Jotun Coatings Zinc Primers

Zinc Primers
Jotun

TKr/Zinc Primers Jotun/Oct. 2007/Jotun/Coatings/Marketing

Jotun Coatings Zinc Primers

Agenda

Corrosion
Corrosion protection with Zinc
Technology
Zinc epoxy versus Zinc silicate
Zinc confusions
Zinc content in Jotun zinc primers
Barrier and Resist projects

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Jotun Coatings Zinc Primers

Corrosion
Corrosion is a reaction between

Material
and
Surrounding environment

.under formation of corrosion products

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Jotun Coatings Zinc Primers

Production and degradation of steel

Reaction between the material and
the surrounding environment takes place
Plates, pipes,
profiles, etc.

Raw material
Iron ore Rust

The presence of Water / Humidity and Oxygen

is a prerequisite for corrosion of steel

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Jotun Coatings Zinc Primers

Manufacturing / refining
- brings the material to a higher energy level

The resistance against oxidation (corrosion) varies for

different materials
When brought in contact with an electrolyte (aqueous
solution that conducts electricity) some metals easily dissolve
into ions. These are called Base metals
Noble metals have a very strong resistance against
corrosion and do not react to form ions unless exposed to
very aggressive chemicals

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Jotun Coatings Zinc Primers

Corrosion / degradation
- brings the material "back" to the stable situation
Corrosiveness in an environment increases or varies with:
Temperature
Salinity
Oxygen content
Water velocity
Acidity
Type of electrolyte
Content of contaminants / pollution that promotes
corrosion
Micro-organisms

Oxidation of metals is a natural process

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Jotun Coatings Zinc Primers

Still the best ..

Zinc containing primers are still

the best foundation for a long
lasting advanced paint system
Cathodic protection
Self repairing
Reducing risk of
undercutting corrosion

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Jotun Coatings Zinc Primers

The ability of providing cathodic protection

Damage in coating to steel surface

Moisture allows Zinc to ionize and
cathodically protecting the steel

Superior adhesion prevents coating undercut

Topcoat
Mid coat
2+ Zinc primer
Zn
Steel

The zinc primer reacts to protect the

steel substrate when the topcoat is damaged

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Jotun Coatings Zinc Primers

Technologies
Shopprimers
Preliminary corrosion protection
Welding and burning properties
Compatible with advanced paint systems
Zinc epoxy primers
Epoxy binder
Primer on UHPWJ and blast cleaned steel
Corrosion protection
Primer in advanced paint systems
Zinc silicate primers
Silicate binder
Primer on blast cleaned steel
Corrosion protection
Primer in advanced paint systems
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Jotun Coatings Zinc Primers

Technologies zinc shopprimers

Binders
Ethyl silicate
Alkali silicate (water borne)
Zinc content
Low
Medium
Preliminary corrosion protection
6 14 months
Welding and burning properties
products tailored to productivity
Compatible with advanced paint systems

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Jotun Coatings Zinc Primers

Zinc shopprimers

Muki Z 2001 Muki Z 3000 Muki Z WB-14 FW

Generic type Low zinc silicate Medium zinc silicate Medium zinc silicate

Volume solids 28 % 28 % 62 %

Protection time 6-8 months 8-10 months 12-14 months

Recommended DFT 15-20 microns 15-20 microns 15-25 microns

Colours Green, red, grey Green, red, grey Grey

Weldability Excellent Good Optimum

Cutability Excellent Good Optimum

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Jotun Coatings Zinc Primers

Technologies - zinc primers

The classification of zinc-rich primers refers to the binder
Two different binders
Silicate inorganic (solvent borne and water borne)
Epoxy organic (solvent borne and water borne)
In general the inorganic binders have better electrical
conductivity than the organic binders and will give a
metallic conductivity all through the coating
Industry guidelines for minimum zinc requirements is given
by organisations and specifications

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Jotun Coatings Zinc Primers

Zinc silicates and zinc epoxies

(Resist 86 and Barrier)

Observations after maintenance work done

under severe and difficult conditions in the
Ekofisk field, North Sea Environments

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Jotun Coatings Zinc Primers

Barrier + vinyl system Resist 86 + vinyl system

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Jotun Coatings Zinc Primers

9 years after last maintenance

Barrier + vinyl system

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Jotun Coatings Zinc Primers

9 years after last maintenance

Resist 86 + vinyl system

TKr/Zinc Primers Jotun/Oct. 2007/Jotun/Coatings/Marketing

Jotun Coatings Zinc Primers

9 years after last maintenance

Barrier + vinyl system

TKr/Zinc Primers Jotun/Oct. 2007/Jotun/Coatings/Marketing

Jotun Coatings Zinc Primers

9 years after last maintenance

Resist 86 + vinyl system

TKr/Zinc Primers Jotun/Oct. 2007/Jotun/Coatings/Marketing

Jotun Coatings Zinc Primers

9 years after last maintenance

Barrier + vinyl system

TKr/Zinc Primers Jotun/Oct. 2007/Jotun/Coatings/Marketing

Jotun Coatings Zinc Primers

9 years after last maintenance

Resist 86 + vinyl system

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Jotun Coatings Zinc Primers

Chemistry - zinc primers

Inorganic : Network of zinc, oxygen and silicon atoms

chemically bonded to each other and to the
steel substrate

Organic : Metallic zinc particles "floating" in a cured

epoxy binder network. The high content of zinc
ensures metallic contact between the zinc and
the steel substrate, and between the individual
zinc particles.

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Jotun Coatings Zinc Primers

Properties - zinc epoxy

Advantages Considerations
Chemically curing
Good corrosion protection Temperature dependent
Good adhesion 2-component (water borne 3-comp)
Pre-treatment: UHPWJ to WJ2 Film thickness: 25 - 90 m
or Sa 2 Not acid- and alkaline resistant
Good mechanical strength (Resistant between pH 6-10)
May be recoated with all types
of paint, except alkyd
Dry heat resistant up to 120C
Short over-coating time

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Jotun Coatings Zinc Primers

Where to use - zinc epoxy primers

Ships
Segments Offshore
Industry

New constructions / Maintenance

Objects Exterior and interior, above and
below water (as holding primer for
underwater use 20-30 microns)

Blast cleaning to UHPWJ WJ2 or

Surface preparation Sa 2

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Jotun Coatings Zinc Primers

Properties - zinc silicate primers

Advantages Considerations
Very good corrosion protection Requires humidity for curing
Very good solvent resistance 2-pack
Very high heath resistance Max. DFT: 100 m
(max 400oC) (alkalisilicate 200 m )
Very high mechanical strength At higher DFT tendency of mud-
Very good adhesion to blast cracking or checking
cleaned steel Curing to be checked before over-
Relatively good recoatability coating (ASTM 4752)
May be recoated with all types of Use a tie coat or mist-coat/full-
paint, except Alkyd coat technique for the first
subsequent coat
Shelf life : 6 months at 23C
(alkali silicate 18 24 months)

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Jotun Coatings Zinc Primers

Where to use - zinc silicate primers

Segments Ships
Offshore
Industry

Objects New constructions / (maintenance)

Exterior above the waterline
Tank coating and water ballast tank

Surface preparation Blast cleaning to minimum Sa 2

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Jotun Coatings Zinc Primers

Jotun zinc primers

Products Vol.solids Generic Type
Barrier 53 % Epoxy
Barrier ZEP 54 % Epoxy
Barrier 77 53 % Epoxy
Barrier 90 53 % Epoxy
WaterFine Barrier 56 % Epoxy - water borne
Resist 78 72 % Ethyl-silicate, inorganic
Resist 86 67 % Ethyl-silicate, inorganic
Resist GTI 67 % Ethyl-silicate, inorganic
Resist 5 WF 75 % Alkali-silicate, inorganic, water borne

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Jotun Coatings Zinc Primers

Zinc - confusions.
Total zinc is the sum of all the zinc compounds in the
formulation including: Zinc dust, zinc oxide, zinc phosphate etc.

Zinc dust 100% - The raw material consists of

Zinc 98.5 % Other components like lead

and other impurities: 1.5%

Metallic zinc 94% Zinc oxide 4.5%

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Jotun Coatings Zinc Primers

SSPC - Paint 20
Zinc rich Inorganic and Organic
Zinc dust content
Level 1
Zinc dust 85% weight in dry film
Level 2
Zinc dust 77%, < 85% weight in dry film
Level 3
Zinc dust 65%, < 77% weight in dry film
Zinc dust quality according to ASTM D 520

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Jotun Coatings Zinc Primers

ISO 12944 (and Norsok)

Zinc dust content

Zinc dust 80% weight in dry film
Zinc dust quality according to ISO 3549

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Jotun Coatings Zinc Primers

ASTM D 520 - levels for lead content

Defines type of zinc dust for pigmentation of coatings

Type I
No max. level of lead content
Type II
High purity grade, max. 0,01% lead content by
weight
Type III
Highest purity grade, max. 0,002% lead content
by weight

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Jotun Coatings Zinc Primers

Zinc in our epoxy primers

Zinc dust Zinc Metallic zinc Zinc oxide
Barrier * 80,0 78,8 75,2 3,6
Barrier 77 77,0 75,8 72,4 3,5
Barrier 90 90,0 88,7 84,6 4,1
Barrier Zep 50,0 49,3 47,0 2,3
WaterFine Barrier 80,0 78,8 75,2 3,6
* In addition to the zinc dust, 6% zinc oxide is added,
giving Barrier a total zinc content of 86%

Standard specification for zinc in Jotun

products is 0.1% lead content
Barrier, Barrier 77, Barrier 90 can be supplied
with ASTM D520 Type II zinc dust

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Jotun Coatings Zinc Primers

Zinc in our silicate primers

Zinc dust Zinc Metallic zinc Zinc oxide

Resist 78 78,0 76,8 73,3 3,5
Resist 86 86,0 84,7 80,8 3,9
Resist 5 WF 90,0 88,7 84,6 4,1
Resist GTI 86,0 84,7 80,8 3,9

Standard specification for zinc in Jotun

products is 0.1% lead content
All Resist products can be supplied with
ASTM D520 Type II zinc dust

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Jotun Coatings Zinc Primers

Barrier in projects

Tianjin port, China 12 units of RMG

Ivana B platform, one of several

installations with Barrier on the
Ivana field in The Adriatic Sea
Kola Bridge, Russia

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Jotun Coatings Zinc Primers

3x660 MW power complex

Resist in projects BARH STPP in India

Guangzhou New
International airport,
China

Essar Oil Refinery at Vadinar in

Gujarat, India

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Jotun Coatings Zinc Primers

Jotun
Zinc Primers
Protects Properties

TKr/Zinc Primers Jotun/Oct. 2007/Jotun/Coatings/Marketing