and
analog output.
Best adjusts the writer on the analyzer. First 0/4 and then 20 mA. If it is not possible, make the alignment
with the potentiometers. Are normally factory-installed already correctly co-ordinated.
20 mA Poti
0/4 mA Poti
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9.18 Installation of a second analog output
for two channel version
A two channels equipment needs two current outputs, an additional board has to be set on the main board.
2 further plug possiblities are not active!
This 2nd current output will be connected at 38 (-) and 39 (+).

Kit CA71 upgrade into two-channel version: Order no.: 51512640 In the upgrade kit you will find all the
parts which are needed.
Note!
For upgrade to two channel an EPROM change is also necessary).
Before removing the old EPROM note down all settings (incl. settings of service submenu)
After change of EPROM the settings has to be checked and renewed if necessary
Placement of the board for 2nd current output, necessary for two channel version
Zweiter Analogausgang
Second analog output board
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9.19 Replacement or installation 2-channel valve board:
1. Rinse system with water in the service menu and then empty it.
2. Remove power supply.
3. Remove line from terminal 74 and 53.
4. Remove valve board.
5. Place new valve board in reverse sequence.
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2
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9.20 Instructions for service kits CA71 CPU module + eprom
* Caution!
Please pay attention to the following warnings for your own safety!
Please pay attention to the operating instructions of your CA71!
Note
Before exchange note down all settings (incl. settings of service submenu)
1. How to use
The parts of this service kit are only to be used as spare parts for instruments of Stamolys CA71 family.
Any other use is not permitted.
2. Handling of electronic modules
Electronic modules are sensitive against electrostatic discharge (ESD).
Before you take a module from its ESD protective packing, discharge yourself e. g. on a protective
conductor. A permanent earth connection, e.g. with ESD wristlet is recommended.
3. Electric safety rules
- Switch off mains before working at the instrument's terminals or opening the housing.
- Protect mains switch against accidental reactivation.
- Make sure that the instrument is powered off.
- Please pay attention: switching contacts of the instrument may be supplied from circuits other than the
instrument itself. Switch off these circuits as well!
4. Working on voltage-carrying installations
If working on voltage-carrying installation is unavoidable, it is only allowed for properly trained
electrotechnical personnel.
5. Feedback to the process
Before switching off an active instrument, consider the feedback to your process. Observe your process if
it is controlled by the instrument via the switching contacts, via a bus system or via the signal output
and a PCS.
6. Remove power supply.
7. To fold out Analyzer housing unscrew the two lower screws 3 or 4 turns and remove the upper screws (
hexagon socket screw key 6 ).
8. Remove flat cable from CPU module.
9. Remove fixing nuts to remove CPU module .
10. Place new CPU module in reverse sequence.
Befestigungsmutter
Fixing nuts
Stecker für
Flachbandkabel
Flat cable connector
Eprom
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9.21 Exchange of pump motor/ motor combinations
Motor positioning the same (picture below) for CA71AM, ..CU, ..AL, ..CR, ..FE, ..MN, ..NO, ..HA. (reagents
with step motor, sample with synchron motor pumped).
For all others positions inverted!
Direct connection without plugs from

step and synchromotor
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Placement of synchromotor and step motor
To change the motors, the cables have to be disconnected (screwdriver) and the fixing screws to be
unscrewed from the front side (4 Phillips screws per motor).
Synchron motor* 20 rpm/230V ORDER NO. 51504190
20 rpm/115V ORDER NO. 51504188
60 rpm/230V ORDER NO. 51504192
60 rpm/115V ORDER NO. 51504191
Step motor ORDER NO. 51504129.
*Reagent pumpe 20 rpm:AM-A,-B,-C;AL;CL;CR;CU;FE;NO;
60 rpm:HA-B;MN-A;NI;
*Sample pump 60 rpm:PH-A,-B,-C,-D;SI-A,-B;HA-A;
9.22 Extension of measuring range by dilution
A dilution is needed if the measuring value is higher than the measuring range. However, in these tests, the
color developed in the sample may be too intense to be measured due to high levels of analyte, or
unexpected colors may develop due to an interference. In either case, dilute the sample to produce a
measurable endpoint or to determine if interfering substances are present.
Note!
Accuracy of dilution will influence accuracy of measurement and errors of measuring value are multiplied
with dilution factor
Dilution can by realized in different ways:
Dilution by an external dilution modul with two peristaltic pumps and mixer
Sample and destilled water (or water which do not content the analyte) are mixed by the dilution module.
The dilution modul can work by
• using same motor speed and different hose diameters for sample and dilution water
• using different motor speed and same hose diameters for sample and dilution water
• or combination of both
The diluted mixture is fed to the analyzer sample inlet.
In this case the concentration of standard solution must be in the origin range of the analyzer. The tables in
chapter 9.22.1 (Dilution factors) shows relative quantities and the multiplication factors to use with our
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tubings. The concentration of the sample is equal to the diluted sample result multiplied by the multiplication
factor. This calculated dilution factors will only give a guideline for selection of hose combinations. After
realization of dilution by the dilution factor must be calculated an set in the menu configuration.
Concentration of the sample before dilution ÷ concentration of the diluted mixture
= dilution factor.
The determination of the solution should happen by laboartory tests.
Note!
The dilution factor has to be checked regulary by laboratory, because it will change by wear and tear of pump
hoses
Example
same motor speed and different hose diameters for sample and dilution water
Measuring range of the analyzer 0,2-15 mg/l
Concentration of the origin sample <=40 mg/l
Calculation of necessary dilution Conc. origin sample ÷ measuring range 40 ÷ 15 = 2,66
Selection of the hose combination Necessary dilution < therotical dilution factor Dilution water:
2,66 < 2,84 * violet-white/
sample: yellow
* out of theoritcal volumes blue
Calculation of the dilution factor to Conc. origin sample ÷ diluted sample 35 ÷ 12,5 = 2,8
be set in menu "Configuration" (detected in laboratory)
Concentration of standard solution e.g. 13 mg/l (suitable for measuring range and
sample concentration)
Concentration of standard solution 13mg/l
to be set in menu "Configuration"
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Example
different motor speed and different hose diameters for sample and dilution water
Motor speed of sample pump 20 upm
Motor speed of dilution water pump 60 upm
Calculation of dilution by pump Upm dilution water pump origin sample ÷ upm 60 ÷ 20 = 3
difference sample pump
Calculation of "pre-dilution" max. conc. origin sample ÷ dilution through 120 ÷ 3 = 40
through pump difference pump
Calculation of additional dilution by Conc. pre-diluted sample ÷ measuring range 40 ÷ 15 = 2,66
hoses
sample: yellow
Concentration of standard solution eg 13 mg/l (suitable for measuring range and
sample concentration)
Concentration of standard solution 13mg/l
Dilution by the sample pump of the analyzer

A second pump hose will be added to the sample pump, that is used to pump dilution water (destilled water
or water which do not content the analyte). Pump hose of sample and pump hose of dilution water are
connected via a T-Piece to the inlet of the mixer.
With this kind of dilution only dilution factors of max 3 can be reached, because no additional dilution by
different pump speed is possible.
Due to the fact that the standard during calibration will be diluted as well, the concentration of the standard
solution has to be adjusted.
Example
Calculation of necessary dilution max. conc. origin sample ÷ measuring range 40 ÷ 15 = 2,66
sample: yellow
Concentration of standard solution Conc. fitting to the measuring range (e.g. 13 x 2,8 = 36,4
13mg/l) x dilution factor
Concentration of standard solution Conc. of standard solution ÷ dilution factor 36,4 ÷ 2,8 = 13
Needed parts
51512086 KIT CA71 hose holder unit for pump to fix the dilution hose on the sample pump
51512096 KIT CA Y tube adapter 1.6*1.6*1.6 mm to connect both pump hoses (sample and dilution
water) together, before they enter the mixer
eg. 51506434 Pump tubings Tygon yellow/blue for use as dilution hose (dilution 1:1 will double the
measuring range
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Dilution water
3
2
P 1
R S
9.22.1 Dilutions by means of sample pump with different hoses

Black / black ID 0,76 mm
Violett / white ID 2,79 mm
Yellow / blue ID 1,52 mm
Yellow / yellow ID 1,42 mm
Calculation of the dilution only calculated with dimension of the tubings

( dilution is done on the same pump, that means same speed and constant dilution) :
Note!
Using black/black hoses for sample should only be done if there is no other solution. The small diameter
causes higher maintenance demand in case of danger of blocking
e.g. dilution water blue/yellow and sample black/black

(1,52/0,76)² = 4 dilution factor
e.g. violet/white dilution water and sample yellow/blue

(2,79/1,52)² = 3,37 dilution factor
e.g. dilution water violet/white and sample yellow/yellow

(2,79/1,42)² = 3,86 dilution factor
e.g. dilution water violet/white and sample black/black

(2,79/0,76)² = 13,48 dilution factor
Calculation of the dilution with theoretical volume:

Tubing color code ml/ rotation
Black/black 0,074 ml/min
Yellow/blue 0,26 ml/min
Yellow/yellow 0,23 ml/min
Violet/white 0,74 ml/min
e.g. dilution water blue/yellow and sample black/black

0,23/0,074 = 3,11 dilution factor
e.g. violet/white dilution water and sample yellow/blue

0,74/0,26 = 2,85 dilution factor
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e.g. dilution water violet/white and sample black/black
0,74/0,074 = 10 dilution factor
9.22.2 Sample Volume per minute
Tubing code Motor Sample volume with Sample volume/60 sec flushing
standard setup
Yellow / blue steppmotor 21 ml 15,75 ml 7 ml
Yellow / blue Synchronous motor 18 ml 13,5 ml 7 ml
Violett / white Synchronous motor 33,6 ml 16,8 ml 10 ml
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9.23 Extension of measuring range by changing the speed of step motor
The measuring range of the analyzer is fixed by the ratio of sample and reagent. Therefore change of this
ratio by changing of the speed of te step motor (service submenu, Rpm) will change the measuring range.
This technique can be used for extension of the measuring range or getting a higher accuracy in low
concentrations (with simultanous decrease of the measuring range!).
For increasing the measuring range the amount of reagent has to be highered or vice versa the amount of
sample during mixing lowered.
E.g in case of CA71AM sample is pumped by the step motor, Reagents are pumped by synchromotor. To
extend the measuring range the speed of stepmotor has to be lowered.
Note!
Pump speed below 5 upm are not satisfying, the accuracy of dosage is too bad
Before exploring the new calibration curve exchange of reagents and wear and tear parts is a must
Detection of the calibration curve should be done at least with 5 samples 20% / 40%/ 60%/ 80%/ 100% of
measuring range. If can be reduced to 3 samples (20% / 60% / 100%) when the curve is linear. Measure of
zero sample (destilled water) has to be done additionally. The frequency used for the data pairs mg/l // Hz
has to be calculated as follws:
(basis frequency - plateau frequency) of sample – (basis frequency - plateau frequency) of destilled water (Please refer
to page 26 ff)
For customized calibration curves the method of „standard addition“ is highly recommended, especcially
when the composition of the sample do not allows to work with the existing curve. Please refer to page 155
Note!
Each change of the ratio sample : reagents will need an adjustment of the internal calibration curve. Proper
documentation of all changes is a must!
How to proceed:
Note!
Documentate all your work (rpm, concentration, basis frequency, plateau frequency) in order to avoid double
work, getting a guidline for the next steps and having a chance to track back your work
1. Note down the actual settings (incl. service submenu) of the analyzer
2. Exchange all wear and tear parts, reagents and clean the photometer cuvette
3. Prepare a standard solution with the highest concentration the analyzer should measure
Use for preparation dilution of a high (eg 1g/l) standard solution with destilled water. Please refer to
chapter 12.2, Sample Dilution Techniques
Note!
Internal calibration curve is highly influencing the accuracy of the analyzer. Therefore proper preparation of
the different standard solutions is essential. Low concentrated standard solutions are not stable. Don't use
them longer than one day.
4. Set the analyzer in service submenu on mode " Lab calibration". Now frequencies will be stored in the
data storage
5. Connect Labtop to RS232 and start AnaWin
6. Change rpm dependent on ist actual value into the right direction. Have a look to the internal calibration
datas. (page 66) If two measuring ranges are mentioned there, use there rpm difference as guideline
7. Connect destilled water to the sample inlet and measure twice or more often if necessary.
The frequency shift is calculated as (basis frequency - plateau frequency) of destilled water (Please refer to page
26 ff) (both frequencies are stored in the datastorage)
8. Connect the prepared standard with high concentration to the sample inlet and measure twice or more
often, if necessary
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Observe in AnaWin if the frequency at the end of the measuring time still drops for more than 2 Hz.
Adjust trea in service submenu, if necessary
The frequency shift is calculated by (basis frequency - plateau frequency) of sample – (basis frequency -
plateau frequency) of destilled water
9. Is the frequency shift minimum as large as the frequency shift of the highest concentration of the origin
internal calibration curve?
Is the variance of both (or more) frequency shifts less than 3%?
10. If not, repeat steps 6 and 7 with smaller ratio (e.g. sample is added by stepmotor: increase rpm)
11. If yes, continue with the selected rpm
12. Prepare a standard that is less concentrated than the highest sample
The concentration should be in the same ratio to the highest concentration as the second highest sample
of the origin internal calibration curve to the highest concentration of the calibration curve (e.g highest
concentration of internal sample curve 10 mg/l, second highest concentration 8 mg/l (20% less). Your
highest concentration 40 mg/l , than you will need 32 mg/l
13. Connect destilled water to the sample inlet and flush the analyzer properly by switching on the sample
pump.
14. Connect the prepared standard with second highest concentration to the sample inlet and measure twice
or more often, if necessary
The frequency shift is calculated by (basis frequency - plateau frequency) of sample – (basis frequency -
plateau frequency) of destilled water
15. Is the frequency shift minimum as large as the frequency shift of the second highest concentration of the
origin internal calibration curve?
Is the variance of both (or more) frequency shifts less than 3%?
16. If not, repeat steps 6 -15 with smaller ratio (e.g. sample is added by stepmotor, increase rpm)
17. If yes, continue with the selected rpm
18. Connect destilled water to the sample inlet and flush the analyzer properly by switching on the sample
pump.
19. Prepare standard solutions with 20% / 40%/ 60% and 80%/ of measuring range. It can be reduced to
samples with 20% and 60% when the curve is linear
20. Connect the prepared standards with to the sample inlet and measure twice or more often, if necessary.
Start with the lowest concentration
The frequency shift of each standard is calculated by (basis frequency - plateau frequency) of sample – (basis
frequency - plateau frequency) of destilled water
21. Enter the datapairs concentration / frequency shift (basis frequency - plateau frequency) of sample – (basis
frequency - plateau frequency) of destilled water into Service submenu "Standard values". For the
concentration of 0mg/l add 0 Hz
22. Adjust the measuring range "MBmax" in service submenu to the requested value
23. Set "mode" in service submenu back to measuring mode
24. Adjust measuring range end in menu Parameter Entry
25. Fill in new standard for the new measuring range and adjust the setting in menu Parameter Entry
26. Enter the frequency shift of destilled water into "Frequency offset" in menu Configuration
27. Start a calibration with the new calibration standard
28. Measure some of the prepared standard solutions to verify your work
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Example of Documentation:
date 13.09.00 conc Basis Plateau Delta
/Parameter: Phos-M 0 6114 6087 27
serial no 10035 0 6113 6093 20
/serial no Photometer: 30050 0 6113 6092 21
/MB-E: 2,5 0 6114 6093 21
/EPROM-Version: 3.1 0,25 6106 6005 101
/step motor rpm: 8 0,25 6107 6003 104
/Sync motor rpm: 60 0,25 6107 6006 101
/sample tube: g-b 0,25 6107 6002 105
/reagent tube: g-b 0,5 6107 5919 188
/Fill: 16 0,5 6109 5919 190
/Rea: 360 0,5 6109 5916 193
/customer: E+H 0,5 6097 5918 179
0,75 6110 5829 281
0,75 6102 5820 282
0,75 6094 5823 271
0,75 6087 5812 275
1 6109 5758 351
1 6109 5763 346
1 6110 5760 350
1 6109 5755 354
1,25 6110 5683 427
1,25 6109 5670 439
1,25 6109 5683 426
1,25 6109 5677 432
1,5 6110 5606 504
1,5 6110 5609 501
1,5 6110 5605 505
1,5 6110 5597 513
1,75 6108 5508 600
1,75 6109 5500 609
1,75 6111 5502 609
1,75 6110 5503 607
2 6112 5421 691
2 6111 5415 696
2 6111 5417 694
2 6112 5415 697
2,5 6112 5267 845
2,5 6104 5267 837
2,5 6112 5287 825
2,5 6113 5275 838
conc. delta 1 Delta 2 Delta3 Delta 4 Delta delta Standard Frequency %-error from
average average - deviation shift per mg MBE
water value
0* 20 21 21 21 0* 0,577
0,25 101 104 101 105 103 81 * 2,062 328,33 0,3%
*
0,5 * 188 190 193 179* 190 169 * 2,517 339,33 0,3%
0,75 281 282 271 275 277 256 * 5,188 342,11 0,6%
*
1* 351 346 350 354 350 329 * 3,304 329,58 0,4%
1,25 427 439 426 432 431 410 * 5,944 328,27 0,7%
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*
1,5 * 504 501 505 513 506 485 * 5,123 323,39 0,6%
1,75 600 609 609 607 606 585 * 4,272 334,62 0,5%
*
2* 691 696 694 697 695 673 * 2,646 336,92 0,3%
2,25
*
2,5 * 845 837 825 838 836 815 * 8,302 326,23 1,0%
* used for calibration curve
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10 Error tracing and trouble-shooting
10.1 Trouble-shooting instructions

Although the CA 71 analyzer is not very prone to faults due to its simple assembly,
problems can, of course, not be completely ruled out.
Possible errors, their causes and their possible remedies are listed below.
10.2 System errors / process errors
Error Cause Solution of problem

Error message Principally a new calibration factor can be put in manually into
„calibration the configuration menu, if a calibration did not succeed. The
failed“ error message is then deleted by a short switching off of the
instrument. If the error occurs frequently, the cause must be
found and eliminated.
Air bubble in the Start calibration manually by changing date of 1. calibration in
system menu parameter entry and start the measurement or see above.
Incorrect Test concentration of the standard in laboratory and if necessary
concentration of the adjust in the menu parameter entry or add new standard .
standard
Incorrect dosage of Check pump hoses for wear and tear. Replace if necessary
standard or reagents
Reagents are Phosphate, ammonium: Mix approx. 10 ml of an ammonium or
contaminated or aged phosphated solution with 1 ml reagent each. If there is no
coloration after max. 10 minutes, the reagents must be
replaced.
Dosage of standard Check valves for contamination, obstruction (visual check)
solution incorrect Replace valve hoses if necessary
Wrong measuring cell Check setting in the configuration menu.
Error message Sedimented particles Rinse tube system of the sample line with 12.5% bleaching
„measuring cell of actuated sludge solution (sodium hypo chloride solution, pharmacy), allow to
soiled“ react for 10 min and thoroughly rinse again with water: Menu
service V1: P; P1: e, P2: a, V2: S, add solution to sample line.
When using an CAT430 or other filter system, check filter and
tubes.
Error message Wrong measuring cell Check setting in the configuration menu
„wrong measuring
cell“
Wrong restistance at In the photmeter electronic (main board) a restistor for
indicator resistor electrical identifying of the photometer type is included. Its
resistance can be changed by e.g. moisture. Dry the photometer
electronic. To allow measurement without error message, the
error can be blocked in service submenu.
Error message „no No sample Sample supply must be ensured.
sample“
Level measurement Check level measurement in sample collector.
defective
Error message Leak in cans or tubes Exchange defective components and clean and dry the affected
„spillage error”“ components.
"error report Leakage on the Check by disconnecting the black connector inside the
Endress+Hauser 135
spillage error and photometer photometer housing. Picture see chapter 9.12. If measurment
error report starts afterwards dry photometer or exchange.
photometer signal
Reason for leakage might be blockage at analyzer outlet or
failed
photometer and must be removed
Error message Photometer defective Exchange photometer

„no measuring
signal“
Electrical connection Check and establish connection.
Fuse defective Replace the fuses F4 or F5.
Measured values Reagents Phosphate, ammonium: Mix approx. 10 ml of an ammonium or

always the same contaminated or aged phosphated standard with 1 ml of reagent each.
(also refer to If there is no coloration after max. 10 min, exchange reagents
measured values
inaccurate)
No sample Ensure supply of samples and reagents. Check level control of
the sample collector, clean sample collector
no reagents
System clogged Rinse tube system of the sample line with 12.5% bleaching
solution (sodium hypo chloride solution, pharmacy), allow to
react for 10 minutes and thoroughly clean again with water.
Menu service. V1: P, P1: e, P2: a, V2: S, add solution to
sampling tube.
Measured values Incorrect Check concentration of standard in the laboratory and if
inaccurate concentration of necessary, adjust in menu parameter entry or replace the
standard standard.
Check calibration factor.
Reagents are too old, Phosphate, ammonium: Mix approx. 10 ml of an ammonium or
or contaminated phosphated solution with 1 ml of reagent each.
If there is no coloration after max. 10 min, exchange reagents
(see capter 9.3
Reagent blind, Calibrate frequency offset after exchange of the reagents and
frequency offset perform then a calibration
Wrong dimension Check setting of "measuring unit" in the configuration menu,
e.g. NO3 instead of NO3-N.
Total-P instead of orthophosphate is determined for comparisn
in the laboratory
Wrong measuring cell Check in the configuration menu "Photometer"
Sample suction time Increase "delay to sample" in menu Configuration
too short
Interferences Clarify matrix (see technical information, measuring principle)
or perform "Standard addition technique to verify matrix
effects. Use stabilized sample as standard
standard is dosed to Check valves and valve settings. Replace valve hoses if
the sample necessary
Measured values Concentration of Check concentration of standard in the laboratory and if
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inaccurate standard necessary, adjust in menu parameter entry or replace standard.
Check calibration factor.
Filter standing time Take counter-sample analyzer at the sample inlet of the
too long instrument. If there are no deviations in this sample, clean ultra
filtration modules or backflush filters more often.
System clogged or Rinse tube system of the sample line with 12.5% bleaching
soiled solution (sodium hypo chloride solution, pharmacy), allow to
react for 10 min. and thoroughly rinse again with water: menu
service: V1: P, P1:e, P2:a, V2:S, add solution to the sampling
tube.
Replace tubes of analyzer and filter system if necessary
Incorrect dosing of Perform visible check of pump hoses and exchange if necessary.
sample or reagents
Laboratory test, Reduce time between sampling and analysis.
sample aging Measure defined standards for check of laboratory procedure.
Sample suction time Increase "delay to sample" in menu Configuration
too short
Measured value Analog output Check in the configuration menu and adjust 0-20 or 4-20 mA.
transmission incorrectly
faulty dimensioned
Incorrect measuring Adjust in menu parameter entry.
range
background noise Test if there are disturbances due to heavy induction sources in
the line.
Impossible to No power Check and ensure power supply.
switch on
analyzer
Fuse Replace fuse F1 (time lag 0,5 A) .
Analyzer runs but Initialization failed Turn off analyzer and turn on again after approx. 30 sec.
display is garbled
or off
Leakage on the Customer service
photometer
Pumps fail to run Fuse Check fuse F2 replace them if necessary.
Pump defective Replace pump
Leak Refer to "spillage error" error mesage
Leak sensor bypassed Interrupt contact between two leak sensor (pins 67-66)
Pumps Condensor C83 Condensor looks like "blown up". Replace condensor or main
(synchromotor) defective board
fail to run or turns
into wrong
direction
Peaks in power Insure correct and stable power supply
supply
Wrong pump Wrong photometer Check configuration menu
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starts type selected in
Parameter setting
Display “Wait” measuring interval change parameters
not finished
Diplay sample collector Ensure sample supply

measurement empty
flushes
Time of 1st change parameters. The date must be between 01.01.96 and
Measurement not the current date
reached
measuring interval check parameters
not finished
Measuring doesn’t Leak in the system Please refer to error message “Spillage error”
start
“1. measuring” not The date must be between 01.01.96 and the current date
reached
Leak detector is Interrupt contact of the two leak detectors.
bypassed
Leak at photometer Check by disconnecting the black connector inside the
photometer housing. Picture see chapter 9.12. If measurment
starts afterwards dry photometer or exchange.
calibration doesn’t “1. calibration” not The date must be between 01.01.96 and the current date
start reached
calibration interval change parameters
not finished or 0h
Leak in the system Please refer to error message “Spillage error”
bridged
flushing doesn’t “1. flushing” not The date must be between 01.01.96 and the current date
start reached
Leak in the system Please refer to error message “Spillage error”
bridged
starts afterwards dry photometer or exchange
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flushing interval not change parameters
finished or 0h
Leakage on the Clogging in the Check by disconnecting the black connector inside the
photometer device or drain line photometer housing Picture see chapter 9.12. If measurment
Clogging, deposit hardness of the water Ammonium: Lime deposits can be removed by using 5%
in the device hydrochloric acid as a cleaning solution. The automatic cleaning
must occur without fail after calibration
Nitrate: Proportioning EDTA into the sample flow, in order to
prevent precipitation of plaster
inadequate sample shorten cleaning intervals of the sample preparation
preparation
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Error: measuring does not start
¾ Leakage inside the photometer: Error message: Spillage error + no phomtometer signal. To test if this is
the reason, open the photometer box and disconnect the black wire cable connector at the photometer.
(see page 57/58 of service manual) When the sample pump works afterwards, the leakage is confirmed.
In this case please check proofness of the hose connections to the photometer in- and outlet. Take out
the black rubber mats and dry them.
¾ Leakage of the photometer is normaly based on missing cable taps or blockage of the outlet. "Free outlet"
should be checked as well.
¾ Leakage inside the Analyzer: Error message: spillage error. To test if this is the reason disconnect the
wire at clamp 66. When the sample pump works afterwards, the leakage or shortcut is confirmed.
¾ In this case check, if there is no moisture or shortcut of the leak detectors inside the reagent
compartment and on the bottom of the analysis part
¾ Leakage in the analyzer compartment is normaly based on blockage of the outlet or wear and tear of
tubing
¾ sample collector is not filled or has an internal error: To test if this is the reason disconnect the
connector from the sample connector box and start the measurement again. If it works, the error is
confirmed.
¾ Check if the sample collector works properly, by setting the analyzer into measuring mode and filling the
sample collector with tap water (no destilled water, because it will need conductivity)
¾ If the analyzer do not start although the sample collector is filled, disconnect the connector again to mask
this error and make measurement possible. Order a new sample collector
¾ Photometer defective or dirty: Error message: no photometer signal or measuring cell dirty. Frequency of
photometer is 0 or 1000 Hz
¾ Check if connections of photometer are proper (when frequency is 0 Hz) or clean photometercuvette
with bleaching lye (when frequency is 1000 Hz)
¾ Exchange of the photometer cuvette might be necessary if cleaning wasn't successfull.
¾ Condensor of synchromotor defective. Visual check: do the condensor looks like blown up. The
condensator is the brown one on the left hand side of the middle positioned fuse. (position C83 of
drawing page 103 in service manual) The capacity this is written on the synchromotor.
Fuses for the photometer
• Fuses of pump or photometer defective or no correct contact between fuse and holder. Please Safety
devices for the photometer take and examine. Mounting plates squeeze together and safety device
replace. The fuses are placed on the ground platine.
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Error: Calibration not possible
¾ While the calibration press the two arrow keys. In the display the announcement of the current
frequency appears.
¾ During the rinsing phase the frequency value goes upward and remains then there stable. (e.g. 6000 Hz)
¾ After addition of the reagent the frequency drops and should not rise any longer during the response
time. (e.g. 5400 Hz).
¾ If the frequency rises however again (e.g. from 5400 to 5700 Hz), then it is an indication, which does
not close a pinch valve correctly. Examine please the seat of the hoses in the valves.
¾ Usually here the hose of the sample does not sit correctly, i.e. during the calibration the standard is
constantly mixed with sample, so that the standard is diluted and no stable frequency announcement is
reached.
¾ Hose examine and check for correctly sit. If this is damaged. Hose renew.
¾ Release afterwards new calibration. Is from this still no calibration possible. The hose of the standard
solution examine whether it opens correctly. If this is the case. Hose renew.
Error: No stable reading
Measurements going up and down. Each measurement shows another value of reading.
¾ While the measurement press the two arrow keys. In the display the announcement of the current
frequency appears.
¾ During the rinsing phase the frequency value goes upward and remains then there stable. (e.g. 6000 Hz)
¾ After addition of the reagent the frequency drops and should not rise any longer during the response
time. (e.g. 5600 Hz).
¾ If the frequency rises however again (e.g. from 5600 to 5700 Hz), then it is an indication, which does
not close a pinch valve correctly. Examine please the seat of the hoses in the valves.
¾ Usually here the hose of the sample does not sit correctly, i.e. during the measurement the sample with
chemicals is constantly mixed with sample, so that the sample is diluted and no stable frequency
announcement is reached.
¾ Hose examine and check for correctly sit. If this is damaged. Replace hoses.
¾ Release afterwards new measurement. Is from this still no stable measurement possible. The hose of the
sample examine whether it opens correctly. If this is the case. Hose renew.
As in the picture to see the upper C-Flex-hose is not pressed. It is in the valve 1 the sample hose or in the
valve 2 the hose for the standard solution. The other side of the pinch valve can be opened, by changing over
in the service menu with valve 1 from P to S. it is now here the hose open, which supplies either standard or
cleaner of the valve 2. At the valve 2 normally the standard is openly through changes over in the service
menu from S to C can here then also the hose by the cleaner be renewed.
Valve 1 Valve 2
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10.3 Chemical interferences
The independence of an analysis process with regard to disturbance components is known as “selectivity”.
Possible selectivity interferences (transverse sensitivities):

1. High concentrations of oxidisable, organic matter which lead to coloration
2. High salt concentrations
3. pH values in extreme acidic or alkaline ranges
10.3.1 Interference for Ammonium measurement

no interferences up to the given concentration
10.3.2 Interference for chlorine measurement

Possible interferences to chlorine measurement due to:
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10.3.3 Interference for chromate measurement
10.3.4 Interference for copper measurement

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10.3.5 Interference for manganese measurement
10.3.6 Interference for nitrite measurement

10.3.7 Interference for phosphate measurement

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10.3.8 Interference for silicate measurement
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11 Circuit plans
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12 General Laboratory instructions
12.1 Basics
• Refer to the safety data sheets when handling reagents.
• Wear protective clothing, protective gloves and protective goggles when handling reagents. If you have
an accident or you feel unwell, consult a physician immediately.
• If reagents come into contact with the eyes, carefully rinse with copious amounts of water with the
eyelid open. If reagents come into contact with the skin, carefully rinse with copious amounts of water.
Consult a physician immediately!
• Rinse bottles, flasks, zylinders, pipetes with destilled water directly after using them.
• If bottles, flasks, zylinders, pipetes are not dry, rinse them with the solution that should be filled in.
• The less operation steps the less the mistakes.
• The larger the used volumes the less the mistakes.
• Cuvette tests with uses less than 0,2 ml sample are not recommendable.
• The statistical safety via correctness of a value increase with the number of the analyses
• Bottles, flasks, zylinders with applied solutions must become labeled with contents, concentration and
date of manufacture.
• As dilution water is always distilled and/or DE-ionized water to be used
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12.2 Sample Dilution Techniques
In some tests, the color developed in the sample may be too intense to be measured. Unexpected colors may
develop in other tests. In both cases, dilute the sample to determine if interfering substances are present. If a
sample must be diluted, use a pipet, graduated mixing cylinder and/or a volumetric flask for accurate
measurement. When diluting, accuracy is important because a slight mistake in measuring a small sample
will cause a substantial error in the result. For instance, a 0.1-mL mistake in the dilution of a 1.0-mL final
volume produces a 10% error in the test result. Therefore a final volume of minimum 50 ml is recommended.
To dilute the sample easily, pipet the chosen sample portion into a clean graduated cylinder (or volumetric
flask for more accurate work). Fill the cylinder (or flask) to the desired volume with deionized water. Mix
well. Use the diluted sample when running the test. The concentration of the sample is equal to the diluted
sample reading multiplied by the multiplication factor. More accurate dilutions can be done with a pipet and
a 100-ml volumetric flask. Pipet the sample and dilute to volume with deionized water. Swirl to mix.
To dilute a sample with a concentration overrange, the following formular could be used for calculation of the
sample amount
Vcylinder [ml ]× c halfMeasuringRange mg 

 l 
V Pipet [ml ] =
cundilutedSample mg 
 l 
Vpipet: How much of the sample has to be filled into the measuring cylinder or volumetric flask? If
Vpipet could not be realized with the pipet in max 2 steps or volume is not able to be added
with the pipet, take the next smaller volume.
Vcylinder: Filling volume of the measuring cylinder or volumetric flask
ChalfMeasuringRange: Half of the measuring range of the used test. Remark: If Vpipet could not be realized with
the pipet in max 2 steps or volume is not able to be added with the pipet, take the next
smaller volume.
CundilutedSample: aprox. concentration of the undiluted sample
The measurement result has to be multiplied with the dilution factor:

VCylinder [ml ]
DilutionFactor =
V Pipette [ml ]
12.3 Correcting for Volume Additions

If you use a large volume of preservative, correct for the volume of preservative added. This accounts for
dilution due to the acid added to preserve the sample and the base used to adjust the pH to the range of the
procedure. This correction is made as follows:
1. Determine the volume of initial sample, the volume of acid and base added, and the total final volume of
the sample.
2. Divide the total volume by the initial volume.
3. Multiply the test result by this factor.
Example:
A one-liter sample was preserved with 2 mL of nitric acid. It was neutralized with 5 mL of 5 N sodium
hydroxide. The result of the analysis procedure was 10.00 mg/L. What is the volume correction factor and
correct result?
1. Total Volume: 1000 ml + 2 ml + 5 ml= 1007 ml
2. Volume correction factor: 1007:1000 = 1,007
3. Correct result: 10,00 mg/l x 1,007 = 10,07 mg/l
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12.4 Using Pipets and Graduated Cylinders
When small sample quantities are used, the accuracy of measurements is

important. illustrates the proper way of reading the sample level or the meniscus
formed when the liquid wets the cylinder or pipet walls.
Rinse the pipet two or three times with the sample to be tested before filling. Use
a pipet filler or pipet bulb to draw the sample into the pipet. Never pipet
chemical reagent solutions or samples by mouth. When filling a pipet, keep the
tip of the pipet below the surface of the sample as the sample is drawn into the
pipet.
Mark bottles, flasks, zylinders etc. always with describtion of the filled in solution
(contents, concentration, date)
Rinse bottles, flasks, zylinders with destilled water directly after using them.
12.5 Using volumetric pipets

Volumetric (transfer) pipets have a bulb in the middle and a single ring above the bulb to indicate the volume
of liquid when it is filled to the mark. Accuracy of volumetric pipets is better than TenSette pipets but
influenced by handling. In case of not trained personal the use of TenSette pipets is recommended.
1 Rinse the pipet two or three times with the sample to be tested before
filling. Use a pipet filler or pipet bulb to draw the sample into the pipet.
Never pipet chemical reagent solutions or samples by mouth. When
filling a pipet, keep the tip of the pipet below the surface of the sample as
the sample is drawn into the pipet.
2 Fill the the pipet over the mark with the liquid
3 Remove drops from pipet tip by using a towel
4 Discharge the liquid until the mark is reached
Endress+Hauser 165
5 Transer the pipet to the flask where the liquid has to be filled in.
To discharge the volumetric pipet, hold the tip of the pipet at a slight
angle against the container wall and drain. Do not attempt to discharge
the solution remaining in the tip of the pipet after draining. Volumetric
pipets are designed to retain a small amount of sample in the pipet tip. If
sample drops stay on the walls of the pipet, the pipet is dirty and is not
delivering the correct amount of sample. Wash the pipet thoroughly with
a laboratory detergent or cleaning solution and rinse several times with
deionized water.
12.6 Using the TenSette Pipet

For best results use a new tip each time you pipet. After several uses, the pipet tip may retain some liquid,
causing inaccurate delivery. Always use careful, even hand movements for best reproducibility. If the pipet
does not operate smoothly, disassemble and coat the piston and retainer with high-quality stopcock grease.
Also coat the metering turret lightly with grease. Refer to the TenSette Pipet manual. For best pipetting
accuracy, the solution and the room temperature should be between 20-25 °C. Never lay the pipet down
with the liquid in the tip. Solution could leak into the pipet and cause corrosion.
Pipette accuracy has to be tested minimum once a year or after events that may influence the accuracy, e.g.
falling on the ground. Test take place by checking the delivery volume with an analysis weight scale. If
equipment is not available pipette can be send to Conducta for check.
Attach a clean tip by holding the pipet body in one hand and gently pressing the
large end of the pipet tip onto the tapered end of the pipet. Be sure a good seal is
obtained
Turn the turret cap to align the desired volume with the mark on the pipet body
Using a smooth motion, press down on the turret cap until it reaches the stop.
Immerse the tip about 5 mm (1/4 inch) below the solution surface to avoid
drawing air into the pipet. Do not insert the tip any deeper or the delivery
volume may be affecte
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While maintaining a constant pressure, allow the turret to return slowly to the
extended position. A rapid return may affect the delivery volume.
With the turret up, take the tip out of the solution and move it to the receiving
vessel. Do not press on the turret cap while moving the pipet.
Use the thumb and forefinger to twist the turret cap to the next higher volume
position to ensure quantitative transfer of the sample. The “F” position provides
full blowout
With the tip in contact with the side of the receiving vessel, slowly and smoothly
press down on the turret cap until it reaches the stop and the solution is
completely discharged.
Note: Tips are made for one way use! Using them more often influence its delivery volume.
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12.7 Interferences
Substances in the sample may interfere with a measurement. If you get an unusual answer, a color that you
don’t expect, or you notice an unusual odor or turbidity, the result may be wrong. Wich substance interfer
wich analysis is described in the analysis method. More information about interferences and methods to
overcome them is contained in Standard Additions.
Standard addition could also be used to check if there is an interference to Stamolys Analyzer
REQUIRED APPARATUS and reagents

Pipet, TenSette ® , 0.1 to 1.0 mL (19700-01)
Pipet Tips, for 19700-01 TenSette ® Pipet (21856-96)
Volumetric flask 100 ml or Cylinder, graduated, mixing, 100-ml
Funnel
Filter paper
beaker
pH Paper
Thermometer
Nitrogen, Ammonia Standard Solution, Voluette ampule, 50 mg/L NH 3 –N, 14791-10
Nitrate Nitrogen Standard Solution, Voluette Ampule, 500 mg/L (NO3 - -N), 10 mL, 14260-10
Phosphate Standard Solution, Voluette ampul, 50 mg/L as PO 4 3- , 10 mL, 171-10
Cuvette test for analyt
12.8 Standard addition
1. Add e.g.1 ml of Standard Solution into a 100-ml volumetric flask or

graduated zylinder. If the flask is not dry, rinse it two or three times with
the filtered sample.
Amount of addition depends on concentration of the used standard
solution, expected concentration of sample and measuring range of the test.
But addition of more than 10 ml of Standard solution into 100ml flask is
not recommended to reduce the influence of dilution effects.
2. Fill the flask (or zylinder) to the desired volume with the filtered sample.
Mix well.
3. Create a second and third standard addition solution by repeating step 1-2 with the double and
tripple amount of standard solution
4. Analyze the standard addition solutions with the cuvette test.

Calculation of the concentration increase:
Vaddedsolution [ml ]× c s tan dardsolution mg 

 l 
cincrease mg  =
 l  V flask [ml ]
Example: adding 2 ml of nitrate standard solution with concentration of
500 mg/l-N into 98ml of a sample with a concentration of 5 mg/l-N will
increase analysis result for 10 mg/l-N to 15 mg/l-N
Endress+Hauser 168
5. If you get about 100% recovery for each addition, everything is working right and your results are
correct. If you don’t get about 100% recovery for each addition, a problem exists. You can tell if you
have an interference. Repeat the Standard Additions using deionized water as your sample. If you get
about 100% recovery for each addition, you have an interference. If you didn’t get good recoveries
with the deionized water, the following checklist may help to find the problem quickly:
a) Are you using the proper reagents in the proper order? Are you using correct amount of sample?
b) Are you waiting the necessary time for color to develop?
c) Are you using the correct glassware?
d) Is the glassware clean?
e) Does the test need a specific sample temperature?
f) Is the sample’s pH in the correct range?
g) Check your reagents. Repeat the Standard analysis using new, fresh reagents. If your results are
good, the original reagents were bad.
h) Check the performance of your instrument. (see DR/2010 Instrument Manual.)
i) Check the performance of the volumetric devices
j) If nothing else is wrong, the standard is almost certainly bad. Repeat the Standard analysis with a
new standard
6. Dilution may help to reduce the interferences by diluting the interferent:

Repeat the test on a sample diluted with deionized water; see Sample
Dilution Techniques.
Compare the result (corrected for the dilution) with the result of the
original test. If these two are not close, the original result may be wrong
and you should make an additional dilution to check the second test (first
dilution). Repeat this process until you get the same corrected result twice
in a row.
Endress+Hauser 169
13 Conversation tables chemical formulas
Concentration of e.g. ammonium can be given as the concentration of the molecul (NH4) or as concentration
of nitrogen, that is included in ammonium (NH4-N) The difference between both is a factor, that is based on
the atomic weights.
The analyzers measure the molecule, but are able to calculate the concentration of the atom (eg. N out of
NH4) by internal division through the factor.
Most of the laboratory photometers for cuvette tests (e.g. Hach DR2010) have the same option. Sometimes
deviation of laboratory result and analyzer result is simply based on the fact, that different concentration units
(e.g. NH4 and NH4-N) are calculated internally. In this case change the measuring unit of the lab device or
analyzer
Remark:
In waste water applications the unit NH4-N, NO3-N or PO4-P is common.
In industrial or potable water application in most of the cases the concentration of the melecul (e.g. NH4) is
common
NO2- Nitrite
NO2 - - N Nitrite - Nitrogen
N = 14 O = 16 1 NO2- = 46 1NO2+ - N = 14
15 x 46
15 mgNO2- - N = ?? mgNO2- = = 66,42mg NO2-
14
( Factor 3.29 )
NH 4+ Ammonia
NH 4+- N Ammonia- Nitrogen
N = 14 H = 1 1 NH 4+= 18 1NH 4+- N = 14
15 x 18
15 mgNH 4+- N = ?? NH 4+ = = 19,3mg NH4+
14 ( Factor1.28 )
NO3- Nitrate
NO3 - - N Nitrate -Nitrogen
N = 14 O = 16 1 NO3- = 62 1NO3+ - N = 14
15 x 62
15 mgNO3- - N = ?? NO3- = = 66,42mg NO3-
14
( Factor 4.43
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PO43- Phosphat
PO43- - P PhosphatePhosphorou
P = 31 O = 16 1 PO43-= 95 1PO43-- P = 31
10 x 95
10 mgPO43-- P = ?? PO43- = = 30,6mg PO43-
31 ( Factor3.06 )
The amount P in PO43- is

¾(P/PO43-) X 100
3-
¾(31/95) X 100 = 33% P in 4
¾So every3 mg/L PO43- 1 mg/L P
¾or 1 mg/L P = 3 mg/L 43-
P2O5 Phosphorous-Pentoxide
P2O5 - P Phoshorous-Pentoxide - Phosphorous
P = 31 O = 16 1 P2O5= 142 1 P2O5 - P = 31
10 x 142
10 mg P2O5 - P = ?? mg P2O5 = = 22,9 mg P2O5
2 x 31 ( Factor 2.29 )
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14 Copy sheets
to Fax-No.:
11.1 Telefax reagents order

to (address E+H-sales center) from (invoice address)
Company:........................................................
.......................................................................
Street: .............................................................
Poc/place: .......................................................
Fax/ phone:.....................................................
Delivery address (if it’s not the same then the invoice address)
Company / name: ...............................................................................................................................
street / poc / place: ............................................................................................................................
Chemicals for Stamolys-Analyser-Aluminium
Quantity order-no. description

CAY939-V10AAE Reagent solution AL1 for 71AL,1l
Reagent solution AL2 for 71AL,1l
Reagent solution AL3 for 71AL,1l
CAY942-V10C10AAE Standard-solution 100 µg/l Al for CA70/71AM,1l
CAY942-V10C25AAE Standard-solution 250 µg/l Al for CA70/71AL,1l
CAY942-V10C50AAE Standard-Lösung 500 µg/l Al for CA70/71AL,1l
CAY942-V10C88AAE Standard-Lösung 1000 µg/l Al for CA70/71AL,1l
Reagents for Stamolys-Analyser-Ammonia
Quantity order-no. Description

CAY140-V10AAE Reagent solution AM1 for CA70/71AM, 1l Reagent
solution AM2 for CA70/71AM, 1l
CAY141-V10AAE Cleaner for CA70/71AM, 1l
CAY142-V10C01AAE Standard 100 µg/l NH4-N for CA71AM, 1l
CAY142-V10C02AAE Standard 500 µg/l NH4-N for CA71AM, 1l
CAY142-V10C05AAE Standard 5 mg/l NH4-N for CA70/71AM, 1l
CAY142-V10C10AAE Standard 10 mg/l NH4-N for CA70/71AM,1l
Endress+Hauser 172
Endress+Hauser 173
Reagents for Stamolys-Analyser-Chrom

CAY846-V10AAE Reagent solution CR1 for CA70/71CR, 1l activ Reagent solution
CR2 for CA70/71CR, 1l activ
CAY846-V10AAH Reagent solution CR1 for CA70/71CR, 1l inactiv Reagent solution
CR2 for CA70/71CR, 1l inactiv
CAY848-V10C10AAE Standard-solution 1 mg/l CrVI for CA70/71CR, 1l
CAY848-V20C20AAE Standard-solution 2 mg/l CrVI for CA70/71CR, 1l
Reagents for Stamolys-Analyser-Copper

CAY850-V10AAE Reagent solution CU1 for CA70/71CU, 1l Reagent solution
CU2 for CA70/71CU, 1l
CAY852-V10C10AAE Standard 1,0 mg/l Cu for CA70/71CU,1l
CAY852-V10C20AAE Standard 2,0 mg/l Cu for CA70/71CU,1l
Reagents for Stamolys-Analyser-Chromater

CAY846-V10AAE Reagent solution CR1 for CA70/71CR, 1l Reagent solution CR2
for CA70/71CR, 1l
CAY848-V10C10AAE Standard 1,0 mg/l Cr for CA70/71CR,1l
CAY848-V10C20AAE Standard 2,0 mg/l Cr for CA70/71CR,1l
Reagents for Stamolys-Analyser-free and total Chlorine

CAY543-V10AAE Reagent solution CL1 for CA70/71CL free Chlorine, 1l
Reagent solution CLl for CA70/71CL free Chlorine, 1l
activ
CAY543-V10AAH Reagent solution CL1 for CA70/71CL free Chlorine, 1l
inactiv
CAY546-V10AAE Reagent solution CL1 for CA70/71CL total Chlorine, 1l
activ
CAY546-V10AAH Reagent solution CL1 for CA70/71CL total Chlorine, 1l
inactiv
CAY544-V10AAE cleaner CL for CA70/71CL,1l
Endress+Hauser 174
Reagents for Stamolys-Analyser-Hardness

Reagent solution HA-A1 for CA71HA-A, 1l Reagent solution
CAY748-V10AAE
HA-A2 for CA71HA-A, 1l
CAY749-V10AAE Reagent solution HA-B1 for CA71HA-B, 1l Reagent solution
HA-B2 for CA71HA-B, 1l
CAY745-V10C10AAE Standard 10 mg/l CaCO3 for CA70/71HA, 1l
Reagents for Stamolys-Analyser-Hydrazine

CAY540-V10AAE Reagent solution HY1 for CA70/71HY, 1l
CAY541-V10AAE Cleaner for CA70/71HY, 1l
CAY542-V10C50AAE Standard 400 µg/l N2H4 for CA70/71HY, 1l
Reagents for Stamolys-Analyser-Iron

CAY840-V10AAE Reagent solution FE1 for CA70/71AM, 1l
CAY842-V10C05AAE Standard-solution 100 µg/l Fe for CA70/71FE,1l
CAY842-V10C20AAE Standard-solution 2,0 mg/l Fe for CA70/71FE,1l
Reagents for Stamolys-Analyser-Manganese

CAY843-V10AAE Reagent solution MN1 for CA70/71MN, 1l activ Reagent solution
MN2 for CA70/71MN, 1l activ
Reagent solution MN3 for CA70/71MN, 1l activ
CAY843-V10AAH Reagent solution MN1 for CA70/71MN, 1l inactiv Reagent
solution MN2 for CA70/71MN, 1l inactiv
Reagent solution MN3 for CA70/71MN, 1l inactiv
CAY844-V10AAE Cleaner for CA70/71MN, 1l
CAY845-V10C10AAE Standard 100 µg/l Mn for CA70/71MN, 1l
CAY845-V10C50AAE Standard 500 µg/l Mn for CA70/71MN,1l
Endress+Hauser 175
Reagents for Stamolys-Analyser-Nitrite

CAY343-V10AAE Reagent solution NO1 for CA70/71NO, 1l activ
CAY343-V10AAH Reagent solution NO1 for CA70/71NO, 1l inactiv
CAY344-V10AAE Cleaner for CA70/71NO, 1l
CAY345-V05C25AAE Standard-stock solution 250 mg/l NO2-N for CA70/71NO, 1l
Reagents for Stamolys-Analyser-Phosphate

CAY240-V10AAE Reagent solution PH1 for CA70/71PH-A+C,1l activ Reagent
solution PH2 for CA70/71PH-B+D,1l activ
CAY240-V10AAH Reagent solution PH1 f.CA70/71PH-A+C,1l inactiv Reagent
solution PH2 f.CA70/71PH-B+D,1l inactiv
CAY243-V10AAE Reagent solution PH1 for CA70/71PH-B+D,1l activ
CAY241-V10AAE Cleaner for CA70/71PH, 1l
CAY242-V10C01AAE Standard 1 mg/l PO4-P for CA70/71PH, 1l
CAY242-V10C03AAE Standard 1,5 mg/l PO4-P for CA70/71PH, 1l
Reagents for Stamolys-Analyser-Silicate

CAY643-V10AAE Reagent solution SI1 for CA71SI, 1l activ Reagent solution SI2 for
CA71SI, 1l activ Reagent solution SI3 for CA71SI, 1l activ
CAY643-V10AAH Reagent solution SI1 for CA71SI, 1l inactiv Reagent solution SI2 for
CA71SI, 1l inactiv Reagent solution SI3 for CA71SI, 1l inactiv
CAY642- Standard 100 µg/l SiO2 for CA70/71SI, 1l
V10C01AAE
V10C05AAE
V10C10AAE
Endress+Hauser 176
Reagents for Ultrafiltration

CAY746-V01AAE cleanerP3-ULTRASIL 130 cautic 100ml
CAY746-V10AAE cleanerP3-ULTRASIL 130 cautic 1l
CAY746-V50AAE cleanerP3-ULTRASIL 130 cautic 5l
CAY747-V01AAE cleanerP3-ULTRASIL 73 acid 100ml
CAY747-V10AAE cleanerP3-ULTRASIL 73 acid 1l
CAY747-V50AAE cleanerP3-ULTRASIL 73 acid 5l
Place Date Signature
Endress+Hauser 177
11.2 Fax order maintenance parts
on (to address of your E+H agency see overleaf BA) of (bill-to-address)
Company:........................................................
Reference: .......................................................
Road:...............................................................
Postal code/place:............................................
Fax / telephone: ..............................................
Ship-to-address (if deviating from above address)

Company/name: .................................................................................................................................
Road/postal code/place:......................................................................................................................
Maintenance kit
Quantity ORDER NO. Description

Chromate, Chlorine (C+D)-Analyser

CAV740-4A Maintenance kit CA 7X SI Silicate-Analyser and CA71Cl Chlorine-
Analyser (A+B)
Endress+Hauser 178
Spare parts for maitenance and service
Quantity Pos. peace/pack. Order no Description

110 12 51506434 Pump tubings Tygon yellow/blue
111 12 51506435 Pump tubings Viton yellow/yellow
111 12 51506437 Pump tubings Tygon black/black
110 12 51508945 Pump tubings Tygon violet/white Silicate
120 15 m 51504116 Hose made of Norprene 1,6 mm
121 7,5 m 51504114 Hose made of C-Flex 3,2 mm
122 7,5 m 51504115 Hose made of C-Flex 6,4 mm
123 1m 51512535 Hose made of C-Flex 1,5 mm for new valve
130 10 51506495 Hose adapter 1,6 x 1,6 mm
131 10 51506490 Hose adapter T 1,6 x 1,6 x 1,6 mm
132 10 51506491 Hose adapter 3,2 x 3,2 mm
10 51506493 Hose adapter T 6,4 x 6,4 x 6,4 mm
10 51506494 Hose adapter 6,4 x 6,4 mm
133 10 51506492 Hose adapter 3,2 x 6,4 mm
134 10 51512096 Hose adapter Y 1,6 x 1,6 x 1,6 mm
2 51505778 Cuvette for photometer
1 51512089 Sample vessel with level detection
1 51512088 Sample vessel w/o level detection
10 51512099 connection nipple sample vessel
51508628 silicon hose ID1.6*OD3.2*WT0.8 (per metre)
51512535 C-Flex hose ID1.5*OD3.2*WT0.8 (per metre)
2 51512101 mixer module
1 51512085 head with rolls for peristaltic pump
1 51512086 hose holder unit for pump
1 51512102 collecting basin
2 51512103 leakage sensor f. collecting basin
2 51512104 drain pipe with hose nipple.
1 51503996 Empty housing
1 51504155 Silicone spray
1 51503943 Cleaning syringe
Place Date signature
Endress+Hauser 179
11.3 Maintenance plan Analyzer no. ...................
weekly
⇒ control and make a note of calibration factor
⇒ looking through (clogging, pump hoses, reagents, sample inlet etc.)
done CW 1 CW 2 CW 3 CW 4 CW 5 CW 6 CW 7 CW 8 CW 9 CW 10 CW 11 CW 12
date
Date
Date
Date
done CW 49 CW 50 CW 51 CW 52 CW 53
Date
Every two weeks

⇒ check the concenration of the calibration standard in the laboratory
if nessecary adjust the concentration in menu parameter entry or exchange standard solution
⇒ Flush the tube system of sample line with water under increased pressure (syringe) and loosen the
clamp of the sample pump
Date
Date
done CW 49 CW 51 CW 53
Date
Monthly
⇒ Replace reagents
⇒ Flush tube system of the sample line with 12.5% bleaching solution (sodium hypo chloride solution,
pharmacy or via STM) and thoroughly rinse again with water: menu service V1: P; P1: e; P2: a; V2:
S. Add solution to sampling tube
⇒ Control and clean sample collector for pollution
⇒ Spray pump tubes with silicon
done Jan Feb Mär Apr Mai Jun Jul Aug Sep Okt Nov Dez
Date
Every 3 months
⇒ Replace pump tubes
Attention: Each manipulation at the reagent pump tubes requires pulling down the reagent tubes at
the cans from the connection board, in order to prevent soiling of the reagents
⇒ Cleaning of the drain line
done Jan Apr Jul Oct
Date
Endress+Hauser 180
11.3.1 Maintenance plan dilution modul
Every two weeks

⇒ Flush the tube system of sample line with water under increased pressure (syringe) and loosen the
clamp of the sample pump
Date
Date
Date
Monthly
⇒ Flush tube system of the sample line with 12.5% bleaching solution (sodium hypo chloride solution,
pharmacy or via STM) and thoroughly rinse again with water: menu service V1: P; P1: e; P2: a; V2:
S. Add solution to sampling tube
⇒ Control and clean sample collector for pollution
⇒ Spray pump tubes with silicon
⇒ check dilution factor (add solution with known concentration to sampling tube, check concentration after
dilution modul by laboratory test)
done Jan Feb Mär Apr Mai Jun Jul Aug Sep Okt Nov Dez
Date
Every 3 month
⇒ replace pump hoses
done Jan Apr Jul Okt
Date
11.3.2 Maintenance plan ultra filtration
Every 2 weeks
⇒ looking through (pressure, sealness, clogging,level of cleaning agent etc.)
Date
Date
Date
alle 2 Monate
⇒ Flush tube system of the sample line with cleaning agent and thoroughly rinse again with water)
done Jan Mar May Jul Seb Nov
Date
yearly
⇒ replace hoses of sample line
Endress+Hauser 181
11.3.3 Stamolys-Analyzer
Instrument Setup Stamolys-Analyzer
Place: ........... ______________________________

Model Typ: ........... ______________________________
Serial No.. Analyzer: ........... ______________________________
Serial No. Photometer: ........... ______________________________
Software-Version: ........... ______________________________
Date: ........... ______________________________
Measuring Cell: ........... _____________________________

Unit of measure: ........... _____________________________
Calibration factor: ........... _____________________________
c-Offset: ........... _____________________________ mg/l µg/l
Dilution: ........... _____________________________
Configuration
Delay to sample: ........... _____________________________ s

Analog output: 0-20 mA 4-20 mA
Alarm A: normally closed normally open
Alarm B: normally closed normally open
Fault signal: normally closed normally open
Frequency-offset (dem. water with reagent) : ........... ________ Hz
Ground line (dem water without reagent) : ...........______ Hz
Measuring range start: ........... _______________________ mg/l µg/l

Measuring range end: ........... _______________________ mg/l µg/l
Alarm value A: ........... _______________________ mg/l µg/l
Alarm value B: ........... _______________________ mg/l µg/l
1. Measuring: ........... _______________________
Parameter entry
Measuring interval: ........... _______________________ min

1. Calibration: ........... _______________________
Calibration intervall: ........... _______________________ h
Calibration standard: ........... _______________________ mg/l µg/l
1. flushing ........... _______________________
Flushing interval: ........... _______________________ h
Flushing hold on:. ........... _______________________ s
Endress+Hauser 182
Submenue:
Errormask ...........
MB> ...........
MBE ...........
Flush 2 ...........
Time fill ...........
Time-rea ...........
U/min ...........
K floating mean ...........
N ........... Points
C1 ........... mg/l // µg/l F1 ........... Hz
C2 ........... mg/l // µg/l F2 ........... Hz
C3 ........... mg/l // µg/l F3 ........... Hz
C4 ........... mg/l // µg/l F4 ........... Hz
C5 ........... mg/l // µg/l F5 ........... Hz
C6 ........... mg/l // µg/l F6 ........... Hz
C7 ........... mg/l // µg/l F7 ........... Hz
C8 ........... mg/l // µg/l F8 ........... Hz
C9 ........... mg/l // µg/l F9 ........... Hz
C10 ........... mg/l // µg/l F10 ........... Hz
date ........... Service-people ...........
AnaWin Software in the internet also avaiable for:

Software for Analyser CA70 from V 3,9 and CA71from V 5.0
serves for readout of attitudes and graphic pursuit of frequency characteristics
You need an PC and an RS232 Datatransfercable
Endress+Hauser 183
Note of calibration factor
Concentration of
Date Calibration factor
standard solution
Endress+Hauser 184
1 CAV740, contents of............................................. 41
1. calibration..................................................55, 122 certificates ............................................................. 18
1. flushing.............................................................. 55 change of stepmotor speed,................................. 118
1. measurement..................................................... 54 channel switching ................................................. 54
2 check of analog output ........................................ 108
2 channel, upgrade ................................................ 88 circuit plans ......................................................... 133
A comissioning instruction Analyser ........................ 34
accuracy, increasing in low concentrations ........118 concentration offset............................................... 56
adjustment of internal calibration curve .............118 concentration-offset adjustment............................ 56
adjustment of level control in sample collector .... 38 CONFIGURATION ................................................ 56
adjustment of measuring values ............................ 56 connection sticker ................................................. 42
adjustment of pump pressure ................................ 93 contents of service kit CAV740 ............................ 41
air bubbles, detection by reaction course ............. 85 conversation tables chemical formulas ............... 157
alarm value ............................................................ 54 correcting for volume additions .......................... 151
analog output .......................................................124 CPU module, exchange of ................................... 111
analog output aligment ........................................108 Cuvette order number......................................... 101
analog output check.............................................108 D
analog output installation, second output ...........109 datastorage............................................................. 72
analog output, second output ..............................108 default settings ................................................ 73, 74
analog output, setting ............................................ 57 default settings submenu................................. 73, 74
analog output, simulation ...................................... 50 default settings, selection of.................................. 56
analog outputs, screening of.................................. 45 default settings, service submenu ................... 75, 76
analyzer, order codes............................................. 17 delay to sample ...................................................... 56
analyzer, structure................................................. 17 delivery, scope of................................................... 18
AnaWin.................................................................. 81 deposits................................................................ 126
aprovals.................................................................. 18 diameter of hoses ................................................ 116
AUTO MEASURING .............................................. 53 dilution .................................................................. 56
B dilution adjustment ............................................... 56
blind value .......................................................27, 60 dilution by dilution module................................. 113
blind value, typical values ..................................... 60 dilution by sample pump..................................... 115
C dilution calculation.............................................. 116
calculation of internal values................................. 26 Dilution factors .................................................... 116
calculation of measurement result ........................ 27 dilution techniques.............................................. 151
Calibration accuracy .............................................. 59 Dimensions Analyser............................................. 28
Calibration Data storage ........................................ 72 display is garbled or off........................................ 124
calibration doesn’t start .......................................125 display of frequency............................................... 71
Calibration example .............................................. 58 dosing time for sample .......................................... 56
calibration factor............................................56, 122 E
calibration factor form .........................................171 edit calibration factor ............................................ 59
calibration factor, determination of....................... 27 electrical conection, extern................................... 44
calibration factor, edit ........................................... 59 electrical connection, internal .............................. 46
calibration factor, importance of ........................... 58 emptying of tubes .................................................. 71
calibration factor, influences ................................. 58 EPROM exchange................................................ 106
Calibration factors factory settings ........................ 73 Error..................................................................... 127
calibration failed ..................................................122 Error Calibration failure ...................................... 128
Calibration failure................................................128 ERROR Display ...................................................... 70
calibration F-Offset for reagents............................ 60 Error masking ........................................................ 62
calibration interval................................................. 55 error message .............................................. 122, 125
Calibration self check ............................................ 59 error messages............................................... 70, 122
Calibration with standard solution........................ 58 Error no stable reading........................................ 128
Calibration, calculation of internal values............. 27 Error trouble shooting ......................................... 122
calibration, manual start of.................................... 58 exchange of CPU module .................................... 111
calibration, need for manually start ...................... 55 exchange of hose holder, pump head ................... 93
calibration, start manually ...................................122 exchange of pumps.............................................. 112
Endress+Hauser 185
exchange of static mixer .....................................100 interferences nitrite............................................. 131
exchange of valve .................................................. 87 interferences phosphate ...................................... 131
exchange of valve hose.......................................... 99 interferences silicate ........................................... 132
extension of measuring range .....................113, 118 Interferences, detection by reaction course.......... 84
external start of measurement ........................45, 49 interferences, detection by standard addition .... 155
F internal calibration curve ...................................... 27
factory settings.................................................73, 74 internal calibration curve, adjustment of ............ 118
factory settings, 115V/50Hz steppmotor and internal calibration curve, standard datas66, 67, 68,
Reagent filling time ........................................... 77 69
factory settings, 115V/60Hz steppmotor and K
Reagent filling time ........................................... 77 key functions ......................................................... 51
factory settings, service submenu ...................75, 76 L
filling of mixture.................................................... 71 laboratory instructions......................................... 150
filling of tubes ........................................................ 71 leak detector of photometer, connection ............ 102
First aid provision ammonium reagents.................. 8 leak in the system................................................ 122
First aid provision chromate reagents ................... 11 Leakage on the photometer................................. 126
First aid provision copper reagents ....................... 12 LED indicator functions......................................... 51
First aid provision iron reagents............................ 11 LED, indicator function ......................................... 20
First aid provision manganese reagents ................ 11 level control in sample collector, adustment of .... 38
First aid provision nitrate reagents ......................... 9 M
First aid provision phosphate reagents.................... 9 Maintenace and spare parts list........................... 165
First aid provision silicate reagents ....................... 10 Maintenance kits ................................................. 165
flushing doesn’t start ...........................................125 manual operation................................................... 71
flushing interval..................................................... 55 manual start of calibration..................................... 58
frequency basic ...................................................... 26 measured value transmission faulty .................... 124
frequency offset measurement ........................27, 60 measured values inaccurate ................................ 123
frequency offset, calculation of.............................. 27 measurement cycle, describtion of ....................... 26
frequency offset, typical values ............................. 60 measurement method, norms ............................... 23
frequency plateau .................................................. 26 measurement of sample ........................................ 27
frequency, display of.............................................. 71 measuring cell soiled ........................................... 122
Functions of AnaWin............................................. 81 measuring cell, wrong ......................................... 122
G measuring cycles per channel ............................... 54
graduated cylinders, how to use..........................152 measuring does not start ..................................... 127
H measuring interval................................................. 54
hardness of the water ..........................................126 measuring principle............................................... 22
hardware nomenclature ........................................ 20 measuring principles ............................................. 23
hose designation .................................................... 34 measuring range .................................................... 54
hose diagram.......................................................... 39 measuring range, extention of .................... 113, 118
hose diameter ......................................................116 measuring ranges of analyzer ................................ 17
hose holder, exchange of....................................... 93 measuring signal, no............................................ 123
I measuring unit....................................................... 56
identification of pump motors .............................113 menu structure, overview ..................................... 52
importance of calibration factor ............................ 58 mixture, filling of................................................... 71
increasing accuracy in low concentrations .........118 motor connection ................................................ 112
installation ............................................................. 28 N
installation examples with sample preparations ... 30 norms of measuring methods................................ 23
Installation instruction Analyser ........................... 34 O
Installation sample collector.................................. 37 offset, frequency .............................................. 27, 60
Installationinstruction electrical connection......... 42 operation of StamoLys ........................................... 19
instrument functions ............................................. 25 order codes analyzer.............................................. 17
Instrument Setup form ........................................169 P
interferences Ammonium ...................................129 PARAMETER ENTRY............................................. 54
interferences chlorine .........................................129 photometer construction..................................... 103
interferences chromate........................................130 Photometer exchange.......................................... 105
interferences copper............................................130 photometer leak detector, connection ................ 102
interferences manganese.....................................131 photometer leakage ............................................. 126
Endress+Hauser 186
Photometer, type of ............................................... 56 service menu ......................................................... 71
pipets, how to use ...............................................152 service submenu.................................................... 53
position of tubes in the valve ..........................87, 99 service submenu factory settings .................... 75, 76
product structure ................................................... 16 service submenu, default settings ................... 73, 74
Proofing of correct feeding sample and reagent.... 14 shelf time of reagents ............................................ 13
Proofing of correct feeding sample and reagent signal connections ................................................. 47
CA71AM-B and C ............................................. 14 silicate, delay to sample......................................... 56
Proofing of correct feeding sample and reagent software upgrade ................................................. 106
CA71PH-C......................................................... 15 Spare parts ............................................................. 40
pump cleaning ....................................................... 92 spare parts list...................................................... 165
Pump combinations .............................................112 Spare parts order form......................................... 165
pump exchange ...................................................112 special cleaning solution ....................................... 55
pump head, exchange of ....................................... 93 spillage error........................................................ 122
pump hose combinations ...................................... 97 standard addition, technique............................... 155
pump hoses, exchange of ................................93, 95 standard calibration datas....................66, 67, 68, 69
pump hoses, interval of exchange......................... 95 start up checklist ................................................... 35
Pump pressure ....................................................... 94 static mixer, exchange of .................................... 100
pump pressure, adjustment of............................... 93 step motor, change of speed................................ 118
pump spare parts ................................................... 93 step motor, identification .................................... 113
Pump turn into wrong direction .........................124 Steppmotor settings 115V/50Hz .......................... 77
pumps do not work..............................................125 Steppmotor settings 115V/60Hz .......................... 77
pumps does not start ...........................................127 storage conditions of reagents............................... 86
Pumps fail to run .................................................124 structure and nomenclature .................................. 39
Pumps seems to mixed up...................................124 structure of analyzer.............................................. 17
pumps, manual operation...................................... 71 submenu, default settings ............................... 73, 74
R switching contacts ................................................. 48
raw value, calculation of........................................ 26 switching on impossible...................................... 124
Reaction course, display by AnaWin ..................... 82 synchromotor, identification ............................... 113
Readout software AnaWin ...................................170 syringe ................................................................. 168
Reagent filling time 115V/50Hz........................... 77 T
Reagent filling time 115V/60Hz........................... 77 TenSette pipette, how to use .............................. 153
reagents life/shelf time ......................................... 13 Terminal ................................................................ 42
reagents order form .............................................159 terminal connectionswitching contacts ................ 48
reagents replacement ............................................ 86 terminal numbers .................................................. 44
reagents safety ......................................................... 8 Tubing combinations............................................. 97
reagents, date of manufacture ............................... 13 tubing live time ..................................................... 99
reagents, storage conditions .................................. 86 tubing order numbers.......................................... 166
reagents, storage temperature............................... 13 tubing periodically check ...................................... 95
reagents, typical look............................................. 14 typical offset values, frequency ............................. 60
relais, terminals ..................................................... 44 U
S upgrade from 1 channel into 2 channel................ 88
sample collector, dimension.................................. 37 upgrade of software ............................................. 106
sample collector, exchange of ............................... 90 upgrade two channel analyzer ............................ 109
sample collector, installation................................. 37 V
sample dilution techniques .................................151 valve hose, exchange of......................................... 99
sample suction .............................................123, 124 valve tubes, position in the valve.................... 87, 99
sample volume.....................................................117 valve, exchange of ................................................. 87
sample, no............................................................122 valves, manual operation....................................... 71
scope of delivery .................................................... 18 W
screeneing of analog outputs ................................. 45 wiring .................................................................... 42
Service check list .................................................167 wiring plan, internal.............................................. 46
service checklist .................................................... 79 wrong pump starts............................................... 124
Endress+Hauser 187

CA71 Service Instructions 02-2005 - E

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CA71 Service Instructions 02-2005 - E

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valid from:

Software version 5.5

1.1 Designated use.......................................................................................................................................................6

2 Safety instructions reagents .................................................................................................................................8

2.1 First aid provisions ................................................................................................................................................8

3.1 Device designation ..............................................................................................................................................18

4 The measuring and evaluation unit ....................................................................................................................21

5 Basics of measurement ......................................................................................................................................24

5.1 Functional principles of colorimetry ...................................................................................................................24

6.1 Incoming acceptance, transport, storage.............................................................................................................31

7.1 Installation electrical connection ........................................................................................................................45

8.1 Operation and commissioning ............................................................................................................................56

9 Service and replacement....................................................................................................................................87

9.1 Service Checklist CA 71......................................................................................................................................87

10 Error tracing and trouble-shooting.................................................................................................................. 135

10.1 Trouble-shooting instructions ...........................................................................................................................135

11 Circuit plans .................................................................................................................................................. 146

12 General Laboratory instructions ..................................................................................................................... 163

12.1 Basics .................................................................................................................................................................163

13 Conversation tables chemical formulas ........................................................................................................... 170

14 Copy sheets ................................................................................................................................................... 172

11.1 Telefax reagents order....................................................................................................................................172

1.1 Designated use

The analyzer CA 71 is a compact analysis system for photometric measurement.

1.2 Installation, commissioning and operation

Please note the following items:

1.3 Operational safety

1.5 Notes on safety conventions and icons

While removing hoses, splashing danger exists.

2.1 First aid provisions

2.1.1 Ammonia Analyzer Reagent AM1 ( CAY140VxxAAE 1 )

After inhaling: provide fresh air.

After inhaling: Provide fresh air, contact a doctor

2.1.3 Nitrate Analyzer Reagent NI1

After inhaling: provide fresh air, consult a doctor

2.1.4 Phosphate Analyzer Molybdenum blue Reagent PH1 ( CAY240VxxAAE 1 )

2.1.5 Phosphate Analyzer Molybdenum blue Reagent PH2 ( CAY240VxxAAE 2 )

After inhaling: provide fresh air, consult a doctor

2.1.7 Silicate Reagent SI1 ( CAY640VxxAAE 1 )

2.1.8 Silicate Reagent SI2 ( CAY640VxxAAE 2 )

General information: No special measures required.

2.1.9 Silicate Reagent SI3 ( CAY640VxxAAE 3 )

General information: No special measures required.

Hazardous ingredients: compund two disodium disulphite

2.1.10 Silicate Cleaner ( CAY641VxxAAE )

2.1.11 Reagent FE1 ( for iron CAY840VxxAAE )

General information: Immediately remove any clothing soiled by the product.

2.1.12 Reagent MN1 ( for manganes CAY843VxxAAE 1 )

General information: Immediately remove any clothing soiled by the product.

2.1.13 Reagent MN2 ( for manganese CAY843VxxAAE 2 )

2.1.14 Reagent MN3 ( for manganese CAY843VxxAAE 3 )

2.1.15 Cleaner for manganese ( CAY844VxxAAE )

General information: No special measures required.

2.1.16 Reagent CR1 ( for chromate VI CAY846VxxAAE 1 )

Hazardous ingredients: compound 2 none

2.1.18 Reagent CU1 ( for copper CAY850VxxAAE 1 )

2.1.19 Reagent CU2 ( for copper CAY850VxxAAE 2 )

After inhalation: Supply fresh air; consult doctor in case of complaints.

Order code activ inactiv

AM1 yellowish tawny or black

2.4 Proofing of correct feeding sample and reagent.

It is the same for different modifications 115/230 V 50/60 Hz.

2.4.1 CA71AM-B and C