JAGRITI PUBLIC SCHOOL

(SENIOR SECONDARY)
Final Term Examination
SUBJECT- CHEMISTRY
Time:- 3 Hours CLASS-XI M:M-70

General Instructions:
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A comprises 16 multiple -choice questions carrying 1 mark each.
(c) SECTION B comprises 5 short answer questions carrying 2 marks each.
(d) SECTION C comprises 7 short answer questions carrying 3 marks each.
(e) SECTION D comprises 2 case - based questions carrying 4 marks each.
(f) SECTION E comprises 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.

[Section A]

=> The following questions are multiple -choice questions with one correct answer. Each
question carries 1 mark. There is no internal choice in this section

1. What will be the molarity of a solution, which contains 5.85 g of NaCl(s) per 500 mL?
(A) 4 mol L-1
(B) 20 mol L-1
(C) 0.2 mol L-1
(D) 2 mol L-1

2. The empirical formula and molecular mass of a compound are CH20 and 180 g
respectively. What will be the molecular formula of the compound?
(A) C9H18O9
(B) CH2O
(C) C6H12O6
(D) C2H4O2

3. Which of the following conclusions could not be derived from Rutherford’s a-particle
scattering experiment?
(a) Most of the space in the atom is empty.
(b) The radius of the atom is about 10 10 m while that of nucleus is 10 15 m.
(c) Electrons move in a circular path of fixed energy called orbits.
(d) Electrons and the nucleus are held together by electrostatic forces of attraction.

4. Which of the following^ the correct IUPAC name?

(a) 3-Ethyl-4,4-dimethylheptane
(b) 4,4-Dimethyl-3-ethylheptane
(c) 5-Ethyl-4,4-dimethylheptane
(d) 4,4-Bis(methyl)-3-ethylheptane

5. Choose the correct answer.

A thermodynamic state function is a quantity :
(a) Used to determine heat changes.
(b) Whose value is independent of path.
(c) Used to determine pressure volume work.
(d) Whose value depends on temperature only.

6. The types of hybrid orbitals of nitrogen in CO2,NH3and BF3 respectively are expected to
be:
(a) sp, sp3 and sp2
(b) sp, sp2, and sp3
(c) sp2, sp and sp3
(d) sp2, sp3 and sp

7. Acidity of BF3 can be explained on the basis of which of the following concepts?

(i) Arrhenius concept (ii) Bronsted Lowry concept

(iii) Lewis concept (iv) Bronsted Lowry as well as Lewis concept.

8. Which of the following is not an example of redox reaction?

(a) CuO + H2 → Cu + H20
(b) Fe202 + 3CO → 2Fe + 3C02
(c).2K + F2 →2KF
(d) BaCl2 + H2S04 →BaS04 + 2HCl

9. Consider the isoelectronic species, Na+, Mg2+, F– and O2–. The correct order of increasing
length of their radii is _________.

(i) F-< O2–< Mg2+< Na+

(ii) Mg2+< Na+< F–< O2–

(iii) O2–< F–< Na+< Mg2+

(iv) O2–< F–< Mg2+< Na+

10. We know that the relationship between Kc/ and Kp is Kp= Kc/(RT)∆n What would be
the value of ∆n for the reaction: NH4 Cl(s)⇄ NH3(g) + HCl(g)
(a) 1
(b) 0.5
(c) 1.5
(d) 2

11.∆U° of combustion of methane is – X kj mol-1 CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) The

value of ∆H° is :
(a) = ∆U°
(b) > ∆U°
(c) < ∆U°
(d) = 0

12. In which of the following, functional group isomerism is not possible?

(a) Alcohols
(b) Aldehydes
(c) Alkyl halides
(d) Cyanides

In the following questions, a statement of assertion followed by a statement of reason is

given. Choose the correct answer out of the following choices:

(a) Assertion and reason both are correct and reason is correct explanation for assertion.

(b) Assertion and reason both are correct but reason is not correct explanation for
assertion

(c) Assertion is correct but reason is wrong statement.

(d) Assertion is wrong but reason is correct statement

13. Assertion: F-atom has a less negative electron affinity than Cl-atom.

Reason Additional electrons are repelled more effectively by 3P-electrons in Cl-atom than
by 2P-electrons in F-atom.

14. Assertion: Boron has smaller first ionization enthalpy than Beryllium

Reason: The penetration of 2s electron by the nucleus is more than 2p electrons.

15. Assertion: Photoelectric effect is most readily shown by cesium metal.

Reason: Photons have easiest access to the surface of cesium metal.

16. Assertion (A) : All isotopes of a given element show the same type of chemical
behavior.

Reason (R) : The chemical properties of an atom are controlled by the number of
electrons in the atom.

[SECTION-B]

This section contains 5 questions with internal choice in one question. The following
questions are very short answer type and carry 2 marks each.

Q17. (a) Give the balanced chemical equation for combustion of Methane gas.
(b) Calculate the amount of water (g) produced by the combustion of 16 g of methane.

Q18. The value of ∆f H for NH3 is – 91.8 kJ mol–1. Calculate enthalpy change for the
following reaction : 2NH3(g) → N2(g) + 3H2(g)

Q19. Write short notes on a) Decarboxylation b) Friedel craft reaction

Q20. Write down the mechanism of Kolbe’ electrolytic method.

Q21.The frequency of the photon having a wavelength equal to 1500 A° ?

Or
An atom having atomic mass number 13 has 7 neutrons. What is the atomic number of
the atom?

[SECTION – C]

This section contains 7 questions with internal choice in one question. The following
questions are short answer type and carry 3 marks each.

22. Write the equations for the following reaction:

a. Ethanol is treated with conc. Sulphuric acid at 443K.
b. butyl chloride is treated with alc KOH.
c. Phenol is treated with Zn dust.

23.Calculate:
(i) Mass in gram of 5.8 mol N2O
(ii) Number of moles in 8.0 g of O2
(iii) Molar mass if 11.2 L at STP weigh 8.5 g
24. A reaction between ammonia and boron trifluoride is given below:
NH3 + BF3 → H3N : BF3. Identify the acid and base in this reaction. Which theory explains
it? What is the hybridisation of B and N in the reactants?

25. Write Lewis structure of the following compounds and discuss its shape on VSEPR
theory - SF6.CO32-,SO2,SF4

26.Give the IUPAC name/structure of:

(i) (CH3)2(C2H5)C-(CH2)3-C(CH3)3
(ii) Ortho-chloro anisole
(iii)

27. Write short notes on

a) Inductive effect b) Electrometric
lectrometric effect c) Hyperconjugation
Or
Giving justification, categorise the following molecules/ions as nucleophile or electrophile:-
electrophile:
HS , BF3, C2H5O, (CH3)3 N:
Cl, CH3-C =O,H2N:, NO2

28. Match the intermediates given in Column I with their probable structure in Column II.
Column I Column II
(i) Free radical (a) Trigonal planar
(ii) Carbocation (b)) Pyramidal
(iii) Carbanion (c) Linear

[SECTION – D

The following questions are case -based questions. Each question has an internal choice
and carries 4 marks.

29. .Read the passage and answer the questions follow:

The electronegativity of any given element is not constant. lt varies depending on the
clement to which it is bound though it is not a measurable quantity. It does provide a
means of predicting the nature of force that holds a pair of atoms together a relationship
that you will explore later.
1.Among the following C, S, N, B, the most electronegative element is: (a) C (6) N (c) S
(d) B

2. Most electronegative halogen is (a) F (b) C (c) Br (d) I

3. The increasing order of electronegativity of elements N, C, Si and P is?

4.The least electronegative element among F, C, Si, P is: (a) Si (b C (c) F (d) P

30.The rotation of carbon-carbon single bond (s-bond), due to cylindrical symmetry of s-

MOs (molecular orbitals) long internuclear axis, in alkanes results into different spatial
arrangements of atoms in space, that are interconvertible. These arrangements are called
conformations.

However, weak repulsive interaction are present between the adjacent bonds in alkanes so
the rotation of C—C single bond is not completely free and is hindered by a small energy
barriers of 1-20 kJ mol-1. The repulsive interaction between the adjacent bond is due to
electron cloud. The two types of conformations are very common, i.e., staggered and
eclipsed.

The conformation in which the hydrogen atoms attached to the two carbon atoms are as
far apart as possible is called the staggered conformation. The conformations in which the
hydrogen atoms attached to the two carbon atoms are as closed as possible is called
eclipsed conformation. Any intermediate conformation between the above two is called
skew or gauche conformation.

1) The Electronic distribution of the sigma molecular orbital is symmetrical around the
internuclear axis of C-C bond which permits free rotation around C-C bond. Such spatial
arrangement of atoms in which conversion of one another takes place by rotation around C-C
bond is known as-
(a) Rotamers (b) Conformer (c) Conformations (d) All of these

2) The possible rotamers of ethane is/are-

(a) 2 (b) 3 (c) 4 (d) ∞

3) The different conformations of ethane cannot be separated and isolated because-

(a) Small energy barrier (b) Large energy barrier
(c) Both ‘a’ and ‘b’ (d) Neither ‘a’ nor ‘b’

Or
The repulsive interaction between the electron clouds, which affects stability of a conformation is
termed as-
(a) Torsional strain (b) Dihedral angle
(c) Torsional angle (d) Conformation
4) Which form of ethane has the least torsional strain?
(a) Staggered (b) Skew boat (c) Eclipsed (d) Boat

[SECTION –E]

The following questions are long answer type and carry 5 marks each. All questions have
an internal choice.

Q31. (i) Define :- 1. Oxidation 2. Reduction 3. Oxidant 4. Reducing agent

On the basis of electron transfer and oxidation number.

(ii) Balance the following equation:- P4(s) + OH – (aq) PH3(g) + H2PO2 – (aq) (in basic
medium)
Or
MnO4 (aq) + SO2(g)
- Mn2 (aq) + HSO4-(aq) (In acidic medium)
+

32.a)Use the molecular orbital energy level diagram to show that N2 would be expected to
have a triple bond, F2, a single bond and Ne2, no bond.
b)Match the shape of molecules in Column I with the type of hybridization in

Column I Column II
(i) Tetrahedral (a) sp2
(ii) Trigonalplaner (b) sp
(iii) Linear (c) sp3
Or
a)What is the effect of the following processes on the bond order in N2 and O2?
(i) N2 → N2 + + e– (ii) O2 → O2 + + e–

b) Give reasons for the following :

(i) Covalent bonds are directional bonds while ionic bonds are nondirectional.

(ii) Water molecule has bent structure whereas carbon dioxide molecule is linear.

(iii) Ethyne molecule is linear.

33. Write shot notes on

a) Markovnikove addition and anti markovnikove addition explain with example

b)Predict the major product (s) of the following reactions and explain their formation.
 1. But-2-yne with lindlar catalyst 2. With Na/liq ammonia
Or
a) An alkene A on ozonolysis gives propn-2-one and propanal .Write down structure and
its IUPAC name.

b) Convert a) ethyne to benzene b) ethanoic acid to methane c) ethyne to ethanal