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Important Questions Class 12 Chemistry Chapter 2
Important Questions Class 12 Chemistry Chapter 2
Chemistry
Chapter 2 – Solutions
2. Which type of solid solution will result by mixing two solid components with
Ans: Mole fraction of any component is given as the ratio of the respective moles of
the same to the total moles of the solution. Here, if we consider x moles of water
then we will have equal i.e., x moles of C2H5OH . Thus,
fraction?
Ans: Out of molarity, molality and mole fraction; mole fraction is the dimensionless
quantity as it is the ratio of similar quantities i.e., moles.
formed.
Ans: If an ideal solution is to be formed, the primary condition to be fulfilled will
be a solution obeying Raoult’s law. Also, the solution should be homogenous and
there must not be any volumetric or thermal effects.
expressed?
Ans: When the solution has trace amounts of solute present in them, the
concentration of the solute is expressed in parts per million i.e., ppm.
11. N 2 and O 2 gases have K H values 76.48 kbar and 34.86 kbar respectively
at 293 K temperature. Which one of these will have more solubility in water?
Ans: In general, lesser the value of K H greater the solubility of a gas at the same
partial pressure. Here, we can see O2 has less value of K H therefore, it will be more
soluble than N 2 .
12. Under what condition molality and molarity of a solution are identical.
Explain with suitable reasons.
Ans: The condition where the molarity and molality of the solution will be identical,
is the presence of high amounts of solvent in the same i.e., dilute solutions.
14. What will happen to the boiling point of the solution formed on mixing two
15. Liquid ‘Y’ has higher vapor pressure than liquid ‘X’, which of them will
16. When 50 mL of ethanol and 50 mL of water are mixed, predict whether the
volume of the solution is equal to, greater than or less than 100 mL. Justify.
Ans: When the equal volume of ethanol and water are mixed together i.e., 50 ml
each then the total volume formed will be less than 100 ml. This is because the
molecules of ethanol are smaller than that of water which makes it fit themselves
within the big water molecules.
18. A and B liquids on mixing produce a warm solution. Which type of deviation
from Raoult’s law is there?
Ans: When mixing A and B produces a warm solution, then the solution will show
negative deviation from Raoult’s law.
20. Mention the unit of ebullioscopic constant (molal boiling point elevation
constant.)
Ans: The unit of ebullioscopic constant or molal boiling point elevation constant is
K kg mol1 .
21. If K f for water is 1.86Kkgmol 1 , what is the freezing point of 0.1 molal
Tf iKf m
Tf Kf m
22. What is reverse osmosis? Give one large scale use of it.
Ans: The process takes place opposite to that of the osmosis (solvent flow towards
solution through semi – permeable membrane) by applying pressure greater than
osmotic pressure on the solution. The most common large scale application is
desalination of seawater.
23. What is the maximum value of van’t Hoff factor (i) for Na2SO4 .10H2O ?
Ans: The maximum value of Van’t Hoff factor (i) for Na 2SO4 .10H2O will be 3.
25. Under what condition is van’t Hoff factor less than one?
Ans: Under association of molecules only, the Van’t Hoff factor will be less than 1.
26. The Phase Diagram for pure solvent and the solution containing non –
volatile solute are recorded below. The quantity indicated by ‘X’ in the figure
is known as:
27. AgNO3 reaction with NaCl in aqueous solution gives white precipitate. If
(b) Ionic compounds are soluble in water but are insoluble in nonpolar
solvents.
Ans: In general, we know the empirical rule of ‘like dissolves like’. Here, the ionic
compounds are polar molecules which are soluble in water due to its polar nature.
3. Draw vapor pressure vs composition (in terms of mole fraction) diagram for
an ideal solution.
Ans:
(ii) Maximum boiling azeotropes – mixture of water and HCl (solutions showing
5. Draw the total vapor pressure vs. mole fraction diagram for a binary solution
exhibiting non-ideal behavior with negative deviation.
Ans:
6. The vapor pressure curve for three solutions having the same non- volatile
solute in the same solvent are shown. The curves are parallel to each other and
Ans: As shown in the figure, the concentration of the three solutions having the same
non – volatile solute in the same solvent will be in the order of A < B < C.
property.
Ans: Colligative properties depend upon the number of solute particles in the
solution. To be more precise, it is the ratio of the number of solute particles to the
number of solvent particles in the solution.
P P0 P
P0 P0
Also, by Raoult’s law we know that,
P0 P
x
P0
where, x is the mole fraction of any component.
Hence, we can say that the relative lowering of vapor pressure of a solvent is a
colligative property.
calculate the vapor pressure of a solution containing equal moles of the two
0 0
substances. [Given: PBenzene = 150 mm of Hg, PToluene = 55 mm of Hg]
PSolution PBenzene 1
0
PToluene
0
2
1
PSolution 150 55 102.5mmHg
2
10. When 1 mole of NaCl is added to 1 liter water, the boiling point increases?
When 1 mole of CH3OH is added to 1 liter water, the boiling point decreases?
Suggest reasons.
Ans: When NaCl (non – volatile solute) is added to water then, the vapor pressure
of the solution is lowered, increasing the boiling point. Whereas, CH3OH is more
volatile than water i.e., has more vapor pressure than that of water decreasing the
boiling point.
n
Tb K b m K b
W
where,
n = number of moles of a component given as,
mass of component
n
molar mass of component
1
Tb
molar mass of component
1 1
TbA and TbB
MA MB
TbA M B
TbB M A
We have given that the molar mass of A > molar mass of B thus, B will show greater
elevation in boiling point.
13. Examine the following illustrations and answer the following questions
(b) Name the phenomenon involved in this experiment so that the level of liquid
particles dissolved in solvent. So, when the non – volatile solute is added to the
solvent due to change in vapor pressure, all other properties change. The relative
lowering in vapor pressure of solute brings depression in freezing point and elevation
in boiling point of the same.
Where,
Ans: In accordance with the given data and formula for Henry’s law;
Concentration of gas,
P 0.95
C 0.0202M
K H 46.82
n M V
n 0.0202 1 0.0202moles
Thus, moles of O2 dissolved in water is 20.2 millimoles.
(a) Aquatic species are more comfortable in cold waters than in warm waters.
Ans: The solubility of oxygen decreases with increase in temperature which makes
aquatic organisms feel comfortable in cold water due to the high amount of dissolved
oxygen.
(b) To avoid bends scuba divers use air diluted with helium.
(c) Cold drinks bottles are sealed under high pressure of CO2 .
Ans: The CO2 gas is filled in the cold drinks under high pressure and sealed as with
high pressure, the solubility of gases in liquid increases.
The relationship between the molar mass of solute and the elevation in boiling point
is given as;
Elevation in boiling point,
Tb K b m
W2
m
M 2 W1
K b W2
M2
Tb W1
Ans: The calcium chloride is responsible for depression in freezing point of water to
an extent from where it cannot form ice hence, clearing the snow from roads.
cold countries.
Ans: The addition of ethylene glycol in car radiators lowers the freezing point of
water so as to avoid bursting of lines in cold winter temperatures.
(c) The freezing point depression of 0.01 m NaCl is nearly twice that of 0.01 m
glucose solution.
Ans: The sodium chloride dissociates in the solution giving two ions and glucose
will never dissociate to form ions. Thus, by the relationship of freezing point
depression;
Tf iKf m
NaCl can have nearly twice the depression in freezing point to that of glucose even
though the concentrations are the same.
Solute undergoing association in the solution, Van’t Hoff factor is less then 1.
Whereas, solute undergoing dissociation in the solution has Van’t Hoff factor more
than 1.
Example:
KCl K Cl
Here, a molecule of KCl gives 2 ions which gives Van’t Hoff factor (i) as 2. This
will reflect in the form of abnormal molecular mass calculations for certain
conditions.
(b) When fruits and vegetables that have been dried are placed in water, they
(c) A person suffering from high blood pressure is advised to take less amount
of table salt.
Ans: The intake of NaCl can result in an increase in the number of solutes in the
body fluids. If the solute concentration is increased, the osmotic pressure increment
can rupture the blood cells.
of an automobile?
Ans: The antifreeze solution is responsible for lowering the freezing point
Tf Kf m
W2
m
M 2 W1
We can say that the lower molar mass will give depression in
Glycerin = 92 g/mol
Ethylene glycol = 62 g/mol
Methanol = 32 g/mol
Thus, methanol will be cheaper for preparing an antifreeze
As, the elevation in boiling point depends upon the Van’t Hoff factor; MgCl2 will
dissociate producing the highest number of ions (3) than that of NaCl (2) and urea(0).
As, the depression in freezing point depends upon the Van’t Hoff factor; CaCl2 will
dissociate producing the highest number of ions (3) than that of NaCl (2) and
sucrose(0).
solvent, determine the vapor pressure (mm of Hg) of the solution. [Given: K b
W2 2.5g
W1 100g
Tb 2C
P 0 1atm 760mmHg
M1 18gmol1
K b W2
Tb
M 2 W1
M 2 9.5gmol1
P0 PS W2M1
P0 M 2 W1
760 PS 2.5 18
0.047
760 9.5 100
The resulting solution was found to freeze at 0.34C . What is the molar mass
of this substance? ( K f for water = 1.86Kkgmol1 ).
W2 15g
W1 450g
Tf 0.34C
K f 1.86Kkgmol1
1.86 1000 15
Tf 0.34
M 2 450
M 2 182.35gmol1
M 185000gmol1
V 450ml 0.45L
T 37 273 310K
R 8.314Jmol1K 1 8314PaLmol1K 1
Osmotic pressure is given as;
WRT
MV
P0 PS
x
P0
P0 PS n2
P0 n1 n 2
If n 2 n1 then,
P0 PS n 2
P0 n1
Thus,
P0 PS W2M1
P0 M 2 W1
(b) How much urea (mol. mass 60 g/mol) must be dissolved in 50g of water so
that the vapor pressure at the room temperature is reduced by 25%? Also
calculate the molality of the solution obtained.
Ans: Given that,
W1 50g
M1 18gmol1
P0 PS W2M1
P0 M 2 W1
W2 18
0.25
50 60
W2 41.67g
W2 1000
m
M 2 W1
Thus,
41.67 1000
m 14m
60 50
(b) The cryoscopic constant of water is 1.86 k/m. Comment on this statement.
Ans: If it is said that the cryoscopic constant of water is 1.86Km1 , it means that the
water has 1.86 K depression in freezing point when the solution has molality of 1 m.
(c) Calculate the amount of ice that will separate out on cooling solution
W2 50g
M 2 62gmol1
K f 1.86Kkgmol1
Tf 9.3C
K f W2 1000
Tf
W1 M 2
1.86 50 1000
9.3
W1 62
W1 161.29g
(b) Why osmotic pressure is preferred over other colligative properties for the
(c) What is the molar concentration of particles in human blood if the osmotic
7.2atm
R 0.0821LatmK 1mol1
T 37C 310K
The osmotic pressure is given as;
CRT
The molar concentration is given as;
C
RT
7.2
C 0.283M
0.082 310
NUMERICAL PROBLEMS
mass of component
Mass percentage = 100
mass of mixture
Here,
Mass of benzene = 22 g
Thus,
mass of benzene
Mass percentage of benzene = 100
mass of mixture
mass of CCl4
Mass percentage of CCl4 = 100
mass of mixture
122
100 84.72%
144
M1 2.5M
M2 2M
V1 V2 500ml
M1V1 M 2 V2
M
V1 V2
M
2.5 2 500
1000
Thus, molarity of the solution = 2.25 M.
Density 0.994gcm 3
x
Mole fraction of CH 3OH 0.02
xy
where, x is the moles of CH3OH and y is the moles of water in the solution.
By calculating, we get;
y 49x
x 1000
Molality 1.13m
y 18
x 994
Molarity 1.0875M
32x 18y
the molarity of the solution. Assume that calcium chloride is completely ionized.
Ans: This illustration can be solved by simple mole concept;
3.01 1022 1
2 5L
Now, we have known that a mole of a substance contains 6.022 1023 molecules .
Thus,
7.525 1022
Molarity 0.125M
6.022 1023
5. 6 103 g oxygen is dissolved per kg of sea water. Calculate the ppm of oxygen
in sea water.
Ans: Given that,
Now,
mass of solute
106
mass of solution
6 103 106
6ppm
1000
6. The solubility of oxygen in water is 1.35 103 molL1 at 20C and 1 atm
pressure. Calculate the concentration of oxygen at 20C and 0.2 atm pressure.
Ans: Given that,
C KHP
Thus,
C
KH 1.35 103 Matm 1
P
Now, at 0.2 atm;
C 2.7 103 M
7. Two liquids X and Y on mixing form an ideal solution. The vapor pressure
of the solution containing 2 mol of X and 1 mol of Y is 550 mm Hg. But when 4
mol of X and 1 mole of Y are mixed, the vapor pressure of solution thus formed
is 560 mm Hg. What will be the vapor pressure of pure X and pure Y at this
temperature?
Ans: Let us consider vapor pressure of X will be P1 and that of Y will be P2 . Also,
x1 and x 2 be their respective mole fractions.
Total pressure, P
P1x1 P2 x 2
Thus,
2 1
P1
2
P 550 …….
2 1 2 1
4 1
P1 P2 560 …….
4 1 4 1
P1 575mmHg
P2 500mmHg
M 2 208gmol1
K b 0.52Kkgmol1
W2 3.12g
W1 250g
By formula we get;
Tb iK b m
Tb Tb M 2 W1
i 2.67
K b m K b W2 1000
BaCl2 Ba 2 2Cl
1 x x 2x
i 1 x x 2x 2.67
Therefore, degree of dissociation is 83.5%.
containing 7.0 g of salt per 100 g of water at 100C is 70%. If the vapor
pressure of water at 100C is 760 mm of Hg, calculate the vapor pressure of the
solution.
Ans: Given that,
Degree of dissociation, = 70%
W2 7g
M 2 164gmol1
W1 100g
M1 18gmol1
P0 760mmHg
Moles of Ca NO3 2
7
0.0426moles
164
Moles of water
100
5.56moles
18
0.0426
0.00762
0.0426 5.56
i 1 n ' 1
Thus, i = 2.4
Now,
P0 P
iX
P0
760 P
2.4 0.00762
760
point equal to 1.62K. Molar freezing point depression constant for benzene is
4.9Kkgmol 1 . What is the percentage association of acid if it forms a dimer in
solution?
Ans: Given that,
W2 2g
W1 25g
K f 4.9Kkgmol1
Tf 1.62K
Hence,
x x 122
i 1 x 1
2 2 241.98
Therefore, degree of association is 99.2%.
11. Calculate the amount of NaCl which must added to one kg of water so that
W1 1kg
K f 1.86Kkgmol1
Tf 3K
M 2 58.5gmol1
Tf M 2 W1
W2 47.2g
i Kf
47.2
0.81mol
58.5
Calculate the freezing point of 0.25 molal solution. The degree of association of
solute A is found to be 0.8. The freezing point of benzene is 5.5C and its K f
value is 5.13 K/m.
Ans: Given that,
Molality = 0.25 m
Tbenzene 5.5C
K f 5.13Km 1
Now,
3A A3
1
3
2
i 1 1
3 3
Van’t Hoff factor, i = 0.467
Tf iKf m
T Tbenzene Tf
Mass of sucrose = 5 g
In general, when two solutions are isotonic with each other means they have equal
osmotic pressure and due its directly proportionality with the concentrations,
isotonic solutions have equal concentrations. Thus,
Conc. Of sucrose = Conc. Of urea
0.877 342
59.9gmol1
5
0.75atm
C 0.0103m
R 0.0820Latmmol1K 1
T 27C 300K
iCRT
0.75
i 2.95
CRT 0.0103 0.082 300
the depression in freezing point is 7K, then find the % of phenol that dimerises.
Ans: Given that,
W2 75.2g
M 2 94gmol1
Tf 7K
K f 14Km 1
W1 1kg
And,
i 1 1
2 2
Now, by formula;
Tf iKf m
Tf M 2 W1
2 1
K f W2 1000
0.75
% Phenol which will dimerise is 75%.
17. An aqueous solution of glucose boils at 100.01C . The molal boiling point
W1 100g
K b 0.5Kkgmol1
M 2 180gmol1
n2
Tb K b
W1
0.01 0.1
n2 2 103 moles
0.5
From mole concept;
mass.
Mass of acid = 86 g
Molar mass of acid = 98 g/mol
mass 100
Volume 56ml
density 1.787
86 1000
M 15.71M
98 56
(b) What volume of the acid has to be used to make 1 liter 0.2M H2SO4 ?
M2 0.2M
V2 1L
M1 15.71M
M 2 V2
V1 0.0127L
M1
86 1000
Molality 62.68m
98 14
19. A solution containing 30g of non-volatile solute exactly in 90g of water has
a vapor pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to
the solution and the new vapor pressure becomes 2.9 kPa at 298 K. Calculate:
W2 30g
W1 90g
PS 2.8kPa
P0 PS W2M1
x
P0 M 2 W1
6 2.8
1 0
M2 P
W2 30g
PS 2.9kPa
P0 PS W2M1
x
P0 M 2 W1
5 2.9
1 0
M2 P
M 2 34gmol1
6 2.8
1
34 P0
Thus, P0 3.4kPa .
20. The vapor pressure of pure liquids A and B are 450- and 750-mm Hg
respectively, at 350K. Find out the composition of the liquid mixture if total
vapor pressure is 600 mm Hg. Also find the composition of the vapor phase.
Ans: Given that,
PA0 450mmHg
PB0 750mmHg
PT 600mmHg
PB PB0 x B PB0 1 x A
So,
PT PA PB
Now,
PT PA0 x A PB0 1 x A
PT PB0
xA 0
PA PB0
From this,
x A 0.5
x B 0.5
Now,
PA 225
yA 0.375
PT 600
yA 1 yA 1 0.375 0.625
at the normal boiling point of the solvent. What is the molar mass of the solute?
Ans: Given that,
W2 2g
W1 100 2 98g
M1 18gmol1
By Raoult’s law;
1.013 1.004 2 18
1.013 M 2 98