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Week 7
Functions of Lipids
Lipids perform three primary biological functions within the body.
I said you're the good kind of fat says one avocado to another
They:
o serve as structural components of cell membranes,
o function as energy storehouses,
o function as important signaling molecules.
• The intense mixing, and the warmth of the stomach combined with being squirted
through the pylorus, the fat empties the stomach as fine fat droplets.
• Most fat digestion occurs in the small intestine. In the small intestine fat droplets join
with bile to make micelles. Micelles travel into the intramicrovillus spaces of the
intestinal membrane to be absorbed by cell transportation.
Take a few minutes to view the video below for more detail on digestion and absorption of
fats.
URL: https://youtu.be/i0kHf_5s3J8
Phospholipids
o Phospholipids make up only 2% of dietary lipids.
o They are found in foods containing lecithin like egg yolks, wheat germ, soy, milk, and
lightly cooked meats. Fatty foods and some vegetable oils also contain phospholipids.
o In our body, they are a major component of cell membrane.
o They build the protective barrier around our body’s cells.
o Phospholipids can dissolve in both water and fats and often are used as emulsifiers. (An
emulsion is a mixture of two or more liquids that are normally unmixable or
unblendable.) They help to disperse triglycerides and cholesterol in watery fluids.
Structure:
Phospholipids
o Phospholipids are made up of 2 fatty acids attached to a glycerol 'head.'
o The glycerol molecule is also attached to a phosphate group.
o 2 hydrophobic tails and 1 hydrophillic head joined by a glycerol molecule and
containing a phosphate molecule
o Hydrophobic: a term referring to water fearing or non-water soluble substances.
o Hydrophilic: a term referring to water loving or water soluble substances.
o The phospholipids are not true fats because they have one of the fatty acids replaced by
a phosphate group.
Sterols
o Sterols are the least common type of lipid and are also known as steroid alcohol.
o They are an important class of organic molecules that occur naturally in plants, animals,
and fungi.
o The most familiar type of sterol is cholesterol. Only a small amount of cholesterol comes
from food as the body produces most of it.
o Cholesterol plays an important structural role in cell membranes and lipoproteins. It is a
precursor to bile salts and other sterol molecules; for example, steroid hormones and
vitamin D.
Sources:
Sterols are not essential to our diets because our bodies produce it. (mainly in the liver)
Structure:
Sterols is made of a 4 ring structure with any of a variety of side chains attached.
They are built from Carbon (C) Hydrogen (H) and Oxygen (O).
o Saturated fatty acids are saturated with hydrogen and found in foods from animals like
beef and dairy products. Saturated fats have been linked to an increased risk of heart
disease
o Unsaturated fatty acids are not saturated with hydrogen and found in foods from plants
like vegetable oils and nuts. Unsaturated fats play a role in lowering the risk of heart
disease.
Phospholipids
o Phospholipids are a major classification of lipids that contains a water loving phosphate
group.
o Phospholipids have a glycerol molecule, two fatty acids and a phosphate group.
o Phospholipids are important components in cell membranes.
o One example of a phospholipid is lecithin which is found in foods like egg yolks. Found
naturally in eyes, soybeans, liver, peanuts, wheat germ. Used as an emulsifier in the
food industry; for example, candy bars and mayonnaise.
Steroids (Sterols)
o Steroids are another class of lipids.
o They contain four rings of carbon atoms and no fatty acids.
o Cholesterol is the most common steroid.
o Over consumption can increase the risk of heart disease but cholesterol is also a
component of your cell membranes and used as a raw material to help make vitamin D,
bile salt, and the hormones testosterone and estrogen.
o Omega-3 fatty acids and Omega-6 fatty acids are unsaturated fats. They're important
to know because two polyunsaturated fats, alpha-linolenic acid, a type of omega-3
fatty acid and linoleic acid, a type of omega-6 fatty acid, are essential fatty acids.
o They must be obtained from the diet because our body cannot make them.
Good and Bad Cholesterol:
o Eating too much Saturated and Trans Fat leads to improper increases in the levels of
cholesterol a fat like substance that helps to keep your body functioning properly, but
too much of which can lead to heart disease and atherosclerosis. Specifically, these
types of fat increase bad cholesterol which is known as low-density lipoprotein or LDL.
o Good cholesterol is known as high-density lipoprotein or HDL and trans fats lower this
kind of cholesterol.
o Good Cholesterol = High Density Lipoprotein HDL
o Bad Cholesterol = Low Density Lipoprotein LDL
o No more than 20 to 35 percent of daily caloric intake should come from fat and the
majority of this fat should come from plant and fish based sources to maximize the
number of unsaturated fats and minimize the number of saturated and trans fats.
o They are chemically similar to cholesterol, and they inhibit the uptake of cholesterol
resulting in a decrease in serum total and LDL-cholesterol levels.
o They compete with cholesterol for incorporation into the micelles, and for uptake by
intestinal cells enhancing cholesterol excretion back into the intestinal lumen.
o Studies show that plant sterols can help lower cholesterol, which is a risk factor for
heart disease.
Guidelines:
From Health Canada:
o Eating up to 3 grams of plant sterols as part of the daily diet increases the removal of
cholesterol from the body.
o The result is a lower LDL-cholesterol, with no effect on HDL (good) cholesterol or
triglycerides.
o A limited number of foods will be allowed to contain up to 1 g of plant sterols per
serving.
o Health Canada research determined the levels and ranges of foods to which plant
sterols could be added without exceeding the upper intake limit of 3 g of plant sterols
per day in adults and 1 g plant sterols per day in children.
o Plant sterol enriched foods used together with cholesterol lowering medications should
be done in consultation with your physician.
o Plant sterols are considered safe, cholesterol-lowering ingredients within the guidelines
set by Health Canada.
o However, plant sterol enriched foods are not recommended for children, breast-feeding
or pregnant women.
o These groups have specific nutritional and dietary needs and lowering blood
cholesterol is not normally a priority for them. (Health Canada Q&A on Plant Sterols).
Polyunsaturated Fat
a Healthy Fat found in plant-based foods and fatty fish:
Omega 3 -mainly from marine and plant oils:
o walnuts, flaxseeds, hemp, chia seeds
o fatty fish such as salmon, mackerel, trout, herring and sardines and eggs
o oils and some soft margarines.
o added to eggs, milk products and some juices.
Omega 6- found in animal products and fast food:
o safflower, sunflower soya bean and corn oils.
o nuts such as almonds, pecans, Brazil nuts,
o seeds such as sunflower seeds and sesame seeds.
o
Saturated Fats
Saturated fat is usually hard at room temperature found in animal based foods. Some of
these fats are linked to high cholesterol and increased risk of heart disease when we eat too
much of it.
Sources:
o Fatty cuts of beef
o Poultry with the skin on
o Lard, shortening and butter
o High fat milk, cheeses and yogurts
o Some vegetable oils like coconut and palm kernel oil. (Sometimes used in fast foods and
processed foods)
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Trans Fats
Trans fat is made when a liquid vegetable oil is changed into a solid fat.
It is often added to processed foods to improve taste, texture and help it stay fresh longer.
Check nutrition labels for specific products but Trans Fats may be in the following:
o Deep fried foods such as spring rolls, chicken nuggets, frozen hash browns, French fries
o Ready to eat frozen foods like pizza burritos, beef patties.
o Hard (stick) margarine and shortening.
o Commercially baked goods like cookies, pies, donuts.
o Convenience foods.
o Toaster pastries (waffles, pancakes, breakfast sandwiches)
o Snack puddings, packaged sweet snacks like cookies and granola bars and package salty
snacks like microwave popcorn, chips and crackers
o Liquid coffee whiteners.
Beneficial Fats:
o There are also fats that can benefit your health.
o Unsaturated fats tend to be liquid at room temperature and are associated with a lower
risk of heart disease.
o Food sources of unsaturated fats include vegetable oil, olive oil, nuts and seeds.
o Essential fatty acids cannot be made by your body, but they are vital to the proper
functioning of your body.
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The Table Gives the Fatty acid, Vitamin E and Cholesterol Composition of some Common
Dietary Fats.
Vitamin
Saturated Monounsaturated Polyunsaturated Cholesterol
E
g/100g g/100g g/100g mg/100g mg/100g
Animal fats
o While Omega 6 is essential in our diets, it can be harmful if it is out of balance with
Omega 3 because Omega 6 can diminish the positive effects of Omega 3.
o The recommendations for the ratio of Omega-3 to Omega-6 fatty acids vary from 5:1 to
10:1.
Omega 3
o Omega 3 fatty acids are also called ω-3 fatty acids or n-3 fatty acids.
o They are polyunsaturated fatty acids (PUFAs) with a double bond at the third carbon
atom from the end of the carbon chain.
o The three types of omega-3 fatty acids involved in our bodies are α-linolenic acid (ALA)
(found in plant oils), eicosapentaenoic acid (EPA), and docosahexaenoic acid (DHA).
o Alpha-linolenic acid (ALA) is a kind of omega-3 fatty acid found in walnuts, edible seeds
like flaxseeds, hemp and chia and in canola, and soy oils.
o Alpha-linolenic acid is similar to the omega-3 fatty acids that are in fish oil,
eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA).
Omega 3 functions:
o A source of ATP (energy).
o Normal growth and development.
o An integral part of cell membranes in the body and affect the function of the cell
receptors in these membranes.
o Provide the starting point for making hormones to regulate blood clotting.
o Formation and growth of retinal structure and function, brain structure and central
nervous system.
Health Benefits:
o Reduce inflammation and may help protect us from chronic diseases, such as heart
disease and arthritis.
o May help ease symptoms of depression, anxiety and stress in some people
o Reduce risk of age related macular degeneration
o Studies have found that children with ADHD have lower levels of Omega-3 fatty acids,
increased Omega 3 may be beneficial.
Who should consume Omega 3
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