BAKLIWAL TUTORIALS

1 By Taruna Ma’am
BAKLIWAL TUTORIALS

2 By Taruna Ma’am
BAKLIWAL TUTORIALS

3 By Taruna Ma’am
BAKLIWAL TUTORIALS

4 By Taruna Ma’am
BAKLIWAL TUTORIALS

5 By Taruna Ma’am
 BAKLIWAL TUTORIALS

ANSWER KEY
Q.1 (5)

Q.2 (3)

It is  * molecular orbital. It has total 3 electrons in superoxide ion

Q.3 (6) All the six terminal P – O bonds are identical

Q.4 (3) Ga + , Pb2+ , Ti + are formed due to inert pair effect so they have ns2 configuration in outermost shell

Q.5 (8) All Hf − B − H b bond angles are identical (t = terminal, b = bridging)

6 By Taruna Ma’am
BAKLIWAL TUTORIALS

7 By Taruna Ma’am
BAKLIWAL TUTORIALS

8 By Taruna Ma’am
BAKLIWAL TUTORIALS

9 By Taruna Ma’am
BAKLIWAL TUTORIALS

10 By Taruna Ma’am
 BAKLIWAL TUTORIALS

ANSWER KEY
Q.6 (3)
Q.7 (6)

Q.8 (6) Four sp-orbitals [Two sp-orbitals by each carbon and two 1s orbitals (one by each H)]

Q.9 (4)

11 By Taruna Ma’am
 BAKLIWAL TUTORIALS

Q.10 (1)

12 By Taruna Ma’am
BAKLIWAL TUTORIALS

13 By Taruna Ma’am
BAKLIWAL TUTORIALS

14 By Taruna Ma’am
BAKLIWAL TUTORIALS

15 By Taruna Ma’am
BAKLIWAL TUTORIALS

16 By Taruna Ma’am
BAKLIWAL TUTORIALS

17 By Taruna Ma’am
BAKLIWAL TUTORIALS

18 By Taruna Ma’am
 BAKLIWAL TUTORIALS

ANSWER KEY
Q.11 (5 or 6)

Q.12 (3) (i), (iii), (iv), (v) are change

Q.13 (4) MnO −4 is tetrahedral ion and there are four triangular faces in MnO −4

Q.14 (4) CO32− + 2H + → H 2O + CO 2 

Q.15 (1) [Pt(en)2 ][PtCl4 ] = No coordination isomer

[Pt(NH3 )4 ][PtCl]4 ]
} Two coordination isomers
[Pt(NH3 )3 Cl][PtNH3 Cl3 ]

19 By Taruna Ma’am
BAKLIWAL TUTORIALS

20 By Taruna Ma’am
BAKLIWAL TUTORIALS

21 By Taruna Ma’am
BAKLIWAL TUTORIALS

22 By Taruna Ma’am
BAKLIWAL TUTORIALS

23 By Taruna Ma’am
 BAKLIWAL TUTORIALS

ANSWER KEY
Q.16 (7)
2Cu2+ + 4I − ⟶ Cu2 I2 + I2
2I − + H2 SO4 + 2H + ⟶ I2 + SO2 ↑ +2H2 O
Conc.

Q.17 (6) Total six ions i.e. Ti3+ , V 3+ , Cr 3+ , Mn3+ , Fe3+ , Ni3+

24 By Taruna Ma’am
 BAKLIWAL TUTORIALS
Q.18 (3)

Q.19 (3)

Q.20 (4)

25 By Taruna Ma’am
BAKLIWAL TUTORIALS

26 By Taruna Ma’am
BAKLIWAL TUTORIALS

27 By Taruna Ma’am
BAKLIWAL TUTORIALS

28 By Taruna Ma’am
BAKLIWAL TUTORIALS

29 By Taruna Ma’am
 BAKLIWAL TUTORIALS

ANSWER KEY
Q.21 (2)
Two elements of 3𝑑-series (Mn, Cr) have 𝑑 5 configuration.

1 𝑉2 𝑂5
Q.22 (5) SO2 + O2 → SO3
2

Q.23 (3) 3MnO2− + −

4 + 4H ⟶ 2MnO4 + MnO2 + 2H2 O

Q.24 (6)
Moles = moles
Mass No. of molecules
=
GMM 𝑁𝐴
0.368 9.032×1020
=
( At. mass of Xe )+(𝑛× At. mass of F) 𝑁𝐴
𝑛=6

Q.25 (6)
12.12gm of cocaine (C𝑛 H21 O4 N) = 24.08 × 1021 molecules
∵ 12.12gm of cocaine contains = 0.04 mol
12.12
1 mol cocaine = = 303 g
0.04
So, mass of C + 21 × 1 + 4 × 16 + 14 = 303 g
Mass of C = 204gm (present in 1 mol )
Hence 204amu of C present in 1 molecule
30 By Taruna Ma’am
BAKLIWAL TUTORIALS

31 By Taruna Ma’am
 BAKLIWAL TUTORIALS

Dinitrogen pentoxide 𝐍𝟐 𝐎𝟓

N2 O5 is prepared by carefully dehydrating HNO3 with P2 O5 at low emperatures. It is a colourless

deliquescent solid, which is highly reactive, is strong oxidizing agent, and is light sensitive. It is the
anhydride of HNO3 .
N2 O5 + H2 O → 2HNO3
N2 O5 + Na → NaNO3 + NO2
N2 O5 + NaCl → NaNO3 + NO2 Cl
N2 O5 + 3H2 SO4 → H3 O+ + 2NO+ −
2 + 3HSO4

In the gas phase N2 O5 decomposes into NO2 , NO and O2 . Nitrogen trioxide NO3 may be formed by
treating N2 O5 with O3 .
𝑋-ray diffraction shows that solid N2 O5 is ionic NO+ −
2 NO3 : it should in reality be called nitronium nitrate.
It is covalent in solution and in the gas phase, and probably has the structure:

32 By Taruna Ma’am