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ROLL NO:46 47 50 68 78
INTRODUCTION:
Defination:
Structure:
OH group attached to one side of benzene. Molecular Formula C6H5OH or C6H6O.
Derivative of benzene Three double bonds sp2 Hibridization.
Nomenclature
o-cresol m-nitrophenyl
2 – chloro - 4 – Niyro phenol
Benzene - 1 , 2 - diol
1 , 3 – Dihydroxy bezene.
Trihydricphenol
Physical properties:
2 It is crystalline in nature.
DOW’S PROCESS:
The reactant chlorobenzene is heated with aqueous sodium hydroxide at temperatures
623K and 300atm to get sodium phenoxide ion. Then in the next step sodium phenoxide
ion is treated with Dilute HCl which gives the final product as phenol.
From Diazonium Salts:
When an aromatic amine is treated with nitrous (NaNO2 + HCl) acid at 160°C, diazonium
salts are obtained.Upon warming with water, these diazonium salts finally hydrolyze to
phenols.
FROM BENZENE SULPHONIC ACID:
• Benzenesulphonic acid can be obtained from benzene by reacting it with oleum. This
benzene sulphonic acid which is treated with sodium hydroxide at high temperatures for
the formation of sodium phenoxide. Finally, sodium phenoxide on acidification gives
phenol.
FROM GRIGNARD REAGENT:
Hydrogenation:
When hydrogen reacts with phenol at 150℃ in the presence of Ni catalyst it gives
cyclohexanol.
Sulphonation :
Phenol reacts with H2SO4 at 25℃ and 100℃ to give ortho and para phenolsulphonic acid
respectively.
Salt formation :