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Technical Advisory Board
Information technology (IT) has had dramatic social and economic impact
in our global society, as continual advancement in semiconductor integrated
circuit (IC) manufacturing technology has enabled ever-greater capacity for
electronic information processing and storage at ever-lower cost per
function. Key to the exponential growth of the IT industry over the past 50-
plus years has been the steady miniaturization of the transistor (the basic
component of an IC) to enable greater degrees of integration and hence
greater IC functionality. The most advanced semiconductor chips today
comprise over 10 billion transistors, with features that are finer than 10 nm.
The fabrication process for such sophisticated products involves hundreds
of steps, each requiring very high precision and/or ultrapure gases and
chemicals. Impressive economies of scale make chips affordable: Presently
the largest semiconductor “fabs” each have the capacity to process the
equivalent of more than 1 million 200-mm-diameter wafers per year.
This handbook provides a broad overview of modern semiconductor
manufacturing and market drivers, and detailed technical descriptions of the
unit processes used today to fabricate the components and the
interconnecting wires comprising an IC. Furthermore, it describes in detail
manufacturing processes for photovoltaic devices, large-area electronics,
and flexible electronics, which are proliferating as we enter the age of
ubiquitous computing. The final sections of this comprehensive reference
cover logistical aspects of semiconductor manufacturing, including
cleanroom design, handling of gases and chemicals, process control, and
factory automation.
This expansive volume is the fruit of Hwaiyu Geng’s labor of love to
rally 70 leading semiconductor manufacturing professionals from across the
world, whose collective experience and expertise span the breadth of the
industry, to archive their expert knowledge. I hope that you will benefit
from this tremendous effort.
TSU-JAE KING LIU, PH.D.
TSMC Distinguished Professor in Microelectronics University of
California, Berkeley
Member, U.S. National Academy of Engineering
Preface
BY
HWAIYU GENG Amica Research, Palo Alto, California
1.1 INTRODUCTION
At the end of 2016, with a world population at 7.4 billion, there were 8
billion connected devices globally.1 In the following decades, the Internet of
Things (IoT), a subset of cyber-physical systems or CPS, would connect
more things around the world exponentially. With increasing processing
power, reducing costs and sizes of microchips, microchips are well
recognized for the advancement of electronics technology that drive the IoT
with phenomenal growth and have transformed almost every facet of daily
life.
“Half a century ago, a young engineer named Gordon E. Moore took a
look at his fledgling industry and predicted big things to come in the decade
ahead. In a four-page article in the trade magazine Electronics, he foresaw a
future with home computers, mobile phones, and automatic control systems
for cars. All these wonders, he wrote, would be driven by a steady doubling,
year after year, in the number of circuit components that could be
economically packed on an integrated chip,”2 written by Dr. Chris Mack in
IEEE’s The Multiple Lives of Moore’s Law.
In IEEE’s Special Report titled 50 Years of Moore’s Law,3 “Moore’s law
has driven technology forward at a staggering clip. We have all benefited
from this miraculous development, which has forcefully shaped our modern
world. In this special report, we find that the end won’t be sudden and
apocalyptic but rather gradual and complicated. Moore’s law truly is the gift
that keeps on giving—and surprising, as well.”
SILICON INGOT
Semiconductor manufacturing begins with a silicon ingot. Silicon ingots
could be made by Czochralski (CZ) process and float-zone process. Float-
zone wafers are generally not larger than 150 mm due to limit of surface
tension during growing process. Most crystal ingots are grown by the
Czochralski method. This method begins by a piece of crystal of silicon,
called seed, is lowered in the near 100 percent pure molten silicon in
crucible. The seed and crucible are rotating in opposite direction while
heating purified silicon to 1200°C in an argon atmosphere. The silicon seed
is slowly withdrawn from molten liquid. Silicon atoms attach to the seed,
resulting in a long crystal rod or ingot, grows with a diameter of most
commonly 200 or 300-millimeter (mm) across in careful control of
temperature, atmosphere, and pressures. It produces electronic grade silicon
that is semiconductor manufacturing quality with silicon purity to
99.9999999 percent.
EPITAXY
Epitaxy is one of the fundamental processes used to make semiconductor
devices. Epitaxy refers to deposit an overlayer of a crystal (epitaxial film) on
a host crystal (substrate) in an ordered fashion. It is desired that the overlayer
has a defined orientation with respect to the substrate. The epitaxial film and
substrate could be same or different materials. There are three types of
epitaxy: liquid phase, vapor phase, and molecular beam epitaxy.
OXIDIZATION
Silicon oxide (SiO2) serves as an electrical insulator that is a key component
in IC circuit. Growth of oxidation can be achieved by dry or wet oxidation.
Oxidation is a diffusion process. Silicon wafers are first heated and
exposed to ultrapure oxygen at elevated temperatures in a diffusion furnace.
By carefully controlled conditions in the furnace, a silicon oxide (SiO2) film,
dry oxidation, with uniform thickness is growth from the SiO2/silicon
interface.
Si + O2 → SiO2
PHOTOLITHOGRAPHY
Photolithography is a process by imprinting a specific IC design pattern on a
wafer. Before performing the photolithography process, a photomask
(reticle) is prepared. A photomask has a copy of the circuit pattern drawn as
an opaque pattern on a quartz plate. A quartz plate is first polished in high
precision. The quartz substrate is then coated with a thin layer of chrome
material by sputtering that is opaque to UV wavelengths. A photosensitive
chemical called resist is spin-coated over the chrome photomask blank. Then
a circuit design pattern is transcribed into the chrome film by electron beam
lithography. After exposure, develop and etch, the photomask blank becomes
a photomask with a copy of the circuit pattern.17,18
Photoresist Application A wafer is coated with a light-sensitive liquid
called photoresist. By pouring a small amount of the photoresist to the center
of the wafer while the wafer is spinning at high speed, the material will
spread over the entire surface in a thin, uniform coating. The photoresist
material is sensitive to “photo” (light) and it “resists” certain chemicals that
are used to remove portions of the material below the photoresist.
Photomask and Exposure A photo aligner precisely aligns the
photoresist-coated wafer to the photomask. The photomask, acting like a
stencil, contains the pattern to be imaged onto the wafer. The aligner projects
light through the photomask and optical reduction lenses to the wafer. This
results in exposure to the photoresist in areas where not protected by the
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Pea Ridge is in the extreme north-west part of Arkansas, situated
in Benton, the corner county of the State. A range of hills—a spur of
the Ozark Mountains—sweeps from Missouri into this corner of the
State, and from thence branches into the Indian Territory, where the
section known as the Boston Mountains is found. Sugar Creek, where
the battle commenced, is situated close to Bentonville, the capital of
the county on the north. Pea Ridge is also adjacent to the same town,
and forms a part of the mountain range just described.
At this time it became evident to the several commanders that a
general contest was inevitable. A decisive combat was, in fact,
desired by both of the opposing forces. General McIntosh, confident
of success with his large army, under the leadership of Price,
McCulloch, Pike and Van Dorn, believed that he could strike a fatal
blow at the Union cause west of the Mississippi, by the annihilation
of the Federal army. General Curtis, on the other hand, was not less
anxious for a contest, even at the fearful disadvantage offered him.
With his keen discrimination, he saw the glorious results of a defeat
of the four rebel chieftains united against him. Should he prove
successful in the almost desperate encounter, it would prove the
destruction of the rebel forces in the two States, and leave a clear
field for future operation. Should he fail—but no true general even
thinks of that after he has made up his mind to fight.
At this time his force was divided into three divisions, as follows:
General Sigel’s Division.—First Brigade, Colonel Gruesel.—36th
Illinois, Col. Gruesel; 25th Illinois, Col. Coler; 44th Illinois, Col.
Knoblesdorf. Second Brigade, Col. Osterhaus.—12th Missouri, Col.
Osterhaus; 17th Missouri, Col. Hassendeufel; 2d Missouri, Col.
Schaeffer. Third Brigade, Col. Asboth.—3d Missouri, Col. Friala;
Illinois Cavalry, (one battalion,) Capt’s. Jenks and Smith; 3d Iowa
Cavalry.
General Davis’s Division.—First Brigade, Col. Benton.—8th
Indiana, Col. Benton; 18th Indiana, Col. Patterson; 22d Indiana, Col.
Hendricks. Second Brigade, Col. Julius White.—59th Illinois, Col.
Fredericks; 37th Illinois, Col. Burnes; Missouri Cavalry, (battalion,)
Maj. Broen; 2d Ohio, battery, Col. Catin; 1st Missouri Light Artillery,
one battery.
General Carr’s Division.—First Brigade, Col. Dodge.—4th Iowa,
Lieut.-Col. Galighan; 35th Illinois, Col. G. A. Smith; 24th Missouri,
(battalion,) Maj. Weston. Second Brigade, Col. Vandenier.—9th
Iowa, Lieut.-Col. Herron; 25th Missouri, Col. Phelps; 9th Iowa,
battery, Capt. Hayden; 1st Iowa, battery, Lieut. David. Third
Brigade, Col. Ellis.—1st Missouri Cavalry, Col. Ellis; 3d Illinois, ——;
6th Missouri, battalion, Maj. Wright.
Opposed to the forces of General Curtis, just enumerated, the rebel
army had fully ten thousand Missouri State troops under Major-
General Price; six to eight regiments of Arkansas troops under
General McCulloch; six regiments of Texans under General Earl Van
Dorn; three thousand Cherokee, Choctaw and Seminole Indians
under Colonel Albert Pike, all under command of Major-General
McIntosh. Besides those mentioned, there were two or three
regiments of Louisiana troops and companies of Mississippi and
Alabama regiments under the command of their respective colonels,
majors and captains.
Upon this occasion the Union troops were well armed and
equipped, while the weapons of the rebels varied in character and
effectiveness. Many of them were excellent, embracing Minie rifles,
Enfield muskets, and good United States muskets. The larger
portion, however, were hunting rifles and shot-guns. The rebels had
eighty-two field pieces, twenty of which were rifled, while General
Curtis’ forces had but forty-nine; nearly all, however, were of
superior manufacture and destructive power.
On the evening of the 5th of March, the scouts of General Sigel
brought in word, that large forces of the rebel cavalry were on the
Pineville road at Osage Spring. Sigel was evidently in a bad position,
and on the following day he commenced moving back, his pickets
being driven in before he could get his wagon train in motion. His
route lay a few miles to the north, when he struck the bed of Sugar
creek, along which he travelled six miles. It was there the battle first
began. General Sigel with two battalions of Missouri infantry and a
squadron of cavalry formed the rear guard of his division, and were
delayed by the train which moved slowly along the rough roads. He
determined not to desert a single wagon to the rebels, although by so
doing, he could have easily reached the main body of the Union
forces.
The enemy made his appearance with 4,000 cavalry, at about 10
o’clock in the morning, a few miles out of Bentonville, and
immediately commenced the attack by a desperate charge. Sigel had
with him nearly 1,000 men. He sent forward two hundred infantry to
prevent the enemy cutting him off, and with the remainder he
received the whole of the vast army. He ordered his men to stand
firm and take good aim. The teams were put upon good pace, and the
enemy came rushing on in several lines. The horsemen on the flanks
and infantry in the rear awaited their approach until within about
200 yards, when they delivered a terrible volley of Minie balls into
the rebel ranks, which had the effect of throwing them into
temporary confusion. In a few minutes the leaders succeeded in
getting them into something like order. This time they came up to
close quarters. The same volley, succeeded by a second and a third,
greeted them. The enemy came on in crowds, and their cavalry
closed all around the little band, notwithstanding horses and riders
were falling thick and fast before its steady fire. General Sigel rode
undismayed along the whole line, inspiring his men. Some of the
cavalry on the flank had succeeded in getting across the road so
cutting the train in two. Here the enemy set up a shout of triumph.
It was short lived. In a minute more the bayonets of the Union
men had done their work, leaving hundreds of dead and wounded in
their tracks. The enemy was driven off, broken and dismayed. Galled
and maddened at the repulse, his scattered ranks could be seen
reforming to renew the attack.
The column was yet seven miles from the encampment. A dispatch
had been sent forward to General Curtis, explaining the position and
asking for assistance. It was hardly possible that the messenger could
have been captured. The enemy was advancing on the road and along
the ridges enclosing the stream. At about two o’clock a second attack
was made and desperately carried forward. The rebel cavalry spurred
their horses right on to the irresistible bayonets, delivering their load
of buckshot from their miscellaneous guns, and then brandishing
huge knives, which every one of them carried in place of sabres.
They surrounded the rear guard a second time, and for a few
minutes friend could hardly be distinguished from foe. The dense
smoke enveloped the whole of the combatants, and for some time it
was doubtful whether any of the Union band survived. The faithful
Germans never faltered for a moment. Their gallant leader struck
down a dozen who clamored for his life, and hewed his way through
a line of enemies to rejoin his command. The bayonets proved the
invincibility of the Union infantry against horsemen. The foe retired
a second time, and for an hour could not be induced to return. By
this time the advance, which had been constantly skirmishing with
the rebel cavalry, announced reinforcements in sight, and a faint
cheer went up, which was re-echoed by the troops from the camp. A
third and last attempt was made to capture the train. It failed, and
the enemy withdrew about 3½ o’clock.
General Sigel reached camp at 4½ o’clock, to receive the
congratulations of the whole army. His loss in the entire march was
estimated at 60 killed and 200 wounded, many of whom fell into the
hands of the rebels, it being impossible to bring them off.
The night of the 6th of March was passed in a state of suspense.
The houses in the valley had been appropriated as hospitals, and a
strong force posted on the hill on the south bank of the creek under
Colonel Carr, with General Sigel occupying the ridge on the north
side, while Colonel Davis occupied the centre, near the crossing. The
enemy, it was supposed, would naturally make the attack from the
Fayetteville road, and the baggage trains and hospitals had been
placed to the rear of the lines. During the night the manifestations
showed conclusively that he was approaching in great strength by the
road leading from Bentonville to Keatsville, thus getting to the flank
and rear. This road lies, after crossing Sugar creek, over a high table
land, called Pea Ridge. It extends from the stage road westwardly
some eight miles along the right bank of Sugar creek.
The ridge is covered with a growth of stunted oaks, and a
sprinkling of larger growth, called post-oaks. Three or four farms
were located upon the ridge two miles west of the road, to which the
name of Leetown has been given. It was near these farms that the
principal part of the fighting took place.
Thursday night, March 6th, was clear and cold; the reflection of
the enemy’s camp-fires could be seen stretching along for miles to
the right. On the Fayetteville road the Union pickets reported
nothing unusual. Several Union field pieces had been placed in
position, sweeping that road. The men slept on their arms, that is
each man lay on the ground in fine of battle with his musket by him,
ready for action at a moment’s notice. A strong picket guard was
extended for a quarter of a mile beyond the lines, and the Federal
soldiers awaited the break of day with premonitions that the
morrow’s sun would be the last which would rise for many of them.
The evidences were very clear on the morning, that a strong force
had been posted on the Fayetteville road, thus standing directly
between the Union forces and their next line at Cassville, completely
cutting off communication with the outer world. The line of battle
was changed. Colonel Carr was sent back along the Fayetteville road,
two miles, with his right resting on Cross Timber Hollows at the head
of Beaver Creek, a tributary of Big Sugar Creek, immediately facing
the rebel batteries on the side of Elkhorn tavern. General Davis, with
the central division, was posted on the top of Pea Ridge, leaving Sigel
to cover the camp with his left wing resting on Sugar Creek. In this
position things stood when the rebels opened the fight with artillery
on the extreme right, from a very advantageous position at the
distance of a mile. The Federal batteries soon replied. The fight raged
in front of Colonel Carr’s division from 10 to 11 o’clock, when another
battery was ordered up to his support, for he was hotly pressed. The
left, as yet, had not been menaced. General Sigel felt confident that
the enemy might be expected to make a descent from the south side,
and it was deemed indispensable to keep the men ready for action in
that direction. Colonel Osterhaus was sent with his brigade in the
morning along the high land in the direction of Leestown, where he
intercepted the reinforcements of the enemy. This was one of the
most spirited and successful attacks of the battle, and resulted in a
complete diversion of the enemy from the overpowered forces of
Colonel Carr, on the Fayetteville road.
The Union cavalry penetrated along the main ridge beyond the
road by which the enemy had advanced, and were on the point of
seizing some of his wagons when a brigade of rebel cavalry and
infantry attacked them. Then followed one of the most sanguinary
contests that ever has been recorded between cavalry. Most of the
fighting was done at close quarters. Pistols and carbines having been
exhausted, sabres were brought into requisition. The rattle of steel
against steel, sabres against muskets and cutlasses, was terrific. The
rebels were Texas Rangers, and fought like demons. The slaughter
was awful. The Missouri cavalry cleaving right and left, left winrows
of dead and wounded in front of their horses. The enemy fell back in
dismay, the valorous Federals pursued them along the road for a
mile, when they opened a battery upon the mass of friends and foes,
plowing through them with solid shot and shell. Colonel Osterhaus
had succeeded in his attempt, and retired, bringing off his dead and
wounded in safety.
Meantime the contest was raging furiously on the extreme right on
both sides of the Fayetteville road. The First and Second Iowa
batteries, planted at an eminence overlooking the declivity in the
road, were plying shrapnel and canister into the ranks of the enemy,
who appeared in immense numbers on all sides, as if to surround the
right of the Union line, and thus completely environ them. In order
to defeat this object, a severe struggle took place for the occupancy of
a rising knoll on the east side of the road. The enemy gained upon
the Federals, and it was not until the men were half stricken down
that they yielded the point. Word had been passed back to General
Curtis that the enemy was pressing severely on the right flank, and
the Union forces were sent back. The section of a battery had been
left on the hill, and the enemy was now turning it upon the Union
lines. Colonel Carr, fearing that no reinforcements would arrive,
collected his strength, and mustered his entire force for a last
desperate charge, resolved to retake the position or perish in the
attempt. A heavy firing on the centre, and a cheer from the advancing
division of General Davis favored the effort. The troops marched up
to the battery amid a storm of shot from their own guns, and, after a
desperate hand-to-hand struggle, finally drove the enemy down the
ravine, in hopeless confusion. Colonel Carr received a wound in the
arm, but remained on the field.
During the night a sharp fire of artillery had been kept up upon the
left, and from two Missouri batteries on the centre, under Colonels
Patterson and Fiala. The enemy had made frequent attempts to gain
a position nearer the Union lines, and succeeded in getting so near
that the balls from their guns would strike near the tents and
baggage wagons. Towards night the enemy made an attempt to break
the Federal centre, but the timely support of a brigade of General
Sigel and a section of artillery promptly repulsed them. The night
closed with skirmishing and sharpshooting.
Occasionally the report of a musket could be heard during the
night, then a second, and an interval of silence. But few of the
soldiers slept. The communication with Springfield was cut off, and
Union messengers were falling into the enemy’s hands. As yet the
Federals had gained little advantage, and with desperate fighting had
only succeeded in repelling equally desperate attacks. Nothing but
hard fighting could avail them. Filled with these thoughts, the
soldiers solemnly gave their wives and children into each others’
charge, no one being aware who the survivor would be. Young men
talked in low voices of the loved ones at home, fathers, mothers,
sisters, sweethearts—and messages full of tender pathos were left to
be given after death. It was indeed, an anxious, mournful night.
The fight on the morning of the 8th, commenced by a salute from
the Union batteries on the extreme right. General Asboth, with a
regiment of infantry and a battalion of cavalry, had been sent to the
support of Colonel Carr, while General Sigel was moving up to a
fresh position on the ridge near Leestown. The enemy was
unprepared for this sudden and vigorous assault, and fled after a
short and spiritless resistance. They ran, leaving four pieces of
artillery behind them, and a fifth was afterwards taken in the pursuit.
The enemy was being turned by the left flank, General Sigel pushing
boldly after him. An hour or more was spent in contesting the
possession of a spot on Cox’s farm, when the rebels fell back to the
hollow.
A pause ensued, when the right, under General Davis, moved
along, and after a sharp contest of half an hour, in which the rebel
General McIntosh, was killed, the enemy began to retreat to Cross
Timber Hollow. The whole line was then ordered forward. The rebels
attempted to make a stand on the next hill, but the Union artillery
played upon them with disastrous effect. The enemy on the road near
the tavern refused to be moved. General Asboth, with a large column
of cavalry, was sent round to outflank them, when another desperate
conflict ensued between the Union cavalry and the Texas and
Louisiana troops. The Indians also took part in it, but beyond shrieks
and yells their influence was not felt. The batteries of the enemy fired
chains, spikes, pieces of bar-iron, and solid shot. It was evident that
his canister and shell were exhausted. Now the Federal batteries on
the right were ordered to the front. Taking a position within five
hundred yards, they poured in an incessant shower of grape, canister
and shell for twenty minutes. A general bayonet charge was then
ordered, and the Union line rushed down the valley and ascended the
opposite hill. A cheer went up from them as they delivered volley
after volley into the enemy’s ranks. The rebels cheered also; and it
was evident that they doubled the Union forces, from the
overwhelming shout that rang up from their lines.
At this time General Sigel was carrying everything before him on
the extreme left. The foe was running, and the Union men catching
the inspiration of the moment rushed on in pursuit. Before one
o’clock the rout was complete.
To the westward of Pea Ridge there was a wide strip of timber
which had been blown down by a hurricane the previous summer.
Across this swarth of uprooted trees, which were larger and denser in
the low lands, the enemy’s cavalry and artillery attempted to retreat,
and were mercilessly pelted with shell. The panic was overwhelming,
and their defeat decided. Muskets, clothing, and shot-guns were
strewn along the woods. Horses roamed about in wild droves. The
cries of the cavalry men and the yells of the Indians, with the groans
of the wounded, surpassed all description. Caissons overturned,
wagons broken down, and horses dying and dead strewed the whole
road. Thirteen cannon, 6 and 12-pounders, were taken in all, besides
thousands of shot-guns and loads of provisions.
It was in this position of affairs that General Price with a
detachment of his army had, in his attempt to make a stand on the
Keatsville road, caught the contagion of his fleeing comrades, and
betook himself to the northward, Colonel Carr and General Asboth
keeping closely after him.
This was probably one of the most hotly contested battles of the
war, when every thing is taken into consideration, and it is worthy of
remark that few officers were wounded, although at all times
exposed even to recklessness. For three days the fighting continued,
the men only resting during the darkness, to renew the attack with
the first light, and even then were but partially allowed to slumber.
Pea Ridge will never be forgotten while we have a history.
The Federal loss in killed, wounded and missing, was 1,351. That of
the rebels about 2,000. Generals McIntosh and McCulloch were
killed.
BATTLE OF NEWBERN, N. C.