Phys. Chem.

Focus 1. The Properties of Gases

Youngmin You
odds2@yonsei.ac.kr
Chemical and Biomolecular Engineering
𝑛
𝑛
𝑛𝑀𝐴𝑣 Δ𝑡
𝑉
 𝑛𝑀𝐴𝑣
𝑉

𝑛𝑀𝑣 𝑛𝑀 𝑣 1 𝑛𝑀𝑣
𝑉 𝑉 3 𝑉
𝑣 + 𝑣 + 𝑣 = 𝑣

𝑛𝑀𝑣 1/3 𝑣 𝑣
𝑝𝑉 /
3 𝑣 𝑣

𝑓 𝑣 𝐾𝑒 𝑓 𝑣 𝑓 𝑣 𝑓 𝑣 𝑓 𝑣 𝐾 𝑒
 𝑓 𝑣 𝑑𝑣 1

/
2𝜋𝑘𝑇 𝜋 /
𝐾 𝑒 𝑑𝑣 𝐾 1 𝑒 𝑑𝑥
𝑚 𝑘

𝑚 /
𝐾
2𝜋𝑘𝑇
𝑚 /
𝑓 𝑣 𝑒
2𝜋𝑘𝑇

/
𝑒 𝑑𝑣 𝑑𝑣 𝑑𝑣

𝑚 /
𝑓 𝑣 𝑑𝑣 4𝜋𝑣 𝑑𝑣 𝑒
2𝜋𝑘𝑇
𝑚 /
𝑓 𝑣 4𝜋 𝑣 𝑒
2𝜋𝑘𝑇
 𝑚 /
𝑓 𝑣 4𝜋 𝑣 𝑒
2𝜋𝑘𝑇

3𝑅𝑇 3 𝜋 /
𝑣 𝑣 𝑓 𝑣 𝑑𝑣 𝑥 𝑒 𝑑𝑥
𝑀 8𝑘 𝑘
/
/
3𝑅𝑇
𝑣 𝑣
𝑀

𝑛𝑀𝑣
𝑝𝑉
3

𝑝𝑉 𝑛𝑅𝑇
 / /
8𝑅𝑇 8 1
𝑣 𝑣 𝑓 𝑣 𝑑𝑣 𝑣 𝑥 𝑒 𝑑𝑥
𝜋𝑀 3𝜋 2𝑘

/ /
2𝑅𝑇 2
𝑣 𝑣
𝑀 3

/
𝑣 2 𝑣
 𝒩𝜎𝑣 Δ𝑡 𝑁 𝑛𝑁 𝑛𝑁 𝑝𝑁 𝑝
𝒩
Δ𝑡 𝑉 𝑉 𝑛𝑅𝑇/𝑝 𝑅𝑇 𝑘𝑇

𝒩𝜎𝑣
𝑝𝜎𝑣
𝑘𝑇

𝑣 𝑘𝑇
𝜆
𝑧 𝜎𝑝
 𝑉
𝑍
𝑉°

𝑝𝑉 𝑍𝑅𝑇

𝑝𝑉 𝑅𝑇 1 𝐵𝑝 𝐶𝑝 ⋯

𝐵 𝐶
𝑝𝑉 𝑅𝑇 1 ⋯
𝑉 𝑉
 𝑛𝑅𝑇 𝑛𝑅𝑇
𝑝 𝑝
𝑉 𝑉 𝑛𝑏

𝑛𝑅𝑇 𝑛𝑅𝑇 𝑛
𝑝 𝑝 𝑎
𝑉 𝑛𝑏 𝑉 𝑛𝑏 𝑉

𝑅𝑇 𝑎
𝑝
𝑉 𝑛𝑏 𝑉
 𝑅𝑇 𝑎
𝑝
𝑉 𝑛𝑏 𝑉

d𝑝
0
d𝑉

d 𝑝
0
d𝑉