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SYSTEMS
Systems
Thermodynamic Basics
Circular Processes
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 2
System and System Boundaries
System
A system is a definable part of the world that is boundary
interesting to us. It is separated from its
environment by a system boundary. System
Environment
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 3 Source: Thielen (2011)
System Types
Isolated system
▪ Matter and energy impermeable Example: Thermos flask
▪ No energy transit possible
Closed system
▪ Matter impermeable Example: Closed cylinder of a combustion
▪ Energy transfer in the form of: engine
− Work Work
− Heat
Heat
Open system
▪ Matter permeable Example: Cooled turbo compressor
▪ Energy transfer in the form of:
Material
− Work Material
− Heat
− Material-bound energy transport
Work Heat
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 4 Source: Thielen (2011)
Contact of Two Technical Systems
Equilibrium A Equilibrium B
Thermally conductive:
“diatherm“ Fully isolated:
“adiabatic“
Pressure Pressure Pressure
Pressure drop increase
Warm Warm
Hot Cold
gas gas
gas gas
Temperature Temperature
Temperature Temperature
drop increase
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 5
From System to Model
In order to be able to describe and analyse the world, we divide the system "world" into
System smaller and smaller pieces, into subsystems, and these in turn into sub-sub-systems etc.
The resulting systems are often analysed with the help of mathematical methods.
A model is closely related to the purpose of the problem being investigated. The problem
determines the system, system boundaries and the relevant system parameters.
Environment
System boundary
Example
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 7
Overview of Energy System Research and Analysis
Definition of energy ▪ Investigation of the structural elements of a system, i.e. the representation
system analysis of how the system works
Goals of systems ▪ Support decisions in energy policy and energy research with regard to
research and systems technologies and infrastructures for energy supply and energy conversion
analysis on a knowledge-based and systematic basis
▪ "What could/should the energy system of the future (in a target year to be
defined) look like, if on the one hand the emission reduction targets of the
European Union in Germany are to be achieved and on the other hand the
Examples
nuclear power phase-out is to be maintained?”
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 8 Source: Möst & Wolf & Grunwald (2008)
Example:
Create a Model of a System Representing a House
𝑥1 (𝑡) 𝑦1 (𝑡)
Input parameters at
System
…
…
time t Outputs at time t
𝑥𝑛(𝑡) 𝑦𝑚 (𝑡)
Electricity People
Air Waste
Water Heat
People Ash
O2
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 9
Example:
Simulating Thermal Energy Flows of a House
𝑸𝑷 Primary energy
𝒇𝑷 Primary energy factor according to DIN 185991
𝑸𝒇𝒖𝒆𝒍 Energy content of the fuel used
𝑸𝑻 Transmission heat losses
𝑸𝑽 Ventilation heat losses
𝑸𝑩 Internal heat demand and losses, e.g. drinking water,
cooling and technical equipment losses
QI +QR QT 𝑸𝑰 Internal heat gains
QP
𝑸𝑺 Solar gains
𝑸𝑨𝑽 Technical system losses of heat generation and distribution
QV 𝑸𝑯𝑾 Heat requirement for hot water heating
𝜼𝑭 Efficiency of heat gains (e.g. 0,95)
QB+QC+QHW +QAV 𝑸𝑹 Regenerative or recovered energy
𝑸𝑪 Cooling requirement
Systems
Thermodynamic Basics
Circular Processes
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 11
What is Thermodynamics?
▪ Energy balancing:
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 12 Source: Baehr & Kabelac (2012)
Elements of Thermodynamics
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 13 Source: Baehr & Kabelac (2012)
State and Process Variables
State variables Process variables
Thermal (depend on the Caloric (describe the energy
prevailing temperature) content of a system) Work: 𝑊
Internal energy: 𝑈 Power: 𝑃 = 𝑑𝑊Τ𝑑𝑡
Temperature: 𝑇
Specific internal energy: 𝑢:=U/m
Enthalpy: 𝐻
Pressure: 𝑝
Specific enthalpy: ℎ: = 𝐻/𝑚 Heat: 𝑄
Entropy: S Heat flow: 𝑄ሶ = 𝑑𝑄ൗ𝑑𝑡
Volume: 𝑉
Specific entropy: 𝑠: = 𝑆/𝑚
Extensive properties: Properties, whose values result from the division of a system as the sum of
the corresponding state variables of the parts: 𝑍 = 𝑍𝐴 + 𝑍𝐵 + 𝑍𝐶 + …
Intensive properties: Properties that are not additive when dividing a system or joining
subsystems into a complete system.
Absolute properties: Not related to a uniform basis.
If one divides the extensive size 𝑍 of a system by its mass, its amount of matter or its volume, one
gets specific quantity, molar quantity and density. They are all intensive sizes:
▪ Specific quantity: 𝑧 ≔ 𝑍/𝑚
▪ Molar quantity: 𝑍𝑚 = 𝑍/𝑛
▪ Density: 𝑍𝑉 ≔ 𝑍/𝑉
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 14 Source: Baehr & Kabelac (2012)
Energy Units, Definitions, Conversion Factors
1) Oil equivalent
2) Prefixes
Coal equivalent
Nano n 10-9 A billionths
3) Kilocalorie -6
Micro u 10 A millionths
4) Kilowatt hour Milli m 10 -3 A thousandths
5) Centi c 10 -2 A hundredths
British Thermal Unit
Kilo k 10 3 thousand
Mega M 10 6 Million (dt. “Million“)
Oil: barrels (bbl); Giga G 10 9 Billion (dt. “Milliarde)
1 bbl = 159 l ≈ 0.136 t Tera T 10 12 Trillion (dt. “Billion“)
Peta P 10 15 Quadrillion
Gas: 1 cubic feet / day = 10.34 m3/year 18
Exa E 10 Quintillion
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 15 Source: Own presentation based on AGEB (2010)
Value of Energy
Law of
The sum of all forms of energy always remains the same, but:
Conservation
Energy = Exergy + Anergy.
of Energy
The part of the energy that can be converted into any other form of
Exergy energy under given thermodynamic conditions of the environment.
The exergy share decreases in all conversion processes.
The part of the energy that cannot be converted into other forms of
Anergy energy, e.g. thermal energy at the temperature level of the
environment.
Energy consumption in the thermodynamic sense does not exist, as the sum of exergy
and anergy is constant (1st law).
However, energy can be degraded form exergy to anergy and it is never possible to
convert anergy into exergy (2nd law). This principle could be interpreted as energy
consumption.
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 16
Definitions of Energy
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 17 Source: Own presentation
Energy of a System (Energy Level)
System boundaries
Ekin
U
-Epot +Epot
Ekin
Epot - Energy of position (potential) (forces on the stationary system)
System energy E = Ekin - Energy of movement (kinetic) (forces on the moving system)
U - Internal energy (forces inside the system)
E = Epot + Ekin + U = const. (Principle of energy conservation: Energy of a constant mass can
neither be “produced“ nor “destroyed“, but is conserved.
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 18
The First Law of Thermodynamics
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 19 Sources: Baehr & Kabelac (2012), Tsatsaronis (2013)
Entropy and the Second Law of Thermodynamics
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 20 Sources: Baehr & Kabelac (2012), Tsatsaronis (2013); Image source: Stündle (2011)
The Limited Convertibility of Energy
▪ The exergy share is decisive for the usability of energy, since energy with a high
exergy share is more valuable than energy with a high anergy share.
▪ Energy that is used in many different processes and converted into different
energies is likely to have a high exergy share.
▪ Simplified formulation of the second law of thermodynamics:
“It is never possible to turn anergy into exergy.“
▪ Conclusions from the combination with the simplified formulation:
− Irreversibilities occur during the conversion of exergy into anergy.
− If the conversion is ideal, the borderline case occurs and no anergy is generated.
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 21 Source: Baehr & Kabelac (2012)
Anergy and Exergy of Energy Forms
U - Internal energy:
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 22 Source: Own representation
Structure
Systems
Thermodynamic Basics
Circular Processes
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 23
Thermodynamic Circular Process of a Gas Power Plant
2 Turbine in
Combustion
chamber
1 Compressor
4
s
Component Function Process step Description
Compression of the air to the high pressure
Compressor 1 to 2 Isentropic compression in the compressor
in the combustion chamber
Combustion 2 to 3 Isobaric heat supply in combustion chamber
Combustion under supply of fuel
chamber 3 to 4 Isentropic expansion in the turbine
Expansion of the combustion gas to 4 to 1 Isobaric heat dissipation (open process)
Turbine
approximately the ambient pressure
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 24 Sources: Strauss (2016), Baehr & Kabelac (2012)
Joule Process of a Gas Turbine Plant
(James Prescott Joule, 1818 – 1889)
p T
Qin 3 p2 = p3 = const.
2 3
p2 = p3
4
2 p1 = p4 = const.
W Q
p1 = p4
1 4 1
V s
Wout: Qin:
−𝑊 = 𝑊𝑖𝑛 − 𝑊𝑜𝑢𝑡 = 𝑄𝑖𝑛 − 𝑄𝑜𝑢𝑡
W in: Qout:
4 T0
T0 = const. 1 4
V s
a d b c e s f
Q0
Conducted work W out (2-3-4-c-a): Applied heat Q (2-3-f-e):
Applied work W in (4-1-2-a-c): Discharged heat Q0 (4-1-e-f):
Effective work: −𝑊 = 𝑄 − 𝑄0
−𝑊 𝑄 − 𝑄0 𝑄0
Thermal efficiency : 𝜂𝑡ℎ = = =1−
𝑄 𝑄 𝑄
𝑇0 Δ𝑠 𝑇0
Carnot efficiency : 𝜂𝐶 = 1 − =1−
𝑇Δ𝑠 𝑇
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 26 Source: Own representation
The Realization of a Continuous Open Circular Process
in Reality: The Gas Turbine (Joule Process)
Cross-section of a stationary
Operating principle
axial gas turbine
▪ In its simplest form, a gas turbine consists
of a turbo compressor, a combustion Combustion
Turbine
chamber, the actual turbine and the chamber
generator.
Compressor Exhaust
▪ Working method: the compressor draws in gas
air from the environment and compresses it
to several times its pressure. The
compressed air is fed into the combustion
chamber where it reacts with the fuel
supplied.
▪ In the turbine, the gas is expanded to
ambient pressure and exits the plant.
▪ The generator, which rotates on the same
shaft, converts mechanical energy into
electrical energy.
▪ The compressor also sits on the same shaft
and is driven by the turbine. Fresh air
▪ In the open process, the combustion air is Energy conversion chain:
drawn in from the environment and the Mechanical
exhaust gases are released back into it. Chemical Thermal Pressure, rotation
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 27 Sources: Baehr & Kabelac (2012), Strauss (2016)
The Realization of a Continuous Open Circular Process
in Reality: The Aircraft Engine (Joule Process)
Cross-section of an aircraft
Operating principle
engine
▪ Air is sucked in and flows through the
engine from the front to the rear (a part of
the air passes outside as a sheath flow).
▪ In the front part the air is compressed by a
compressor over several stages.
▪ In the combustion chamber, thermal energy
is added to the compressed air by the
continuous combustion of the fuel.
▪ The exhaust gas jet is accelerated, flows
through the turbine blades at the rear of the
engine and exits the turbine.
▪ The resulting thrust jet provides the
propulsion energy for the aircraft.
▪ The rotational energy absorbed via the Energy conversion chain:
turbine blades simultaneously drives the Mechanical
Chemical Thermal Pressure, rotation
compressor.
Kerosene Combustion Kinetic
Recoil
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 28 Sources: Baehr & Kabelac (2012), Strauss (2016)
Example: Thermal Power Plant Berlin Mitte
Turbine: Casing
with guide vanes
Combustion
Turbine: Impeller
chamber
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 29 Image sources: Berliner Kurier (2013), Vattenfall (2013)
References – Literature
▪ AGEB (2010): Arbeitsgemeinschaft Energiebilanzen e.V. Einheitenumrechner. http://www.ag-
energiebilanzen.de/33-0-Energieeinheitenumrechner.html
▪ Baehr & Kabelac (2012): Baehr, H. D.; Kabelac, S.: Thermodynamik: Grundlagen und technische Anwendungen;
mit zahlreichen Tabellen sowie 74 Beispielen. 16. neu bearb. und erw. Aufl. Springer-Lehrbuch. Berlin, 2016.
▪ Imboden (2008): Imboden, D.M: Systemanalyse: Einführung in die mathematische Modellierung natürlicher
Systeme. 3. korrigierter Nachgedruckt der 1. Auflage. Springer, 2008.
▪ Möst & Wolf & Grunwald (2008): Möst, D.; Fichtner, W.; Grunwald, A.: Energiesystemanalyse: Tagungsband des
Workshops "Energiesystemanalyse" vom 27. November 2008 am KIT Zentrum Energie, Karlsruhe.
▪ Schellong (2016): Schellong, W.: Analyse und Optimierung von Energieverbundsystemen. Springer-Verlag Berlin
Heidelberg.
▪ Strauss (2016): Strauss, K.: Kraftwerkstechnik zur Nutzung fossiler, nuklearer und regenerativer Energiequellen.
7. Auflage, Springer Vieweg, S. 25. VDI-Buch, Berlin, 2016.
▪ Thielen (2011): Thielen, K.: Skript – Technische Thermodynamik. https://www.thm.de/wi/images/user/Thielen-
72/Downloads/Thermodynamik/TT-A.pdf
▪ Tsatsaronis (2008): Tsatsaronis, G.: Thermodynamik I, Skript zur Vorlesung. Institut für Energietechnik,
Energieumwandlung und Umweltschutz. Technische Universität Berlin, 2008.
▪ Tsatsaronis (2013): Tsatsaronis, G.: Energietechnik II, Skript zur Vorlesung. Institut für Energietechnik,
Energieumwandlung und Umweltschutz. Technische Universität Berlin, 2013.
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 30
References – Image Sources
▪ Berliner Kurier (2013): http://www.berliner-kurier.de/berlin/kiez---stadt/das-kraftwerk-an-der-jannowitzbruecke-im-
heissen-herz-von-mitte-4009658
▪ Stündle (2011): Pendelschwingung; https://upload.wikimedia.org/wikipedia/commons/1/1c/Pendelschwingung.gif
▪ Vattenfall (2013): Umwelterklärung 2013 – Heizkraftwerk Mitte, Berichtsjahr 2012.
Systems | Prof. Dr.-Ing. Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 31