BAKLIWAL TUTORIALS

1 By Taruna Ma’am
BAKLIWAL TUTORIALS

2 By Taruna Ma’am
BAKLIWAL TUTORIALS

3 By Taruna Ma’am
BAKLIWAL TUTORIALS

4 By Taruna Ma’am
BAKLIWAL TUTORIALS

5 By Taruna Ma’am
BAKLIWAL TUTORIALS

6 By Taruna Ma’am
BAKLIWAL TUTORIALS

7 By Taruna Ma’am
 BAKLIWAL TUTORIALS

ANSWER KEY

Q.1 (B) Q.2 (B) Q.3 (D) Q.4 (B) Q.5 (C)
Q.6 (D) Q.7 (D) Q.8 (C) Q.9 (BCD) Q.10 (AB)

8 By Taruna Ma’am
BAKLIWAL TUTORIALS

9 By Taruna Ma’am
BAKLIWAL TUTORIALS

10 By Taruna Ma’am
BAKLIWAL TUTORIALS

11 By Taruna Ma’am
BAKLIWAL TUTORIALS

12 By Taruna Ma’am
BAKLIWAL TUTORIALS

13 By Taruna Ma’am
BAKLIWAL TUTORIALS

14 By Taruna Ma’am
BAKLIWAL TUTORIALS

15 By Taruna Ma’am
BAKLIWAL TUTORIALS

16 By Taruna Ma’am
BAKLIWAL TUTORIALS

17 By Taruna Ma’am
BAKLIWAL TUTORIALS

18 By Taruna Ma’am
 BAKLIWAL TUTORIALS
Q.1 A metallic atom which has equal number of total s-and total p-electrons then find total vacant orbital(s) in valence shell
of that atom

Q.2 Out of given ten molecules total molecules which have dipole moment zero is.
𝐼𝑂𝐹5 , 𝐻2 𝑂2 , 𝐶𝐼𝐹3 , 𝐶𝑂2 , 𝐶𝑂𝑆2 , 𝑃4 , 𝑆8 , 𝐶𝐻2 (𝐶𝑁)2 , 𝐶2 (𝐶𝑁)4 , 𝐶2 𝑁2

Q.3 In the following nine series select total number of series in which 2nd memer has high boiling point as compared to 1st
member.
boiling point as compared to 1st member.
Series- CH4 , SiH4 , GeH4 , SnH4
Series - NH3 , PH3 , AsH3 , SbH3
series - HF, HCl, HBr, HI
Series - He, Ne, Ar, Kr
Series - F2 , Cl2 , Br2 , I2
Series - H2 O, H2 S, H2 Se, H2 Te
Series - BF3 , BCl3 , BBr3
Series - 0 -dichlorobenzene, 𝑚-dichlorobenzene, 𝑝-dichlorobenzene
Series - 𝑂-hydroxybenzaldehyde, 𝑚-hydroxybenzaldehyde, p-hydroxybenzaldehyde

19 By Taruna Ma’am
 BAKLIWAL TUTORIALS
SOLUTIONS
Q.1

Mg = 1s 2 , 2s 2 2p 6 ,3s 2 ,3p 0x 3p 0y 3p 0z ,3d 0xy 3d 0yz 3d 0xz 3d 0x 2 − y2 3d 0z2

( Eight orbitals ) Vacant

Q.2

Q.3 B.P. depends on molecular weight or hydrogen bonding.

20 By Taruna Ma’am
BAKLIWAL TUTORIALS

21 By Taruna Ma’am
BAKLIWAL TUTORIALS

22 By Taruna Ma’am
 BAKLIWAL TUTORIALS

Q.4 Total number of electrons are required to be added in molecular oxygen to separate them as a stable
atomic ions is

Q.5 𝐴𝐵2 𝐿2 , 𝐴𝐵4 𝐿, 𝐴𝐵3 𝐿2 , 𝐴𝐵2 𝐿3 , 𝐴𝐵5 𝐿, 𝐴𝐵4 𝐿2 , 𝐴𝐵2 𝐿, 𝑂𝐴𝐵4 , 𝑂𝐴𝐵3 , 𝐴𝐵2 𝑂3 , 𝐴𝐵2 𝑂𝐿2 , 𝐴𝐵4 𝑂𝐿
Where A is central atom, B is surrounding atom, O-oxygen, L is lone pair.
Among the following molecules, number of molecules in which lone pair and / or O-atoms have no
preference for occupying any specified position i.e., they can occupy any available position.

Q.6 For the given species number of species which do/does not exist:
𝐵𝐹63− , 𝐵𝑖𝐶𝑙, 𝑆𝐻2 , 𝐻𝑁3 , 𝑆𝐼6 , 𝐶𝑠𝑋𝑒𝐹5 , 𝑃𝑏𝐼2 , 𝐶𝑙𝐹7 , 𝑁𝐹6− , 𝐿𝑖2 𝐶𝑂3 , 𝐾𝐻3

23 By Taruna Ma’am
 BAKLIWAL TUTORIALS
SOLUTIONS

Q.4
O 2 + 4e − → 2O 2−
Molecular oxygen

Q.5 In sp2 – and sp3 – hybridization L.P. can occupy any position
In octahedral geometry one L.P. can occupy any position but 2nd L.P occupy any position on 1st L.P.

Q.6 Non-existing molecule/ion 𝐵𝐹63− , 𝐵𝑖𝐶𝑙, 𝑆𝐼6 , 𝐶𝑙𝐹7 , 𝑁𝐹6− , 𝐾𝐻3

24 By Taruna Ma’am
BAKLIWAL TUTORIALS

25 By Taruna Ma’am
BAKLIWAL TUTORIALS

26 By Taruna Ma’am
BAKLIWAL TUTORIALS

27 By Taruna Ma’am
BAKLIWAL TUTORIALS

28 By Taruna Ma’am
BAKLIWAL TUTORIALS

29 By Taruna Ma’am
BAKLIWAL TUTORIALS

30 By Taruna Ma’am
 BAKLIWAL TUTORIALS

Q.1 All the given species undergoes dimer formation, dimerization of which molecule does not require vacant
orbital.
AlCl3 , HCOOH, BH3 ,ClO3 , ICl3 , NO2 , BeCl2 , BeH2 ,Cl

Q.2 Out of given 9 statements total number of statements which are CORRECT for graphite.
Statement – Three dimensional network like structure
Statement – C is sp2 hybridised
Statement – Lubricant use
Statement -  -bond(s) presents
Statement – C-C bond length is almost same as C2 H 6

Statement – Van der Waal’s forces present

Statement – Used as a abrasive
Statement - C-C bond length is more than H−C  C−H

Statement – It conducts electricity.

31 By Taruna Ma’am
 BAKLIWAL TUTORIALS
SOLUTIONS

Q.1
HCOOH = Dimerize due to hydrogen bonding
•
Cl O3 = Dimerize due to covalent bonding (𝐶𝑙2 𝑂6 )
•
N O2 = Dimerize due to covalent bonding (𝑁2 𝑂4 )
•
Cl = Dimerize due to covalent bonding (𝐶𝑙2 )

Q.2 Six statement are correct which are II, III, IV, VI, VII, IX

32 By Taruna Ma’am