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Ferrous Metals
and Alloys
5.1 INTRODUCTION
Ferrous metals are defined as, those which contain iron as their main constituent. Iron is
abundant, easy to convert from ore to a useful form, and iron and steel are sufficiently
strong and stable for most engineering application.
Ferrous materials, have iron as their base and due to wide range of their properties are
most useful in engineering machines and structures. Owing to the advents in steel
technology and casting technique ferrous metals are cast, shaped and machined in various
shapes and sizes. Several standard shapes of sections are available commercially which
make the job of designer and constructor much easier. They are used for making trusses,
bridges, ships and boilers. For such construction standard section and sheets or plates of
steel are available. The other machine parts like shafts, gears, bearings, pulleys and bodies
of machines can be made in steel through forming, cutting or casting processes or their
combination. Metal cutting tools, dies, punches, jigs and fixtures are also made in ferrous
metal. One of the largest consumer of steel is automobile industry. Despite the modern
trend of making light cars nearly 60% of weight of a car is still due to steel and an average
passenger car contains about 500 kgf of steel in India. Perhaps in countries like U.S.A.
where cars of bigger size are in use this weight could be as high as 800 kgf/car.
The first human effort in the direction of making tools was based upon meteoritic iron
obtained from meteorite that had struck the earth. This happened more than 3000 B.C. In
India the well known Ashoka Column in Delhi was constructed more than 4000 years ago.
The blast furnace was invented in 1340 AD and then it became possible to produce large
quantities of iron and steel.
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5.2.1 Iron
The large family of iron alloys called steel are the most frequently used metal. Iron is
believed to be the tenth abundant element in the universe. Iron makes up 5% of the earth,
crust, easy to convert from ore to a useful form, and iron is sufficiently strong and stable.
FERROUS METALS AND ALLOYS 61
Iron is a metal extracted from iron ore, and is almost never found in the free elemental
state. In order to obtain elemental iron, the impurities must be removed by chemical
reduction. Iron is used in the production of steel, an alloy or solid solution of different
metals, and some non-metals, particularly carbon.
Iron (as Fe2+, ferrous ion) is a necessary trace element found in all known living
organisms. Iron-containing enzymes, usually containing heme prosthetic groups, participate
in catalysis of oxidation reactions in biology, and in transport of a number of soluble gasses.
5.3.2 Contaminants
Ideally iron ore contains only iron and oxygen. In nature this rarely is the case. Typically,
iron ore contains a host of deleterious elements which are unwanted in modern steel.
1. Silica: Iron ore typically contains silicates, usually in the form of quartz. Silica is
undesirable because silicon does not bond with carbon during the smelting process
and can remain in the iron after it is refined. Historically, siliceous iron ore created
wrought iron, a malleable and strong form of iron used by blacksmiths throughout
history. Modern steel-making techniques generally use lime and other fluxes to help
remove the silica from the molten iron ore, and form a slag on the surface of the
molten metal. This slag can then be removed.
2. Phosphorus: Phosphorus is deleterious because it makes steel brittle, even at
concentrations of as little as 0.5%. Phosphorus cannot be easily removed by fluxing
or smelting, and so iron ores must generally be low in phosphorus to begin with. The
iron pillar of India which does not rust, however, is protected by a phosphoric
composition. Phosphoric acid is used as a rust converter because phosphoric iron is
less susceptible to oxidation.
FERROUS METALS AND ALLOYS 63
3. Aluminium: Aluminium is generally present in iron ores as clay. This is usually
removed by washing the iron ore, and by fluxing. However, again, iron oxide deposits
must be relatively low in aluminium in order to be considered ore.
4. Sulphur: Sulphur is unwanted because it produces undesirable sulphur dioxide
gases in the flue emissions from a smelter and interferes with the smelting process.
may take place, basically the reaction of iron oxide with carbon produces carbon monoxide,
which in turn reacts with the iron oxide, reducing it to iron. Preheating the incoming air is
necessary because the burning coke alone does not produce sufficiently high temperatures
for the reactions to occur.
Fig 5.1
The molten metal accumulates at the bottom of the blast furnace, while the impurities
float to the top of the metal. At intervals of four to five hours, the molten metal is tapped,
into ladle cars. Each ladle car can hold as much as 160 tons of molten iron. The molten
metal at this stage has a typical composition of 4 per cent carbon, 1.5 per cent silicon, 1 per
cent manganese, 0.04 per cent sulphur, and 0.4 per cent phosphorus, with the rest being
pure iron. The molten metal is referred to as pig iron. Use of the word pig comes from the
early practice of pouring molten iron into small sand molds, arranged like a litter of small
pigs around a main channel. The solidified metal is called pig and is used in making iron
and steels. The blast furnace is shown in Fig. 5.1.
FERROUS METALS AND ALLOYS 65
The blast furnace remains an important part of modern iron production. Modern furnaces
include Cowper stoves to pre-heat the blast air to high temperatures in order to avoid cooling
(and thus having to re-heat) the mix, and use fairly complex systems to extract the heat
from the hot carbon dioxide when it escapes from the top of the furnace, further improving
efficiency. The largest blast furnaces produce around 60,000 tonnes of iron per week, enough
for about four cars per minute. This is a great increase from the 18th century, when charcoal
blast furnaces averaged 400 tons per year.
Grey cast iron has hardness varying between 149 and 320 BHN and UTS of 150 to 400
MPa.
Uses: Grey cast iron is used in machine tool structures, sanitary work, piston rings, rolling
mills, manhole cover and household appliances.
5.8 STEEL
The most important engineering material today is steel. Iron is the base of all steels which
are widely used for making machines and structures. Ferrous materials are cast, shaped
and machined in various shapes and sizes. Serval standard shapes and sections are available
commercially making designing and constructing easy. The standard sections, sheets and
plates are often used in making boilers, ships, bridges and trusses. Machine parts like
shafts, gears, pulleys, bearings and bodies of machines are made in steel through such
technologies as forming, forging, cutting welding or casting. Steel is used for making punches
dies, jigs, fixtures and cutting tools. Automobile industry is a large consumer of steel. The
increased use of steel in industry is because of its capacity to be produced in various alloyed
forms and response to heat treatment.
Plain carbon steel contains 0.1-0.8% carbon used for general engineering purposes
and 0.9%-1.2% carbon used for wear resistance. Between 1.3 and 2.2% C ferrous material
is normally not used, whereas between 2.4 and 4.2% C it is cast iron.
Steel is a metal alloy whose major component is iron, with carbon content between
0.02% and 1.2% by weight. Carbon is the most cost effective alloying element for iron, but
many other alloying elements are also used. Carbon and other elements act as hardening
agent, preventing line defects in the iron crystal lattice from sliding. Varying the amount
of alloying elements and their distribution in the steel controls qualities such as the hardness,
ductility, and tensile strength. Steel with increased carbon content can be made harder
and stronger than iron, but is also more brittle. The maximum solubility of carbon in iron is
1.7% by weight, occurring at 1130° Celsius; higher concentrations of carbon or lower
temperatures will produce cementite which will reduce the material strength. Steel is also
to be distinguished from wrought iron with little or no carbon, usually less than 0.035%.
5.9 STEEL-MAKING
Steel was first produced in China and Japan in about 600-800 A.D. The process is essentially
one of refining the pig iron obtained from the blast furnace. The refining of pig iron consists
in reduction of the percentage of manganese, silicon, carbon, and other elements, and
control of its composition by the addition of various elements. The molten metal from the
blast furnace is transported into one of three types of furnaces. The steel-making furnaces
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are open hearth, electric, or basic oxygen. The name open hearth derives from the shallow
hearth shape that is open directly to the flames that melt the metal. Developed in the
1860s, the open-hearth furnace is being replaced by electric furnace and by the basic-
oxygen process. These newer methods are more efficient and produce better quality steels.
Steel scrap and a small amount of carbon and limestone are dropped into the electric
furnace through the open roof. Electric furnaces can also use 100 per cent scrap as its
charge. The roof is then closed and the electrodes are lowered. Power is turned on, and
within a period of about two hours the metal melts. The current is shut off, the electrodes
are raised, the furnace is tilted, and the molten metal is poured into a ladle, which is a
receptacle used for transferring and pouring molten metal. Electric furnace capacities range
from 60 to 90 tons of steel per day. The quality of steel produced is better than that of open-
hearth or basic-oxygen process.
In the indirect arc electric furnace as shown in Fig. 5.3, the arc is struck between two
electrodes close to metal.
FERROUS METALS AND ALLOYS 71
The vigorous agitation by the oxygen refines the molten metal through an oxidation
process in which iron oxide is first produced. The oxide reacts with the carbon in the molten
metal, producing carbon monoxide and carbon dioxide. The iron oxide is reduced to iron.
The lance is retracted and the furnace is tapped by tilting it. The opening in the vessel is so
provided that the slag still floats on the top of the molten metal as seen in Fig. 5.5 (e). The
s!ag is then removed by tilting the furnace in the opposite direction.
The BOF process is capable of refining 250 tons of steel in 35 to 50 minutes. Most BOF
steels, which are of better quality than open-hearth furnace steels and have low impurity
levels, are processed into plates, sheets, and various structural shapes, such as I-beams
and channels.
Steel may also be melted in induction furnaces from which the air has been removed,
similar to the one shown in Fig. 5.4. The vacuum melting produces high quality steels
because the process removes gaseous impurities from the molten metal.
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The plain carbon steels are also divided into three groups, as follows:
(a) Eutectoid Steels: Ideally these steels contain 0.83% carbon and structure is entirely
lamellar pearlitic. However, fully pearlitic structure exists in steels containing 0.8%C.
Mn to an extent of 1% reduces carbon in eutectoid steel to 0.7%.
(b) Hypo Eutectoid Steels: Steel containing carbon between 0.008% and 0.83% are
hypoeutectoid. The structure is made of grains of pearlite and ferrite. The increasing
carbon increases proportion of pearlite and thus strength (pearlite is stronger) but
ductility reduces.
(c) Hyper Eutectoid Steels: Steel containing carbon in excess of 0.8% fall in this class.
Pearlite and cementite are present in structure. The strength is high but ductility is
low.
4. Carbon Tool Steel: The carbon percentage varies between 0.9 to 1.6. High hardness
can be achieved through treatment. They are very resistant to wear and hence make good
tooling material.
The common tool steels contain C, W, Cr, Mo, V, Mn, Si in the range of 0.6 to 1.0%. For
shock resistance C is restricted to 0.5%. High temperature strength is provided by 2 to 18%
of W and Mo. V between 0.1 to 2% helps hardenability. Si is added to tool steels to improve
toughness.
5. QUESTIONS
1. Give the classification of metals.
2. What are the effects of different alloying elements on cast iron?
3. How cast iron differs from steel?
4. How will you classify steel?
5. Differentiate among low-carbon steel, medium-carbon steel, high carbon steel.
6. Differentiate between the followings:
(i) White cast iron and Nodular cast iron.
(ii) Grey cast iron and Alloy cast iron.
7. Write the short notes on the following:
(i) Iron ore
(ii) Pig iron
(iii) Blast furnace
8. Define alloy steel. Why the alloying elements are added to steel?
9. What is the effect of carbon, sulphur and phosphorus on the properties of steel?
10. Classify stainless steel and mention uses of different stainless steels.
11. What are different alloying elements present in tool steels? What properties develop by their
addition? Describe the applications.
12. What properties are desired in tool steels? Correlate these properties with alloying elements.
13. What are hard and soft magnetic materials? Give examples of iron base materials and other
alloys used as magnetic materials.
14. What is high speed steel? Describe composition of 18:4:1 steel. For what purposes this steel
is suitable?
15. Give general classification of material.
16. What is pig iron? How is it produced and what are its uses?
17. Distinguish between grey cast iron and white cast iron. Mention uses.
18. Distinguish between malleable and nodular cast irons.