CHEMISTRY)

ASN 2
OYganic CHEMISTRY OH

O Aude styength:

O Alcohol < phenol < coboxeaid

CHz C00 H STRy| NO
<;ltsot 4-nityo 4-methl 4-methoy
benzoicaid bengolcacd beng0ic aud
CH,coOH MI
Foymic aGd Bengoic alid acetic aud CHE ka od
Acidie sStyength pka
h ce0M > tHñ cooH >hy cooH >> cHy-CooH JASN
CH-H-coo#
CHg-C00H > CH,cH, CH,(oOHt > 2 Baic styength:
F
CH, -H-cooH H,cHacooH Baie strenoth ac kb &apkb
CHcl;co04> 9,N CH,cooH
CF,cooH > Ccl,cooH >
NC-CH,coOH F-CH2CooH

cooH > H,C< co OH Gas phal:

3°amine > 'mine >i amine NH,
3-utro
pYopon-l-ol <4-me tny pheno] e phenol e phenol (CH) NH CHy NH
CHCHaCHt,oH
2
2,4,6 - trinitro phenol
< 3.5- dinito phenol < H Aniine Ethanamine
H
NO
In aqueousS Soution:
Boiling poirt ;
> aldehy de
O Conbocic c d > alCohol > ketone
NH ethey > alkane
cH) NH > cHyNH >CH)N> NHg > >CH,cHs CH,
CH,co OH > CHycHzOH >CHyCHO > CH0cH,
GHS), NH >G), N > GHgNHs > NHg >
P-nutro anine < aniline e P- tolidine O pentan -|-ol > pertanal> ethoxy ethame> n-butane
NH
Methanol < ethanol < propa-l-ol < Btan-2-o1
N CH,OH
MISTRYASNCHE
< Butan-I-ol < penton--ol
CHyCHzcH,CHSoH CHycHycHzcHscHyoH

P-ritro phenol > o-nitro phenol

H

NO

ALCohol > famine >2'amine >'amine

CHCHNHCH, >
CH,cHcHyOH > cH,CHSEHy NHa >
 6

CHF < CH,ct c CH8Y <cH,I density :

CHzcl < cHCHycl <cHcHaCHcl
CH,cA < cHzct, < CHcl,
Bromo fotw) ASN
Bromo methane dibromo 9 CHcl < CHyCHyd CH, CH,Ctyce
methane

cl GCHE * di polemoment:
CH,- H-CH, <CH,CH cHycl < CH, CHycHyCHsci
(- chloyo
MI
2-chlero propone (-chloreo STRY
butane
tsopropy chlevida)
propane h > (-d

CH,--cHy < CH,-H-cH,CH? < CHyCH,ceHyBY

Melting point :

> CsHsdHg
CHyoH > CHy CHoH > CHe ctheHOH s:B>A
3
CH, cOOH > CH, CHyCôoH
A
S A>B
HEMISTeY/ JASN A
D>c>
B> SN':
B>cD A>SN:
A
>G>c>D ASn:
B>A DC
B A
phe bengaldehyde
aldehyde tolu Bengaldehy
P. >de > P-nibO B>A SN:
A>B SN
tone ke
butyl
ketone tet C>B>A SN A>B>c SN'i
Di-teyt
but >methyl acetone> Acetaldehyde>
pentona A
(ethano) pertone 2-bvomo butone the -me
Cacetm propanal Acekaldehyde |-BYomd
e propanome >B>c A
SN: C>B>A SN
, CH--cH> CHycH,-E-H> -l-H> CH, 2Y
R-i-H ST
CHEMI GY
ketne dehyde AL O
>B> A SN
6) HcN (o)Yeatim JASN
CHg
:BYMg
A
additiam mucleophiie touwetidy Reactiviby
 phenol 24,6-tiby
omo
Todofovm +3B
[Naor] 2-b-cH
I, R-CooNa
CH +
ppt whitewater’ By, phenol
+t
CA- cH--
oY foy Tast
Todofovmn ) phenol. foy tut wats Bromine )
comple) (violet
Mivver]
[stlver
Hao 2 + NH 2-coo+
+ Aq 2
3Ht| t
3Hel+ Fece9 CçHsOH
’ 6Feclst
(AqMs)]"+* t
R-2cno+ complee Fecl,’
Violet phenol
t
Avomatte] nol: phe for test Fecl, Neutal
(Alphattes
en+Silvey
tvvov Tollens Aldehydes+ heating om
only alcohol 1
en silver
Ammanteal ent Reag Tollen's ASN
CHEMI
STR minte abtes
Aldekydes foy Tests)Tollen olcohol 2
Immediataly 3
alcohol
appeatg tunbidity ALCohol
Ppt Yelloe Ovange
ov
blTmmisci
e)
H,N-NH C=0+ Hcl R-oH+
dvazine phenyl D?NThro 4- 2, DNP 2,4- Znel, anhyd +HeL conc. :entYeag Lucas
Aldahydass alcohols: for tet Lucos O
ound ConGavbonyl foy ast DNP 2,o- 4) tests chemica CHEMISTRy
ASN
) Fehltng s test far 4ltpkette Alde hy de 9 Hinsberg test for 23° amine5:
chloyide
ag Cuso, Solutfon Allkalme Sodium Hinsberg's Yeag ert’ Benzene sulphong
Potassia a GeHs S0,c)
Tavtavate product
[Rochella salt] amine+ Hinsbeng neagut ’ Soluble im olka)
Aliphetie Aldahyde +Fahling's solution
Reddish Bvoasn PA Ccu,o] 2°amine t Hinsbehg neagnt ’ pobut
(insolable in olkaly)
R-cHo + 2 cu +SOH"’R- Goo* + Cu,o + 3H,o
3°amine t Hins brg neaget’ o Yeatim
s) Sodtun Bi-Cavbanade test ev arbozy lie Acid
+ Hel
Cav bowylie Acid +Na Hco’Bvisk Hevvescence of H
co
R-coo H+ NaHco, 2 CooNa + ca,] + H,o (amine) (Souble in olkal)
)Carby laming teat far Bimary Aminas
(Tsoayantde Test)
2 amine
(nsoluse in alkal)
Anine + CHCy + kOH Nat, Foul sna lling Substance
[AItphat?e Cavbyl Amnide] [Tsocyania A20 dye tet for aromastic amine;
Avonatte] Heat 2-NG+ 3 kcl + 3H,o
2-NH t CHcl, + 3koH NH 243-248h
[To-yanide] +NaNo,t Hc

Aniline oMB-Naphthol
ASN CHEMISTRY
oYange hed dye
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