Njeets FT 2 - Jee Adv p2 - 20042024

FIITJEE NJEETS JEE ADVANCED
PHYSICS, CHEMISTRY & MATHEMATICS

JEE (A) NJEETS -2 PAPER - 2 20/04/2024
Time Allotted: 3 Hours Maximum Marks: 240
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
NJEETS JEEA TEST - 2
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into Two sections: Section-A & Section-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Question Paper Format & Marking Scheme For All Three Parts.
(i) Section-A contains 8 multiple choice questions with one or more than one correct option.
Marking Scheme : +4 for correct answer, 0 if not attempted and –2 marks in all other cases.
(ii) Section-A contains 2 paragraphs type questions. Each paragraph describes an experiment, a situation
or a problem. Two multiple choice questions will be asked based on this paragraph. One or more than
one option can be correct.
Marking Scheme : +4 for correct answer, 0 if not attempted and –2 marks in all other cases.
(iii) Section-C contains 8 question. The answer to each question is a Single digit integer ranging from 0 to
9 (both inclusive).
Marking Scheme : +4 for correct answer and 0 in all other cases.
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Batch :___________________ Date of Examination :___________________
Enrolment Number :______________________________________________
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JEE(A) NJEETS -2 -(Paper-2)-PCM-IITJEE-2
Useful Data
PHYSICS
Acceleration due to gravity g = 10 m / s2
Planck constant h = 6.6 × 10–34 J-s
Charge of electron e = 1.6 × 10–19C
Mass of electron me = 9.1 × 10–31 kg
Permittivity of free space 0 = 8.85 × 10–12 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K–1 mol–1
CHEMISTRY
Gas Constant R = 8.314 J K−1 mol−1

= 0.0821 Lit atm K−1 mol−1
= 1.987  2 Cal K−1 mol−1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No.: H=1, He=2, Li=3, Be=4, B=5, C=6, N=7, O=8, F=9, Na=11, Mg=12, Al = 13,
Si = 14, P = 15, S = 16, Cl = 17, Ar =18, K=19, Ca=20,Cr=24, Mn=25, Fe=26, Co=27, Ni=28,
Cu=29, Zn=30, As=33, Br = 35, Ag = 47, Si = 21, Sn = 50, Ti = 22,I = 53, Xe = 54, Ba = 56,
Pb = 82, U = 92, V = 50.
Atomic masses: H =1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16, F=19, Na=23, Mg=24,
Al=27, Si=28, P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59, Ni=58.7,
Cu=63.5, Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137,
Pb = 207, U = 238.


PART-I : PHYSICS
SECTION-A (One or More Than One Options Correct Type)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
1. A metallic conductor of irregular cross-section is
shown. A constant potential difference is applied
across the ends 1 & 2. Then : 1 P Q 2
(A) The current at the cross-section P equals the
current at the cross-section Q.
(B) Electric field at P is less than that of Q.
(C) Power loss at Q is greater than that at P.
(D) Electrons crossing per unit area per unit time is higher at Q than P.
2. Monochromatic light of frequency f1 is incident on a photocell and the stopping potential is found
to be V1. What is the new stopping potential of the cell if it is radiated by monochromatic light of
frequency f2?
h h h h
(A) V1 − ( f2 − f1 ) (B) V1 + ( f1 + f2 ) (C) V1 − ( f1 + f2 ) (D) V1 + ( f2 − f1 )
e e e e
3. An observer rides with a sound sources of frequency 200 Hz and moving with velocity
40 m/s towards a large vertical wall. [Take velocity of sound as 340 m/s]
(A) Number of waves striking the wall per second is 680/3Hz.
3
(B) Wavelength of reflected wave is m.
2
680
(C) The frequency of reflected wave is Hz.
3
160
(D) Beat frequency is Hz.
3
Space For Rough Work


4. A freshly prepared sample of certain radioactive substance has an activity R0. After a time
interval t activity decreases to R.
1  R0 
(A) Decay constant for the decay process is n
t  R 
n2
(B) Half life of the radioactive substance is t
R 
n 0 
R
1 n2
(C) Decay constant for the decay process is
t  R 0 
n 
 R 
R 
(D) Half life of the radioactive substance is t n  0 
R
5. If the temperature of the body is raised to a higher temperature T', then choose the correct
statement(s)
(A) The intensity of radiation for every wavelength increases
(B) The maximum intensity occurs at a shorter wavelength
(C) The area under the graph increases
(D) The area under the graph is proportional to the fourth power of temperature
6. The diagram shows a small bead of mass m and charge q. The bead Diameter = 5m
can be freely moved on the circular insulted path of diameter 5m. On
a horizontal plane. In the same plane a charge is placed at a distance V0
4L from bead as shown. If potential due to given charge at P is V the
velocity with which the bead should be projected so that it can (Positive Charge)
a, m
complete the circle. 4L P
6qV qV 3qV 3qV

(A) (B) (C) (D)
m m m 2m


7. In the diagram shown the medium boundary is given by the equation

y = x2. Below it medium air is air (µ = 1) and above it medium has
refractive index 2. Co-ordinates of the point in first quadrant after
which light. Will pass in the second medium. µ=2
 1 1  1 1 medium
(A)  ,  (B)  , 
 2 3 12   3 12 
 2 1  2 1
(C)  ,  (D)  , 
 3 12  3 2 6
8. A boy in the elevator with open roof shoots a bullet in vertical upward direction from a height of
1.5 above the floor of the elevator. The initial speed of the bullet with respect to elevator is
15 m/s. The bullet strikes the floor after 2 seconds. Then (Assuming g = 10 m/s2)
(A) Lift is moving with constant speed
(B) Lift is moving with upward acceleration of 5.75 m/s2
(C) Lift is moving with downward acceleration of 5.75 m/s2
(D) Distance travelled by bullet during its flight can not be calculated from the given data.
SECTION-A : Comprehension Type (One or More Than One Option Correct)

This section contains 2 paragraphs, type questions. Each paragraph describes an experiment, a
situation or a problem. Two multiple choice questions will be asked based on this paragraph.
One or more than one option can be correct.
Paragraph for Question Nos. 9 to 10
Two astronauts, each having a mass ‘M’ are connected by a rope of length ‘d’ having negligible
mass. They are isolated in space, orbiting their center of mass at speed ‘v’. Treat astronauts as
d
particles. By pulling the rope, one astronaut shortens the distance between them to ' '.
2
9. Calculate work done by the astronaut in shortening the rope :
(A) 2Mv 2 (B) 3Mv 2 (C) Mv 2 (D) zero
10. Physical quantity that will remain conserved during the process of pulling in rope.
(A) Speed of astronauts (B) Energy of the system
(C) Angular speed of astronauts about COM (D) Angular Momentum


Paragraph for Questions 11 and 12

A 6.0 V battery supplies current to the circuit shown in the figure. R1 R2
When double throw switch ‘S’ is open as shown, the current in the
battery is 1.00 mA. When the switch is closed in position ‘a’. The R2
current in the battery is 1.20 mA. When switch is closed in position ‘b’ a
6.0V S R3
the current in the battery is 2.00 mA. b
11. The value of resistance R1 is
(A) 2.00 k (B) 1.00 k (C) 3.00 k (D) 4.00 k
12. The value of resistance R3 is

(A) 2.00 k (B) 1.00 k (C) 4.00 k (D) 3.00 k
SECTION-C: (Single digit integer)

This section contains 8 questions. The answer to each question is a single digit integer ranging from
0 to 9 (both inclusive).
1. Determine the resistance (in ) to be connected across a and b 3 2
a
in given circuit to dissipate maximum power through it. 6
3
+ + 2
5V - 5V -
b
2. The figure shows a RC circuit with a parallel plate capacitor. Before -Q0
switching on the circuit, plate A of the capacitor was given a charge A B
–Q0 while plate B had no net charge. a
R
Now, at t=0, the circuit is switched on. How much time
(in seconds) will elapse before the net charge on plate A becomes
2  106
zero. Take C = 1 F, Q0 = 1 mC,  = 1000 V and R =  
n (3)
3. A thin prism P1 with angle 4 and made from glass of refractive index 1.54 is combined with
another thin prism P2 made from glass of refractive index 1.72 to produce dispersion without
deviation. Calculate the angle of prism P2 (in degrees)


4. The 1/v versus displacement graph of a particle is shown in the 1/v (s/m)
figure, where v is the speed of the particle. The particle is moving B

4
in a straight line along positive x-axis. Calculate the time taken (in
seconds) by the particle to reach from the point A to B .
2
A
0 2 x (m)
5. A 6000 Kg freight car rolls along rails with negligible

friction. The coil is brough to rest by a combination of two
K2
coiled springs as shown. The force constants of the V
springs are, K1 = 1600 N/m and K2 = 3400 N/m. After the
K1
first spring compresses a distance of 30.0 cm, the
second spring acts with the first to increase the force as
additional compression occurs. The car comes to rest
50.0 cm after first contacting the two spring system. The
n
car’s initial speed is m / s. The value of n is
10
6. One end of a uniform 4.00 m long rod of weight Fg is supported by a

cable. The other end rests against the wall, where it is held by friction
as shown. The coefficient of static friction between the wall and the
rod is µs = 0.5. The minimum distance x from point A at which an
additional object, also with same weight Fg, can be hung without
14.1 37°
causing the rod to slip at point A is . The value of n is :
A B
n
x
Fg
7. Assume a deuteron and a triton are at rest when they fuse according to the reaction
1 H + 1H → 2He + 0n + 17.6MeV.
2 3 4 1
The kinetic energy acquired by the neutron is nearly 2n MeV. The value of n is :
d
8. = 10−4 in Young’s double slit experiment, where d is distance between slits and D is the
D
distance of screen from the slits. The resulting intensity is equal to the intensity due to individual
slit 0 at a point on the screen. Find the distance of point P from the central maximum (in mm) if
 = 6000 A.


PART−II: CHEMISTRY
1. Which of the solubility order is correct?
(A) BeO < MgO < CaO < SrO < BaO (B) NaBr < KBr < RbBr < CsBr
(C) NaClO3 > KClO3 > RbCiO3 > CsClO3 (D) BeS2O3 < MgS2O3<SrS2O3
2. Which of the following is incorrect?

(A) Na3PO4(aq.) + AgNO3 ⎯⎯→ Light yellow precipitate
(B) ⎯⎯⎯
Cold
→ Re ddish brown precipitate
KHCO3 + HgCl2
⎯⎯⎯⎯
Boiled
→ No precipitate
(C) On adding HgCl2 to KHCO3 solution in cold, pH decreases drastically
(D) Na2CO3 (aq.) + BaCl2 (aq.) ⎯⎯→ white precipitate
excess of NaOH solution
Clear solution
3. Which among the following are true about silicones?

(A) They are formed by hydrolysis of R2SiCl2 followed by heating
(B) They are polymers made up of R2SiO unit
(C) They are made up of SiO44− units
(D) the are unreactive and insulators of electricity
4. Which of the following statements is /are incorrect for ideal gas?

(A) The volume of a gas always increases when the temperature is increased
(B) Equal volume of gases under the same conditions of temperature and pressure contain the
same number of molecules
(C) Root mean square velocity is directly proportional to square root of molar mass of the gas
(D) A gas in a closed container has different density in different parts
5. Reaction of RCONH2 with Br2 and KOH gives RNH2 as the main product. The intermediates
involved in the reaction is (are)
(A) RCONHBr (B) RNHBr (C) R−N=C=O (D) RCONBr2
space For Rough Work


6. A new C−C bond formation is possible in

(A) Cannizzaro reaction (B) Aldol condensation
(C) Friedel Craft reaction (D) Reimer−Tieman reaction
O
7.
−
⎯⎯⎯⎯⎯⎯⎯(i) OH
(ii)CH CH Br
→ products
3 2
NH
(iii)NH2 −NH2 ,H+ 
O
Product are
HO
O
N NH2 N
(A) CH3CH2NH−NH2 (B) CH3CH2NH2 (C) (D)
N
O
OH
8. AgCl has a rock salt lattice with edge length of 720 pm, which is the correct option
(A) Second nearest neighbour of Ag+ are 12
(B) Third nearest neighbour of Ag+ are 8
(C) Second nearest neighbour is at distance 509 pm
(D) Third nearest neighbour is at distance 509 pm
SECTION-A: Comprehension Type (One or More Than One Option Correct)

situation or a problem. Two multiple choice questions will be asked based on this paragraph. One or
more than one option can be correct.
Read the paragraph carefully and answer the following questions:
Halogens on reaction with each other forms a number of inter halogen compounds depending upon the
conditions. All possible combinations XY are known containing two different halogen atoms. There are
many other compound in which a less electronegative halogen atom is bond to 3,5 or 7 more
electronegative halogen atoms to form stable molecule.
9. Which of the following colourless gas

(A) ClF3 (B) BrF3
(C) IF3 (D) ClF
10. The shape of [I5]− is not

(A) pentagonal bipyramidal (B) square pyramidal
(C) bent (D) linear



Read the paragraph carefully and answer the following questions:
Molecular formula of three different complex compounds is CrCl3. 6H2O. They all show different
colours i.e. green, blue−green and violet respectively
11. Find out the correct statement(s) for compound in which maximum anion satisfies secondary
valency.
(A) show hydrated isomerism
(B) show geometrical isomerism
(C) water molecule ratio inside and outside the co-ordination sphere is 2:1
(D) violet in colour
12. Find out the correct statement (s) for compound in which anions satisfies only primary valency:
(A) it is green in colour
(B) does not show any isomerism
(C) value of absorbed  is minimum in comparison of other isomers
(D) paramagnetic in nature
SECTION−C: (Single digit integer)

This section contains 8 questions. The answer to each question is a single digit integer ranging from 0
to 9 (both inclusive).
1. 200 ml of tap water containing Mg(HCO3)2 was titrated with 90 ml of M/50 HCl with methyl
orange as indicator. The resulting solution requires further 6 ml of 0.1 M NaOH to make the
solution neutral. Calculate ‘y’, if total hardness as parts of CaCO3 per 106 parts of water is
y102
2. The t1 2 of M220 is 6.93 sec. Then, the number of nucleus of M which is equivalent to 2 millicurie
is 7.4 10x . Find x.
3. How many of following statement/s is/are correct?

a) In dimethyl formamide (DMF), the order of nucleophilicity is Cl− > Br− > I−
b) In gas phase, the approximate order of nucleophilicity is
MeO− > Cl− > Br−
c) In water, the order of nucleophlicity is Cl− > Br− > I−
d) In an experiment, (CH3CH2CH2CH2)4N+X− in acetone where X− is a halide ion, the
nucleophilicity order is
Cl− > Br− > I−
CH3
-
e) H3C O is good nucleophile than OCH3− in water
CH3


4. H3C CH3
H3C CH3 dilute H 2SO4

A
OH OH
How many statements are true about A?
1. A can give test with sodium
2. A shows iodoform test
3. A gives Tollens test
4. A gives slowly 2, 4−DNP test
5. A gives Schiff’s test
6. A gives FeCl3 test
5. Number of compounds having C1−C4 linkage among the following

Sucrose, Maltose, Lactose, Amylopectin, Cellulose:
6. H2C CH3
+
H3C OH ⎯⎯⎯
H

→ Products
CH3
The number of possible organic products will be
7. Molar conductivity of aqueous solution of HA is 200 S cm2 mol−1, pH of this solution is 4. Calculate the
value of pKa(HA) at 25C.
 2 −1  2 −1  2 −1
Given: M (NaA) = 100 S cm mol ; M (HCl) = 425 S cm mol ; M(NaCl) = 125 S cm mol
8. Ag2S + KCN ⎯⎯→[Ag(CN)x ]−n

Excess
[Ag(CN)x ]−n + Zn ⎯⎯→[Zn(CN)y ]−n
Find the sum of x and y.


PART-III : MATHEMATICS
7
 −1 1 −1 
2
sin x
1. Let J = −1 cot x + cot x dx,K = −2 | sin x |dx . Then which of the following alternative(s)
is/are correct?
(A) 2J + 3K = 8 (B) 4J2+K2=262 (C) 2J−K=3 (D) J = 2
K 5
3n −1 3n
r r
2. Tn =  2 ,S =  , then  n {1, 2, 3, …}:
r = 2n r + n r =2n +1 r + n
2 n 2 2
1 1 1 1
(A) Tn  ln2 (B) Sn  ln2 (C) Tn  ln2 (D) Sn  ln2
2 2 2 2
3. If sin(x+20°)=2sinx cos40° where x (0, 90°), then which of the following hold good?
x x
(A) sec = 6 − 2 (B) cot = 2 + 3 (C) tan4x = 3 (D) cosec 4x = 2
2 2
4. The equation sin4x+cos4x+sin2x+k=0 must have real solutions if:

1 3 1 1 3
(A) k=0 (B) k  (C) − k (D) − k
2 2 2 2 2
5. A random variable X follows binomial distribution with mean a and variance b . Then
a a2 a2
(A) a  b  0 (B)  1 (C) is an integer (D) is an integer
b a−b a+b
6. Consider the lines

x − 2 y −1 z + 2
L1 : = =
1 7 −5
L2 : x−4 = y + 3 = −z
Then which of the following is/are correct ?
(A) Point of intersection of L1 and L2 is (1, −6, 3)
(B) Equation of plane containing L1 and L2 is x+2y+3z+2=0
 13 
(C) Acute angle between L1 and L2 is cos−1  
 15 
(D) Equation of plane containing L1 and L2 is x + 2y + 2z + 3 = 0


7. Consider the line L1 : x = y = z and the line L2 : 2x + y + z − 1 = 0 = 3x + y + 2z−2, then:

1
(A) The shortest distance between the two lines is
2
(B) The shortest distance between the two lines is 2
(C) Plane containing the line L2 and parallel to line L1 is z−x+1=0
(D) Perpendicular distance of origin from plane containing line L2 and parallel to line L1 is 1
2
8. If 100
C6 + 4. 100
C7 + 6. 100
C8 + 4. 100
C9 + 100 x
C10 has the value equal to C y ; then the possible
value(s) of x+y can be
(A) 112 (B) 114 (C) 196 (D) 198
SECTION-A : Comprehension Type (One or More Than One Option Correct)

situation or a problem. Two multiple choice questions will be asked based on this paragraph.
One or more than one option can be correct.
Paragraph for Question 9 to 10
f(x) is a continuous function satisfying x4−4x2  f(x)  2x2 −x3  x  [0, 2] such that the area bounded by
y = f(x), y = x4 − 4x2, the y-axis and the line x =t(0  t  2) is n times the area bounded by
y = f(x), y = 2x2−x3, y-axis and the line x= t(0  t  2). Then
9. f(x) attains a point of inflexion at x = (when n = 2)

3 1
(A) 2 (B) (C) 1 (D)
2 2
1
10. The value of  f(x)dx
−1
is
2 2
(A) (23 − 10n) (B) (10n − 17)
15(n + 1) 15(n + 1)
2 2
(C) (23 + 10n) (D) (10n + 17)
15(n + 1) 15(n + 1)


Paragraph for Question 11 to 12
Let X = {1, 2, 3}. A number is selected from set X with replacement and this process is done 1100
times. For each i, 1  i  3, Let f(i) represents the number of times the number ‘i’ is selected. Clearly,
f(1) + f(2)+f(3) = 1100. Also, let S denotes the total sum of 1100 numbers selected. If S 3 = 162f(1) f(2)
f(3).
11. The value of harmonic mean of f(1), f(2) and f(3) is

(A) 100 (B) 200 (C) 300 (D) 400
12. There are f(1) number of red balls, f(2) number of blue balls, f(3) number of white balls and x
number of green balls. (balls of same colour are identical). The balls are arranged in a row
such that no two balls of same colour are consecutive. Let x1 and x2 are minimum and
maximum value of x respectively for which above arrangement is possible then x1 + x2 is
(A) 1200 (B) 900 (C) 1300 (D) 800
SECTION-C : (Single digit integer)

This section contains 8 questions. The answer to each question is a single digit integer ranging from
0 to 9 (both inclusive).
1. Tangents are drawn from the point (−1, 2) on the parabola y2=4x. The length, these tangents
will intercept on the line x = 2 is A B . Find A + B.
2. Circles A and B are externally touches to each other and to line t. The sum of the radii of the
two circles is 12 and the radius of circle A is 3 times that of circle B. The area in between the
b
two circles and its external tangent is a 3 − then find the value of a−b
2


e2x − (1 + 4x)1/2
3. If f(x) = for x  0
ln(1 − x 2 )
and f(x) is continuous at x=0, then the value of f(0) is −P. Find P
4. Let f(x) = ax + b, with a and b real numbers; f1(x) = f(x) and fn+1(x) = f(fn(x)); nN. If
f7(x)=128x+381, then (a+b) is
7fmin + fmax
2 2
5. If f(x) = 7esin x
− ecos x
+ 2, then find the value of
6. The set of positive values of the parameter ‘a’ for each of which the function
f(x)=sin2x−8(a+1)sinx−(4a2+8a−14)x is monotonic increasing in R and has no critical points
(P, )
Q − R . Find P+Q+R.
1
7. Let f(x) satisfy all the conditions of mean value theorem in [0,2], if f(0) = 0 and f (x)  for all
2
x, in [0,2] then |f(x)|  P. Find P.
8. Let a function f is defined as f:{1, 2, 3, 4} → {1, 2, 3, 4}. If f satisfy f(f(x)) = f(x),

 x {1, 2, 3, 4}, then the number of such functions is (35 + P). Find the value of P.


FIITJEE NJEETS JEEA

JEE (ADV) - 2024
NJEETS - 2 Paper Code
Conduction Date: 20/04/2024
PAPER - 2
SET-A
ANSWER KEY
PART – I (PHYSICS) PART – II (CHEMISTRY) PART – III (MATHS)
SECTION-A SECTION-A SECTION-A
1. A, B, C, D 1. C 1. A,B
2. D 2. B,C,D 2. A,B
3. A, B, C, D 3. A,B,D 3. A,B
4. A, B 4. A,C,D 4. A,B,C
5. A, B, C, D 5. A,C 5. A, B,C
6. A 6. B,C,D 6. A,B,C
7. A 7. B,D 7. A,D
8. B, D 8. A,B,C 8. B,D
SECTION-A SECTION-A SECTION-C
9. B 9. A,D 9. C
10. D 10. A,B,D 10. B
11. B 11. A,B,C 11. C
12. D 12. C,D 12. A
SECTION-C SECTION−C SECTION-C
1. 5 1. 3 1. 8
2. 2 2. 8 2. 3
3. 3 3. 3 3. 4
4. 6 4. 2 4. 5
5. 3 5. 4 5. 8
6. 5 6. 2 6. 8
7. 7 7. 4 7. 1
8. 2 8. 6 8. 6


HINTS & SOLUTION

SECTION-A
1. A, B, C, D
 = neAVd = constant.
2. D
1
Maximum kinetic energy, 2
mv max. = eVs
2
According to Einstein’s photoelectric equation hf = eVs +  or eVs = hf − 
As per question, eV1 = hf1 −  ………(i)
and eV2 = hf2 −  ………(ii)
Subtracting them, we have, e ( V1 − V2 ) = h ( f1 − f2 )
or eV2 = hf2 − hf1 + eV1
h
or V2 = ( f2 − f1 ) + V1.
e
3. A, B, C, D
C  V0
f= .f0
C  Vs
C→ Sound velocity
V0→Observer velocity
VS→Source velocity.
4. A, B
5. A, B, C, D
Graph between spectral emissive power and to wavelength
T2
T1
m2 m1
6. A
Energy conservation between P and R V0
KQq 1 kQq 1
+ mv 02 = + mV 2 R p,q,m
4L 2 L 2 Q 4L
force equation at R
kQ.q mv 2 kQ
T− 2 = and =V
L L 4L
Minimum value of V = 0
6q.V
 V0 =
m


7. A
1 sin  =  2 sin90
1
sin  =
2 

= 
6
y = x2
dy 1
= 2x = tan  =
dx 3
1
x=
2 3
1
y= .
12
8. B, D
SECTION-A
9. B
Apply conservation of Angular momentum about COM, to calculate final speed of the
astronauts. Work =  K.E. = 3 Mv2
10. D
11. B
12. D
When switch is open
6
= 1 10−3 …….(i)
R1 + R2 + R3
When switch is closed in position ‘a’
6
= 1.2  10−3 ……(ii)
R2
R1 + + R3
2
When switch is closed in position ‘b’
6
= 2  10−3 …….(iii)
R1 + R2
Solving these equations we get
R1 = 1000, R2 = 2000 and R3 = 3000 .
SECTION-C
1. 5
Use Kirchoff’s law to find current in external resistance & maximize power.
2. 2 dq
q dq dt q –q
− +E− R = 0
C dt A B
Q0 /2 t a
dq dt
  = − 
R
− Q0 /2
q − CE 0 RC
3. 3

(1 – 1)A1 = (2 – 1)A2
4. 6
1
Area under graph =  v dx = t
5. 3
Use conservation of Mechanical Energy.
6. 5
The rod is in equilibrium. The net force and the net torque (about any point) should be zero.
7. 7
Use energy & momentum conservation.
8. 2
 = 40 cos2 (  / 2)
So, 0 = 40 cos2 (  / 2 )
1
cos (  / 2 ) =
2

(  / 2) =
3
2  2  1  1 d
= = x =
3    3    D
y .
CHEMISTRY
HINTS & SOLUTION
SECTION-A
1. C
(A) size difference between M2+ & O2− decreases (M=Be, Mg, Ca, Sr, Ba); Lattice energy
decrease less rapidly then hydration energy hence solubility decreases.
(In (B) , (C) and (D) r− >> r+. Hence solubility decreases down the group.
2. B,C,D
H O
(A) PO43− + AgNO3 ⎯⎯⎯
2 → Ag3PO4 
Light yellow precipitate
(B) ⎯⎯⎯
Cold
→ No precipitate
HCO3− + HgCl2
⎯⎯⎯⎯
Boiled
→ 3HgO.HgCO3 
reddish brown precipitate
(C) On boiling pH decrease drastically. Due to

 H+ + CO32−
HCO3− ⎯⎯ →
Hg2 +
3HgO.HgCO3 +H+


H O
(D) Na2CO3 + BaCl2 ⎯⎯⎯
2
→ BaCO3 
white precipitate
No change
Excess of NaOH
3. A,B,D
SiO44− are called orthosilicates
4. A,C,D
PV = nRT (Ideal gas),
3RT
Vrms=
M
5. A,C
O
OH− OH− ||
→ RCONHBr ⎯⎯⎯
RCONH2 ⎯⎯⎯→RCONH ⎯⎯⎯ → R − C− N − Br ⎯⎯→ Br2
R − N = C = O ⎯⎯⎯→ RNH2
2 H O
6. B,C,D
7. B,D
O OH
O
−
⎯⎯⎯⎯⎯
OH
→ NH −NH ,H+ N
NH CH CH Br
3 2
N ⎯⎯⎯⎯⎯⎯
2 2
→ + CH3CH2NH2
CH3 N
O
O OH
8. A,B,C
720 pm
720
xz = = 509 Cl
2 x
y
720 3
yz = = 623.5
2 z Ag
SECTION-A
9. A,D
IF3 is solid , BrF3 is liquid
10. A,B,D
I
I I
I I
11. A,B,C
[Cr(H2O)4Cl2]Cl.2H2O Green in colour
12. C,D
1. [Cr(H2O)4Cl2]Cl .2H2O, green in colour
2. [Cr(H2O)6]Cl3, Violate in colour
3. [Cr(H2O)5Cl]Cl2. H2O, blue − green in colour
SECTION−C
1. 3


1
(Meq)Mg(HCO = (Meq)CaCO =  90 − 0.1 6 = 1.2
3 )2 3 50
0.06
Hardness =  106 = 300 ppm
200
2. 8
dN
= K No, 1millicurie = 3.7  107 dps
dt
0.693
K=
t1/2
3. 3 (a, b, d are correct).
In polar protic and nonpolar solvent, nucleophilicity order is I−>Br−>Cl−
In polar aprotic solvent, nucleophilicity order is Cl− > Br− > I−
In gas phase, strong base is a good nucleophile. If nucleophile is sterically hindered,
nucleophilicity decreases
4. 2
H3C CH3
A is CH3
O CH 3
It can give Iodoform test & 2−4−DNP test.
5. 4
Sucrose have C1−C2 linkage while other has C1−C4 linkage
6. 2
CH3
H2 C CH3 CH3
+
H3C OH ⎯⎯⎯
H

→ H3C C CH CH3 + H2C C CH 2 CH3
CH3
7. 4
   
M (HA) = M (HCl); +M (NaA) − M (NaCl)
= 425+100−125= 400 S cm2 mol−1
pH = 4, [H+] = 10−4 = aC
 200
= m = = 0.5;
  400
m
(C ) 10 −4 (0.5)
Ka = = = 10 −4 ;pK a = 4
(1 −  ) (1 −  )
8. 6
Ag2S+4 KCN 2K[Ag(CN)2] + K2S
2K[Ag(CN)2] + Zn ⎯→ K2[Zn(CN)4] + 2Ag


HINTS & SOLUTIONS

MATHEMATICS
SECTION-A
1. A,B
 
2 2
1
J =   cot −1 + cot −1 x dx +  (tan−1 x + cot −1x)
−1  
x 0
 
0 2
J =  (  + )dx +  dx
−1
2 0
2
5
J= 2J=5
2
0 2 4 6 7
K=
−2 
 0+ 0+
0
0+
2 4
0+  dx
6
K=
2. A,B
3. A,B
sin(x+20°)=sin(x +40°)+sin(x-40°)
sin(x+20)−sin(x−40)=sin(x+40°)
2cos(x−10)sin30=sin(x+40)
cos(x−10) = cos(50−x)  x=30°
4. A,B,C
sin4x+cos4x+sin2x+k=0
1
1 − sin2 2x + sin 2x + k = 0
2
(1−t)2 = 3+2k t=sin2x
0  (1 − t)2  4
0  3 + 2k  4
3 1
 − k
2 2
5. A,B,C
Sol. Suppose
Here, and
, then
Now,
⇒
[alternate (a)]
and
Also,
6. A,B,C
7. A,D
8. B,D
100
C6 + 4. 100C7 + 6. 100C8 + 4. 100C9 + 100
C10
= 101
C7 + 3. C8 + 3.
101 101
C9 + 101
C10
= 101
C7 + 101
C8 + 2( C8 +
101 101
C9 ) +101 C9 +101 C10


= 102 C8 +102 C9 +102 C9 +102 C10

= 103 C9 +103 C10 =104 C10 = 104
C94
SECTION-A
9. C
10. B
t t
4 2 2 3
( )
 f(x) − (x − 4x )dx = n  2x − x − f(x) dx on differentiation
0 0
f(t)−(t4−4t2) = n{(2t2−t3)−f(t)}
n t 4 − 4t 2
 f(t) = {2t 2 − t 3 } +  t  [0,2]
n +1 n +1
1 1
1
−1 f(x)dx =
n + 1−1
(x 4 − nx 3 + 2(n − 2)x 2 )dx .
11. C
f(1) + f(2) + f(3) = 1100
S = f(1) + 2f(2) + 3f(3)
By, AM, GM
S
 (f(1)2f(2)3f(3))1/3
3
 S3  27.6f(1)f(2)f(3)
 S3  162 f(1) f(2) f(3)
But given, S3 = 162 f(1) f(2) f(3)
 equality holds when, f(1) = 2f(2) = 3f(3)
 f(1) = 600, f(2) = 300, f(3) = 200
3
HM = = 300
1 1 1
+ +
f(1) f(2) f(3)
12. A
x1 = 99 and x2 = 1101
x1 + x2 = 1200
SECTION-C
1. 8
SS1 = T2 (−1,2) P
 (y2−4x) (y12 − 4x1) = [yy1 − 2(x + x1)]2
(x1, y1)  (−1, 2)
And solving with x = 2
 y2+2y−17=0 x=2
(y1 − y 2 ) = (y1 + y 2 ) − 4y1y 2 = 72 = 6 2

2
A=6, B=2,  A+B = 8 Q
2. 3
r+R=12
R =3r  R = 9, r = 3, AOT=60°, OPD = 30° 
O
60° T
BPT=120° 30°
1 D P
Area of trapezium OPBA = (3 + 9) 122 − 62 = 36 3
2
A B
1 81
Area of sector OAT = (9)2 =
6 6


1 9
Area of sector BPT =  (3)2 =
32 3
 81 9   33
 Required area 36 3 −  +  = 36 3 −
 3 3  2
3. 4
e2x − 1 + 4x e2x + 1 + 4x e4x − (1 + 4x)
lim  = lim
x →0 ln(1 − x 2 ) e2x + 1 + 4x x →0 ln(1 − x 2 ).(e2x + 1 + 4x )
 4x (4x)2 (4x)3  2  16 43 
 1 + + + .....  − (1 + 4x) x  + x + ....
= lim   =  
1! 2! 3! 2 3!
x →0 ln(1 − x )
2
− x 2
(1 + 1)
( − x 2 ).(e2x + 1 + 4x )
(−x2 )
16
=− = −4  P=4
22
4. 5
f2(x) = f(f(x)) = a (ax+b) + b = a2x+ab+b
f3(x) = a(a2x+ab+b) = a3x+a2b+ab+b
……
f7(x) = a7x + (a6+a5+a4+….+a+1)b = 128x+381
a7 = 128  a = 2
b(26+25+….+2+1) = 381
b=3  a+b=5
5. 8
f (x) = (7esin x + ecos x )sin2x
2 2
f(x) = 0  x = 0, n
Imax = 7e+1, fmin=9−e
6. 8
f(x)>0 x  R
2 cos 2x−8(a+1)cosx−(4a2+8a−14)>0
(cosx−) (cosx-)>0
where  = (a + 1) + 2a2 + 4a − 2
and  = (a + 1) − 2a2 + 4a − 2
 cosx− < 0, since cos x−<0 , a>0  (a+1) − 2a2 + 4a − 2 > cosx, x  R
 (a+1) − 2a2 + 4a − 2 > 1  a2+4a−2 < 0
 a(−2 − 6, 6 − 2)  a  (0, 6 − 2) since a > 0
 P+Q+R=8
7. 1
f(2) − f(0) f(2) − 0
= f (x)  = f (x)
2−0 2
f(2) 1
 −1  f(2)  1  |f(2)|  1 P=1
2 2
8. 6
f(f(x) = f(x)  f(y) = y if f(x) = y
Case-1 range contains exactly one element  4C1 ways = 4

(remaining 3 elements can be mapped in one way)

Case-2  range contains exactly two element  4C2 = 6 ways
(remaining 2 elements can be mapped in 22 ways)
 6×4 = 24
Case 3  range contains exactly three element  4C3 = 4 way
(remaining elements can be mapped in 3 ways
 4 ×3 = 12
Case 4  range contains all elements  4C4 = 1 ways
Total = 4 + 24 + 12 + 1 = 41 ways.


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FIITJEE NJEETS JEE ADVANCED

PHYSICS, CHEMISTRY & MATHEMATICS

B. Filling of OMR Sheet

Name of the Candidate :__________________________________________

Batch :___________________ Date of Examination :___________________

Enrolment Number :______________________________________________

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Acceleration due to gravity g = 10 m / s2

Planck constant h = 6.6 × 10–34 J-s

Charge of electron e = 1.6 × 10–19C

Mass of electron me = 9.1 × 10–31 kg

Permittivity of free space 0 = 8.85 × 10–12 C2/N-m2

Density of water water = 103 kg/m3

Atmospheric pressure Pa = 105 N/m2

Gas constant R = 8.314 J K–1 mol–1

Gas Constant R = 8.314 J K−1 mol−1

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6qV qV 3qV 3qV

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7. In the diagram shown the medium boundary is given by the equation

SECTION-A : Comprehension Type (One or More Than One Option Correct)

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Paragraph for Questions 11 and 12

12. The value of resistance R3 is

SECTION-C: (Single digit integer)

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figure, where v is the speed of the particle. The particle is moving B

5. A 6000 Kg freight car rolls along rails with negligible

6. One end of a uniform 4.00 m long rod of weight Fg is supported by a

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2. Which of the following is incorrect?

3. Which among the following are true about silicones?

4. Which of the following statements is /are incorrect for ideal gas?

space For Rough Work

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6. A new C−C bond formation is possible in

SECTION-A: Comprehension Type (One or More Than One Option Correct)

9. Which of the following colourless gas

10. The shape of [I5]− is not

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Paragraph for Question Nos. 11 to 12

SECTION−C: (Single digit integer)

3. How many of following statement/s is/are correct?

space For Rough Work

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H3C CH3 dilute H 2SO4

5. Number of compounds having C1−C4 linkage among the following

The number of possible organic products will be

8. Ag2S + KCN ⎯⎯→[Ag(CN)x ]−n

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4. The equation sin4x+cos4x+sin2x+k=0 must have real solutions if:

Batch :_ Date of Examination :_