SOU.

NALINI YASHAWANTRAO DODE JUNIOR COLLEGE

STD :- FYJC STREAM :- SCIENCE

SUBJECT :- CHEMISTRY MARKS :- 25

Q.1 SELECT AND WRITE CORRECT ALTERNATIVE FROM THE FOLLOWING.(03)

i. CGS unit of density is --------

a.kgm³. b.kg/m³. c.gcm³. d.g/cm³.

ii. The molecular mass of sodium hydroxide is -----.

a.20. b.40. c.60. d.100

iii.ns¹ is a general outermost electronic configuration of -------

a. Group 1. b. Group 2. c group 16. d. Group 17

Q.2. Answer the following.(04)

i. Write the statement of law of definite proportion.

1. The law of definite proportions, also known as the law of constant proportions, states ‘that the
individual elements that constitute a chemical compound are always present in a fixed ratio’ (in terms
of their mass). This ratio does not depend on the source of the chemical compound or the method
through which it was prepared.

ii. Calculate molecular mass of urea ([(NH2)2CO] .

4 (H) + 2 (N) + (O) + (C)

= 4 (1) + 2(14) + (16) + (12)
= 4 + 28 + 16 + 12
= 60
As a result, the urea’s molecular mass is 60 g/mol.
 iii. Write electronic configuration of sodium.
The electronic configuration of sodium is 1s²2s²2p⁶3s¹

iv. Write group number and block of silicon.

Silicon is a non-metallic chemical element with atomic number 14. It belongs to group 14 and period 3 in
the p-block of the periodic table

Q.3. answer the following questions. (08)

i. Define unit. Write the SI unit of electric current and luminous intensity.
A unit is an internationally accepted standard for measurements of quantities . It is an arbitrarily
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chosen standard which is widely accepted by society and in terms of which other quantities of similar
nature may be measured . 1

 Current: ampere (A)

 Luminous intensity: candela (cd)

ii. Convert 100⁰C temperature into Fahrenheit and Kelvin.

100⁰C temperature into Fahrenheit

F = C(9⁄5) + 32

F = 100(9/5) +32

= 180 + 32

= 212 F

100⁰C temperature into Kelvin.

K = C + 273

= 100 + 273

= 373 K

iii. Calculate the number of moles present in 0.4 gram of sodium

hydroxide solution.
Given,
Volume of NaOH is 1 L.
The mass of NaOH is 4.0 g.
The molar mass of NaOH is 40 g/mol.
The formula for calculating the number of moles is shown below.
n=m/M
Where,
n is the number of moles.
m is the given mass
M is the molar mass
To calculate the number of moles of sodium hydroxide (NaOH), substitute the values of
mass and molar mass in the above equation.
⇒n=4.0g /40 gmol-1

⇒n=0.1mol

iv. Define atomic size.How does it vary in group ?

The atomic size refers to the distance between the center of an atom’s nucleus and its outermost shell. when
moving down a group in the periodic table, the atomic size increases1. This is because new shells are being
added as we go down the group

Q.4. Answer the following questions. (06)

i. Explain the Gay-Lussac's law with suitable example.

Gay-Lussac’s law is a gas law which states that the pressure exerted by a gas (of a given mass and kept at a
constant volume) varies directly with the absolute temperature of the gas. In other words, the pressure exerted
by a gas is proportional to the temperature of the gas when the mass is fixed and the volume is constant.

Example :

When a pressurized aerosol can (such as a deodorant can or a spray-paint can) is heated, the resulting increase
in the pressure exerted by the gases on the container (owing to Gay-Lussac’s law) can result in an explosion.
This is the reason why many pressurized containers have warning labels stating that the container must be kept
away from fire and stored in a cool environment.

ii. Explain molarity with respect to following points

a. Definition
 the molarity of a given solution is the total number of moles of solute
per litre of solution.

b. Formula to determine the molarity.

M=n/V
Here,

M is the molality of the solution that is to be calculated

n is the number of moles of the solute

V is the volume of solution given in terms of litres

c. Unit mol/dm3

iii.Exaplain characteristics of f- block.

The f-block elements are a group of elements in the periodic table that are often referred to as inner
transition metals1. They are placed between the s-block and d-block elements and provide a transition in the
6th and 7th rows of the periodic table1. The f-block elements are further classified into two
series: lanthanides and actinides1.

Here are some general characteristics of f-block elements:

 They are usually heavy metals2.

 They generally have high melting and boiling points2.
 They exhibit variable oxidation states2.
 They have the tendency to form colored ions2.
 They have the tendency to form complex compounds2.
 The actinoids in the f-block elements are radioactive in nature2.

Q.4.Answer the following.(04)

Find the empirical formula and the molecular formula of an organic

compound from the data given below:
C=75.92%, H=6.32% and N=17.76%

The vapour density of the compound is 39.5.

Atomic mass :- [C=12, H=1, N=14, Na=23, O=16.]

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