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WASTE
Waste (or wastes) are unwanted or unusable materials. Waste is any
substance which is discarded after primary use, or is worthless,
defective and of no use.
TYPES AND CHARACTERIZATION Examples include municipal solid waste (household trash/refuse),
agriculture waste, animal waste, industry based (may be hazardous
or non hazardous waste), wastewater (such as sewage, which
contains bodily wastes (feces and urine) industry specific), hospital
waste, radioactive waste, and others.
According to the Basel Convention on the Control of
Transboundary Movements of Hazardous Wastes and their
Disposal of 1989 : Wastes are substance or objects, which are
disposed of or are intended to be disposed of or are required to be
disposed of by the provisions of national law.
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Chips of wood
Wastewater (Lignin,
hemicellulose etc. )
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MSW MSW
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E WASTE
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Resource
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1. Physical
2. Moisture content
3. Bulk density
4. Chemical analysis
5. Proximate analysis
6. Ultimate analysis
7. Heating value
8. Leaching characteristics/Permeability or
Hydraulic conductivity
Sampling Method
100-200 kg is the optimum size
Coning and Quartering method is employed
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CONING AND QUARTERING METHOD AS PER USEPA Coning and Quartering Method
Timarpur plant in Delhi started in 1990, the plant was based on a technology
imported from Danish firm Volund Milijotecknik. The plant was designed to
incinerate 300 tonnes of municipal solid waste every day and generate 3.75 MW of
power. But the waste didn't have enough calorific value and the plant was shut after
21 days of operation.
The calorific value figures given to the firm were double of the actual.
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CHEMICAL ANALYSIS
1.Organic matter
2.Total N
3.Phosphorus
4.Potassium MSW GENERATION
5.C/N Ratio
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➢ Proximate analysis
➢ Ultimate analysis
➢ Heating/calorific value
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Determination of Moisture from first sample: Heating up to 920ºC in absence of air removes volatile matters, subsequent
Mass of sample = 0.9945 g heating up to 815ºC in presence of air burns all fixed carbon of the sample
leaving behind ash in the crucible.
Mass of dry MSW= (9.5340 - 8.5506) = 0.9834 g
Mass of moisture = (0.9945 - 0.9834) = 0.0111 g Determination of Ash from second sample:
% Moisture = 0.0111×100/0.9945 = 1.11% Mass of sample = 1.0120 g
Mass of crucible = 8.5685 g
Mass of ash (remnant in crucible) = (8.6255 - 8.5685) = 0.0570 g
% Ash = 0.0570 × 100/1.0120
= 5.63 %
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3. Experimental determination
NO2
combustion)
Response
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HEATING VALUE FROM PROXIMATE ANALYSIS HEATING VALUE FROM ULTIMATE ANALYSIS
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VM 5 10 15 20 25 30 35 38 40
Hydrogen : 3.11 %
a
100
60
Nitrogen : 1.25 %
0 10 20 30 40
VM
Sulphur : 1.15 %
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BOMB CALORIMETER
HEATING VALUE OF
GASEOUS/LIQUID FUELS:
EXPERIMENTAL METHODS
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❖Ash fusion is the process by which the ash produced by the combustion of a ❖It’s a process used to determine the behavior of ash under combustion conditions
fuel, melts and solidifies into clumps or lumps. in boilers and other combustion equipment.
❖This occurs in boilers and other combustion equipment, and can cause problems ❖It involves heating a cylindrical specimen of ash under controlled conditions in a
such as clogging of equipment and reduced efficiency. furnace and recording the temperatures at which the ash begins to soften,
❖Ash fusion temperature (AFT) is the temperature at which the ash begins to melt deform, and melt.
and fuse. ❖ASTM E1857-04 Standard Test Method for Ash Fusion Determination in
Coal and Coke is a widely used method to determine the ash fusion
❖AFT is a important parameter for the design and operation of boilers and other
combustion equipment, as they can predict potential ash-related problems such temperatures of coal, coke, and other carbonaceous materials.
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❖Softening Temperature (ST): Temperature at which the cone has fused down to
a spherical lump in which the height is equal to the width at the base.
flow, when heated at a specified rate in controlled, mildly in a nearly flat layer with a maximum height of 1.6 mm.
reducing, and where desired, oxidizing atmospheres.
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❖It can help to predict potential ash-related problems in boilers and other combustion
Taking sufficient ash for the number of cones desired from
equipment. For example, if the ash fusion temperatures are low, this may indicate that the various parts of the bulk ash. Moistening the ash with a few drops
ash will melt and fuse at lower temperatures, which can lead to clogging of equipment of a clear, filtered (if necessary) 10 % solution of dextrin
and reduced efficiency. containing 0.1 % salicylic acid as a preservative and working it
❖Secondly, it can also help to optimize the design and operation of boilers and other
into a stiff plastic mass with a spatula.
combustion equipment. For example, if the ash fusion temperatures are known, the design
of the equipment can be optimized to ensure that the ash does not melt/fuse at
temperatures that are too low.
❖Design of most coal combustion and coal conversion equipment anticipates that the ash
either remain solid or assume some degree of fluidity, depending on the particular design.
❖Ash fusibility temperatures predict whether the ash will perform properly in the process
for which the coal was chosen.
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ASH FUSION
LEACHING CHARACTRISTICS
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Q = – KA (∆h/∆L)
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Silt Clay
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Particle Sizes
⚫ Clay: less than 0.002 mm
⚫ Silt: 0.002 - 0.005 mm
⚫ Sand: 0.05 – 2 mm
➢ 0.05 - 0.24 mm fine
⚫ Gravels: 2 - 75 mm
⚫ Cobbles:75 - 250 mm
⚫ Stones: 250 - 600 mm
⚫ Boulders: >600 mm
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⚫ Large components of silt and clay, making it ⚫ Mostly sand and gravel
"muddy" when wet. ⚫ has large pore spaces and allows water to easily
⚫ Pore spaces are smaller and hold more water run through it
⚫ little surface area for the particle volume
⚫ As clay soils begin to dry, they may still hold
⚫ contaminants travel downward very fast
large quantities of water.
⚫ The small particle size and adhesive in
nature.
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Inlet
water Computations
Water
reservoir coefficient of permeability k, is:
V •L (cm/sec)
h k=
Manometer h• A • t
overflow
where: V = quantity of flow, cm3
t = elapsed time, sec
Soil h = loss of head in length, cm
specimen L L = length of soil specimen, cm
Overflow to
maintain A = cross-sectional area of specimen, cm2
constant Porous stone
head
Temperature correction factor for viscosity is to be incorporated
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standpipe Computations
cross-sectional α
Coefficient of permeability:
valve B
αL h 1
k= ln (cm/sec)
Αt h 2
where: α = inside area of standpipe, cm 2
Porous stone A = cross sectional area of specimen, cm2
h1
h1 = height of water in standpipe above at time (t=0), cm
h2 h2 = height of water in standpipe above at the end of the test, cm
Soil
L L = length of soil specimen, cm
specimen
t = elapsed time, sec
Cross-
section Α
Temperature correction factor for viscosity is to be incorporated
Water reservoir Water out flow
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nT 2. Remove the protective cover (paraffin wax) from the sampling pipe.
k 20 = kT (cm/sec)
n 20
3. Place the sampling pipe in the sample extraction frame, and push the plunger
to get a cylindrical form sample having height equal to that of specimen holder.
where: k20 = coefficient of permeability at 20 οC temperature of
4. The specimen shall be placed centrally over the porous disc to the drainage
water base.
kT = coefficient of permeability measured at water
temperature Τ οC) 5. The angular space shall be filled with an impervious material such as cement
slurry or wax, to provide sealing between the soil specimen and the specimen
nT = viscosity of water at temperature Τ οC holder against leakage from the sides.
n20 = viscosity of water at temperature 20 οC
6. The drainage cap shall then be fixed.
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