Jee 2023

Atomic Structure
Shilpi Kaushik
NIT Jalandhar
Next Chemistry Session Details

Chapter Name Thermodynamics

Date 5 Dec

Time 12:00 PM
t.me/vedantumath1
 New JEE 2024
Chemical Kossel - Lewis approach to chemical bond formation, the

Bonding concept of ionic and covalent bonds.

and Ionic Bonding: Formation of ionic bonds, factors affecting the

Molecular formation of ionic bonds; calculation of lattice enthalpy.

Structure Covalent Bonding: Concept of electronegativity, Fajan's rule,

dipole moment; Valence Shell Electron Pair Repulsion (VSEPR)
theory and shapes of simple molecules.
Quantum mechanical approach to covalent bonding:
Valence bond theory - Its important features, the concept of
hybridization involving s, p, and d orbitals; Resonance.
Molecular Orbital Theory - Its important features, LCAOs, types
of molecular orbitals (bonding, antibonding), sigma and
pi-bonds, molecular orbital electronic configurations of
homonuclear diatomic molecules, the concept of bond order,
bond length and bond energy.
Elementary idea of metallic bonding. Hydrogen bonding and its
applications.
Atomic
Mole Concept
Structure|
| Class
Class11th
11thJEE
JEE New Syllabus

Weightage of Chemical Bonding in JEE Main (Last 5 yrs)

Year 2023 2022 2021 2020 2019 Average

% 2.8% 4.5% 4.1% 5% 2.1% 3.7%

 Most Important Topics

1. VSEPR Theory
2. Hybridisation
3. MOT
Let’s see the Mind Map
Geometry in which the central atom has no lp of e-

Number of electron Arrangement of

Molecular Geometry Examples
pairs electron pairs

2 BeCl2, HgCl2

3 BF3

4 CH4, NH4+
Geometry in which the central atom has no lp of e-

Number of Arrangement of electron

Molecular Geometry Examples
electron pairs pairs

5 PCl5

6 SF6
 Geometry in which central atom has one or more lp of e-

No. of
Molecule No. of lone Arrangement of
Bonding Shapes and Examples
Type pairs electron pairs
Pairs

AB2E 2 1 Bent, SO2, O3

AB3E 3 1 Trigonal Pyramidal, NH3

AB2E2 2 2 Bent, H2O

 Geometry in which central atom has one or more lp of e-

No. of
Molecule No. of lone Arrangement of
Bonding Shapes and Examples
Type pairs electron pairs
Pairs

AB4E 4 1 See saw, SF4

AB3E2 3 2 T- Shape, ClF3

 Geometry in which central atom has one or more lp of e-

No. of
Molecule No. of lone Arrangement of electron
Bonding Shapes and Examples
Type pairs pairs
Pairs

AB5E 5 1 Square Pyramidal, BrF5

AB4E2 4 2 Square Pyramidal, XeF4

 Hybridisation

Molecule Structure Type B+L Hybridisation

BeCl2 Cl−Be−Cl AB2 2 sp

BF3 AB3 3 sp3

SO2 AB2L 3 sp3

PCl5 AB3 5 sp3d

NH3 AB3L 4 sp3

 MOT

❖ Order of energy in molecular orbitals of diatomic molecules.

● From H2 to N2

σ 1s < σ *1s < σ 2s < σ *2s < 𝜋 2px = 𝜋 2py < σ 2pz < 𝜋 *2px = 𝜋 *2py < σ *2pz

● For O2 and F2:

σ 1s < σ *1s ; < σ 2s < σ *2s < σ 2pz < 𝜋 2px = 𝜋 2py < 𝜋 *2px = 𝜋 *2py < σ *2pz
σ *, 𝜋 * = antibonding molecular orbital
σ, 𝜋 = bonding molecular orbital

Nb - Na
Bond order =
2
Nb = No. of electron in bonding MO’s
Na = No. of electron in antibonding MO’s
 MOT

Molecule or Bond order

MO configuration Magnetic
ion behaviour

H2 (σ 1 s)2 1 Diamagnetic

H2+ (σ 1 s)1 0.5 Paramagnetic

H2 (σ 1s)2. (σ * 1s)1 0.5 Paramagnetic

KK(σ 2s)2, (σ * 2s)2 (σ 2pz)2

O22- (𝜋 2px)2, (𝜋 2py)2 1 Diamagnetic
(𝜋 *2px)2, (𝜋 *2py)2

KK(σ 2s)2, (σ * 2s)2 (σ 2pz)2

F2 (𝜋 2px)2, (𝜋 2py)2 1 Diamagnetic
(𝜋 *2px)2, (𝜋 *2py)2
Let’s understand Types of Problems and
their Variations
Type 1 Fajan’s Rule
Type 2 VSEPR Theory
Type 3 Hybridisation
Type 4 MOT
Type 5 Dipole Moment and Bond Polarity
Type 1

Type 2

Type 3

Type 4

Type 5
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Homework Problems for Practice
Chemical Bonding

Next we will cover Electrochemistry

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8th Jan 2020-(Shift 1)