UNIVERSITY OF MADRAS

PRACTICAL EXAMINATION -APRIL 2024

SUB: INORGANIC CHEMISTRY PRACTICAL SUB. CODE :

CLASS : I. MSC DATE : 10.04.2024 BATCH : I

SKILL VALUE

Q-1 Mixture given to the candidates

Mn, Sr,Se, V 1,8,9

Co, Bi, Zr, Mo 2,7,10,15
W,Ce,Ni,Ba 3,6,11,14
Li, Cu,PB, V 4 , 5,12,13

Q-2 Preparation : Hexathioureacopper (I) chloride

Q-3 .Estimation of Zinc

1.Preparation of standard solution :

Weight of zinc sulphate taken = 0.03 g
0.03 ×1000
=
65.3× 100
= 0.0046 N
2.Titration I: Standardization of EDTA
Volume of Zinc solution V1 = 20 ml
Normality of zinc solution N1 = 0.0046 N
Volume of EDTA V1 = 15.8 ml
15.8× 0.0046
Strength of EDTA =
20
= 0.0036
3.Titration II: Estimation of Zinc
Volume of EDTA V1 = ml
Strength of EDTA N1 = 0.0036 M
Volume of Zinc sulphate V1 = 20 ml
Normality of Zinc sulphate N2 = ?
Normality of Zinc sulphate =
−−¿
The weight of Zn present in the given solution = 65.37 ×− 1000 ¿ × 100
= ------------g
 Skilled assistant Internal External
UNIVERSITY OF MADRAS
PRACTICAL EXAMINATION -APRIL 2024

SUB: INORGANIC CHEMISTRY PRACTICAL SUB. CODE :

CLASS : I. MSC DATE : 12.04.2024 BATCH : II
SKILL VALUE
Q-1 Mixture given to the candidates

Mn, Sr,Se, V 4,8,12,

Co, Bi, Zr, Mo 3,7,11
W,Ce,Ni,Ba 2,6,10,14
Li, Cu,PB, V 1, 5 ,9,13

Q-2 Preparation : Hexathiourealead(II) nitrate

Q-3 .Estimation of Magnesium

1.Preparation of standard solution :

Weight of zinc sulphate taken = 0.03 g

0.03 ×1000
=
65.3× 100
= 0.0046 N
2.Titration I: Standardization of EDTA
Volume of Zinc solution V1 = 20 ml
Normality of Zinc solution N1 = 0.0046 N
Volume of EDTA V1 = 15.8 ml
15.8× 0.0046
Strength of EDTA =
20
= 0.0036 N
3. Titration II: Estimation of Zinc
Volume of EDTA V1 = ml
Strength of EDTA N1 = 0.0036 M
Volume of Magnesium sulphate V1 = 20 ml
Normality of Magnesium sulphate N2 = ?
Normality of Magnesium sulphate =
−−¿
The weight of Zn present in the given solution = ×− 1000 ¿ × 100
= ------------g
Skilled assistant Internal External