Date Planned : __ / __ / __ Daily Tutorial Sheet-1 Expected Duration : 90 Min

Actual Date of Attempt : __ / __ / __ Level-1 Exact Duration :_________

1. The correct order of reducing abilities of hydrides of V group elements is :

(A) NH3  PH3  AsH3  SbH3  BiH3 (B) NH3  PH3  AsH3  SbH3  BiH3
(C) NH 3  PH3  AsH 3  SbH3  BiH 3 (D) SbH3  BiH 3  AsH3  NH3  PH3

2. The correct order of acidic nature of oxides is in the order :

(A) NO  N 2O  N 2O 3  NO 2  N 2O5 (B) N 2O  NO  N 2O 3  NO 2  N 2O5
(C) N 2O5  NO2  N2O3  NO  N 2O (D) N 2O5  N2O3  NO2  NO  N 2O

3. Which of the following(s) when heated give nitrogen gas ?

(A) (NH 4 )2 Cr2O7 (B) Ba(N 3 )2 (C) NH 4 NO 3 (D) Both (A) & (B)

4. Which of the following pairs is obtained on heating ammonium dichromate ?

(A) N 2 and H2O (B) N 2O and H2O (C) NO 2 and H2O (D) NO and NO 2

5. The most stable hydride is :

(A) NH3 (B) PH 3 (C) AsH 3 (D) SbH 3

6. Which of the element of nitrogen family produce maximum number of oxy-acids ?

(A) N (B) P (C) As (D) Sb

7. Which of the following is the correct order of increasing enthalpy of vaporization ?

(A) NH3  PH3  AsH3 (B) AsH3  PH3  NH3
(C) PH3  AsH 3  NH 3 (D) NH 3  AsH 3  PH 3

8. Correct order of decreasing thermal stability is as :

(A) NH 3  PH 3  AsH 3  SbH3 (B) PH3  NH 3  AsH 3  SbH3
(C) AsH3  PH3  NH3  SbH3 (D) SbH3  AsH3  PH3  NH3

9. The following are some statements related to V A group hydrides :

(I) Reducing property increases from NH3 to BiH 3

(II) Tendency to donate lone pair decreases from NH3 to BiH 3

(III) Thermal stability of hydrides decreases from NH3 to BiH3

(IV) Bond angle of hydrides decreases from NH3 to BiH3

The correct statements are :
(A) (I), (II), (III) and (IV) (B) (I), (III) and (IV)
(C) (I), (II) and (IV) (D) (I) and (IV)

10. The correct order of boiling points of the hydrides of nitrogen family is :
(A) NH 3  PH 3  AsH 3  SbH3 (B) PH3  AsH3  NH3  SbH3
(C) NH3  PH3  SbH3  AsH3 (D) NH3  PH3  AsH3  SbH3

Level-1 80 DTS-1 | p-Block Elements-II

11. When plants and animals decay, the organic nitrogen is converted into inorganic nitrogen. The inorganic
nitrogen is in the form of :
(A) Ammonia (B) Elements of nitrogen
(C) Nitrates (D) Nitrides

12. When heated NH3 is passed over CuO, gas evolved is :

(A) N2 (B) N 2O (C) HNO3 (D) NO 2

13. N forms NCl 3, whereas P can form both PCl3 and PCl5 why ?
(A) P has low lying 3d orbital which can be used for bonding but N 2 does not have low lying 2d
orbital
(B) N 2 atom is larger than P in size
(C) P is more reactive towards Cl and N 2
(D) None of above

14. A hydride of nitrogen which is acidic is :

(A) N 3H (B) N 2H2 (C) NH3 (D) N 2H4

15. Most unstable hydride is :

(A) NH3 (B) PH3 (C) AsH3 (D) BiH3

Level-1 81 DTS-1 | p-Block Elements-II