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NAMING IUPAC - Conchem
NAMING IUPAC - Conchem
2. CH3—CH—CH2—CH3
|
CH3
Drawing Alkanes
1. Draw the hydrocarbon chain: Looking at the
prefix, determine how many carbons in the
parent chain. Leave room to add in hydrogens.
2. Add Alkyl Groups: Using the numbers in the
name, determine the locations of any alkyl
groups.
3. Correct Alkyl Groups: Using the prefixes, make
sure the alkyl groups are correct using the alkyl
name. ex. Methyl is CH3 , Ethyl is CH2—CH3
Examples
Draw the condensed structural formula for each
of the following:
1. 2,4-dimethylpentane
2. 4-ethyl-3-methylheptane
3. methylpropane
Cycloalkanes
• Cycloalkanes are alkanes in which the carbon
atoms are arranged in a ring, or cyclic structure.
• Structural Formula for Cyclopentane.
2. CH3—CH2—CH2—CH=CH—CH3
Alkynes
• Alkynes: hydrocarbons that contain triple
covalent bonds
• Formula for finding molecular formula for
noncyclic alkanes with one triple bond: CnH2n-2
Systematic Naming of Alkynes
• Rules are similar to those for naming an alkene.
• If there is more than one triple bond, the suffix is
changed to indicate the number of triple bonds.
Ex: 2 = -adiyne 3 = atriyne
Alkyne Nomenclature
1. Name the parent hydrocarbon: find the
longest continuous chain of carbons that
contains the triple bond(s).
“Prefix for number of carbons” + “-yne”
If more than one triple bond, modify the suffix.
2. Add the names of the alkyl groups: add
them in alphabetical order and if there is
more than one of the same group present,
attach the appropriate numerical prefix to
the name.
3. Number the carbon atoms in the parent hydrocarbon:
Number them carbon atoms in the chain so that the
first carbon atom in the triple bond nearest the end of
the chain has the lowest number. If numbering from
both ends gives the same numbers, then number from
the end nearest the first alkyl group.
4. Insert Position Numbers: place triple-bond position
numbers before the name of the parent hydrocarbon
and the alkyl group position numbers before the name
of the corresponding alkyl group.
5. Punctuate the name: Use hyphens to separate the
position numbers from the names. If there is more
than one number if front of a name, use commas to
separate the numbers.
Examples:
Name the following alkynes:
1. CH≡C—CH—CH3
|
CH3
2. CH3—CH2—CH2—C≡CH
Aromatic Hydrocarbons
• Aromatic Hydrocarbons: have six-membered
carbon rings and delocalized electrons.
• Benzene: is the primary aromatic hydrocarbon.
C6H6 It is a six carbon atom ring with three double
bonds.
Section 3: Functional Groups
• Functional Group: is an atom or group of
atoms that is responsible for the specific
properties of an organic compound.
• Compounds that contain the same functional
group can be classified together because they
will undergo the same types of chemical
reactions.
Classes of Organic Compounds
• Alcohols: are organic compounds that contain
one or more hydroxyl groups.
– Functional Group: —OH
• Alkyl Halides: are organic compounds in
which one or more halogen atoms—fluorine,
chlorine, bromine, or iodine—are substituted
for one or more hydrogen atoms.
– Functional Group: —X (X= F, Cl, Br, or I)
• Ether: are organic compounds in which two
hydrocarbon groups are bonded to the same
atom of oxygen.
– Functional Group: —O—
• Aldehydes: are organic compounds in which
the carbonyl group is attached to a carbon
atom at the end of a carbon-atom chain.
O
||
– Functional Group: —C—H
• Ketone: are organic compounds in which the
carbonyl group is attached to carbon atoms
within the chain.
O
||
– Functional Group: —C—
• Amine: are organic compounds that can be
considered to be derivatives of ammonia, NH3.
– Functional Group: —N—
|
• Carboxylic Acids: are organic compounds that
contain the carboxyl functional group.
O
||
– Functional Group: —C—OH
• Ester: are organic compounds that have
carboxylic acid groups in which the hydrogen
of the hydroxyl group has been replaced by an
alkyl group.
O
||
– Functional Group: —C—O—