MOLAR MASS OF ELEMENTS Atoms and molecules are minute particles. The mole concept allows us to count these particles and establish a standard for reaction stoichiometry. It explains the properties of gases, provides universally accepted standard for mass, and helps us to distinguish between elements and compounds. In SI unit, the atomic counting unit is the mole, which comes from a Latin word that means “heap” or “huge pile.” Mole (mol) is the amount of substance that contains as many particles as there are atoms in 12 grams of Carbon -12. The mole equivalent to Avogadro’s number, . The number that one mole represents is expressed as follows: 1 mol = or particles Such particles could be atoms (for elements), molecules (for covalent compounds), formula units (for ionic compounds), ions (for charged substances). One mole of a certain element implies two things: 1. The atomic mass expressed in grams is different for each element . This mass is known as the molar mass of the element. Molar mass of the element = atomic mass expressed in g/mol of the element 2. Avogadro’s number of atoms is the same for all elements. 1 mol C= 12. 01 g = atoms 1 mol O=16.00 g = atoms 1 mol Na= 22.99 g= atoms 1 mol Hg= 200.6 g = atoms
This means that one mole of any element is equal to
atoms. INTERCONVERTING MOLES, MASS, AND NUMBER OF CHEMICAL ENTITIES One of the reasons the mole is such a convenient unit for laboratory work is that it allows you to calculate the mass or number of entities of a substance in a sample if you know the amount or number of moles of the substance. Conversely, if you know the mass (or number of entities) of a substance, you can calculate the number of moles. The molar mass, which expresses the equivalent relationship between 1 mole of a substance and its mass in grams, can be used as a conversion factor. We multiply by the molar mass of an element or compound (M, in g/mol) to convert a given amount (in moles) to mass (in grams): 1.What is the mass of 3. 00 mol of C? (Moles to mass) 2. How many moles are present in 25.6 g of C? (Mass to moles) 3.What is the mass of 1.806 x 10^24 atoms of C? (Number of Particles to mass) 4. How many individual atoms are present in 24.8 g of C? (Mass Number to Number of Particles) MOLAR MASS OF COMPOUNDS The formula mass (molecular mass) of a compound is determined from the atomic mass (in g) and the number of atoms of each element as indicated by the chemical formula. The formula mass is expressed in g/mol. The mass of one mol ( molecules or formula units) is referred to as the molar mass of the compound. The molar masses of various compounds differ, but the number of molecules or formula units per one mole of substance remains constant. In summary, you may follow the step- by- step process to get the molar mass of compounds. Step 1: Write down all the elements in the compound. Step 2: Write down the number of atoms of each element in the compound. Step 3: Identify the atomic mass of each element, then add up the masses. 1. What is the mass of 2.55 mol of ? 2. How many formula units of does this amount represent? The stoichiometry tells us what quantity of each reactant we need in order to get enough of our desired product. Because of its real-life applications in chemical engineering as well as research, stoichiometry is one of the most important and fundamental topics in chemistry. QUIZ TIME! 1. Silver (Ag) is used in jewelry and tableware but no longer in U.S. coins. How many grams of Ag are in 0.0342 mol of Ag? 2. Graphite is the crystalline form of carbon used in “lead” pencils. How many moles of carbon are in 315 mg of graphite? 3. Iron (Fe), the main component of steel, is the most important metal in industrial society. How many Fe atoms are in 95.8 g of Fe? 4. Manganese (Mn) is a transition element essential for the growth of bones. What is the mass in grams of Mn atoms, the number found in 1 kg of bone?