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Metals and Non-Metals
Metals and Non-Metals
R
Pure Mixture
Substance s
Example:
Hydrogen, Helium, Oxygen
Aluminum (Al) is the most abundant metal, it constitutes 8% of the earth’s crust while
Fe is the second most abundant metal, and it constituents 5% of the earth’s crust.
OCCURRENCE OF
Combined State METALS Free State
Highly reactive metals are present Less reactive metals are generally
in the form of their compounds found in their elemental form in
as carbonates, sulphates, oxides the free state or in native state.
etc.
Gold (Au), Silver (Ag), Platinum
In the reactivity series, all the (Pt) etc. are found as such in
metals above copper are found in nature.
the combined form as sodium is
present in the form of sodium
chloride, sodium nitrate, sodium
carbonate etc.
METAL
Properties of Metals S
Metals are Generally Hard
Most of metals are hard except sodium, Potassium. Metals like iron, copper, Aluminium
etc. are very Hard
Sonorous
Metals make a ringing sounds when we strike them, this is why metals are used for
making bells, musical instruments etc.
METAL
Properties of Metals S
Thermal Conductivity
Transfer of heat from one end of a substance to the another end is known as
thermal conductivity.
Exception: Hg and Pb are poor conductors of heat.
Electrical Conductivity
Metals are good conductor of electricity, due to presence of free
electrons. Example: Ag, Cu
METAL
Properties of Metals S
Density
Metals usually have high densities i.e., they are heavy substances, due to rigid
structures
ACTIVITY SERIES OF
METALS
CHEMICALPROPERTIES OF
Melectropositive
Metals are ETALS elements
Metals are very reactive
Metals tend to lose electrons easily and form positively charged ions called
cations.
Example:
a) 𝐍𝐍𝐍𝐍+ + 𝐞𝐞− (loss of one
𝐍𝐍𝐍𝐍 electron)
b) 𝐌𝐌𝐌𝐌+ + 𝟐𝟐𝐞𝐞− (loss of two
𝐌𝐌
𝐌 𝐌 electron)
CHEMICALPROPERTIES OF
ME
1. Reaction ofTALSwith Oxygen
Metals
𝐌
𝐌𝐞𝐌
𝐌𝐍𝐍
𝐌𝐌 + 𝐎𝐎𝐎𝐎𝐎𝐎𝐌𝐌𝐞𝐞𝐎𝐎 𝐌
𝐌𝐞𝐌
𝐌𝐍𝐍
𝐌𝐌 𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
Metal oxides are basicoxides since they form bases (or alkalis i.e., water soluble
bases) when dissolved in water and turn red litmus blue.
𝐌
𝐌𝐞𝐌
𝐌𝐍𝐍
𝐌𝐌 𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 + 𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖
𝐖 𝐁𝐁𝐍𝐍𝐁𝐁𝐞𝐞
CHEMICALPROPERTIES OF
MEofTSodium
A. Reaction ALSwith
Oxygen
𝟒𝟒𝐍𝐍𝐍𝐍 𝐁𝐁 + 𝐎𝐎𝟐 𝟐𝟐𝐍𝐍𝐍𝐍𝟐𝟐𝐎𝐎
𝐌𝐌 𝐁𝐁
𝐒𝐨𝐨𝐨𝐨𝐨𝐨𝐒𝐒 𝐒𝐒𝐨𝐨𝐨𝐨𝐨𝐨𝐒𝐒𝐒𝐒
𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐍𝐎𝐍
𝐎𝐎𝐎𝐎𝐎𝐌𝐌𝐞𝐞𝐎𝐎
𝐍𝐍𝟐𝟐𝐎𝐎 𝐁𝐁 + 𝐇𝐇𝟐𝟐𝐎𝐎 𝟐𝟐𝐍𝐍𝐍𝐍𝐎𝐎𝐇𝐇 𝐍𝐍𝐚𝐚
𝐒𝐒𝐨𝐨𝐨𝐨𝐨𝐨𝐒𝐒𝐒𝐒 𝐌
𝐌 𝐒𝐒𝐨𝐨𝐌𝐌𝐒𝐒𝐒𝐒𝐌𝐌𝐞𝐞 𝐒𝐒𝐍𝐍𝐁𝐁𝐞𝐞
𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖 𝐍𝐍𝐌𝐌𝐚𝐍𝐍𝐌𝐌𝐨𝐨
𝐖 𝐒𝐒𝐨𝐨𝐨𝐨𝐨𝐨𝐒𝐒𝐒𝐒
𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
CHEMICALPROPERTIES OF
MEofTMagnesium
B. Reaction ALS with
Oxygen
𝟐𝟐𝐌𝐌𝐌𝐌 𝐁𝐁 + 𝐎𝐎𝟐 𝟐𝟐𝐌𝐌𝐌𝐌𝐎𝐎 𝐁𝐁
𝐌𝐌 𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒𝐒𝐒𝐒
𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒𝐒𝐒𝐒 𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐎𝐎𝐎𝐎𝐎𝐎𝐌𝐌𝐞𝐞𝐎𝐎
𝐌𝐌𝐌𝐌𝐎𝐎 + 𝐇𝐇𝟐𝟐𝐎𝐎 𝐌
𝐌𝐌𝐌 𝐎𝐎𝐇𝐇 𝟐 𝐍𝐍𝐚𝐚
𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒𝐒𝐒𝐒 𝐌
𝐌 𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒𝐒𝐒𝐒
𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖
𝐖 𝐒𝐒𝐍𝐍𝐁𝐁𝐞𝐞
CHEMICALPROPERTIES OF
MEofTCopper
C. Reaction ALSwith
Oxygen
𝐎𝐎𝟐
𝟐𝟐𝐨𝐨𝐂𝐂𝐂𝐂𝐞𝐞𝐖 𝐒𝐌𝐌𝐖𝐖𝐨𝐎𝐎𝐌𝐌 𝐡𝐡𝐞𝐞𝐍𝐍𝐌𝐌𝐨𝐨𝐎𝐎𝐌𝐌 𝟐𝟐𝐨𝐨𝐂𝐂𝐂𝐂𝐞𝐞𝐖𝐖
𝐖𝟐𝟐𝟐𝟐𝐒𝐒 + 𝟐𝟐𝟐𝟐𝐒
𝐒𝐎𝐎 (𝐈𝐈𝐈𝐈)
𝐎𝐎𝐎𝐎𝐎𝐎𝐌𝐌𝐞𝐞𝐎𝐎
𝐎𝐎𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝟐𝟐𝐒𝐒𝐎𝐎 + 𝐇𝐇𝟐𝟐𝐎𝐎 𝟐𝟐𝐒𝐒 𝐎𝐎𝐇𝐇 𝟐
𝟐𝟐𝐨𝐨𝐂𝐂𝐂𝐂𝐞𝐞𝐖𝐖 𝟐𝟐𝐨𝐨𝐂𝐂𝐂𝐂𝐞𝐞𝐖𝐖 𝐈𝐈𝐈𝐈
𝐈𝐈𝐈𝐈 𝐌
𝐌
𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖 𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 𝐒𝐒𝐍𝐍𝐁𝐁𝐞𝐞
𝐖
CHEMICALPROPERTIES OF
MEofTAluminum
D. Reaction ALS with
Oxygen
𝟒𝟒𝟒𝟒𝐌𝐌 𝐁𝐁 + 𝟐𝟐𝟒𝟒𝐌𝐌𝟐𝟐𝐎𝐎𝟑𝟑 𝐁𝐁
𝐍𝐍𝐒𝐒𝐂𝐂𝐡𝐡𝐨𝐨𝐌𝐌𝐞𝐞𝐖𝐖𝐨𝐨𝐚𝐚
𝟑𝟑𝐎𝐎𝟐 𝐌 𝐌 𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞𝐁𝐁
CHEMICALPROPERTIES OF
MEOxides
Amphoteric TALS
Those oxides that can reactwith acids as well as bases are called amphoteric
oxides. Examples:
𝟒𝟒𝐌𝐌𝟐𝟐𝐎𝐎𝟑𝟑 𝐁𝐁 + 𝟔𝟔𝐇𝐇𝟐𝟐𝐌𝐌 𝐍𝐍𝐚𝐚 𝟐𝟐𝟒𝟒𝐌𝐌𝟐𝟐𝐌𝐌𝟑𝟑 𝐍𝐍𝐚𝐚 + 𝟑𝟑𝐇𝐇𝟐𝟐𝐎𝐎 𝐌
𝐌
Some more examples of amphoteric oxides are ZnO, PbO, SnO etc.
CHEMICALPROPERTIES OF
MEofTMetals
2. Reaction ALSwith Water
Hydrogen gas is produced when metals reactwith water.
𝐌
𝐌𝐞𝐌
𝐌𝐍𝐍
𝐌𝐌 + 𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖
𝐖 𝐌
𝐌𝐞𝐌
𝐌𝐍𝐍
𝐌𝐌 𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 + 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎𝐎 𝐌𝐌𝐍𝐍𝐁𝐁
Highly reactive metals form their respective hydroxides while less reactive metals
form their respective oxides.
𝐌
𝐌𝐞𝐌
𝐌𝐍𝐍
𝐌𝐌 + 𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖
𝐖 𝐌
𝐌𝐞𝐌
𝐌𝐍𝐍
𝐌𝐌 𝐎𝐎𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 + 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎𝐎 𝐌𝐌𝐍𝐍𝐁𝐁
CHEMICALPROPERTIES OF
MEofTPotassium
A. Reaction ALS with
Water
+ 𝟐𝟐𝟐𝟐𝐎𝐎𝐇
𝐇 𝐇𝐇𝟐𝟐
𝐏𝐏𝐨 𝐌
𝐌
𝐍𝐍𝐁𝐁𝐨𝐒𝐒𝐒 𝐌𝐌𝐞𝐞𝐖𝐖𝐨
𝐒𝐒𝐂𝐂𝐞𝐞𝐖𝐖𝐍𝐨
𝐨𝐌
𝐍𝐨𝐒𝐒𝐌𝐒𝐒𝐖𝐖𝐞
+
𝐒 𝟐𝟐𝟐𝟐 𝟐𝟐𝐇𝐇𝟐𝟐𝐎𝐎 𝐞
↑
𝐏𝐏𝐨𝐨𝐌𝐌𝐍𝐍𝐁𝐁𝐁𝐁𝐨𝐨𝐒𝐒𝐒𝐒
𝟐𝟐𝐨𝐨𝐌𝐌𝐨𝐨 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎
𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐰𝐰𝐍𝐍𝐌𝐌𝐞𝐖𝐖 𝐎
CHEMICALPROPERTIES OF
MEofTSodium
B. Reaction ALSwith
Water
𝟐𝟐𝐇𝐇𝟐𝟐𝐎𝐎 𝟐𝟐𝐍𝐍𝐍𝐍𝐎𝐎𝐇𝐇 𝐇𝐇𝟐𝟐
𝐒𝐒𝐨𝐨𝐨𝐨𝐨𝐨𝐒𝐒𝐒 𝟐𝟐𝐨𝐨𝐌𝐌𝐨𝐨 𝐌𝐌𝐞𝐞𝐖𝐖𝐨
𝐒𝐒𝐂𝐂𝐞𝐞𝐖𝐖𝐍𝐨
𝐨𝐌
𝐍𝐨𝐒𝐒𝐌𝐒𝐒𝐖𝐖𝐞
𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎
+
𝐒𝟐𝟐𝐍 𝐍𝐍𝐍 + 𝐰𝐰𝐍𝐍𝐌𝐌𝐞𝐖𝐖 𝐞
𝐒𝐒𝐨𝐨𝐨𝐨𝐨𝐨𝐒𝐒𝐒𝐒 𝐎 ↑
𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
CHEMICALPROPERTIES OF
Note METALS
In case of sodium and potassium, the reaction is so violent and exothermic that
the evolved hydrogen immediately catches fire.
Calcium and magnesium floats on water because bubbles of hydrogen gas formed
during reaction with water sticks to the surface of calcium and it floats over water.
CHEMICALPROPERTIES OF
MEofTMagnesium
C. Reaction ALS with
Water
𝐌
𝐌𝐌𝐌 𝐇𝐇𝟐𝟐𝐎𝐎 𝐌
𝐌𝐌𝐌 𝐎𝐎𝐇𝐇 𝟐 𝐇𝐇𝟐𝟐
𝐇𝐇𝐨𝐨𝐌𝐌 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎
𝐰𝐰𝐍𝐍𝐌𝐌𝐞𝐖𝐖 + 𝐎 ↑
+ 𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒𝐒𝐒𝐒
𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐨𝐨𝐁𝐁𝐒𝐒𝐒𝐒 𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐌
𝐌𝐌𝐌 + 𝐌𝐌𝐌𝐌𝐎𝐎 + 𝐇𝐇𝟐𝟐
𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐨𝐨𝐁𝐁𝐒𝐒𝐒 𝐇𝐇𝟐𝟐𝐎𝐎 𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒𝐒𝐒↑ 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎
𝐒 𝐒𝐒𝐌𝐌𝐞 𝐒 𝐎
𝐍𝐍𝐒𝐒 𝐎𝐎𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
CHEMICALPROPERTIES OF
MEofTZinc
D. Reaction ALwith
S
Steam
𝐙𝐙𝐎𝐎 + 𝐙𝐙𝐎𝐎𝐎𝐎 + 𝐇𝐇𝟐𝟐
𝐙𝐙𝐨𝐨𝐎𝐎𝐚 𝐒𝐒𝐌
𝐌𝐞
𝐚𝐇𝐇𝟐𝟐𝐎𝐎𝐍𝐍𝐒𝐒
↑
𝐙𝐙𝐨𝐨𝐎𝐎𝐚𝐚 𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎𝐎
CHEMICALPROPERTIES OF
MEofTIron
E. Reaction ALwith
S Steam
𝟑𝟑𝟑𝟑𝐞𝐞 + 𝟐𝟐𝐇𝐇𝟐𝟐𝐎𝐎 𝟑𝟑𝐞𝐞𝟑𝐎𝐎𝟒 +
𝐖𝐈 𝐖𝐨𝐨𝐎 𝐒𝐒𝐌𝐌𝐞𝐞𝐍𝐍𝐒𝐒 𝐖
𝐈 𝐖𝐨𝐨𝐎𝐎
𝟒𝐎𝟒𝐇𝐇𝟐𝟐 ↑𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎𝐎 𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
CHEMICALPROPERTIES OF
MEofTMetals
3. Reaction ALSwith Dilute Acids
Metal salt and hydrogen gas are produced when a metal reacts with dilute
acid.
𝐌𝐌𝐞𝐌𝐌𝐍𝐍
𝐌𝐌 + 𝐃𝐃𝐨𝐨𝐌𝐌𝐒𝐌𝐌𝐞𝐞 𝐒𝐨𝐨𝐎𝐎𝐞𝐞𝐖𝐖𝐍𝐍𝐌𝐌 𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨 𝐌
𝐌𝐞𝐌
𝐌𝐍𝐍
𝐌𝐌𝐁
𝐁
𝐍𝐍
𝐌𝐌𝐌
𝐌 + 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎𝐎
𝐌𝐌𝐍𝐍𝐁𝐁
CHEMICALPROPERTIES OF
MEofTNA
A. Reaction aLSDilute
with
Acid
𝟐𝟐𝐍𝐍𝐍𝐍 𝟐𝟐𝐇𝐇𝟐𝟐𝐌𝐌 𝐍𝐍𝐚𝐚 𝟐𝟐𝐍𝐍𝐍𝐍𝟐𝟐𝐌𝐌 𝐇𝐇𝟐𝟐
+ 𝐨𝐨𝐨𝐨.𝐌𝐌 + 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎
𝐒𝐒𝐨𝐨𝐨𝐨𝐨𝐨𝐒𝐒𝐒𝐒 𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚 𝐒𝐒𝐨𝐨𝐨𝐨𝐨𝐨𝐒𝐒𝐒𝐒 𝐎 ↑
𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨 𝟐𝟐𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐨𝐨𝐞𝐞
‘𝐇𝐇𝟐𝟐’ is evolved readily and
vigorously.
CHEMICALPROPERTIES OF
MEofTMagnesium
B. Reaction ALS with Dilute
Acid
𝐌
𝐌𝐌𝐌 𝟐𝟐𝐇𝐇𝟐𝟐𝐌𝐌 𝐌𝐌𝐌𝐌𝟐𝟐𝐌𝐌𝟐𝟐 + 𝐇𝐇𝟐𝟐
𝐨𝐨𝐨𝐨𝐌𝐌.
𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚 𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒𝐒𝐒 ↑ 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎
𝐎
+ 𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨 𝐒
𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒𝐒𝐒𝐒 𝟐𝟐𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐨𝐨𝐞𝐞
‘𝐇𝐇𝟐𝟐’ is evolved quite less
readily.
CHEMICALPROPERTIES OF
MEofTAlAwith
C. Reaction LSDilute
Acid
𝟐𝟐𝟒𝟒𝐌𝐌 𝐁𝐁 + 𝟔𝟔𝐇𝐇𝟐𝟐𝐌𝐌 𝟐𝐌
𝟒 𝐌𝟐𝟐𝐌
𝐌𝟑𝟑 𝐍𝐍𝐚𝐚 + 𝟑𝐇
𝐇𝟐𝟐 𝐌
𝐌
𝐍𝐍𝐚𝐚 ↑
𝟒𝟒𝐌𝐌𝐒𝐒𝐒𝐒𝐨𝐨𝐎𝐎𝐨𝐨𝐒𝐒𝐒𝐒 𝐨𝐨𝐨𝐨𝐌𝐌. 𝟒𝟒𝐌𝐌𝐒𝐒𝐒𝐒𝐨𝐨𝐎𝐎𝐨𝐨𝐒𝐒𝐒𝐒 𝟐𝟐𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐨𝐨𝐞𝐞 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎𝐎
𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚
‘𝐇𝐇𝟐𝟐’ is evolved comparatively
𝐍𝐍𝐚
𝐚𝐨 less
readily.
CHEMICALPROPERTIES OF
MEofTZinc
D. Reaction ALwith
S Dilute
Acid
𝐙𝐙𝐎
𝐎 𝐁 𝟐𝟐𝐇𝐇𝟐𝟐𝐌𝐌 𝐍𝐍𝐚𝐚 𝐙𝐙𝐎𝐎𝟐𝟐𝐌𝐌𝟐𝟐 𝐍𝐍𝐚𝐚 +
+ 𝐨𝐨𝐨𝐨.𝐌𝐌 𝐇𝐇𝟐𝟐 ↑
𝐙𝐙𝐨𝐨𝐎𝐎𝐚𝐚 𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚
𝐙𝐙𝐨𝐨𝐎𝐎𝐚𝐚 𝟐𝟐𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐨𝐨𝐞𝐞
𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨 𝐇𝐇𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐌𝐌𝐞𝐞𝐎𝐎
‘𝐇𝐇𝟐𝟐’ is evolved comparatively less
readily.
CHEMICALPROPERTIES OF
MEofTCopper
E. Reaction ALSwith Dilute
Acid
𝟐𝟐𝐒𝐒 𝐁𝐁+ 𝐇𝐇𝟐𝟐𝐌𝐌 𝐍𝐍𝐚𝐚 No
𝟐𝟐𝐨𝐨𝐂𝐂𝐂𝐂𝐞𝐞𝐖𝐖 𝐨𝐨𝐨𝐨𝐌𝐌.
𝐡𝐡𝐎𝐎𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚𝐡𝐡𝐌𝐌𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚
reaction
𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨
‘𝐇𝐇𝟐𝟐’ is evolved because Cu is less reactive than hydrogen andcannot displace it from
acid.
CHEMICALPROPERTIES OF
MEofTMetals
4. Reaction ALSwith Salt Solutions of lessreactive
metals:
𝐌𝐌𝐨𝐨𝐖𝐖𝐞 𝐒𝐍
𝐍𝐌𝐌
𝐌𝐌 𝐁𝐁𝐨𝐨𝐌𝐌𝐒𝐒𝐌𝐌𝐨𝐨𝐨𝐨𝐎𝐎 𝐨𝐨𝐨𝐨
𝐖𝐖𝐞𝐌 𝐌
𝐞𝐞𝐍𝐍
𝐚𝐚𝐌𝐌
𝟏𝟏𝐨𝐨𝐫𝐞 +𝐒
𝐍
𝐍𝐌𝐌
𝐌𝐌
𝐌𝐌𝐞𝐁𝐁𝐁𝐁
𝐁𝐁
𝐨𝐨𝐌𝐌𝐒𝐌𝐌𝐨𝐨𝐨𝐨𝐎𝐎 𝐨𝐨𝐨𝐨 𝐌𝐌𝟐𝟐 𝐌𝐌𝟐𝟐 + 𝐒
𝐍
𝐍𝐌𝐌
𝐌𝐌 𝐁𝐁𝐨𝐨𝐌𝐌𝐒𝐌𝐌𝐨𝐨𝐨𝐨𝐎𝐎
𝐞 𝐖𝐖𝐞𝐞𝐍𝐍𝐚𝐚𝐌𝐌𝐨𝐨𝐫𝐞𝐞 𝐒𝐒𝐞𝐞𝐌𝐌𝐍𝐍𝐌𝐌
𝐨𝐨𝐨𝐨 𝐌𝐌𝟏𝟏
Here M1 and M2represents two different
metals.
CHEMICALPROPERTIES OF
MEofTIron
A. Reaction ALwith
S Copper solution
𝐖
𝐈 𝐖𝐨𝐨𝐎𝐎 + 𝟐𝟐𝐨𝐨𝐂𝐂𝐂𝐂𝐞𝐞𝐖𝐖 𝐈𝐈𝐈𝐈 𝐁𝐁𝐒𝐒𝐌𝐌𝐂𝐂𝐡𝐡𝐍𝐍𝐌𝐌𝐞𝐞 𝐖
𝐈 𝐖𝐨𝐨𝐎𝐎 𝐈𝐈𝐈𝐈 𝐁𝐁𝐒𝐒𝐌𝐌𝐂𝐂𝐡𝐡𝐍𝐍𝐌𝐌𝐞𝐞 + 𝟐𝟐𝐨𝐨𝐂𝐂𝐂𝐂𝐞𝐞𝐖𝐖 𝐒𝐞𝐞𝐌𝐌𝐍𝐍𝐌𝐌
Copper (II) sulphate solution is blue; iron sulphate solution is light green when dilute.
During reaction, the blue colour of solution fades and the iron metal is seen to turn
red- brown as the displaced copper gets deposited on it.
CHEMICALPROPERTIES OF
MEofTMagnesium
B. Reaction ALS with Copper Sulphate Solution
Magnesium being more reactive displaces ‘Cu’ from its salt which gets deposited as
pure metal.
𝐌𝐌𝐌𝐌 𝐁𝐁 + 𝟐𝟐𝐒𝐒𝐒𝐒𝐎𝐎𝟒 𝐍𝐍𝐚𝐚 𝐌𝐌𝐌𝐌𝐒𝐒𝐎𝐎𝟒𝟒 𝐍𝐍𝐚𝐚
𝐌𝐌𝐍𝐍𝐌𝐌𝐎𝐎𝐞𝐞𝐁𝐁𝐨𝐨𝐒 + 𝟐𝟐𝐒𝐒 𝐁
𝐁
𝐒𝐒𝐒 𝐁𝐁𝐌𝐌𝐒𝐒𝐞𝐞 𝟐𝟐𝐨𝐨𝐌𝐌𝐨𝐨𝐒𝐖𝐖𝐌𝐌𝐞𝐞𝐁𝐁𝐁𝐁
𝐖
𝐞𝐂𝐨
𝐖
𝟐
On adding magnesium to blue copper (II) sulphate solution, the blue colour fades
as colourless magnesium sulphate is formed and brown bits of copper metal form
a precipitate.
CHEMICALPROPERTIES OF
MEofTSilver
C. Reaction ALSwith Copper sulphate solution:
Silver, being less reactive than copper, cannot displace Cu from its solution. Hence,
no reaction takes place.
𝟒𝟒𝐌𝐌 𝐁𝐁 + 𝟐𝟐𝐒𝐒𝐒𝐒𝐎𝐎𝟒 𝐍𝐍𝐚𝐚 No reaction
𝐒𝐒𝐨𝐨𝐌𝐌𝐫𝐞𝐞𝐖𝐖 𝐁𝐁𝐌𝐌𝐒𝐒𝐞𝐞
USES OF
MEaspect
Metals are important in every TAL ofS
life. Some uses of metals are mentioned
below:
USES OF
METALS
1. Metals in Bio-processes
Iron (Fe) is a constituent of hemoglobin. Na, Mg, K, Ca etc., are essential metals
required as minerals in the living body.
USES OF
Mand
2. Metals in daily Goods ET ALS
Machines
Copper (Cu) and Aluminum (Al) are used for making electrical wires andcables. Iron is
used for making stove burners, gutter pipe, railway tracks etc. steel (Iron and Carbon)
is used for making engine parts, utensils, equipment's etc.
USES OF
METALS
3. Metals in Accessories
Gold (Au), Silver (Ag) and Platinum (Pt) are used to make
jewelry.
USES OF
METAand
4. Metals in Health Equipment's LSinstruments
Mercury (Hg) is used in thermometers, sphygmomanometers and barometers
etc.
Practice Time
Q. Which of the following elements is found in native
state?
a) Iron (Fe) b) Sodium
c) Platinum (Na)
(Pt) d) All of
these
Practice Time
Q. Select the correct one
a)Metals conduct electricity but not
heat
b)Metals have shiny surfaces
c)All metals are generally coloured
d)Metals generally have low melting
point
Practice Time
Q. It it possible to store copper sulphate solution in a silver
container?
a) No b) Yes
c) Can’t d) Depends upon
say conditions
NON-
A non metal is an elementMETALS
whose atoms readily gain electrons to form negative ions
Non-metals are electronegative elements as they form negative ions by gaining
electrons.
NON-
METALS
Occurrence of Non-Metals
Non-metallic oxides generally are acidic in nature because they form acids on dissolving
in water and turns blue litmus paper red.
𝐍𝐍𝐨𝐨𝐎𝐎−𝐒𝐒𝐞𝐞𝐌𝐌𝐍𝐍𝐌𝐌𝐌𝐌𝐨𝐨𝐚𝐚 𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 + 𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖
𝐖 𝟒𝟒𝐚𝐚𝐨𝐨𝐨𝐨
CHEMICALPROPERTIES OF NON-
MET ALS
A. Reaction of Carbon with Oxygen
When carbon reacts with oxygen it forms acidic oxide i.e., carbon dioxide CO2. This is
in water forms carbonic acid. A solution of carbon dioxide gas in water turns blue
litmus paper red, showing that it is acidic in nature.
𝟐𝟐 𝐁𝐁 + 𝐎𝐎𝟐 𝟐𝟐𝐎𝐎𝟐𝟐 ↑
𝟐𝟐𝐍𝐍𝐖𝐖𝐒𝐒𝐨𝐨𝐎 𝐌 𝟐𝟐𝐍𝐍𝐖𝐖𝐒𝐒𝐨𝐨𝐎𝐎
𝐎
𝐌 𝐨𝐨𝐨𝐨𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐎𝐎𝐎𝐎𝐎𝐎𝐌𝐌𝐞𝐞𝐎 𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨𝐨𝐨𝐚𝐚 𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐎
𝟐𝟐𝐎𝐎𝟐𝟐 𝐌
𝐌 + 𝐇𝐇𝟐𝟐𝐎𝐎 𝐇𝐇𝟐𝟐𝟐𝐎𝐎𝟑
𝟐𝟐𝐍𝐍𝐖𝐖𝐒𝐒𝐨𝐨𝐎𝐎 𝐌
𝐌 𝐍𝐍𝐚𝐚
𝐨𝐨𝐨𝐨𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖 𝟐𝟐𝐍𝐍𝐖𝐖𝐒𝐒𝐨𝐨𝐎𝐎𝐨𝐨𝐚𝐚
𝐖 𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨
CHEMICALPROPERTIES OF NON-
MET ALS
B. Reaction of Sulphur with Oxygen
Sulphur forms acidic Sulphur dioxidewith oxygen which in turn gives sulphurous acid
on dissolving in water.
𝐒 𝐎𝐎𝟐 𝐒𝐒𝐎𝐎𝟐 ↑
𝐎
𝐎
𝐎𝐎
𝐎𝐎𝐌𝐌 𝐒𝐒𝐒𝐒𝐌𝐌𝐂𝐂𝐡𝐡𝐒𝐒𝐖𝐖
+ 𝐞𝐎
𝐎 𝐨𝐨𝐨𝐨𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐒𝐒𝐒𝐒𝐌𝐌𝐂𝐂𝐡𝐡𝐒𝐒𝐖𝐖
𝐒𝐒𝐎𝐎𝟐 + 𝐇𝐇𝟐𝐒𝐒𝐎𝐎𝟑
𝐒𝐒𝐒𝐒𝐌𝐌𝐂𝐂𝐡𝐡𝐒𝐒𝐖 𝐇𝐇 𝐎𝐎 𝐒𝐒𝐒𝐒𝐌𝐌𝐂𝐂𝐡𝐡𝐒𝐒𝐖𝐖𝐨𝐨𝐒𝐒𝐁𝐁
𝟐𝟐
𝐖 𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨
𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖
𝐨𝐨𝐨𝐨𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞 𝐖
𝐞
CHEMICALPROPERTIES OF NON-
MET ALS
C. Reaction of Phosphorus with Oxygen
Phosphorus forms phosphorus pentaoxide with oxygen which gives phosphoric acid
on dissolving in water.
𝐏𝐏𝟒𝟒 + 𝟓𝟓𝐎𝐎𝟐 𝟐𝟐𝐏𝐏𝟐𝐎𝐎𝟓
𝐏𝐏𝐡𝐡𝐨𝐨𝐁𝐁𝐂𝐂𝐡𝐡𝐨𝐨𝐖𝐖𝐒𝐒𝐁 𝐎𝐎𝐎𝐎𝐎𝐎𝐌𝐌𝐞𝐞𝐎 𝐏𝐏𝐡𝐡𝐨𝐨𝐁𝐁𝐂𝐂𝐡𝐡𝐨𝐨𝐖𝐖𝐒𝐒𝐁𝐁
𝐁 𝐎 𝐂𝐂𝐞𝐞𝐎𝐎𝐌𝐌𝐍𝐍𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞
𝐏𝐏𝟐𝐎𝐎𝟓 + 𝟐𝟐𝐇𝐇𝟑𝐏𝐏𝐎𝐎𝟒
𝐏𝐏𝐡𝐡𝐨𝐨𝐁𝐁𝐂𝐂𝐡𝐡𝐨𝐨𝐖𝐖𝐒𝐒𝐁 𝟑𝟑𝐇𝐇𝟐𝟐𝐎𝐎 𝐏𝐏𝐡𝐡𝐨𝐨𝐁𝐁𝐂𝐂𝐡𝐡𝐨𝐨𝐖𝐖𝐨𝐨𝐚𝐚
𝐖
𝐖𝐍𝐍
𝐌𝐌𝐞𝐖 𝐍𝐍𝐚𝐚𝐨𝐨𝐨𝐨
𝐁
𝐂𝐂𝐞𝐞𝐎𝐎𝐌𝐌𝐍𝐍𝐨𝐨𝐎𝐎𝐨𝐨𝐨𝐨𝐞𝐞 𝐖
CHEMICALPROPERTIES OF NON-
MET ALS
2. Reaction with water
Generally, non-metals do not reactwith water or steam. This is because non-metals
cannot give electrons to reduce hydrogen ions of water into hydrogen gas.
3. In the solid state, the ionic compounds are non-conductors but in the molten (fused) or
in the aqueous state, they conduct electricity.
ORES
The minerals from which the metals can be conveniently and economically extracted
are known as ‘Ores’.
Concentration of
ore
l
reactivity
Sulphide
I
reactivity
Sulphide
ore ore ore ore
Oxide of Metal
metal
Reduction to Refining
metal
Purification of
metal
EXTRACTION OF METALS ACCORDING TO THEIR
REACTIVITY
A) Mining of Ore
Generally ores are found deep inside the earth but some may be present only a few
metres under earth’s surface. Mining is the process to take out the ores from mines.
B) Sizing of Ores
Mined ores are found generally in form of big lumps which are crushed into small
pieces and then powdered.
EXTRACTION OF METALS ACCORDING TO THEIR
REACTIVITY
C) Enrichment of Ore
The removal of undesired foreign impurities i.e., gangue from ore is called
concentration of ore.
EXTRACTION OF METALS ACCORDING TO THEIR
REACTIVITY
Low Reactivity
Metals low in the activity series are very unreactive. The oxides of these metals can
be reduced to metals by heating alone.
𝟐𝟐𝐇𝐇𝐇𝐇𝐇𝐇
𝟐𝟐𝟐𝟐𝟐𝟐𝟐𝟐 𝐬𝐬 + 𝟑𝟑𝐎𝐎𝟐 𝟐𝟐 𝟐𝟐𝟐𝟐𝟐𝟐𝐎𝐎 𝐬𝐬 + 𝟐𝟐𝟐𝟐𝐎𝐎𝟐𝟐 𝟐𝟐
𝟐𝟐𝐇𝐇𝐇𝐇𝐇
𝟐𝟐𝟐𝟐𝟐𝟐𝐎𝐎 𝐬𝐬 𝐇 𝟐𝟐𝟐𝟐𝟐𝟐 𝐥𝐥 +
𝐎𝐎𝟐 𝟐𝟐
EXTRACTION OF METALS ACCORDING TO THEIR
REACTIVITY
Low Reactivity
Copper which is found as Cu2S in nature can be obtained from its ore by just heating in
air.
𝟐𝟐𝐇
𝐇𝐇𝐇
𝟐𝟐𝟐𝟐𝐮𝐮𝟐𝟐𝟐 + 𝐇 𝟐𝟐𝟐𝟐𝐮𝐮𝟐𝟐𝐎𝐎 𝐬𝐬
𝟑𝟑𝐎𝐎𝟐 𝟐𝟐 +
𝟐𝟐𝐇𝐇𝐇𝐇𝐇
𝟐𝟐𝟐𝟐𝐮𝐮𝟐𝟐𝐎𝐎 + 𝐇
𝟐𝟐𝟔
𝟐𝟔
𝟐𝟐
𝐎𝟐𝐎
𝐮𝐮𝟐𝟐 𝐬𝟐
𝐬𝟐+
𝟐𝟐𝐮𝐮𝟐𝟐𝟐 𝟐𝟐𝐎𝐎𝟐𝟐 𝟐𝟐
EXTRACTION OF METALS ACCORDING TO THEIR
REACTIVITY
Middle Activity
The metals in the middle of the activity series such as (Fe, Zn, Pb, Cu)
It is easy to extract metal from its oxide so to make it easy first we have to
covert sulphides and carbonates into oxide
𝟐𝟐𝟐𝟐𝐎𝐎 𝐬𝐬 + 𝟐𝟐𝟐𝟐 𝐬𝐬 +
𝟐𝟐 𝐬𝐬 𝟐𝟐𝐎𝐎 𝟐𝟐
EXTRACTION OF METALS ACCORDING TO THEIR
REACTIVITY
High Activity
By electrolysis of molten ore
At Cathode
𝐍𝐍𝐇𝐇+ + 𝟏𝟏𝐇𝐇−
𝐍𝐍𝐇𝐇
At Anode 𝟐𝟐𝟐𝟐𝐥𝐥− 𝟐𝟐𝐥 𝟐 +
𝟐𝟐𝐇𝐇−
EXTRACTION OF VARIOUS METALS ACCORDING TO
THEIR REACTIVITY
Thermite process
The reaction of iron (III) oxide (Fe2O3) with aluminum is used to join railway tracks or
cracked machine parts. This reaction is known as the thermit reaction.
𝟐𝟐𝐮𝐮𝟐𝟐+ + 𝟐𝟐𝐇𝐇−
𝟐𝟐𝐮
𝐮
REFINING OF
Reaction at AnodeMET ALS
𝟐𝟐𝐮𝐮 𝟐𝟐𝐮𝐮𝟐+ +
𝟐𝟐𝐇𝐇−
CORROSIO
Silver articles become blackN
after some time when exposed to air. This is because it
reacts with Sulphur in the air to form a coating of Silver Sulphide.
Copper reacts with moist CO2in the air and slowly loses its shiny brown surface and
gains a green coat. This green substance is copper carbonate.
Iron when exposed to moist air for a long time acquires a coating of a brown
flaky substance called rust.
PREVENTION OF
CORROSION
A) By Painting
The most popular and common method of rust prevention is painting which prevents
the direct contact of moist air and iron material.
PREVENTION OF
CO
B) By Greasing orRROSION
Oiling
Grease or oil also prevents the direct contact of iron material with moist air and
hence prevent rusting.
PREVENTION OF
CORROSION
C) By Galvanisation
Galvanisation is a process of depositing a thin layer of zinc metal on iron
objects.
AQUA
Freshly prepared mixture ofR EGIA hydrochloric acid and concentrated nitric acid
concentrated
in the ratio 3 : 1.
It can dissolve gold, even though neither of these acids can do so alone. Aqua regia
is a highly corrosive, fuming liquid.
It is one of the few regents that is able to dissolve gold and platinum.