Gas can be liquefied at room temperature by the application of moderate pressure
Butane – Safer to handle with storage pressure upto 3 atm
Boiling point (-40ºC)
Maximum vapour pressure = 16.9 bar
Volume of the cylinder – 28.2 litres for 12 kg
39.95 litres for 17 kg
In case of leakage, it can form an explosive mixture with air
These gas mixed with any adoring agent to detect the leakage
Mercaptans or sulphides CHARACTERISTICS OF LPG
LPG is stored as a liquid under pressure, is colourless and its
weight as a liquid is approximately half that of an equivalent volume of water. In changing from a liquid state to gas LPG expands approximately 260-times its original volume at normal atmospheric conditions. A mixture of LPG vapour in air of between 2% and 10% by volume is flammable. LPG vapour is approximately 1.5 times denser than air LPG vapour in common with most light hydrocarbon vapours, is slightly anaesthetic and also cause suffocation if present in sufficiently high concentrations. CHARACTERISTICS OF LPG LPG is odorised (by adding ethyl mercaptan) at source to be detectable by smell at a concentration in air of about 20% of lower flammability limit, i.e. a vapour/air mixture of 0.5% by volume.
Owing to its rapid vaporization and consequent lowering of
temperature, LPG, particularly liquid, can cause severe frost burns if brought into contact with the skin. PROPERTIES OF LPG Formula = C3H8 + C4H10 Molecular Weight = 44.09 Stoichiometric AFR = 15.7 Octane number = 97 to 112 Auto-ignition Temp = 457°C Flammability Limits = 2.1 to 9.5 Lower Calorific Value = 23000 kJ/L Density = 0.5 kg/L Burns with Visible flame Fuel properties Propane is a hydrocarbon fuel, chemical description C3H8. Its boiling point is - (-42°C) Its octane rating is - 104 Latent heat of vaporization = (426 kJ/kg) (25300 kJ/L) Autoignition temperature - (457°C) Stoichiometric by weight = 15.5:1 Molecular weight = 44.09 Carbon % by weight = 89% Hydrogen % by weight = 18% Flammability limits = 2.1 – 9.6% Expansion rate = 270:1 (expands in volume 270 times from liquid to ambient pressure vapor) Advantages of LPG Environment friendly - clean air Less dependence on fossil fuel Economic benefits Provides more energy on weight basis Higher octane rating Simpler molecular structure Low carbon to hydrogen ratio No crankcase dilution Does not wash oil from cylinder walls( Engine life is increased by 50%) – Low strain on lubricants Lead free Disadvantages of LPG Special feed system is required Vehicle weight is increased TYPES OF LPG VEHICLES Operating mode in IC engines SI engines – 100% replacement CI engines – Dual fuel mode ( 60% diesel + 40% LPG) LPG Feed system LPG conversion Kit Gas regulator Filter Vapouriser/ regulator converter Gas carburettor or mixer Electronic switch LPG conversion Kit TECHNICAL ISSUES FOR LPG Reduced volumetric efficiency & less partial pressures in the intake manifold results in power loss To store same amount of energy as gasoline, it requires double space than an equivalent gasoline tank Engine Valve seat wear due to lack of lubricity LPG Kit requires a vaporizer due to Phase change (Liquid to Gaseous) Use of domestic LPG as an auto fuel is a widespread problem. Requires vapour withdrawal technology for kits. Variable Fuel Composition affects performance and emissions Heavier than air so does not disperse quickly MATERIAL COMPATIBILITY OF LPG
Stainless Steel is compatible with LPG and is the
primary choice Elastomers are compatible with LPG as they retain their form and are used for tubing Brass and Copper can also be used for storage tanks and piping Aluminum is compatible with LPG but is a secondary choice