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0 7 . 4 108 g of aluminum reacts with 1.21 kg of copper chloride to produce copper. box

The equation for the reaction is:

2 Al + 3 CuCl2 → 3 Cu + 2 AlCl3

Calculate the maximum mass of copper produced in grams (g).

You should determine the limiting reactant.

Relative atomic masses (Ar): Al = 27 Cu = 63.5

Relative formula masses (Mr): CuCl2 = 134.5 AlCl3 = 133.5

[6 marks]

Limiting reactant is

Mass of copper = g

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Potassium has different isotopes. box

0 1 . 4 What is meant by ‘isotopes’?

You should refer to subatomic particles.

[2 marks]

0 1 . 5 Table 1 shows the mass numbers and the percentage abundance of two
isotopes of potassium.

Table 1

Mass number Percentage abundance

39 93.1

41 6.9

Calculate the relative atomic mass (Ar) of potassium.

Give your answer to 1 decimal place.

[3 marks]

Relative atomic mass (1 decimal place) = 8

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0 1 Magnesium is in Group 2 of the periodic table. box

1.0 g of magnesium reacted with chlorine to produce magnesium chloride.

0 1 . 1 Which types of element react when magnesium reacted with chlorine?

[1 mark]
Tick () one box.

A metal and a metal

A metal and a non-metal

A non-metal and a non-metal

0 1 . 2 Write the word equation for the reaction when magnesium reacts with chlorine.
[1 mark]

+ →

0 1 . 3 What apparatus was used to measure the mass of 1.0 g of magnesium?

[1 mark]
Tick () one box.

Balance

Beaker

Ruler

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0 1 . 4 What mass of magnesium chloride was produced? box

[1 mark]
Tick () one box.

Less than 1.0 g

1.0 g

More than 1.0 g

0 1 . 5 Magnesium reacts with oxygen to produce magnesium oxide.

Calculate the percentage mass of magnesium in magnesium oxide (MgO).

Relative atomic mass (Ar): Mg = 24

Relative formula mass (Mr): MgO = 40

[2 marks]

Percentage mass of magnesium = %

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Magnesium carbonate decomposes to produce magnesium oxide and carbon dioxide. box

The word equation for the reaction is:

magnesium carbonate → magnesium oxide + carbon dioxide

Four students heated 2.00 g of magnesium carbonate for 10 minutes.

Table 1 shows the results.

Table 1

Mass of carbon dioxide produced in g

Student 1 Student 2 Student 3 Student 4 Mean

0.97 0.91 0.50 0.95 X

0 1 . 6 What is the most likely reason for Student 3’s anomalous result?
[1 mark]
Tick () one box.

The student heated more than 2.00 g of magnesium carbonate.

The student heated the magnesium carbonate for less than 10 minutes.

The student used a higher temperature.

0 1 . 7 Calculate value X in Table 1.

Do not use the anomalous result.

Give your answer to 2 significant figures.

[3 marks]

X (2 significant figures) = g 10

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0 6 Metal oxides are produced when metals are heated in air. box

A student investigated the change in mass when 0.12 g of magnesium was

heated in air.

Figure 5 shows the apparatus.

Figure 5

The student measured the mass of magnesium oxide produced.

0 6 . 1 0.12 g of magnesium reacted to produce 0.20 g of magnesium oxide.

Calculate the number of moles of oxygen gas (O2) that reacted.

Relative atomic mass (Ar): O = 16

[3 marks]

Moles of oxygen gas =

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0 6 . 2 The student repeated the experiment without a lid on the crucible. box

Suggest why the mass of magnesium oxide produced would be different without a lid
on the crucible.
[2 marks]

0 6 . 3 Copper reacts with oxygen to produce copper oxide.

63.5 g of copper produces 79.5 g of copper oxide.

Calculate the mass of copper oxide produced when 0.50 g of copper

reacts with oxygen.

Give your answer to 3 significant figures.

[3 marks]

Mass (3 significant figures) = g

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0 6 . 4 Iron reacts with oxygen to produce an oxide of iron. box

0.015 moles of iron reacts with 0.010 moles of oxygen gas (O2).

Determine:
• the formula of the iron oxide produced
• the balanced symbol equation for the reaction.
[4 marks]

Formula of iron oxide =

Balanced symbol equation

12

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0 5 . 6 The student repeated the experiment with an unknown metal Q instead box

of magnesium.

All the other variables were kept the same.

The student recorded a smaller temperature change.

Suggest the identity of metal Q.

Give one reason for your answer.

[2 marks]

Metal Q

Reason

0 5 . 7 A copper sulfate solution contained 0.100 moles of copper sulfate dissolved

in 0.500 dm3 of water.

Calculate the mass of copper sulfate in 30.0 cm3 of this solution.

Relative formula mass (Mr): CuSO4 = 159.5

[4 marks]

14
Mass = g

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0 6 . 3 Gold reacts with the elements in Group 7 of the periodic table. box

0.175 g of gold reacts with chlorine.

The equation for the reaction is:

2 Au + 3 Cl2 → 2 AuCl3

Calculate the mass of chlorine needed to react with 0.175 g of gold.

Give your answer in mg

Relative atomic masses (Ar): Cl = 35.5 Au = 197

[5 marks]

10
Mass of chlorine = mg

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0 4 This question is about copper and fuels. box

0 4 . 1 Copper is extracted from low-grade ores by phytomining.

Describe how copper metal is produced by phytomining.

[4 marks]

0 4 . 2 Another method of extracting copper from low-grade ores is bioleaching.

A solution of copper sulfate (CuSO4) produced by bioleaching has a

concentration of 0.319 g/dm3

Relative atomic masses (Ar): Cu = 63.5 O = 16 S = 32

Calculate the number of moles of copper that can be produced from 1 dm3 of
this solution.
[3 marks]

Number of moles of copper = mol

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0 7 . 4 The student gradually added nitric acid to ammonia solution. box

Which row, A, B, C or D, shows the change in pH as the nitric acid is

added until in excess?
[1 mark]
Tick () one box.

pH of ammonia pH after addition of

solution at start excess nitric acid

A 10 7

B 2 10

C 7 1

D 10 2

0 7 . 5 Calculate the percentage by mass of oxygen in ammonium nitrate (NH4NO3).

Relative atomic masses (Ar): H=1 N = 14 O = 16

Relative formula mass (Mr): NH4NO3 = 80

[3 marks]

Percentage by mass of oxygen = %

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0 2 . 4 The student gradually added nitric acid to ammonia solution. box

Which row, A, B, C or D, shows the change in pH as the nitric acid is

added until in excess?
[1 mark]
Tick () one box.

pH of ammonia pH after addition of

solution at start excess nitric acid

A 10 7

B 2 10

C 7 1

D 10 2

0 2 . 5 Calculate the percentage by mass of oxygen in ammonium nitrate (NH4NO3).

Relative atomic masses (Ar): H=1 N = 14 O = 16

Relative formula mass (Mr): NH4NO3 = 80

[3 marks]

Percentage by mass of oxygen = %

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0 4 Fertilisers are formulations. box

0 4 . 1 What is a formulation?
[1 mark]

0 4 . 2 A bag of fertiliser contains 14.52 kg of ammonium nitrate (NH4NO3).

Relative formula mass (Mr): NH4NO3 = 80

Calculate the number of moles of ammonium nitrate in the bag of fertiliser.

Give your answer in standard form to 2 significant figures.

[4 marks]

Moles of ammonium nitrate = mol

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0 6 Group 2 metal carbonates thermally decompose to produce a metal oxide and a gas. box

0 6 . 1 Give the formula of each product when calcium carbonate (CaCO3) is heated.
[2 marks]

and

0 6 . 2 The relative formula mass (Mr) of a Group 2 metal carbonate is 197

Relative atomic masses (Ar): C = 12 O = 16

Calculate the relative atomic mass (Ar) of the Group 2 metal in the metal carbonate.

Name the Group 2 metal.

[3 marks]

Relative atomic mass (Ar) =

Metal

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0 8 This question is about iron. box

Iron reacts with dilute hydrochloric acid to produce iron chloride solution and one
other product.

0 8 . 1 Name the other product.

[1 mark]

0 8 . 2 Suggest how any unreacted iron can be separated from the mixture.
[1 mark]

Magnesium reacts with iron chloride solution.

3 Mg + 2 FeCl3  2 Fe + 3 MgCl2

0 8 . 3 0.120 g of magnesium reacts with excess iron chloride solution.

Relative atomic masses (Ar): Mg = 24 Fe = 56

Calculate the mass of iron produced, in mg

[5 marks]

Mass of iron = mg

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0 4 . 8 A student repeated the experiment with a different Group 2 metal carbonate (XCO3). box

The relative formula mass (Mr) of XCO3 is 84

Relative atomic masses (Ar): C = 12 O = 16

Calculate the relative atomic mass (Ar) of X.

Name metal X.

Use the periodic table.

[4 marks]

Relative atomic mass (Ar) =

Metal X is

16

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