THEOR ES

VA RIOUS ADSORPTLON 1e0THERM13

The Vaunow adborsom ouoMMm

ano

adboypuen Uyohouwm
HHeundku odonpuen ibdhawM
Jomkn adsorphe uotwm.

aug m4 adsovptuen othm,

ang wH pHoposool that duaw

pohwaeM aolbrhed
equhvium dpa0 aLDNS Mmolecules
Malaudls and
ka
AB
(q)+B(g
Conrslat cko goMOOad vaadlo
Ka Cqi ubyimm
d 2qiibvium oustant 4o bedk wayd reactuen

eguOmthon
Rate
FovwMN ka AT[]
Baotwd kd TAB
A Cqu ium,
o ood

ka aJe] ABJ kd

K ka= AB
kd CAJ Cel

To devive lag mWH quatter a

Paramey i. intxooueod

ites h a
wr¢o lo wh ich
no.

mololss
Coud by g
Thon - 9 ) he.
Uhoccuplid by gas moo cule

foYwaod eaduen= PCI 9) -O

Rate ot
on P (1-0) -O
Rate s6 adnph
Rate adnphon kaPC1-9

imiay
dosj01(tjon
(A)
Raro
ka -5)
o6 dosorptho
=

Rate
ption Tato.
equuium adsophon ralo =
dasDY
4
 kaP (1- 0 d 9-6
kaP kaPO = kd

KaP kol + ka PO

kaP =
(kd + Ka P) 8

kaP -G)
kd KaP
nod
dandminoutoN
Div&do núlamON CUDT
get
kd in e O
ka-P
kd w knOW

P
kkd kd

KP
I+kP
known a langmu
Tfus
adsorphioh uatuoM
 LIMITATLON 9

Adaorbed ga has, to bohao

idaally in vdpoY phas

Vald undlo4 ou pmessuHO
Lang muM

ponbe for
Lang muw equõuen

monolay0 my
X LIMITATOv9

AdosoY bed qa ha to bohauo

icdoaa in vapoY phao

lou pmookuO
vald undlosy
*
Lang muM
ohy
porabe (or
Langmuwyequauen

moholayon my

kP
1+kP

Vm
Vm +kP
V kP (o kP
Vr

Vm
V kP

Muthipy by P
P
PVm
P
KVm
+ Vm
Eq ig lincas

dyoy m
 OF & PE UES
LANO4 MUIR EQUATTON ADORPTLON

AS AS
B+8 BS
AO O

AAA +S
S

KA AS
AS

kA
Adsovphion
ka Pa 9v -0
Desophion

A+

A
AP Ov kA
A kA PA 9v
kAPaOv

+S B
 kR Pe v A)
YEke
Ye e-
K P Ov = ke O8.
ke Pe 9v kePeOy
kp

v
(kAfa+kela
(kal'a+ kels )e
)v
ka PA v ke Pe
Ga + Og =

4 Pi

3ub (in)
KA A

(14ki)
r kg P Ov
LANCNMUIR EQVATON ON
Di930CIMON O
PECIES
ADSORPTwN DF A SINGLE

A
RA
AS
LA
A2+29S AS
A
AdsoYpHon
Ya=ka PA 9
9y
Desorption
2
Y=kaGA
eA
Equk hvium
YA YA

k Pa, 6) -kaPa®v
2

B-a) -
bub in e pt
2
A ka Pa l-0a

KA Pa
OA) 2

(kala)
1 -QA
ka A)
APA)