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SABU THOMAS
The Vice Chancellor of Mahatma Gandhi University, Kottayam
and
Founder Director of International and Inter University Centre for
Nanoscience and Nanotechnology, and Professor at School of
Chemical Sciences, Mahatma Gandhi University, Kottayam, India
NANDAKUMAR KALARIKKAL
Director and an Associate Professor of International and Inter
University Centre for Nanoscience and Nanotechnology, and Director
and Chair of School of Pure and Applied Physics, Mahatma Gandhi
University, Kottayam, India
YVES GROHENS
Director of LIMATB Laboratory, University of South Brittany (UBS),
France
VANJA KOKOL
Associate Professor at University of Maribor, Faculty of Mechanical
Engineering, Slovenia
Elsevier
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This book and the individual contributions contained in it are protected under copyright by
the Publisher (other than as may be noted herein).
Notices
Knowledge and best practice in this field are constantly changing. As new research and
experience broaden our understanding, changes in research methods, professional practices,
or medical treatment may become necessary.
Practitioners and researchers must always rely on their own experience and knowledge in
evaluating and using any information, methods, compounds, or experiments described
herein. In using such information or methods they should be mindful of their own safety
and the safety of others, including parties for whom they have a professional responsibility.
To the fullest extent of the law, neither the Publisher nor the authors, contributors, or
editors, assume any liability for any injury and/or damage to persons or property as a matter
of products liability, negligence or otherwise, or from any use or operation of any methods,
products, instructions, or ideas contained in the material herein.
List of Contributors xi
1.1 Introduction 1
1.2 Emerging 2D Nanomaterials: Uniqueness and Advances 3
1.3 Synthesis Approaches 5
1.4 Summary and Outlook 16
References 17
v
vi Contents
4.1 Introduction 85
4.2 CS Fundamentals 88
4.3 Microstructural Characteristics of Combustion-Derived Nanomaterials 95
4.4 Conclusions 112
References 114
Index 557
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LIST OF CONTRIBUTORS
xi
xii List of Contributors
Krystian Mistewicz
Institute of Physics, Silesian University of Technology, Katowice, Poland
N.M. Mubarak
Department of Chemical Engineering, Faculty of Engineering and Science,
Curtin University, Sarawak, Malaysia
A.S. Mukasyan
Department of Chemical & Biomolecular Engineering, University of Notre,
Notre Dame, IN, United States
Ramanuj Narayan
Polymers and Functional Materials Division, CSIR-Indian Institute of Chemical
Technology, Hyderabad, India
Jovan M. Nedeljković
Vinča Institute of Nuclear Sciences, University of Belgrade, Belgrade, Serbia
Sabzoi Nizamuddin
School of Engineering, RMIT University, Melbourne, VIC, Australia
Marian Nowak
Institute of Physics, Silesian University of Technology, Katowice, Poland
José Antonio Palenzuela
Department of Organic Chemistry, Universitary Institute of Bio-Organic
Chemistry, University of La Laguna, La Laguna, Tenerife, Spain
A.B. Pandit
Institute of Chemical Technology, Matunga, India
Dipak Pinjari
Institute of Chemical Technology, Matunga, India
Yasir Beeran Pottathara
University of Maribor, Faculty of Mechanical Engineering, Slovenia
G. Praveen
International and Interuniversity Centre for Nanoscience and Nanotechnology,
Mahatma Gandhi University, Kottayam, India
Khadija Qureshi
Department of Chemical Engineering, Mehran University of Engineering and
Technology, Jamshoro, Pakistan
Shweta Raj
Department of Biotechnology, National Institute of Technology, Warangal,
India
K.V.S.N. Raju
Polymers and Functional Materials Division, CSIR-Indian Institute of Chemical
Technology, Hyderabad, India
D. Narayana Rao
School of Physics, University of Hyderabad, Hyderabad, India
xiv List of Contributors
Tanima Saha
Department of Molecular Biology & Biotechnology, University of Kalyani,
Kalyani, India
V. Saikiran
Department of Electronics and Physics, Institute of Science, GITAM,
Visakhapatnam, India; School of Physics, University of Hyderabad, Hyderabad,
India
Noor Salam
Department of Chemistry, University of Kalyani, Kalyani, India
Santanu Sasidharan
Department of Biotechnology, National Institute of Technology, Warangal,
India
Prakash Saudagar
Department of Biotechnology, National Institute of Technology, Warangal,
India
Yogesh Sharma
Centre of Nanotechnology, Indian Institute of Technology Roorkee, Roorkee,
India; Department of Physics, Indian Institute of Technology Roorkee,
Roorkee, India
M.T.H. Siddiqui
School of Engineering, RMIT University, Melbourne, VIC, Australia
Shirish Sonawane
Chemical Engineering Department, National Institute of Technology, Warangal,
India
Shriram Sonawane
Chemical Engineering Department, Visvesvaraya National Institute of
Technology, Nagpur, India
F.A. Taher
Chemistry Department, Faculty of Science (Girls Branch), Al-Azhar University,
Cairo, Egypt; Al-Azhar Technology Incubator (ATI), Cairo, Egypt; Physics
Department, Faculty of Science, (Girls), Al-Azhar University, Cairo, Egypt
Sabu Thomas
The Vice Chancellor of Mahatma Gandhi University, Kottayam, India; Founder
Director of International and Inter University Centre for Nanoscience and
Nanotechnology, Mahatma Gandhi University, Kottayam, India; Professor at
School of Chemical Sciences, Mahatma Gandhi University, Kottayam, India
Lazaros Tzounis
Department of Materials Science & Engineering, University of Ioannina,
Ioannina, Greece
List of Contributors xv
Chad Wallis
School of Aerospace and Mechanical Engineering, University of Oklahoma,
Norman, OK, United States
X.S. Zhao
School of Chemical Engineering, The University of Queensland, Brisbane,
QLD, Australia
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CHAPTER 1
Contents
1.1 Introduction 1
1.2 Emerging 2D Nanomaterials: Uniqueness and Advances 3
1.3 Synthesis Approaches 5
1.3.1 Top-Down Approaches 5
1.3.2 Bottom-Up Approaches 13
1.4 Summary and Outlook 16
References 17
1.1 INTRODUCTION
Nanoscience and nanotechnology represent the manipulation of matter
on an atomic and molecular scale, which holds enormous economic
potential for the present and future markets. The production of ever
smaller, faster, and more efficient products with acceptable price-to-
performance ratios has become an increasingly important success factor in
the international competition for many industries. One of the first insights
into the potential benefits of making devices at the nanoscale was by
Corresponding Author: ptyasirbeeran@gmail.com