RETS - 02 PCM JA - II - CWT - 02 - (22.10.2023) 12th.

JEE EXPERT
RANK ELEVATOR TEST SERIES (RETS - 02)

CHAPTER WISE TEST (CWT) - 02
PAPER - II : JEE ADVANCED
[Batch - : 12th & 12th Pass]
DATE : 22.10.2023
T ime: 3 hou r s M ax . M a rk s: 1 8 0
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS
A. Question paper format :

1. The question paper consists of 3 parts (Physics, Chemistry and Mathematics,). Each part has 3 sections.
2. Section I contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which
ONLY ONE is correct.
3. Section II contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE THEN ONE is/are correct.
4. Section III contains 6 questions. The answer to each of the questions is an integer, ranging from 0 to 9. The answer will
have to be appropriately bubbled in the ORS as per the instructions given at the beginning of the section.
5. Section IV contains 2 groups of questions. Each groups has 2 questions based on a paragraph. If the numerical
value (integer). The answer to each question is a NUMERICAL VALUE but you have to fill the option as nearest
integer.
B. Marking Scheme :
6. For each question in Section-I, you will be awarded 3 marks if you darken the bubble corresponding to the correct answer
and zero mark if no bubbles is darkened. minus one (–1) mark will be awarded for in this Section.
7. For each question in Section-II, you will be awarded 4 marks if you have darkened only the bubble corresponding to the
correct answer and zero mark if no bubbles are darkened. In all other cases, minus two (–2) mark will be awarded.
8. For each question in Section-III, you will be awarded 4 marks if you darken the bubble corresponding to the
correct answer and zero mark if no bubbles is darkened. No negative marks will be awarded for in this Section.
9. For each question in Section-IV, you will be awarded 3 marks if you darken the bubble corresponding to the
correct answer and zero mark if no bubbles is darkened. No negative marks will be awarded for in this Section.
Student's Name Enrollment Number
I have read all the instructions and I have verified all the information filled
shall abide by them. in by the candidate.
.................................................................... ....................................................................
Signature of the Candidate Invigilator Signature:

[RETS - 02] [JEE ADV-II] [CWT - 02]
PART- I : PHYSICS
SECTION - I : (Maximum Marks: 12)
 This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) & (D). ONLY ONE of these four options is
correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : + 3 If only the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : – 1 In all other cases.
1. Find the current in the branch CD. Consider the battery to

be ideal.
(A) 1.2 A
(B) 3 A
(C) 1.8 A
(D) None of these
2. Find the value of R such that power dissipated in

it is maximum.
(A) 8/5 ohm
(B) 2 ohm
(C) 5 ohm
(D) 3/7 ohm
Space for Rough Work
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3. You are in a car standing by a traffic light and at time t = 0 the light turns green. You start to
accelerate during the first 2 seconds with uniform acceleration of 1 m/s2, after that acceleration
is ceased. At the instant the light turns green a cyclist passes through the intersection moving
with a speed 3 m/s in the same direction as your car is moving. At that instant, the cyclist starts
to brake with a constant acceleration of magnitude a. At time t = 4 seconds the cyclist stops at
the same location where you are. The value of a is
(A) 0.40 m/s2 (B) 0.60 m/s2 (D) 0.25 m/s2 (D) 0.75 m/s2
4. An object is thrown with velocity v from the edge of a cliff above level ground. Neglect air
resistance. In order for the object to travel a maximum horizontal distance from the cliff before
hitting the ground, the throw should be at an angle θ with respect to the horizontal of
(A) greater than 60° above the horizontal
(B) greater than 45° but less than 60° above the horizontal
(C) greater than zero but less than 45° above the horizontal
(D) greater than zero but less than 45° below the horizontal
SECTION - II : (Maximum Marks: 12)

 This section contains THREE (03) questions.
 Each question has FOUR options(A), (B), (C) & (D). ONE OR MORE THAN ONE of these
four option is correct answer
5. Two large parallel plates are located in vacuum. One of them serves as cathode, a source of
electrons whose initial velocity is negligible. An electron flow directed towards opposite plate
produces a space charge causing the potential in the gap between the plates to vary as
V  ax1/3 , where a is a positive constant, and x is the distance from the cathode. Then
(A) The space charge density is non-uniform and decreases with increasing value of x.
(B) The space charge density is non-uniform and increases with increasing value of x.
(C) The current density between the plates is uniform.
(D) The current density between the plates is non uniform.
6. A homogeneous Proton beam accelerated by a potential difference V has a round cross section
of radius a. The beam current is I. Mass of one proton is m. Then
2I m
(A) The electric field at radial distance a/2 from the axis of the beam is
 0 a 2eV
3I m
(B) The electric field at radial distance a/3 from the axis of the beam is
 0 a 2eV
I m
(C) The electric field at radial distance a/2 from the axis of the beam is
 0 a 2eV
3I m
(D) The electric field at radial distance a/3 from the axis of the beam is
2 0 a 2eV
7. A particle of mass m is moving along the +x-axis with a constant speed v0. At time t = 0 it
enters a region in space between two parallel plates which are separated by a distance ℎ and are
contained in the x-z plane. The figure shows a side view of the plates, the +z axis is out of the
page (screen). While the particle is between the plates, it is acted on by both gravity and by a
time varying force that points upward (along the +y-direction) and has magnitude F = bt,
where b is a positive constant that is sufficiently large such that the particle hits the top plate
without ever touching the bottom plate.
(A) The particle will be closest to the bottom plate after time t = 2mg/b
(B) The trajectory of the particle will be parabolic.
(C) The particle will be closest to the bottom plate after a time t = mg/b.
(D) The trajectory of the particle will be a non - parabolic path.
SECTION - III : (Maximum Marks: 24)

(INTEGER TYPE)
 This section contains Six (6) questions.
 The answers to questions is a NON- NEGATIVE INTEGER.
 For each question, darken the bubble (corresponding to all the integers appearing in the answer)
in the ORS. Also fill the adjacent boxes by writing the correct answer in numeral form.
Full Marks : + 4 If only (all) the correct option(s) is (are) chosen.
Negative Marks : 0 In all other cases.
8. Three 60 –W, 120 –V light bulbs are connected

across a 120-V power source, as shown in the
figure. find The total power dissipated in the three
bulbs
9. A battery of 11 Volt is inserted in one of the branches of the circuit

shown in figure, with purpose that it dissipates minimum power. What
will be the current through the 2 resistance for this position of the
battery?
10. Consider the circuit shown in the figure. Find the potential difference
between points a and b.
11. A car is traveling at a constant speed of 54 km/hr when its driver sees a child run into the road.
The driver applies her brakes until the child returns to the sidewalk and then accelerates to
resume her original speed 54 km/hr. The acceleration record of the car is shown in the figure.
Given x  0 when t  0 , and the average velocity of the car during the interval 1s  t  t1 is v.
Then the value of 10v is
12. A train starting from rest travels the first part of its journey with constant acceleration f 1, the
second part with constant speed ‘v’ and the third part with constant retardation f 2 and is then
reduced to rest again. If the average speed for the whole journey were 7 v/ 8, and total journey
is 280 km, then the distance (in km) described with constant speed is
13. The motion of a vibrating particle is defined by the position vector


r   8sin  t  iˆ   2 cos 2 t  ˆj , where r and t are expressed in meter and meter/sec2
respectively. What is the radius of curvature (in meter) of path followed, at t  1 sec.
SECTION- IV : (Maximum Marks: 12)

Paragraph with Numerical Value Integer
 This section contains Two (02) paragraphs.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE but you have to fill the option as
nearest integer.
 For each question, enter the correct numerical value corresponding to the answer in the
designated place using the mouse and the onscreen virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to interest
integer
Paragraph for Question 14. to 15.
Two projectiles are launched from the foot of an inclined plane with equal initial speeds as
shown in the figure.
Both the objects hits the same target after moving through air in respective times T 1 = 4 sec
and T2 = 6 sec.
14. The distance between the foot point and impact point on the inclined plane is………meters.
15. At the time of impact, the ratio of speed of 1 to that of 2 is……
The figure shows part of some electrical circuit.
All three ammeters are identical and each have resistance of 2 ohm. Between A and B there is
constant potential difference of 19 V. Ammeter A1 and A2 reads 2.5 A and 1.5 A respectively.
16. The reading of A3 is ………..Ampere
17. If R2 is variable, then the value of R2 at which A3 reads zero is ………ohms
PART- II : CHEMISTRY
correct answer.
1. Given
(A) 2CO g  O2  g   2CO2  g  H1  x kJ mol
 1
 1
(B) C(graphite) + O2(g)  CO2(g) H2  y kJ mol
"The H for the reaction
1
C(graphite)  O 2  g   CO  g  is
2
x  2y x  2y 2x  y
(A) (B) (C) (D) 2y  x
2 2 2
2. A, B and C are hydroxy compounds of the elements X, Y and Z, respectively. X, Y and Z are
in the same period of the periodic table. A gives an aqueous solution of pH less than seven. B
reacts with both strong acids and strong alkalis. C gives an aqueous solution which is strongly
alkaline.
Which of the following statements is/are true?
I. The three elements are metals
II. The electronegativities decreases from X to Y to Z.
III. The atomic radius decreases in the order X, Y and Z.
IV. X, Y and Z could be phosphorus, aluminium and sodium, respectively.
(A) I, II, III only correct (B) I and III only correct
(C) II, IV only correct (D) II, III and IV only correct
3. Fe2O3(s) + 3/2C(s)  3/2CO2(g) + 2Fe(s) Ho = +234.1 kJ

C(s) + O2(g)  CO2(g)Ho = –393.5 kJ
Use these equations and Ho values to calculate Ho forthis reaction.
4Fe(s) + 3O2(g)  2Fe2O3(s)
(A) –1648.7 kJ (B) –1255.3 kJ (C) –1021.2 kJ (D) –129.4 kJ
4. How much energy must besupplied to change 36 g ofice at 0 °C to water at roomtemperature,

25 °C?
Data for Water, H2O
 Hofusion = 6.01 kJ·mol–1
CP, liquid = 4.18 J·K–1·g–1
(A) 12 kJ (B) 16 kJ (C) 19 kJ (D) 22 kJ
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5. Which of the following options is/are correct?

(A) Size of Zirconium of Hafnium are almost same
(B) less energy is required to remove 6s orbital electrons as compared to 5s orbital electrons
(C) Due to filling of electrons in 4f subshell, effective nuclear charge increases that results into
Lanthanoid contraction
(D) Last element of Lanthanoid series is Lutetium and its atomic number is 72.
6. For a reaction taking place in a container in equilibrium with its surroundings, the effect of
temperature on its equilibrium constant K in terms of change in entropy is described by
(A) With increase in temperature, the value of K for exothermic reaction decreases because the
entropy change of the system is positive
(B) With increase in temperature, the value of K for endothermic reaction increases because
unfavourable change in entropy of the surroundings decreases
(C) With increase in temperature, the value of K for endothermic reaction increases because the
entropy change of the system is negative
(D)With increase in temperature, the value of K for exothermic reaction decreases because
favourable change in entropy of the surroundings decreases
7. Which of the following is / are correct statement(s)?

(A) Tl3+ salts are better oxidizing agents. (B) Ge+ salts are better reducing agents.
(C) Pb4+ salts are better oxidizing agents. (D) As5+ salts are better oxidizing agents.

(INTEGER TYPE)
8. How many of the following options is/are correct?

In a one-litre flask, 6 moles of A undergoes the reaction A(g)  P(g) The progress of product
formation at two temperatures (in Kelvin), T1 and T2, is shown in the figure :
If T1 = 600 K and T2 = 300 K, then;

i. The value of equilibrium constant (Kp) for reaction at T1 temperature is 0.5
ii. The value of equilibrium constant (Kp) for reaction at T2 temperature is 2.0
iii The above chemical reaction is endothermic in nature
log K2 K2
iv  is valid for above chemical reaction
log K1 K1
v. The value of G1o is 600  R  n (2)
1
vi. The value of Go2 is 300  R  n  
 2
vii The Value of   G o2   G 1o  is  R  n(2) Y  where the value of Y is 900
9. How many of the following options is/are correct?

One mole of an ideal gas at 900 K, undergoes two reversible process, I followed by II, as
shown below. If the work done by the gas in the two processes are same, then
(U: internal energy, S : entropy, p : pressure, V = volume, R = gas constant)

5
(Given: molar heat capacity at constant volume, CV,m of the gas is R )
2
I. The value of change in internal energy for process I is 1800R
ii. The value of change in internal energy for process II is 450R
iii. Process I is reversible adiabatic process
iv Process I is reversible adiabatic expansion process
v Process II is reversible isothermal expansion process
vi The value of work done in process I is -1800R
vii The value of T1 is 900 K
viii The value of T2 is 180 K
V3
ix The value of n ( ) is 10
V2
10. Among the following the number of state variables is __________ .

Pressure (P), Temperature (T), Gibbs free energy (G), Internal energy (U), Volume (V), Heat
(q), Enthalpy (H), Electric potential (V) Irreversible expansion work, Reversible expansion
work
11. Find the value of (X+Y+W)

i For complete combustion of ethene.
C2H4(g) + 3O2(g)  2CO2(g) + 2H2O(1) the amount of heat produced as measured in bomb
calorimeter is 1406 KJ-mol1 at 300K. The value of enthalpy change for the reaction is
H   WkJ / mol (Round off to nearest integer)
ii One mole of an ideal gas at 350K is in a 2.0 L vessel of thermally conducting walls, which are
in contact with the surroundings. It undergoes isothermal reversible expansion from 2.0 L to
3.0 L against a constant pressure of 4 atm.
The change in entropy of the system (  Ssystum) is XJ K1 (Round off to nearest integer)
The change in entropy of the surroundings (  Ssurroundings) is Y J K1 (Round off to nearest
integer).
Given: R= 8.314 J K1 Mol1.
12. The Value of ( X + Y + Z ) is

(i) The entropy values (in JK-1 mol-1) of H2(g) = 130, Cl2(g) = 223 and HCl(g) = 186 at 298 K and
1 atm pressure.
Entropy change for the following reaction is X JK-1 mol-1
H 2(g)  Cl 2(g)  2HCl(g)
(ii) The work done to contract a gas in a cylinder is 462 joules. 128 joule energy is evolved in the
process. The internal energy change in the process is Y Joule
(iii) Given that

2C(s)  2O2 (g)  2CO2 (g); H  787 kJ
1
H 2 (g)  O 2 (g)  H 2 O(l); H  286 kJ
2
1
C 2 H 2 (g)  2 O 2 (g)  2CO 2 (g)  H 2O(l); H  1301kJ
2
Heat of formation of acetylene is Z kJ
13. How many of the following statements is/are CORRECT?

(i) H0f  H (aq)  0 ; Under standard conditions
(ii) If the enthalpies of formation of Al2O3 and Cr2O3 are –1596 kJ and –1134 kJ respectively, then
the value of H for the reaction 2Al + Cr2O3  2Cr + Al2O3 is 462 k J
(iii) H 0f H 2 O  0 ; Under standard conditions
(vi) Magnitude of work in reversible isothermal expansion is greater than magnitude of work in
irreversible isothermal expansion
(v) Magnitude of work in two step irreversible expansion is greater than magnitude of work in
three step irreversible expansion
(vi) Change in internal energy for reversible isothermal expansion process is zero, if ideal gas is the
working substance
(vii) Change in Enthalpy for reversible isothermal expansion process is zero, if van der waal gas is
the working substance
(viii) Equation of state of Adiabatic process is TV  1 , if ideal gas is the working substance
(ix) Equation of state of Adiabatic process is T(V  nb) 1 , if Van der waal`s gas is the working
substance
(x) Magnitude of work in reversible isothermal expansion of a Van Der Waal`s gas is
 V  nb  2  1 1 
nRTn  2 n a V  V 
 V1  nb   2 1
(xi) Total heat supplied in reversible isothermal expansion of a Van Der Waal`s gas is
 V  nb 
nRTn  2 
 V1  nb 
(xii) Change in internal energy in reversible isothermal expansion of a Van Der Waal`s gas is
 1 1
n 2 a   
 V2 V1 
(xiii) H0C Cs (Graphite) Hf0 CO2g
(xiv) The unsaturation factor or H-deficiency index of the molecular formula C5H12 is zero

nearest integer.
integer
Enthalpy of sublimation may be determined experimentally but instead of that let us explore an
easier roate for this datum. Enthalpy changes depends only on the initial & the final states &
not on the path. Therefore we must find the same value for enthalpy change whether the
system goes directly from a solid to gas or through the intermediate state of a liquid therefore.
Hsub = Hfus + Hvap. above equation is true only when values are measured at the same
temperature, but if enthalpy data are given at different temperature than enthalpy change can
be calculated by kirchaff’s law.
H2 – H1 = (C P  C P )( T2  T1 )
2 1
If molar heat capacity of

H2O(s) = 35.5 Jk–1 mol–1
H2O(l) = 75.5 Jk–1 mol–1
H2O(g) = 30.5 Jk–1 mol–1
heat of vaporization = 40.66 kJ/mol
heat of fusion of H2O = 6.0 kJ /mol
14. Molar enthalpy of vaporization of H2O at 0ºC is – x kJ/mol The value of x is (Nearest integer )
15. Molar enthalpy of fusion of H2O at 100ºC in kJ/mol
When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at
constant pressure, a temperature increase of 5.7°C was measured for the beaker and its
contents (Expt. 1). Because the enthalpy of neutralisation of a strong acid with a strong base is
a constant (–57.0 kJ mo1–1), this experiment could be used to measure the calorimeter constant.
In a second experiment (Expt. 2), 100 mL of 2.0 M acetic acid (Ka = 2.0  10–5) was mixed
with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise
of 5.6°C was measured. (Consider heat capacity of all solutions as 4.2 J g –1 K–1 and density of
all solutions as 1.0 g mL–1)
16. Enthalpy of dissociation (in kJ mol–1) of acetic acid obtained from the Expt. 2 is
17. The pH of the solution after Expt. 2 is (Round off to nearest integer)
PART- III : MATHEMATICS

correct answer.
1. If n is an even number and ,  are the roots of equation x2 + px + q = 0 and also of equation
1  x  n 
x 2n  pn x n  qn  0 and f  x   , then f   = (where n + n  0, p  0)
1 x n

(A) 0 (B) 1 (C) – 1 (D) none of these
2. The equation (x – 3)9 + (x – 32)9 + (x – 33)9 + ……+ (x – 39)9 = 0

(A) all the roots are real (B) one real and 8 imaginary roots
(C) real roots namely x = 3, 32, …..,39 (D) five real and 4 imaginary roots
3. If x1 , x 2 , x 3 , x 4 are roots of the equation x 4  x 3 sin 2  x 2 cos 2  x cos   sin   0 then

4
 tan
i 1
1
x i is equal to
  
(A)    (B)   2 (C)     (D)    2
2 2
n
 2m 
4.  tan 1   is equal to
m m 2
4 2
m 1
 n2  n   n2  n 
(A) tan 1  2  (B) tan 1  2 
n n2 n n2
 n2  n  2 
(C) tan 1   (D) None of these
 n n 
2

5. Which of the following is a rational number

 1  3
(A) sin  tan 1 3  tan 1  (B) cos   sin 1 
 3 2 4
 1 63   1 5
(C) log 2  sin  sin 1  (D) tan  cos 1 
 4 8  2 3 
 1  1
6. If z = sec–1  x    sec 1  y   where xy < 0, then the possible values of z is (are) :
 x  y
8 7 9 21
(A) (B) (C) (D)
10 10 10 10
7. If ,  are the roots of the equation

 1  x 2  1  x 
 tan      3  1 tan    3  0,    then
 5  5
5 35
(A)      (B)    
12 12
25 2
(C)    (D) 3  4  0
12

(INTEGER TYPE)
3 816
8. If sin 1 x  sin 1 y  sin 1 z  then the value of 3000  x  y  z   2 is equal to
2 x  y2  z 2
9. If cos–1 x – cos–1 (y/2) = , then 400(4x2 – 4xy cos  + y2) + 328 sin2  is equal to a sin2 where
a = ______ .
10. If  = 2sin–1(2/3) and  = 2tan–1 9, then 80 cosec2  + 81cosec2  is equal to _____.
32
11. If (sin–1 x)2 + (sin–1 y)2 + (sin–1 z)2 = , then the maximum value of x + y + z is _____.
4
12. Let x, y, z be non-negative integers such x + y + z = 12, then the maximum value of (xyz + xy +
yz + zx)/16 is _____.
x 3  6x 2  11x  6 a
13. The least possible value of a for which   0 does not have a real solutions
x 3  x 2  10x  8 30
is ____.

nearest integer.
integer
If f : (0, )  (0, ) satisfy f(xf(y)) = x2ya (a  R), then
14. Value of a is
15. Number of solutions of 2f(x) = ex is
Let f(x) = x2 + b1x + c1, g(x) = x2 + b2x + c2 . Let the real roots of f(x) = 0 be ,  and real roots
of g(x) = 0 be  + h,  + h. The least value of f(x) is –1/4. The least value of g(x) occurs at
x = – 7/2
16. The least value of g(x) is k find absolute value of 12k:
17. The roots of f(x) = 0 a and b then sum of the roots is:

RETS - 02 PCM JA - II - CWT - 02 - (22.10.2023) 12th.

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JEE EXPERT

RANK ELEVATOR TEST SERIES (RETS - 02)

A. Question paper format :

Signature of the Candidate Invigilator Signature:

1. Find the current in the branch CD. Consider the battery to

2. Find the value of R such that power dissipated in

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SECTION - II : (Maximum Marks: 12)

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SECTION - III : (Maximum Marks: 24)

8. Three 60 –W, 120 –V light bulbs are connected

9. A battery of 11 Volt is inserted in one of the branches of the circuit

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13. The motion of a vibrating particle is defined by the position vector

Space for Rough Work

SECTION- IV : (Maximum Marks: 12)

Paragraph for Question 14. to 15.

15. At the time of impact, the ratio of speed of 1 to that of 2 is……

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Paragraph for Question 16. to 17.

The figure shows part of some electrical circuit.

16. The reading of A3 is ………..Ampere

17. If R2 is variable, then the value of R2 at which A3 reads zero is ………ohms

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3. Fe2O3(s) + 3/2C(s)  3/2CO2(g) + 2Fe(s) Ho = +234.1 kJ

4. How much energy must besupplied to change 36 g ofice at 0 °C to water at roomtemperature,

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SECTION - II : (Maximum Marks: 12)

5. Which of the following options is/are correct?

7. Which of the following is / are correct statement(s)?

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SECTION - III : (Maximum Marks: 24)

8. How many of the following options is/are correct?

If T1 = 600 K and T2 = 300 K, then;

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9. How many of the following options is/are correct?

(U: internal energy, S : entropy, p : pressure, V = volume, R = gas constant)

10. Among the following the number of state variables is __________ .

11. Find the value of (X+Y+W)

12. The Value of ( X + Y + Z ) is

(iii) Given that

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13. How many of the following statements is/are CORRECT?

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SECTION- IV : (Maximum Marks: 12)

Paragraph for Question 14. to 15.

If molar heat capacity of

15. Molar enthalpy of fusion of H2O at 100ºC in kJ/mol

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Paragraph for Question 16. to 17.

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PART- III : MATHEMATICS

2. The equation (x – 3)9 + (x – 32)9 + (x – 33)9 + ……+ (x – 39)9 = 0

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3. If x1 , x 2 , x 3 , x 4 are roots of the equation x 4  x 3 sin 2  x 2 cos 2  x cos   sin   0 then

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SECTION - II : (Maximum Marks: 12)

5. Which of the following is a rational number

7. If ,  are the roots of the equation