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Lampiran 1. Perhitungan

1. Pembuatan Larutan Induk MB 200 ppm dalam 250 mL

200 ppm = 200 mg / 1000 mL
= 50 mg / 250 mL
= 0,05 g / 250 mL
2. Pembuatan Larutan Standar MB
0 ppm
M1.V1 = M2.V2
200 ppm . V1 = 0 ppm . 100 mL
V1 = 0 mL

1 ppm
M1.V1 = M2.V2
200 ppm . V1 = 1 ppm . 100 mL
V1 = 0,5 mL

2 ppm
M1.V1 = M2.V2
200 ppm . V1 = 2 ppm . 100 mL
V1 = 1 mL

3 ppm
M1.V1 = M2.V2
200 ppm . V1 = 3 ppm . 100 mL
V1 = 1,5 mL

4 ppm
M1.V1 = M2.V2
200 ppm . V1 = 4 ppm . 100 mL
V1 = 2 mL

5 ppm
M1.V1 = M2.V2
200 ppm . V1 = 5 ppm . 100 mL
V1 = 2,5 mL

6 ppm
M1.V1 = M2.V2
200 ppm . V1 = 6 ppm . 100 mL
V1 = 3 mL
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3. Perhitungan Konsentrasi (Ce)

3.1 Massa Surfaktan Optimum
Persamaan Kurva Kalibrasi : y = 0,2137x – 0,0015
No Massa Surfaktan (mg) Abs
1 0 0,99
2 3 0,504
3 6 0,502
4 9 0,491
5 12 0,383
6 15 0,218

a. Biochar non Surfaktan

y = 0,2137x – 0,0015
0,99 = 0,2137x – 0,0015
x = (0,99 + 0,0015)/0,2137
x = 4,640 ppm

b. SDBS 3 mg
y = 0,2137x – 0,0015
0,504 = 0,2137x – 0,0015
x = (0,504 + 0,0015)/0,2137
x = 2,365 ppm

c. SDBS 6 mg
y = 0,2137x – 0,0015
0,502 = 0,2137x – 0,0015
x = (0,502 + 0,0015)/0,2137
x = 2,356 ppm

d. SDBS 9 mg
y = 0,2137x – 0,0015
0,491 = 0,2137x – 0,0015
x = (0,491 + 0,0015)/0,2137
x = 2,305 ppm

e. SDBS 12 mg
y = 0,2137x – 0,0015
0,383 = 0,2137x – 0,0015
x = (0,383 + 0,0015)/0,2137
x = 1,799 ppm
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f. SDBS 15 mg
y = 0,2137x – 0,0015
0,218 = 0,2137x – 0,0015
x = (0,218 + 0,0015)/0,2137
x = 1,027 ppm

3.2 pH Optimum
Persamaan Kurva Kalibrasi : y = 0,2137x – 0,0015

No Ph Abs fp
1 2 0,298 10
2 4 0,202 10
3 7 0,881 1
4 10 0,057 1
5 12 0,328 1

a. pH 2
y = 0,2137x – 0,0015
0,298 = 0,2137x – 0,0015
x = (0,298 + 0,0015)/0,2137 x 10
x = 14,015 ppm

b. pH 4
y = 0,2137x – 0,0015
0,202 = 0,2137x – 0,0015
x = (0,202 + 0,0015)/0,2137 x 10
x = 9,523 ppm

c. pH 7
y = 0,2137x – 0,0015
0,881 = 0,2137x – 0,0015
x = (0,881 + 0,0015)/0,2137
x = 4,130 ppm

d. pH 10
y = 0,2137x – 0,0015
0,057 = 0,2137x – 0,0015
x = (0,057 + 0,0015)/0,2137
x = 0,274 ppm
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e. pH 12
y = 0,2137x – 0,0015
0,328 = 0,2137x – 0,0015
x = (0,328 + 0,0015)/0,2137
x = 1,542 ppm

3.3 Waktu Kontak Optimum

Persamaan Kurva Kalibrasi : y = 0,2137x – 0,0015

Waktu
No Abs
(min)
1 15 0,119
2 30 0,084
3 45 0,074
4 60 0,055
5 75 0,04

a. 15 menit
y = 0,2137x – 0,0015
0,119 = 0,2137x – 0,0015
x = (0,119 + 0,0015)/0,2137 x 10
x = 0,564 ppm

b. 30 menit
y = 0,2137x – 0,0015
0,084 = 0,2137x – 0,0015
x = (0,084 + 0,0015)/0,2137 x 10
x = 0,400 ppm

c. 45 menit
y = 0,2137x – 0,0015
0,074 = 0,2137x – 0,0015
x = (0,074 + 0,0015)/0,2137
x = 0,353 ppm

d. 60 menit
y = 0,2137x – 0,0015
0,055 = 0,2137x – 0,0015
x = (0,055 + 0,0015)/0,2137
x = 0,264 ppm
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e. 75 menit
y = 0,2137x – 0,0015
0,04 = 0,2137x – 0,0015
x = (0,04 + 0,0015)/0,2137
x = 0,194 ppm

4. Perhitungan Kapasitas Adsorpsi (Qe)

4.1 Massa Surfaktan Optimum
a. Biochar non Surfaktan
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 4,640 mg/L) x 0,025 L) / 0,125 g
= 4,072 mg/g

b. SDBS 3 mg
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 2,365 mg/L) x 0,025 L) / 0,125 g
= 4,527 mg/g

c. SDBS 6 mg
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 2,356 mg/L) x 0,025 L) / 0,125 g
= 4,529 mg/g

d. SDBS 9 mg
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 2,305 mg/L) x 0,025 L) / 0,125 g
= 4,539 mg/g

e. SDBS 12 mg
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 1,799 mg/L) x 0,025 L) / 0,125 g
= 4,640 mg/g

f. SDBS 15 mg
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 1,027 mg/L) x 0,025 L) / 0,125 g
= 4,795 mg/g
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4.2 pH Optimum
a. pH 2
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 14,015 mg/L) x 0,025 L) / 0,125 g
= 2,197 mg/g

b. pH 4
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 9,523 mg/L) x 0,025 L) / 0,125 g
= 3,095 mg/g

c. pH 7
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 4,130 mg/L) x 0,025 L) / 0,125 g
= 4,174 mg/g

d. pH 10
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 0,274 mg/L) x 0,025 L) / 0,125 g
= 4,945 mg/g

e. pH 12
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 1,542 mg/L) x 0,025 L) / 0,125 g
= 4,692 mg/g

4.3 Waktu Kontak Optimum

a. 15 menit
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 0,564 mg/L) x 0,025 L) / 0,125 g
= 4,887 mg/g

b. 30 menit
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 0,400 mg/L) x 0,025 L) / 0,125 g
= 4,920 mg/g

c. 45 menit
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 0,353 mg/L) x 0,025 L) / 0,125 g
= 4,929 mg/g
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d. 60 menit
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 0,264 mg/L) x 0,025 L) / 0,125 g
= 4,947 mg/g

e. 75 menit
Qe = ((Co – Ce) x V) / m
= ((25 mg/L – 0,194 mg/L) x 0,025 L) / 0,125 g
= 4,961 mg/g

5. Perhitungan % Adsorpsi
5.1 Massa Surfaktan Optimum
a. Biochar non Surfaktan
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 4,640) / 25) x 100
= 81,441%

b. SDBS 3 mg
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 2,365) / 25) x 100
= 90,538%

c. SDBS 6 mg
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 2,356) / 25) x 100
= 90,576%

d. SDBS 9 mg
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 2,305) / 25) x 100
= 90,781%

e. SDBS 12 mg
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 1,799) / 25) x 100
= 92,803%

f. SDBS 15 mg
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 1,027) / 25) x 100
= 95,891%
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5.2 pH Optimum
a. pH 2
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 14,015) / 25) x 100
= 43,940%

b. pH 4
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 9,523) / 25) x 100
= 61,909%

a. pH 7
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 4,130) / 25) x 100
= 83,482%

c. pH 10
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 0,274) / 25) x 100
= 98,905%

d. pH 12
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 1,542) / 25) x 100
= 93,832%

5.3 Waktu Kontak Optimum

a. 15 menit
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 0,564) / 25) x 100
= 97,745%

b. 30 menit
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 0,400) / 25) x 100
= 98,400%

c. 45 mnenit
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 0353) / 25) x 100
= 98,587%
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d. 60 menit
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 0,264) / 25) x 100
= 98,942%

e. 75 menit
% adsorpsi = ((Co – Ce) / Co) x 100%
= ((25 – 0,194) / 25) x 100
= 99,223%