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Solar cell
Efficiency Issues of Solar cell
Photovoltaic (PV) Scheme
• Highly purified silicon (Si) from sand, quartz, etc. is “doped” with intentional
impurities at controlled concentrations to produce a p-n junction
– p-n junctions are common and useful: diodes, CCDs, photodiodes, transistors
• A photon incident on the p-n junction liberates an electron
– photon disappears, any excess energy goes into kinetic energy of electron (heat)
– electron wanders around drunkenly, and might stumble into “depletion region”
where electric field exists (electrons, being negative, move against field arrows)
– electric field sweeps electron across the junction, constituting a current
– more photons more electrons more current more power
photon of light
Si doped with
electric field n-type silicon
phosphorous, e.g.
Si doped with
boron, e.g.
p-type silicon liberated electron
2
Provide a circuit for the electron flow
• Without a path for the electrons to flow out, charge
would build up and end up canceling electric field
– must provide a way out
– direct through external load
current flow
external load
3
Generic photovoltaic cell
• Simplest equivalent circuit for a photovoltaic cell
– Consists of diode parallel with ideal current source. Ideal current source
delivers current in proportion to solar flux to which it is exposed.
• To give Vd V IR S
q(V IR S )
I I SC I 0 exp 1
kT
• Adding series resistance to the PV equivalent circuit causes
the voltage at any given current to shift to the left by ΔV=IRS.
• Finally, PV equivalent circuit including both series
and parallel resistance.
oPV Cells
oModules
oArrays
Layers of a Solar Module
• At any given current, I-V curve for the module with one shaded
cell drops by ΔV. The huge impact can be seen by figure below.
Factors affecting Efficiency of
Solar Cell
• Transparency Loss
Major Loss Mechanism
• Excess Excitation Loss
• Reflection loss on Surface: A portion of the incident light that is
reflected from the surface of the solar cell is called reflection
losses. Losses as low as 3% for silicon cells have been reported.
• Incomplete Collection of EHPs
• Recombination Before Drift : An important loss is the
recombination of photo excited electron hole pair before drifting
by the depletion layer to create photocurrent. This is happened
due to short diffusion length compared to the thickness of the cell
structure or due to short life time of the carrier. This loss can be
kept to a minimum by using semiconductor with appropriate
properties especially long lifetime for the photogenerated carrier.
This can also be done by eliminating all unnecessary defects.
• Series and Shunt Resistance
Thank You