Derive the titration curve for strong acid and strong base titration

name reagents conc volume ratio name reagents conc volume ratio
acid HCl 0.001 0.01 0.1 1 acid HCl 0.1 1
base NaOH 0.001 0.01 0.1 50 1 base NaOH 0.2 25 1
Kw 1.00E-14 Kw 1.00E-14

0.001 0.01 0.2

HCl volume [H+] pH [H+] pH HCl volume [H+] pH
0.00 1.00E-11 #REF! 1.00E-12 12.00 0.00 5.00E-14 13.30
1.00 1.04E-11 10.98 1.04E-12 11.98 1.00 5.31E-14 13.28
2.00 1.08E-11 10.97 1.08E-12 11.97 2.00 5.63E-14 13.25
3.00 1.13E-11 10.95 1.13E-12 11.95 3.00 5.96E-14 13.22
4.00 1.17E-11 10.93 1.17E-12 11.93 4.00 6.30E-14 13.20
5.00 1.22E-11 10.91 1.22E-12 11.91 5.00 6.67E-14 13.18
6.00 1.27E-11 10.90 1.27E-12 11.90 6.00 7.05E-14 13.15
7.00 1.33E-11 10.88 1.33E-12 11.88 7.00 7.44E-14 13.13
8.00 1.38E-11 10.86 1.38E-12 11.86 8.00 7.86E-14 13.10
9.00 1.44E-11 10.84 1.44E-12 11.84 9.00 8.29E-14 13.08
10.00 1.50E-11 10.82 1.50E-12 11.82 10.00 8.75E-14 13.06
11.00 1.56E-11 10.81 1.56E-12 11.81 11.00 9.23E-14 13.03
12.00 1.63E-11 10.79 1.63E-12 11.79 12.00 9.74E-14 13.01
13.00 1.70E-11 10.77 1.70E-12 11.77 13.00 1.03E-13 12.99
14.00 1.78E-11 10.75 1.78E-12 11.75 14.00 1.08E-13 12.97
15.00 1.86E-11 10.73 1.86E-12 11.73 15.00 1.14E-13 12.94
16.00 1.94E-11 10.71 1.94E-12 11.71 16.00 1.21E-13 12.92
17.00 2.03E-11 10.69 2.03E-12 11.69 17.00 1.27E-13 12.90
18.00 2.13E-11 10.67 2.13E-12 11.67 18.00 1.34E-13 12.87
19.00 2.23E-11 10.65 2.23E-12 11.65 19.00 1.42E-13 12.85
20.00 2.33E-11 10.63 2.33E-12 11.63 20.00 1.50E-13 12.82
21.00 2.45E-11 10.61 2.45E-12 11.61 21.00 1.59E-13 12.80
22.00 2.57E-11 10.59 2.57E-12 11.59 22.00 1.68E-13 12.78
23.00 2.70E-11 10.57 2.70E-12 11.57 23.00 1.78E-13 12.75
24.00 2.85E-11 10.55 2.85E-12 11.55 24.00 1.88E-13 12.72
25.00 3.00E-11 10.52 3.00E-12 11.52 25.00 2.00E-13 12.70
26.00 3.17E-11 10.50 3.17E-12 11.50 26.00 2.13E-13 12.67
27.00 3.35E-11 10.48 3.35E-12 11.48 27.00 2.26E-13 12.65
28.00 3.55E-11 10.45 3.55E-12 11.45 28.00 2.41E-13 12.62
29.00 3.76E-11 10.42 3.76E-12 11.42 29.00 2.57E-13 12.59
30.00 4.00E-11 10.40 4.00E-12 11.40 30.00 2.75E-13 12.56
31.00 4.26E-11 10.37 4.26E-12 11.37 31.00 2.95E-13 12.53
32.00 4.56E-11 10.34 4.56E-12 11.34 32.00 3.17E-13 12.50
33.00 4.88E-11 10.31 4.88E-12 11.31 33.00 3.41E-13 12.47
34.00 5.25E-11 10.28 5.25E-12 11.28 34.00 3.69E-13 12.43
35.00 5.67E-11 10.25 5.67E-12 11.25 35.00 4.00E-13 12.40
36.00 6.14E-11 10.21 6.14E-12 11.21 36.00 4.36E-13 12.36
37.00 6.69E-11 10.17 6.69E-12 11.17 37.00 4.77E-13 12.32
38.00 7.33E-11 10.13 7.33E-12 11.13 38.00 5.25E-13 12.28
39.00 8.09E-11 10.09 8.09E-12 11.09 39.00 5.82E-13 12.24
40.00 9.00E-11 10.05 9.00E-12 11.05 40.00 6.50E-13 12.19
41.00 1.01E-10 10.00 1.01E-11 11.00 41.00 7.33E-13 12.13
42.00 1.15E-10 9.94 1.15E-11 10.94 42.00 8.38E-13 12.08
43.00 1.33E-10 9.88 1.33E-11 10.88 43.00 9.71E-13 12.01
44.00 1.57E-10 9.81 1.57E-11 10.81 44.00 1.15E-12 11.94
45.00 1.90E-10 9.72 1.90E-11 10.72 45.00 1.40E-12 11.85
46.00 2.40E-10 9.62 2.40E-11 10.62 46.00 1.78E-12 11.75
47.00 3.23E-10 9.49 3.23E-11 10.49 47.00 2.40E-12 11.62
48.00 4.90E-10 9.31 4.90E-11 10.31 48.00 3.65E-12 11.44
49.00 9.90E-10 9.00 9.90E-11 10.00 49.00 7.40E-12 11.13
49.20 1.24E-09 8.91 1.24E-10 9.91 49.20 9.28E-12 11.03
49.40 1.66E-09 8.78 1.66E-10 9.78 49.40 1.24E-11 10.91
49.60 2.49E-09 8.60 2.49E-10 9.60 49.60 1.87E-11 10.73
49.80 4.99E-09 8.30 4.99E-10 9.30 49.80 3.74E-11 10.43
50.00 1.00E-07 7.00 1.00E-07 7.00 50.00 1.00E-07 7.00
50.20 2.00E-06 5.70 2.00E-05 4.70 50.20 3.35E-03 2.47
50.40 3.98E-06 5.40 3.98E-05 4.40 50.40 3.37E-03 2.47
50.60 5.96E-06 5.22 5.96E-05 4.22 50.60 3.39E-03 2.47
50.80 7.94E-06 5.10 7.94E-05 4.10 50.80 3.40E-03 2.47
51.00 9.90E-06 5.00 9.90E-05 4.00 51.00 3.42E-03 2.47
52.00 1.96E-05 4.71 1.96E-04 3.71 52.00 3.51E-03 2.46
53.00 2.91E-05 4.54 2.91E-04 3.54 53.00 3.59E-03 2.44
54.00 3.85E-05 4.41 3.85E-04 3.41 54.00 3.67E-03 2.44
55.00 4.76E-05 4.32 4.76E-04 3.32 55.00 3.75E-03 2.43
56.00 5.66E-05 4.25 5.66E-04 3.25 56.00 3.83E-03 2.42
57.00 6.54E-05 4.18 6.54E-04 3.18 57.00 3.90E-03 2.41
58.00 7.41E-05 4.13 7.41E-04 3.13 58.00 3.98E-03 2.40
59.00 8.26E-05 4.08 8.26E-04 3.08 59.00 4.05E-03 2.39
60.00 9.09E-05 4.04 9.09E-04 3.04 60.00 4.12E-03 2.39
 Absorbance vs. Concentration
Concentration Conc Absorbance (at 690 nm)
2.00 x 10-5 M 2.00E-05 0.906
5.00 x 10-5 M 5.00E-05 0.969
1.00 x 10-4 M 1.00E-04 1.05
2.00 x 10-4 M 2.00E-04 1.38
5.00 x 10-4 M 5.00E-04 2.4

Titration curve (HCl vs NaOH)

14.00
12.00
10.00
8.00 0.00
pH

6.00 1
4.00
2.00
0.00
0

10

20

30

40

50

60
HCl (mL)

3 Absorbance (at 690 nm) vs. Concentration

y = 3173.8x + 0.7888
2.5 R² = 0.9941
2 2.4
1.5
1 1.38
1.05
0.5 0.9060.969
0
0.00E+00 1.00E-04 2.00E-04 3.00E-04 4.00E-04 5.00E-04 6.00E-04