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Gen CHEM 1 Lecture 1
Gen CHEM 1 Lecture 1
1
(The Electronic Structure of Atoms)
Fire
Earth Air
Water
Atomic Models (Cont.)
J. J. Thomson (1900)
He discovered electron and proposed a model of the
atom called “Plum Pudding Model.”
Rutherford’s Model:
“A nucleus exists in
the center of the
atom.”
“The nucleus contains
protons and neutrons
which together
account for the mass.”
“Electrons, which occupy most of the total volume
of the atom, are outside the nucleus and move
rapidly around it.”
Atomic Models (Cont.)
“Electrons move in
definite orbits around
the nucleus.”
“These orbits, or
energy levels are
located at certain
distances from the
nucleus.”
“Electrons normally
exist in the lower
energy state (ground
state).”
“When an electron
jumps into higher
energy state it is
said to be in an
exited state.”
Atomic Models (Cont.)
“Electron cloud is a
space in which electron
are likely to be found.”
“Electrons whirl about
the nucleus billion of
times in 1 second.”
“They are not moving
around in random
pattern.”
Quantum Mechanics
THE WAVE NATURE OF LIGHT
Electromagnetic Radiation
Light travels through space in a wave motion.
Quantum Mechanics (Cont.)
Definitions
Sample Problem:
What is the frequency of red light with a wavelength of
700nm and violet light with a wavelength of 400nm?
Quantum Mechanics (Cont.)
Heinrich Hertz
Generated electromagnetic waves with long wavelengths
larger than those of visible light and who demonstrated that
long wavelength radiation exhibits the same phenomena as
light does.
Electromagnetic
Radiation
(Spectra).
Quantum Mechanics (Cont.)
Sample Problem:
Consider a violet light with a wavelength of 400nm.
(a) Calculate the energy, in joules, of one photon
of this light.
(b) Calculate the energy in kilojoules of one mole
of such photons.
Quantum Mechanics (Cont.)
ATOMIC SPECTRA
Isaac Newton
Showed that visible (white light) from the sun can be
broken down into its various component by a prism.
Definitions
Continuous Spectrum – spreading out Absorption Spectrum – when
into a wide range band of the white light. continuous radiation (white light)
passes through a substance, certain
Emission Spectrum – When an element wavelengths of radiation may be
absorbs sufficient energy (from a flame or absorbed. These wavelengths are
electric arc), it emits radiant energy in the characteristics of a substance that
form of light. When this radiation is passed absorbs the radiation and pattern of
through a prism, it separates into a these lines are referred to as an
component wave length. absorption spectrum.
Quantum Mechanics (Cont.)
Bohr’s Theory:
1. The electron of the hydrogen atom can exist only in certain
circular orbits (energy levels or shell).
2. The electron has a definite energy characteristic of the orbit
in which it is moving.
3. When an electron of an atom is as close to the nucleus, it is
in the condition of the lowest energy called the ground state.
When an atoms are heated in an electric arc or Bunsen
burner, electron absorbs energy and jump to outer levels,
which are higher energy states (excited state).
4. When an electron falls back to a lower level, it emits a
definite amount of energy. The energy difference between
the high-energy state and low-energy state is emitted in the
form of a quantum of light.
Quantum Mechanics (Cont.)
E = -RH / n2
Where: E – energy of the electron
RH – Rydberg Constant (2.180 x 10-18 J)
n – energy level
ΔE = hν = Ehi – Elo
hv = -RH[(1/nhi2) – (1/nlo2)]
v = [RH/h] [(1/nlo2) – (1/nhi2)]
Sample Problem:
What are the frequency and wavelength of the line
in the hydrogen spectrum that corresponds to an
electron transition from n=3 level to n=2 level?
Quantum Mechanics (Cont.)
The Relationship
between Electron
Transitions of a
Hydrogen Atom
and the Spectral
Lines.
Quantum Mechanics (Cont.)
n l Spectral Lines
1 0 s type (sharp)
2 0 s
1 p type (principal)
3 0 s
1 p
2 d type (diffuse)
4 0 s
1 p
2 d
3 f type (fundamental)
Quantum Mechanics (Cont.)
Quantum Mechanics (Cont.)
Concepts:
Hund’s Rule
When filling a set of degenerate energy levels, the
electron enter the orbitals singly, with spins in the same
direction (same as s number), until the set is half filled,
before they pair up with opposite spins.
Pauli’s Exclusion Principle
Each electron within a given atom must have a
unique set of the four quantum numbers.
Quantum Mechanics (Cont.)
Aufbau’s Principle
Electrons will
successively occupy
the available orbitals
on order of
increasing energy.
Quantum Mechanics (Cont.)
Example:
Write the
possible set of
quantum
numbers for the
electrons in:
(a) 3s
(b) 3d
(c) 4f
Quantum Mechanics (Cont.)
s and p Orbitals
d Orbitals
Electronic Configuration
Electronic Configuration
Refers to the arrangement of electrons in energy
levels.
Methods of Writing
1. Orbital method
2. Shell method
3. Arrow Rectangular method
4. Core Method
Electronic Configuration (Cont.)
Related Concepts:
Magnetism
TREND:
TREND:
LEFT RIGHT decreases*
* this happens when comparing both
metals and non-metals but by TOP BOTTOM increases
comparing the metals and non-metals, nonmetals
have larger ionic radius than metals.
Periodic Relations of Elements (Cont.)