CLASSROOM CONTACT PROGRAMME

(Academic Session : 2023 - 2024)

LEADER & ACHIEVER COURSE

PHASE : MLP, MAZV, MAZX, MAZY, MAZK, MAPA, MAPB, MSP1, MSP2, LAKSHYA
TARGET : PRE-MEDICAL 2024
Test Type : MAJOR Test Pattern : NEET (UG)
TEST DATE : 13-03-2024
ANSWER KEY
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A. 4 3 4 2 2 2 3 3 1 3 1 3 2 4 3 3 2 2 2 3 4 2 4 3 1 2 1 2 4 4
Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. 1 4 4 1 3 2 4 1 1 1 4 1 2 3 2 3 3 3 4 2 4 1 3 4 2 2 2 1 4 1
Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A. 3 2 2 3 2 1 2 2 3 4 3 3 1 3 4 3 4 1 4 3 3 1 1 3 3 1 3 4 1 4
Q. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
A. 3 2 3 2 2 1 2 1 4 1 4 3 1 2 3 3 2 4 4 2 1 3 3 4 1 3 1 3 2 3
Q. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150
A. 2 4 1 4 3 4 2 4 1 1 2 3 4 3 4 4 2 1 1 1 4 3 4 4 1 3 4 2 1 2
Q. 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
A. 3 3 2 2 3 1 3 3 3 1 3 1 2 4 1 2 2 1 3 3 3 4 3 2 2 3 1 3 2 4
Q. 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200
A. 3 2 4 2 2 2 2 3 3 1 3 3 3 4 4 3 3 3 1 4

HINT – SHEET

SUBJECT : CHEMISTRY 5. Ans ( 2 )

SECTION-A

1. Ans ( 4 )
O3
CH ≡ CH −F→
e
−−−−−→
Δ Zn/H2 O

2. Ans ( 3 )
Rate of ESR ∝ +M, +H & +I effect.
3. Ans ( 4 ) 6. Ans ( 2 )
1° alcohol is obtained.
⇒ Nitrobenzene do not undergo
7. Ans ( 3 )

friedal craft's reaction

4. Ans ( 2 ) 8. Ans ( 3 )
– CCl3 It not get more stabilisation.

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9. Ans ( 1 ) 22. Ans ( 2 )
In presence of peroxide HBr gives 1-bromobutane Compounds contain same F.G.
by Antimarkonikov rule.
23. Ans ( 4 )
10. Ans ( 3 )
Trans-But-2-ene is more stable than Cis-But-2-ene
5 π + 13 σ
11. Ans ( 1 )
Lone pair on sp3 N atom.

12. Ans ( 3 ) 24. Ans ( 3 )

Ka ∝ Acidic strength.

13. Ans ( 2 ) 4-Bromo-3-chlorobenzoic acid

−M, −H, −I
Acidic strength ∝
+I, +H, +M

14. Ans ( 4 )
25. Ans ( 1 )
anti aromatic Alkanol ( – OH) / Alcohol → CnH2n + 2O
Since Alkanol does not have π bond or ring the
number of H will be same as Alkane i.e. 2n + 2
15. Ans ( 3 )
Due to resonance and H-bonding. 26. Ans ( 2 )

16. Ans ( 3 )

17. Ans ( 2 )
Antiaromatic compounds are unstable at room
temperature.
27. Ans ( 1 )
18. Ans ( 2 ) CH3COOH acetic acid (common name)
Stable by resonance.
28. Ans ( 2 )
19. Ans ( 2 ) Benzene carbonyl chloride.
Acetic acid do not form identical R.S.
29. Ans ( 4 )
20. Ans ( 3 )
Ethanoic anhydride
NH2 – NH2 does not contain carbon.

21. Ans ( 4 ) 30. Ans ( 4 )

Because O is involved in ring. Has different molecular formula.
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31. Ans ( 1 ) 40. Ans ( 1 )
Chain isomers due to difference in main chain. Bayer reagents (1% cold alkaline KMnO4) is
32. Ans ( 4 ) used to test the unsaturation.
Metamer due to different radicals around – O –
41. Ans ( 4 )
33. Ans ( 4 )
2 – CH3 group (bulkier group) are nearer.
34. Ans ( 1 )
Compounds purified by steam distillation 42. Ans ( 1 )
which are immiscible in water but steam 1
Boiling point of alkane ∝ M.wt ∝ .
volatile. Branching

35. Ans ( 3 ) 43. Ans ( 2 )

(A) Chloroform & aniline – Distillation due to Nucleophilicity ∝ – ve charge on less E.N. atom
large difference in boiling point
+I + M, +H
∝
(B) Aniline & water – Steam distillation due to −M, −H, −I
aniline is steam volatile and insoluble in water 44. Ans ( 3 )
(C) Amino acids – Chromatography due to less Not valid R.S due to nonavailability of d-orbital
in quantity in N-atom.
(D) Glycerol from spentlye – Distillation under 45. Ans ( 2 )
reduced pressure due to glycerol decomposed at Maximum e – density on 2 and 5 position.
its boiling point 46. Ans ( 3 )

SECTION-B

36. Ans ( 2 )
Directing group is – CH3
37. Ans ( 4 )
(i) CH3 – is ortho para directory.

(ii) does not give Friedel carts reaction. 1

Bond length ∝
bond order
38. Ans ( 1 )
47. Ans ( 3 )
Fact
39. Ans ( 1 ) 48. Ans ( 3 )
Allylic substitution takes place at high % of chlorine = 35.5 × 0.287 × 100
temperature by FRSR. 143.5 × 0.099
= 71.72

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49. Ans ( 4 ) 64. Ans ( 3 )
NCERT Pg. # 235
65. Ans ( 2 )
NCERT-11, Pg. # 230
SUBJECT : BOTANY
66. Ans ( 1 )
SECTION-A NCERT Pg. # 160
51. Ans ( 4 ) 67. Ans ( 2 )
NCERT, Pg. # 211 NCERT Pg. # 160
52. Ans ( 1 ) 68. Ans ( 2 )
XI NCERT Pg # 218 NCERT XI, Pg. # 237
53. Ans ( 3 ) 69. Ans ( 3 )
NCERT XI, Pg. # 223 NCERT XI, Page No. - 227,230 + Module
54. Ans ( 4 ) 70. Ans ( 4 )
NCERT XI Pg#220 XI NCERT Pg No - 237
55. Ans ( 2 )
71. Ans ( 3 )
NCERT, XI Pg. # 218, 219 XI NCERT Pg No - 232, 233
56. Ans ( 2 ) 72. Ans ( 3 )
NCERT, Pg. # 222 NCERT, Pg. # 233
57. Ans ( 2 ) 73. Ans ( 1 )
NCERT, Pg. # 213, 214, 215 XI NCERT Page No. # 230
58. Ans ( 1 ) 74. Ans ( 3 )
NCERT XI Pg#220 NCERT-XI, Pg # 250
59. Ans ( 4 ) 75. Ans ( 4 )
XI NCERT page No. # 207 NCERT Pg. # 251
60. Ans ( 1 ) 76. Ans ( 3 )
NCERT XI, Page No. 211,214 NCERT XI Pg. # 248
61. Ans ( 3 ) 77. Ans ( 4 )
NCERT-XI Pg. 212 NCERT XI Page-No. 248, 249, 250
62. Ans ( 2 ) 78. Ans ( 1 )
NCERT, Pg. # 231 NCERT-Page No. 253
63. Ans ( 2 ) 79. Ans ( 4 )
NCERT, XI Pg. # 230 NCERT Page No. - 249
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80. Ans ( 3 ) 96. Ans ( 1 )

NCERT Page No. 240 NCERT XI Pg. # 250
97. Ans ( 2 )
81. Ans ( 3 )
NCERT-XI Pg. No. # 241
NCERT-XI Pg. No. # 239
82. Ans ( 1 ) 98. Ans ( 1 )
NCERT-XI Pg. No. # 243 NCERT-XI Pg. No. # 245
83. Ans ( 1 ) 99. Ans ( 4 )
NCERT Page no. - 240 NCERT XI Page No. 249
84. Ans ( 3 )
100. Ans ( 1 )
NCERT XI Pg. No :- 244 NCERT, Pg. # 222
85. Ans ( 3 )
NCERT, Pg. # 232, figure SUBJECT : ZOOLOGY

SECTION-A
SECTION-B
101. Ans ( 4 )
86. Ans ( 1 )
Module No. # 7, Pg. No. # 3
NCERT, Pg. # 213
102. Ans ( 3 )
87. Ans ( 3 )
Module-7, Pg.#6
NCERT-XI Pg. No. # 212, 213

89. Ans ( 1 ) 103. Ans ( 1 )

NCERT-XI Pg. 212 XI NCERT Pg. No :- 319

90. Ans ( 4 ) 104. Ans ( 2 )

NCERT-XI Pg. No. # 231 XI NCERT Pg. No :- 318

91. Ans ( 3 ) 107. Ans ( 2 )

NCERT Pg. # 235 NCERT XI - Pg. No. 318

92. Ans ( 2 ) 111. Ans ( 1 )

NCERT XI, Pg. # 230 XI NCERT Pg. No :- 319
93. Ans ( 3 ) 112. Ans ( 3 )
NCERT-XI, Pg # 248 Module No. # 7, Pg. No. # 74
94. Ans ( 2 ) 113. Ans ( 3 )
NCERT XII - 241
Module No. # 7, Pg. No. # 72, 73
95. Ans ( 2 )
114. Ans ( 4 )
NCERT Page No. - 240
XI NCERT Page. No :- 342
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115. Ans ( 1 ) 148. Ans ( 2 )
NCERT Pg. No :- 338 Module-7 Page No.#04
150. Ans ( 2 )
116. Ans ( 3 ) XI NCERT Pg. No :- 317, 319
XI NCERT Pg. No :- 335
SUBJECT : PHYSICS
118. Ans ( 3 )
NCERT Page No. # 338 SECTION-A

121. Ans ( 2 ) 151. Ans ( 3 )

NCERT, Pg. # 332 Q2 250
β= ⇒ 5= ⇒ W = 50 J
W W
123. Ans ( 1 ) Q1 = Q2 + W
XI NCERT Pg. No :- 337 = 250 + 50
= 300 J
124. Ans ( 4 ) 152. Ans ( 3 )
XI NCERT Pg. No :- 335 Q
Q = W + ΔU [W = ]
4
125. Ans ( 3 )
Q
NCERT-XI, Pg. # 280, 281 Q = + ΔU (C = Molar specific heat)
4

127. Ans ( 2 ) 3Q 3 3
ΔU = ⇒ µCv Δ T = µC Δ T ⇒ Cv = C
4 4 4
NCERT Pg # 312 (E), 313 (H)
4 4 f
C = Cv = ( R) [For diatomic gas f = 5]
128. Ans ( 4 ) 3 3 2
XI NCERT Page No. 307 4 5 10
C = × R = R
3 2 3
129. Ans ( 1 ) 153. Ans ( 2 )
NCERT XI Pg.No.: 304 Slope of P-V graph in adiabatic process ∝ γ .
133. Ans ( 4 ) γ1 < γ2 γ mo > γ di
NCERT Pg # 312 (E), 313 (H) 2 is monoatomic, 1 is diatomic

SECTION-B
154. Ans ( 2 )
Here, WAB = 0 and
138. Ans ( 1 )
2P0
NCERT XI Pg.No.: 309 (E) ; 310 (H) WBC = nR(2T0) ℓ n ( ) = – 2RT0 ℓ n2
4P0

139. Ans ( 1 ) So work done on the gas = +2RT0 ℓ n2

NCERT XI Pg.No.: 303 (E), 304 (H)
155. Ans ( 3 )
142. Ans ( 3 ) P1V1 γ = P2V2 γ
NCERT-XII, Pg. # 338 V1
3/2
P2 = (1) [ ]
(V1 /4)
143. Ans ( 4 )
NCERT-XI, Pg. # 330, Para (22.1) P2 = 8 atm

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156. Ans ( 1 ) 161. Ans ( 3 )
ad is Adiabatic ⇒ T1 Vaγ−1 = T2 Vdγ−1 P = σ AT4 ⇒ P ∝ T4
bc is Adiabatic ⇒ T1 Vbγ−1 = T2 Vcγ−1 1
According to Wein's law, T ∝
λm
Va Vd V V 4
= ⇒ a = b 1
Vb Vc Vd Vc ⇒P ∝( )
λm
157. Ans ( 3 ) P λm
4
⇒ 2 =( 1 )
Δ U = nCV Δ T = n(5/2)R Δ T P1 λm 2
4
⎛ λ
⇒ P2 =
⎞
0
Δ Q = nCP Δ T = n(7/2) R Δ T
P 1 ⎝ 3 λ0 ⎠
2
n7
W = ΔQ – ΔU = R Δ T – n5 R Δ T = nR Δ T nP 16 16
2 2 ⇒ = ⇒n=
W 2 P 81 81
=
ΔQ 7 162. Ans ( 1 )
52 − 36 52 + 36
( ) = K ( − 20)
10 2
158. Ans ( 3 ) 16
= K(24)
1 10
λm =
√ 2 n π d2 1
= 3K ..........(i)
159. Ans ( 3 ) 5
36 − T 36 + T
= K[ − 20]
Internal energy of n moles of an ideal gas at 10 2
36 − T T −4
= K[ ] ..........(ii)
temperature T is given by 10 2
f (i)/(ii)
U= nRT [f=degrees of freedom]
2
10 3
=
U1 = U2 5 (36 − T ) (
T −4
)
2

f1n1T1 = f2n2T2 10 T – 40 = (36 – T) 6 × 5

n1 f2 T 2 3 × 2T 6
∴ = = = 10 T – 40 = 36 × 30 – 30 T
n2 f1 T 1 5×T 5
Here, f2 = degrees of freedom of He = 3 40 T = 1120
and f1 = degrees of freedom of H2 = 5
160. Ans ( 1 ) 163. Ans ( 2 )
(νr.m.s )N2 = (νr.m.s )O2
Power ∝ T4 – T04
3RT 3R × 400 (1000)4 − (500)4
√ =√ 60
28 32 =
P2 (1500)4 − (500)4
400 × 28
T= = 350 K 60 24 − 1 15
32 = =
P2 4
3 −1 80

(350 – 273) = 77°C P2= 320 W

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164. Ans ( 4 ) 172. Ans ( 4 )
m
T1 = 2π √

T2 = 2π√ m
2k

40 − T 80 − T 90 − T 173. Ans ( 3 )
+ + =0
R R R T.E. = (PE)min + (K.E.)max
3T = 210 ⇒ T = 70oC
165. Ans ( 1 ) 9 = 5 + (K.E.)max
Let equilibrium temperature is "T" (K.E.)max = 4 J
mℓ ⋅ sℓ (T − Tℓ ) = mo ⋅ so ⋅ (To − T ) This is KE at mean position
0.5 × 4000 × (T – 5) = 0.8 × 3500 (12 – T) 174. Ans ( 2 )
T = 9.08 A
At x =
166. Ans ( 2 ) 4

At lower pressure, water boils at lower

1 A2 1 15
temperature K. E. = K ( A2 − ) = KA2 ( )
2 4 2 16
167. Ans ( 2 ) 1 15
KA2 ( )

4 3 K. E. 2 16 15
Thermal capacity = ms = v ρ s = πr ρs = 1
=
3 T . E. KA2 16
2

mA s A r3 ρ A s A 175. Ans ( 2 )
= A
mB s B r3B ρB sB

1 2 1 1
= × × =
8 1 3 12

168. Ans ( 1 ) 2(d1 + d2) = v(t1 + t2)

( γ real)glass = ( γ real)steel 330 × (3 + 5)
d1 + d2 = = 1320 m
2
( γ a)glass + γ glass = ( γ a)steel + γ steel
176. Ans ( 3 )
⇒ 153 × 10 – 6 + 3 α = 144 × 10 – 6 + 3 × 12 × 10 – 6
In RT experiment
⇒ α = 9 × 10 – 6 /°C
V = 2n ( ℓ 2 – ℓ 1)
169. Ans ( 3 ) 2 × 250(99.2 − 32.2)
Strain developed : V = = 335 m/s
100
ε = α Δ T = (12 × 10 – 6) (50) = 6 × 10 – 4
170. Ans ( 3 ) 177. Ans ( 1 )
−bt
A = A0 e 2m
γRT
f same ⇒ √ same ⇒ √ T same
171. Ans ( 3 ) MW MW
273 + 47 273 + C
K(ℓT otal ) K×4 4K ⇒ = ⇒ C = 7°C
Klonger part = = = 32 28
ℓLonger 3 3
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178. Ans ( 3 ) 184. Ans ( 2 )
ω
√ I1 13 Speed of wave, v = .
= K
√I
2 10 100
⇒v= = 5 m/s
2 20
Imax (√ I1 + I2 ) √

=[ ]
185. Ans ( 2 )
Imin (√ I1 − √ I2 )
2 2 For rotational equilibrium
13 + 10 23
=( ) =( )
13 − 10 3 τc.w = τA.c.w

179. Ans ( 2 ) m × 2 ℓ + 3 × 3 ℓ = 12 ℓ
At x = 0, y = a sin ω t, so y' = – a sin ω t at x = 0
2 m = 3 ⇒ m = 1.5 kg
180. Ans ( 4 )
Number of beats per second SECTION-B
v v 1 1
= − = 330 ( − ) = 66 − 60 = 6 186. Ans ( 2 )
λ1 λ2 5 5.5
181. Ans ( 3 ) By FLOT :
I1 ω21 A21 υ21 A21 1 × 25 25
= 2 2 = 2 2 = = dQ = dW + Δ U
I2 ω 2 A2 υ 2 A2 4×4 16
183. Ans ( 4 ) Also, in adiabatic process
Particle velocity dy = −ν (
dy
) (dQ = 0) dW = – Δ U
dt dx
dy if, dW = +ve
or = – wave velocity × slope of the wave
dt
then, Δ U = – ve
187. Ans ( 2 )
At constant pressure,

Heat required = nCp Δ T

(1) For upward velocity, ν Pa = + ve, so slope must
be negative which is at the points D, E and F. ⇒ 310 = 2 × Cp × (35 – 25)

(2) For downward velocity, ν Pa = – ve, so slope 310

⇒ Cp = = 15.5 J/mol − K
20
must be positive which is at the points A, B and H.
Similarly, at constant volume
(3) For zero velocity slope must be zero which is at
C and G. Heat required = nCV Δ T
(4) For maximum magnitude of velocity, |slope| =
= 2(Cp – R) × (35 – 25) ( ∵ Cp – CV = R)
maximum, which is at A and E. Hence, given
alternative (4) is wrong. = 2 × (15.5 – 8.3) × 10 = 2 × 7.2 × 10 = 144 J

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188. Ans ( 3 ) 192. Ans ( 3 )
For A to B, process is isobaric y1 = Anetsin( ω t + ϕ 1)
V ∝ T b √ 3/2
tan ϕ 1 = =
a 1/2
Since TA > TB ⇒ VA > VB
π
tan ϕ 1 = √ 3 ⇒ 60°; ϕ 1 = radian
For B to C, Process is isothermal 3
1 y2 = Anet sin( ω t + ϕ 2);
P ∝
V 1 π
P B > P C ⇒ VB < VC
tan ϕ 2 = = 45°; ϕ 2 = radian
1 4
π π
For C to A, process is isochoric Δϕ = ϕ1 – ϕ2 = −
3 4
P ∝ T π
Δϕ = radian
12

193. Ans ( 3 )

189. Ans ( 3 )
7 7 5
γ= , Cp = R, Cv = R
5 2 2
4 8 6
γ = , Cp = R, Cv = R Net downward force = (mg – qE)
3 2 2
μ 1 Cp 1 + μ 2 Cp 2 15
γmix = =
μ 1 Cv 1 + μ 2 Cv 2 11 qE
geff = ( g− )

190. Ans ( 1 ) m

In isochoric process V = constant and P ∝ T ℓ

T = 2π √
geff
∴ P – T graph is a straight line passing
through origin. 
 ℓ
T = 2π 
qE
nR ⎷
g−
But since P =[ ] T m
V
1 194. Ans ( 4 )
slope of the straight line ∝
V
(slope)1,2 < (slope)3,4 ∴ V2 > V3
Also V1 = V2 and V3 = V4
191. Ans ( 3 )
If it takes time 't' for formation of thickness y of
the ice, then t ∝ y2.
If for thickness of 1 cm, it takes 7 hours, then
for thickness of 2 cm, it takes 28 hours.
For thickness to change from 1 cm to 2 cm, it 2π
Phase difference =
takes 28 – 7 = 21 hours. 3
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195. Ans ( 4 ) 198. Ans ( 3 )
x = 3sin( π t + π /6) VH 2 γH M
= √ 2 × He
VHe γHe M H2
differentiating w.r.t. t VH 2 √ 7 3 4 √ 42
= × × =
dx VHe 5 5 2 5
v= = 3 π cos( π t + π /6)
dt
200. Ans ( 4 )
again differentiation w.r.t. t
v 1 √T 1 T
2 n= = = √
a = – 3 π sin( π t + π /6) 2L 2L μ 2L πr2 ρ
T
at t = 1, a = +1.5 π 2 cms – 2 ∴n∝√ (for constant L and ρ )
r2

196. Ans ( 3 ) n′  r2 (T /2) 1
∴ = × =√
Theory based n ⎷
T (2r)
2 8

197. Ans ( 3 ) n
⇒ n′ =
2 × 10−8 2 √2
L = 10 log10 ( ) decibel
10−12

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