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Vat Photopolymerization
ISO/ASTM definition: “vat photopolymerization, —an additive manufacturing process in
• The first patent was filed in 1975 which described a two-laser 2PP process. The
first parts were made by Dr. Hideo Kodama of Japan using SL in 1981.
• Additional patents followed in 1984 when in three different parts of the world,
Claude André, Alain Le Méhauté and Olivier de Witte, and lastly on August 8 in
• Chuck Hull was the first to commercialize the technology when he founded 3D
Systems in 1986.
• In 1988, 3D Systems commissioned Alberts Consulting Group to create a file
format that could be sliced, resulting in the STL file format.
• In 1991, Cubital introduced the Solid Ground Curing process but later ceased
operations in 1999.
• In 2015 Carbon3D introduced a novel concept named CLIP using an oxygen-
permeable bottom plate to help speed up the printing process.
• As the original patents surrounding this technology have lapsed, many startups
have emerged taking advantage of this original AM process.
• This process involves using a liquid resin as the main type of material(polyethylene,
polypropylene etc.,).
• Specifically, this liquid resin has the special property of being able to become solid once it is
exposed to light.
• This light can be ultraviolet as in SL processes, or for 2PP, with two photons of near-infrared
(NIR) light hit within a very short period of time (several femtoseconds)[12].
• This liquid resin is held in a container or vat, in which a flat build platform is partially
submerged.
• This light can be a UV laser(SL), a digital light processing (DLP) projector, a UV light bulb
filtered through a printed mask(SGC), an LCD screen similar to home theater projectors(CLIP),
or even from very quick pulses (femtoseconds in length) of near infrared (NIR) laser light
• Once the resin is cured and made solid, the build platform either moves further into the vat, or
partially comes out of the vat leaving the solid cured portion just under the surface and then the
process is repeated.
• In the case of SGC, the uncured resin is removed and then replaced with a liquid wax that
solidifies, and then both the cured resin and wax is machined flat using a cutter and prepared
• If the process involves the platform coming out of the vat the resin needs to be transparent or
have the solidification process occur at the very bottom of a vat with a clear window or
bottom.
• However, this can cause the resin to solidify to the bottom which would prevent the platform
from moving, or cause it to solidify so closely to the bottom that when the build platform
moves up, significant suction is created which results in very slow movements.
• Recent developments by Carbon3D and the creation of the CLIP
process have resulted in very quick builds due to the clear bottom
of the resin within a certain zone around the clear bottom of the vat,
• This has shown to increase build speeds from 25-100 times compared