DAV PG College Karnal

BSc -1 (Major)

TM= 40

Timings = 1.5 hr

Q1) Compulsory Questions (2 marks each)

i) Discuss Afbau rule

ii) Find the number od angular and radial nodes in 5s orbital
iii) Why is the size of cation smaller than size of neutral atom?
iv) Explain electromeric effect.
v) Explain the order of stability of carbocation in order of increasing stability. Also justify the
answer
C6H5 – CH2 + ; NO2 –C 6H5 –CH2 + ; CH 3O—C 6H5—CH2 +
SECTION –A

Q2) a) An electron is in the 4f orbital .Write the values of n, l, m, s . (3)

b) Define the Pauli exclusion principle. (2)

OR

Q3) Calculate the effective nuclear charge of 3p electron in Phosphorus atom. (5)

SECTION – B

Q4 ) a) Define ionization energy .(2)

b) Explain electron affinity of F is less than Cl. (3)

OR

Q5 ) Explain why electron affinity of noble gases are zero. (5)

SECTION – C

Q6) Define the localized or delocalized chemical bond . Give examples. (2)

b) What is hyperconjugation ? How it differs from Resonance ? (3)

OR

Q7) Define resonance and explain the conditions for resonance . (5)

SECTION –D
Q8) What are the different types of carbene. Give examples of reaction involving the each type of
carbene. (5)

OR

Q9) What are free radicals ? Explain the order of stability of alkyl free radicals on the basis of
hyperconjugation. (5)