2025 - JEE Advanced - 1 - Paper - 2

JEE Advanced - 1 | Paper - 2 | JEE 2025 (Gen -1 & 2)
Date: 28/1/2024 Maximum Marks: 180
Timing: 2:00 PM to 5:00 PM Duration : 3.0 Hours
General Instructions
1. The question paper consists of 3 Subjects (Subject I: Physics, Subject II: Chemistry, Subject III: Mathematics).
Each Part has four sections (Section 1, Section 2, Section 3 and Section 4).
2. Section 1 contains 4 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
Only One Choice is correct.
Section 2 contains 3 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which One or More Than One Choice is correct.
Section 3 contains Two (02) Paragraphs. Based on each paragraph, there are Two (02) questions. The answer to
each question is an Integer value.
Section 4 contains 6 Non-Negative Integer Type Questions. The answer to each question is a Non-Negative
Integer.
3. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your Test Code, Roll
No. and Group properly in the space given in the ANSWER SHEET.
Vidyamandir Classes: Innovating For Your Success
MARKING SCHEME
SECTION – 1 | (Maximum Marks: 12)
 This section contains Four (04) Multiple Choice Questions.
 Each question has Four options (A), (B), (C) and (D). Only one of these four options is the correct
answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme.
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : −1 In all other cases.

 This section consists of Three (03) Questions. Each question has FOUR options. One or More Than
One of these four option(s) is(are) correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen, and it is a
correct option
Zero Mark: 0 if none of the options is chosen (i.e. the question is unanswered)
Negative Marks: –2 In all other cases.

 This section contains Two (02) Paragraphs. Based on each paragraph, there are Two (02) questions. The
answer to each question is an Integer value.
Full Marks : +3 If ONLY the correct numerical value is entered in the designated place.
Zero Marks : 0 In all other cases

 This section contains SIX (06) Questions.
 The answer to each question is a Non-Negative Integer
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
VMC | JEE Advanced-1 | JEE 2025 2 Paper - 2 | Gen - 1 & 2

SUBJECT I : PHYSICS 60 MARKS
SECTION-1
This section consists of 4 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. From the top of a building of height h, a stone A is thrown vertically upwards with velocity v0 . At the same
instant, another stone B is thrown vertically downwards with velocity v0 from the same point. The stone A
reaches its highest point at the same instant the stone B reaches the ground. The velocity v0 is equal to:
2 gh gh
(A) 2gh (B) gh (C) (D)
3 2
2. If the vector addition of two unit vectors is also a unit vector, then the magnitude of their vector difference
is :
1
(A) 2 (B) 3 (C) (D) 5
2
SPACE FOR ROUGH WORK

3. A horizontal pipe with two parts of different areas of cross-section A and a as shown is initially empty and
exposed to atmosphere. Now water starts flowing at constant volumetric flow rate V in the pipe. The
difference in height of water in the two arms of the U-tube after the flow becomes steady is:
V2  1 1  V2 V2 V2
(A)  2  2  (B) (C) (D)
2g  a A  2 gAa 2 g ( A2  a 2 ) 2 g ( A2  a 2 )
4. A projectile is launched at an angle ‘  ’ with the horizontal with a velocity 20 ms 1 . After 10s, its
inclination with horizontal is ‘  ’. The value of tan  will be : ( g  10 m / s 2 )

(A) tan   5sec  (B) tan   5sec 
(C) 2 tan   5sec  (D) 2 tan   5sec 

SECTION-2
This section consists of 3 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONE OR MORE THAN ONE CHOICE is correct.
5. A train is moving on a railway track with a speed v. At time t  0, the driver notices that the tracks are
broken at a distance of 175 m ahead of the train. Let tr  reaction time of the driver, and amax  maximum
possible retardation of the train. Then, for which of the following option(s), the driver will be able to save
the train from reaching the broken tracks.
(A) v  30m/s, amax  5m/s2 , tr  0.5s (B) v  30m/s, amax  3m/s2 , tr  0.25s
(C) v  40m/s, amax  5m/s 2 , tr  0.25s (D) v  40m/s, amax  5m/s 2 , tr  0.5s
6. Two solid spheres A and B of equal radius R but of different densities

 A and  B are connected by a light string. They are fully immersed in a liquid
of density 2. They get arranged into an equilibrium state as shown with a
tension T in the string. If  B  3, then choose correct statements :
(A) A   (B)  A  2
4 3
(C) T  R g (D) T  4R 3g
3

7. In an imaginary gravitational field, the gravitational potential energy of a particle of mass m at a distance r
kr 2
from the centre of the field force is given by u  , where k is a positive constant of appropriate
2
dimensions. If the particle is moving in a circular orbit of radius r about the centre, choose the correct
options.
kr 2
(A) Total energy of the particle is 
2
(B) Total energy of the particle is kr 2
3/2
(C) The orbital time period of the particle is proportional to r
2
(D) The angular momentum of the particle about the centre is proportional to r

SECTION-3
This section consists of TWO (02) Paragraphs. Based on each paragraph, there are TWO (02) questions. The answer to
each question is an Integer Value.
Paragraph for Questions 1 - 2

Consider the arrangement shown in figure. The string is wrapped around a
uniform solid cylinder which rolls without slipping. The other end of the
string is passed over a massless, frictionless pulley and connected to a block.
Mass of the cylinder is M  4 kg and its radius is 50 cm. The mass of the
falling block is m  1 kg. Take g  10 m/s 2 .
1. Find the acceleration (in m/s 2 ) of falling block.
2. Find the length (in m) of string that unwraps from the cylinder by the time block falls through a height of
2m.

Suppose two planets (spherical in shape) of equal radii R but mass M and 4 M have a centre to centre
separation of 6R. A satellite of mass ‘m’ is projected from the surface of the planet of mass ‘M’ directly
towards the centre of the second planet.
3. The net gravitational field due to the two planets is zero at a distance of xR from the centre of planet of
mass M. Then the value of x is__________ .
aGM
4. The minimum speed ‘u’ required for the satellite to reach the surface of the second planet is .
R
Then the value of 10a is ________.

SECTION-4
This section consists of 6 NON-NEGATIVE INTEGER Type Questions. The answer to each question is a NON-NEGATIVE
INTEGER.
5. A bullet is travelling with a speed of 500 m/s towards a 10 cm thick wooden sheet. After passing through
the sheet, its velocity is reduced to 150 10 m / s . How many more such sheets are required to completely
stop the bullet, assuming all the sheets offer same retardation to the bullet.
6. A small particle is released from the top of a smooth inclined plane ABC.
The angle of the incline suddenly changes from 60° to 30° at point B.
Assume that collision between the particle and the incline is totally
inelastic. Find the speed (in m/s) of the particle when it reaches the
bottom C of the incline. (Take g  10 m/s 2 )
7. A ball dropped on a large inclined plane, bounces repeatedly. Every bounce is perfectly elastic. The range
on inclined plane between the first and second bounce is R12 and that between the second and the third
R23
bounce is R23 . Find the ratio .
R12

8. A solid sphere of mass m and radius R is placed over a
plank of same mass m which is kept on a smooth
horizontal surface. A horizontal force of magnitude F
is applied on the plank as shown. There is sufficient
friction between the sphere and plank to prevent
slipping. If F  9 N , m  1kg and R  10 cm , the
2
acceleration of plank is ______ m / s .
9. A long, thin glass capillary is dipped just below the surface of water filled in a beaker to a height
h1  12cm . Now, oil is poured gently into the beaker to a height h2  10cm . It is now observed that the
surface of water in the capillary is at the same level as the surface of oil in the beaker. If the radius of the
capillary is   104 m , find  .
3 3
[Given:  water  10 kg m oil  7.14  102 kgm3 , g  9.8 m/s 2 ,
Surface Tension of water = 0.07 N/m
Angle of contact of water with glass = 0°,
the oil and water are immiscible]
10. A small block is kept on a horizontal turntable at a distance of 25 cm from its axis. The turntable starts
1
from rest and rotates with a constant angular acceleration of rad / s 2 . The block is observed to slip on the
3
1
table after 2 seconds. If the coefficient of friction between block and table is , find the value of .


SUBJECT II : CHEMISTRY 60 MARKS
SECTION-1
1. The interaction energy of London force is inversely proportional to sixth power of the distance between
two interacting particles but their magnitude depends upon:
(A) Charge of interacting particles (B) Mass of interacting particles
(C) Polarisability of interacting particles (D) Strength of permanent dipoles in the particles
2. A reaction has K eq  0.020 at 300 K, and its K eq value increases with increasing temperature. What can
 
be inferred about the value of Hrxn and Srxn , assuming that they are independent of temperature?
I. Hrxn  0 II. Srxn  0

(A) I only (B) II only (C) Both I and II (D) Neither I nor II
3. The ionization energy of which element is closest to that of fluorine (F)?

(A) O (B) Ne (C) Cl (D) Ar
4. On the basis of VSEPR theory, what shape is predicted for the SOCl2 ?
(A) Tetrahedral (B) T-shaped
(C) Trigonal planar (D) Trigonal pyramidal

SECTION-2
5. Among the following, the correct statements about the compressibility factor (Z) of real gases are:
(A) If Z < 1, intermolecular repulsive forces are more dominant
(B) If Z < 1, intermolecular attractive forces are more dominant
(C) If Z > 1, intermolecular repulsive forces are more dominant
(D) If Z > 1, intermolecular attractive forces are more dominant
6. Given below is the plot of pH vs volume of NaOH added in an acid-base titration. The correct statement/s
among the following is/are:
(A) Before the equivalence point, a series of buffer solutions determine the pH
(B) The graph represents the titration of a strong acid with NaOH
(C) At the equivalence point, hydrolysis of the anion of the acid determines the pH
(D) After the equivalence point, buffer solution determines the pH

7. Sulphur difluoride, SF2 , is very unstable, converting to disulphur tetrafluoride, S2 F4 , in which all four
fluorines are in different environments. Identify correct statement regarding structure of S2F4.
(A) One of the sulphur has “see saw” molecular shape
(B) One of the sulphur is sp3d hybridized
(C) One of the sulphur do not have lone pair electron
(D) There is one S = S bond

SECTION-3

2 
The presence of CO3 , HCO3 and CO2 in body fluids helps to stabilize the pH of these fluids despite
the addition-removal of H  ions by body processes. Answer the following questions about solutions
7
containing these species in varying combinations at 25°C. K1 and K 2 for H2CO3 are 4.2 10 and
4.0 1011, respectively. [log 2 = 0.30; K w H  1014 ]

2O
 2
1. Calculate the pH expected for 1 : 1 mixture of HCO3 and CO3 . (Nearest integer)
2
2. Calculate the pH expected for 0.4 M solution of CO3 . Assume degree of hydrolysis is small compared to
unity. (Nearest integer)

The oxidation number/state of a metal in a compound is sometimes presented according to the notation
given by German chemist, Alfred stock. It is popularly known as stock notation. According to this, the
oxidation number is expressed by putting a Roman numeral representing the oxidation number in
parenthesis after the symbol of the metal in the molecular formula. Thus, aurous chloride and auric chloride
are written as Au(I)Cl and Au(III)Cl3 . Mixed salts are those salts that contain more than one basic or acid

radical. Acid radicals are radicals coming from an acid (other than H ) while basic radicals are radical

coming from a base (other than OH ). Sodium potassium carbonate (NaKCO 3 ) and bleaching powder
(CaClOCl) are mixed salts as these contains two basic radicals Na  and K  (NaKCO 3 ) and acid radicals
Cl and ClO  (CaClOCl).
3. Find the percent by mass of iodine in hypothetical compound Iodine(V)iodate. (Nearest integer)
[Atomic mass of O = 16, I = 127]
4. If inert pair effect is ignored then how many of the following are correct formula of simple salt or mixed
salt made up of thalium ion, iodide ion and triiodide ion?
TI, TI3 , TI5 , T I7 , T I 9 , T 2 I 4 , T 2 I12

SECTION-4
INTEGER.
5. Nitrogen gas is kept in an open beaker at 273 K and 1 atm pressure. If the pressure of the surrounding
suddenly falls to 0.5 atm and the temperature increases to 546 K, then the percentage of nitrogen remaining
in the beaker is x% of the initial amount. Find the value of x. (Nearest integer)
6. In a well-insulated vessel, 50.0 g ice at 0.0°C is added to 350 g water at 32.0°C. What is the final
temperature (in °C) when the mixture reaches equilibrium? (Nearest integer)
1
[The heat of fusion of ice is 334 J g and specific heat capacity of water is 4.184 J/g/°C]
7. 40.0 mL of 0.200 M aqueous NaOH is added to 200.0 mL of 0.100 M aqueous NaHCO3 in a flask
maintained at 25°C. Neglecting the effects of dilution, –q J heat is released in this reaction. Find the value
of q. (Nearest integer)
H f , kJ mol 1
OH (aq) –230
HCO 3 (aq) –692
CO32 (aq) –677
H 2 O( ) –286

8. A 60.0 g sample of CaCO 3 is heated to 950 K in a 1.00 L evacuated container, where it reacts according to
the following equation:
CaCO 3 (s)  CaO(s)  CO 2 (g)
After equilibrium is attained, the pressure of CO 2 (g) is 30.0 mm Hg. When the experiment is repeated
using 120.0 g CaCO 3 , what is the equilibrium pressure P? (In mm Hg) (Nearest integer)
9. At TK, the following reaction is at equilibrium when all substances are at standard pressure? Assume that
entropies and enthalpies of reaction do not vary with temperature. Find the value of T in nearest integer.
PCl3 (g)  Cl2 (g)  PCl5 (g)
Substance H f , kJ mol 1 S, J mol1 K1

PCl3 (g) –288.7 311.6
Cl2 (g) 0 223.1
PCl5 (g) –374.9 364.2

10. 1.000 g of a weak base is titrated with 1.000 M aqueous HCl to give the data shown. What is pK b of weak
base? (Nearest integer)

SUBJECT III : MATHEMATICS 60 MARKS
SECTION-1
2
 sec A cosec A 
1. If A  5 then the value of expression   is:
 (1  4sin 2 A) (4 cos 2 A  1) 
 
(A) 6 (B) 8 (C) 16 (D) 24
12
4x
2. Let P ( x)  x 2   log10 (4.9), A   P( ai ) , where a1, a2 ,....., a12 are positive reals and
3 i 1
13
B   P(b j ) where b1 , b2 ,....b13 are non-positive reals, then which one of the following is always
j 1
correct?
(A) A  0, B  0 (B) A  0, B  0 (C) A  0, B  0 (D) A  0, B  0

3. Let bi  1 for i = 1, 2, …. 101. Suppose log e b1 ,log e b2 ,...., log e b101 are in Arithmetic Progression (A.P.)
with the common difference log e 2 . Suppose a1, a2 ,.....a101 are in A.P. such that a1  b1 and a51  b51 . If
t  b1  b2  ...  b51 and s  a1  a2  ....  a51 then
(A) s  t and a101  b101 (B) s  t and a101  b101
(C) s  t and a101  b101 (D) s  t and a101  b101
4. Two points A( x1 , y1 ) and B ( x2 , y2 ) are chosen on the graph of f ( x)  ln x with 0  x1  x2 . The points
C and D trisect line segment AB with AC < CB. Through C a horizontal line is drawn to cut the curve at
E ( x3 , y3 ) . If x1  1 and x2  1000 then the value of x3 equals.
(A) 10 (B) 10 (C) (10) 2/3 (D) (10)1/3

SECTION-2
5. If the equation ax 2  bx  c  0 (a  0) has two real roots  and  such that   2 and   2 ,
then which of the following statement is/are true?
(A) a | b |  c  0 (B) c  0, b 2  4ac  0
(C) 4a  2 | b |  c  0 (D) 9a  3 | b |  c  0
6. Consider an A.P. (with distinct terms) with first term cos  & common difference 2 cos 2 . Let S k denotes
S kp
the sum of first k terms. If is independent of k then, find  .
Sk
2 
(A) 0 (B) (C)  (D)
3 4
7. If two distinct chords of a parabola y 2  4ax passing through (a, 2a) are bisected on the line x  y  1 ,
then the length of the latus rectum can be
(A) 2 (B) 1 (C) 4 (D) 3

SECTION-3

A coplanar beam of light emerging from a point source has the equation x  y  2(1   )  0,   R . The
rays of the beam strike an elliptical surface and get reflected. The reflected rays from another convergent
beam having equation x  y  2(1  )  0,   R . Further, it is found that the foot of the perpendicular
from the point (2, 2) upon any tangent to the ellipse lies on the circle x 2  y 2  4 y  5  0
1. If the eccentricity of the ellipse is e then the value of 9e 2 is equal to:
2. The square of the area of the largest triangle that an incident ray and the corresponding reflected ray can
enclose with the axis of the ellipse is equal to:

Consider a circle x 2  y 2  a 2 . Given A(a, 0) lying on the circle and D (, ) be a given exterior point of
the circle. BC be an arbitrary chord of the circle through point D inclined at an angle  with the positive x-
axis. Also, DB  r1 and DC  r2 .
p 2  m2  a 2
3. If the harmonic mean of BD and DC is (where p, m, k are integers) then the value of
|( cos k    sin k )|
p  m  k is ______.
4. If the locus of the centroid of ABC is Ax 2  By 2  2 Hxy  2Gx  2 Fy  C  0 then the value of
2A  H
is _______.
B

SECTION-4
INTEGER.
5.  
If       1;  2   2   2  2 ; 3  3   3  3 , then find the value of 6  4   4   4 .
6. In a GP the ratio of the sum of the first eleven terms to the sum of the last eleven terms is 1/8 and the ratio
of the sum of all the terms without the first nine to the sum of all the terms without the last nine is 2. Find
the number of terms in the GP.
7. Consider a ABC whose sides AB, BC and CA are represented by the straight lines
2 x  y  0, x  py  q and x  y  3 respectively. The point P(2, 3) is the orthocentre, then find the value
of (p + q).

e e
8. If a variable line has its intercepts on the coordinate axes equal to e and e , where and are the
2 2
eccentricities of a hyperbola and its conjugate hyperbola, then the line always touches the circle
x 2  y 2  r 2 , where r = ________.
9. A circle x 2  y 2  4 x  2 2 y  c  0 is the director circle of the circle S1 , and S1 is the director circle
of circle S 2 , and so on. If the sum of radii of all these circles is 2, then the value of c is k 2 , where the
value of k is _______.
 tan 20  tan 72  tan 88 

10. Let L denotes the value of   and M denotes the value of
 tan 20 tan 72 tan 88 
8 2 sin 5 sin 55 sin 65 , then find 2 log 3 ( L  M ) .

2025 - JEE Advanced - 1 - Paper - 2

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JEE Advanced - 1 | Paper - 2 | JEE 2025 (Gen -1 & 2)

Date: 28/1/2024 Maximum Marks: 180

Timing: 2:00 PM to 5:00 PM Duration : 3.0 Hours

SECTION – 2 | (Maximum Marks: 12)

SECTION – 3 | (Maximum Marks: 12)

SECTION – 4 | (Maximum Marks: 24)

VMC | JEE Advanced-1 | JEE 2025 2 Paper - 2 | Gen - 1 & 2

SUBJECT I : PHYSICS 60 MARKS

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 3 Paper - 2 | Gen - 1 & 2

inclination with horizontal is ‘  ’. The value of tan  will be : ( g  10 m / s 2 )

VMC | JEE Advanced-1 | JEE 2025 4 Paper - 2 | Gen - 1 & 2

6. Two solid spheres A and B of equal radius R but of different densities

VMC | JEE Advanced-1 | JEE 2025 5 Paper - 2 | Gen - 1 & 2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 6 Paper - 2 | Gen - 1 & 2

Paragraph for Questions 1 - 2

1. Find the acceleration (in m/s 2 ) of falling block.

Paragraph for Questions 3 - 4

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 7 Paper - 2 | Gen - 1 & 2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 8 Paper - 2 | Gen - 1 & 2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 9 Paper - 2 | Gen - 1 & 2

SUBJECT II : CHEMISTRY 60 MARKS

I. Hrxn  0 II. Srxn  0

3. The ionization energy of which element is closest to that of fluorine (F)?

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 10 Paper - 2 | Gen - 1 & 2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 11 Paper - 2 | Gen - 1 & 2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 12 Paper - 2 | Gen - 1 & 2

Paragraph for Questions 1 - 2

4.0 1011, respectively. [log 2 = 0.30; K w H  1014 ]

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 13 Paper - 2 | Gen - 1 & 2

Cl and ClO  (CaClOCl).

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 14 Paper - 2 | Gen - 1 & 2

OH (aq) –230

HCO 3 (aq) –692

CO32 (aq) –677

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 15 Paper - 2 | Gen - 1 & 2

Substance H f , kJ mol 1 S, J mol1 K1

Cl2 (g) 0 223.1

PCl5 (g) –374.9 364.2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 16 Paper - 2 | Gen - 1 & 2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 17 Paper - 2 | Gen - 1 & 2

SUBJECT III : MATHEMATICS 60 MARKS

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 18 Paper - 2 | Gen - 1 & 2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 19 Paper - 2 | Gen - 1 & 2

SPACE FOR ROUGH WORK

VMC | JEE Advanced-1 | JEE 2025 20 Paper - 2 | Gen - 1 & 2

Paragraph for Questions 1 - 2

1. If the eccentricity of the ellipse is e then the value of 9e 2 is equal to:

SPACE FOR ROUGH WORK