HINTS & SOLUTIONS (PRACTICE PAPER-1) ANSWER KEY

Que s. Ans. Que s. Ans. Que s. Ans. Que s. Ans. Que s. Ans. Que s. 1 D 16 A 31 B 46 B 61 C 76 2 B 17 B 32 B 47 C 62 B 77 A 92 D 107 C 3 C 18 B 33 B 48 B 63 A 78 B 93 D 108 D 4 C 19 D 34 D 49 C 64 B 79 C 94 A 109 B 5 D 20 B 35 D 50 B 65 C 80 A 95 C 110 B 6 D 21 B 36 C 51 A 66 D 81 B 96 D 111 A 7 A 22 D 37 D 52 B 67 D 82 B 97 A 112 A 8 B 23 A 38 B 53 A 68 D 83 C 98 A 113 A 9 B 24 B 39 B 54 A 69 C 84 A 99 C 114 D 10 A 25 B 40 A 55 B 70 C 85 A 100 D 115 D 11 C 26 A 41 D 56 C 71 C 86 B 101 B 116 B 12 D 27 D 42 C 57 A 72 D 87 A 102 D 117 A 13 D 28 B 43 A 58 A 73 B 88 C 103 A 118 B 14 D 29 A 44 59 C 74 B 89 B 104 B 119 A 15 B 30 A 45 D 60 B 75 C 90 B 105 D 120 B

Ans. B Que s. 91 A Ans. Que s. 106 D Ans.

PART-I (1 Mark) MATHEMATICS

2# & 1 $x2 ' x3 ! $ ! % " 7

1.

& 1# $ 2! r 7 General term = ( 1) Cr $ x ! % "

Tr + 1 = ( 1) Cr = ( 1) Cr = ( 1) Cr = ( 1) Cr
r 7 r 7 r 7 r 7

7 'r

& 2# $ 3! $x ! % "

7 'r 2r x 2 x3 7 'r 2r ( x 2 3 21'3r ( 4r x 6 21(r x 6

For the coefficient of x4,

T3 + 1

21 ( r =4 6 21 + r = 24 r = 24 21 r=3 = ( 1)3 7C3

=1 = 35.

7*6*5 3*2

Pre-foundation Career Care Programmes (PCCP) Division

1 1

z
2.

z z = 1 and | z | = 1
z = x + iy

Let Then,

z = x iy
|z|=

x2 ( y2 = 1
x2 + y2 = 1

or

x ( iy x ' iy ( x ' iy x ( iy = 1

x 2 ' y 2 ( 2ixy ( x 2 ' y 2 ' 2ixy x2 ( y2 2( x 2 ' y 2 ) x2 ( y2

=1

=1

2x2 2y2 = x2 + y2 x2 = 3y2 x= Now,

2

3y x +y =1 3y2 + y2 = 1 4y2 = 1
2

y2 = y= Then, x =

1 4 1 2
3 2

) Different complex number are : z = 3. Let A 1 = B Therefore AB = +,

235 37 / 2 1 0/ A 0 - = 0 1 41 43 . 10 1.
R1 3 R1 35

1 1 1 1 3 3 3 3 +i ,z= i ,z= + i and z = i . 2 2 2 2 2 2 2 2

37 / 2 2 1 / 0 1 35 0 35 0A 0 - = 0 0 1141 43 . 1 .
R 2 3 R 2 ' 41R1 37 / 2 2 1 / 01 35 0 35 0 12 - = 0 41 A 0 00 ' 0' 10 0 35 1 . 1 35 . R2 3 ' 35 R2 12
2 2

Pre-foundation Career Care Programmes (PCCP) Division

2 1 / 0 37 / 2 0 35 1 0 35 - = 0 41 35 A 0 0 ' 10 1 . 12 . 1 12
37 R2 35

R1 3 R1 '

2 43 0' 12 1 0 2 / A 0 - = 0 41 0 10 1. 1 12

37 / 12 35 ' 12 .

2 43 0' 12 A = 0 41 0 1 12

37 / 12 35 ' 12 .

2 ' 43 37 / 12 A = 0 1 41 ' 35 .

det (12A) = | 43 35 4137| = 1505 1517 = 12.

5

4.

Given :

4n
n 61

1
2

72 6

5 n 61

41
5

1 ( 3 ( 5 ( ... ( ( 2n 1)
3

( 23 ( 33 ( ..... ( n3

4 n (n ( 1)
2 n 61

n2 4

5 n 61

4 (n ( 1)
5

$1 ( 40 2 1%
n 61

2&

1
2

# / ( ......... ! ' 13 " .

2

40 1n
n 61

2 1
2

/ ' 1.

& 72 # $ ! 4 $ 6 ' 1! . % "

Pre-foundation Career Care Programmes (PCCP) Division

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5.

4ax2 + xy + 4y2 = 0 m1 + m2 = m1 + m2 = m 1m 2 = m 1m 2 =
a b '2h b

'1 4

4a =a 4 Given : m2 = m12 '1 4 4m12 + 4m1 = 1 4m12 + 4m1 + 1 = 0 (2m1 + 1)2 =0

m 1 + m 12 =

'1 2 m1 m2 = a m1 m12 = a m 13 = a
m1 =

& ' 1# $ ! =a % 2 "

) 6. a=
'1 . 8

y = 2x2 + x 2
A

Let point A is (t1, 2t12 + t1 2 ) and point B is (t2, 2t22 + t2 2) Given : Mid point of AB is (0, 0) So,
2

t1 ( t 2 = 0 8 t1 + t2 = 0 2
2

2t 1 ( t 1 ' 2 ( 2t 2 ( t 2 ' 2 =0 2 2(t12 + t22) + (t1 + t2) 4 = 0 2[(t1 + t2)2 2t1t2] + 0 4 = 0 2[0 2t1t2] = 4 4t1t2 = 4 t1 t2 = 1 (t1 t2)2 = (t1 + t2)2 4t1t2 = 0 4( 1) =4 t1 t2 = 2. Distance AB :
AB = AB =
( t 1 ' t 2 ) 2 ( ( 2t 1 ( t 1 ' 2 ' 2t 2 ' t 2 ( 2)2
2 2

( t1 ' t 2 )2 ( 2( t1 ' t 2 ) ( ( t1 ' t 2 )

Pre-foundation Career Care Programmes (PCCP) Division

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AB = AB = AB =

( 2)2 ( 92( t 1 ( t 2 )( t1 ' t 2 ) ( ( t 1 ' t 2 ): 4 ( 92(0) ( ( 2):

4(4 =
2

8=2 2.

7.

0, c 4
3x +

1 (1, 1) 1 1 1

Perperndicular from (1, 1) on line 3x + 4y + c = 0 =1 9 ( 16 |7+c|=5 7+c= 5 c=57 c = 12 | c | = 12.

&R# &P# p cos2 $ ! + r cos2 $ ! %2" %2"

3(4(c

4y +

c , 0 3

c = 0

8.

s(s ' r ) s(s ' p) +r pq qr

s [s r + s p] q
s [2s r p] q s [p + q + r r p] q

=s = 9.

p(q(r . 2

3cos2x sin2x sin4x cos2x = 0 8 3(1 sin2x) sin2x sin4x (1 sin2x) = 0 8 3 sin2x 3sin4x sin4x 1 + sin2x = 0 8 4sin4x + 4sin2x 1 = 0 8 4sin4 4sin2x + 1 = 0 8 (2 sin2x 1)2 = 0 8 2sin2x = 1 5 5

Pre-foundation Career Care Programmes (PCCP) Division

sin2x =

1 2 1

8 ) 10. ;=

sinx =

2 sin x has 4 solution in the interval [0, 27].

& 1# 1 sin1 $ ! %4" 2

sin2; =

1 4

2sin;<cos; = sin;<cos; =

1 4

1 8 Value of : 64sin; + 64cos; 8sec; 8cosec; + tan; + cot;

& sin ; cos ; # ( ! = 64(sin; + cos;) 8 (sec; + cosec;)+ $ % cos ; sin ; "

sin2 ; ( cos2 ; # 1 # & & 1 $ ! ( $ ! = 64(sin; + cos;) 8 + ! sin ; cos ; % cos ; sin ; " $ % "
& sin ; ( cos ; # 1 ! + = 64(sin; + cos;) 8 $ % sin ; cos ; " sin ; cos ;
(sin ; ( cos ;) +8 1/ 8 = 64(sin; + cos;) 64 (sin; + cos;) + 8 = 8.

= 64(sin; + cos;) 8

11.

C @ & & 1# & 1 # & 1 #= = 2 n lim B lim x30 $ L= n $ x sin$ x ! ( x sin$ x 2 ! ( .... ( x sin$ x n !? 35 = % " % " % "= % A >
C 1 & 1 # & 1 #@ lim B lim x sin ( lim x 2 sin$ 2 ! ( ......... ( lim x n sin$ n !? L= n 3 5 x 30 x 30 x x 30 %x " % x "> A

lim D0 ( 0 ( 0 ( .......... . ( 0E L= n 35
L=0

12.

C for x G 1@ =x3 = ? f(x) = B 2 = = ax ( bx ( c for x F 1 A >

f(x) = 3x2 = 2ax + b [f(x)] x = 1 = 6x = 2a 8 6 = 2a a = 3.

13.

f(x) = x3 3ax2 + b f(x) = 3x2 6ax For the f(x) to be increasing f(x) > 0. 3x2 6ax > 0 3x (x 2a) > 0 (x 2a) > 0 [! x > 0] x > 2a So, a G 0.

Pre-foundation Career Care Programmes (PCCP) Division

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14.

Hx ' 9x :I!dx J 9x:cos$ %2 "

1 2 3

&7

&7 # = cos$ 2 Hx ' 1I!dx + % " 1

Hx ' 2I!dx J 2 cos$ %2 "

2
2
3

&7

2 &7 #/ 0 sin$ 2 Hx '1I! "0 % 7 0 0 2 1 .

2 4 [1 ' 0] ( [1 ' 0] 7 7 6 . 7

2 &7 #/ 0 sin$ 2 Hx ' 2I! "0 % 7 + 20 0 2 1 .

= = 15.

Let A =

1 {(2n + 1) (2n + 2) ------- (2n + n)}1/n n

( 2n ( n) / 2 ( 2n ( 1) ( 2n ( 2) ( 2n ( 3 ) 1 ..... lim log 0 n n n 1 n . n n3 5

log A =

log A =

2& 1 #& 2 #& 2# & n #/ 1 lim log 0$ 2 ( n !$ 2 ( n !$ 2 ( n !.....$ 2 ( n !n 3 5 "% "% " % ". n 1%
1

log A =

J log( 2 ( x )dx
0
1

log A = x log( 2 ( x)' x ( 2 log(2 ( x) 0 log A = [log 3 1 + 2 log 3 2 log2] log A = [log 3 loge + log 9 log4] log A = [log (27/4e)] A = (27/4e). 16.
V1 + V2 + V3 = 0

V1 ' V2 = ?
V1 ( V2 = V3 V1 ( V2 . V1 ( V2 = ' V3 . ' V3
2 2 2

H I H I

V1

+ V2 + 2V2 . V2 = V3

1 + 1 + 2V2 . V2 = 1
2V2 . V2 = 1 V2 . V2 =

'1 2

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V1 ' V2

= V1

+ V2 2 V1 . V2

'1 2 =1+1+1=3
=1+12
2

V1 ' V2

=3

V1 ' V2 =

3.

17.

Total number of possible cases = 4 + 3 + 2 + 1 = 10 Favourable cases = {(H T T H T),(T H T H T ), (T T H H T ), (T T T H H)} Total number of favourable cases = 4 ) p(4th toss is a head) =
4 10 2 . 5

= 18. a + b + c = even

Case 1 : All taken are even : < 5C3 = 10 Case 2 : One even + 2 odd : 5C1 5C2 = 50 Total = 10 + 50 = 60. 19. 2log(x 2y) = logx + logy log(x 2y)2 = log(xy) (x 2y)2 = xy x2 + 4y2 4xy = xy x2 + 4y2 5xy = 0 x2 4xy xy + 4y2 = 0 x(x 4y) y (x 4y) = 0 (x y)(x 4y) = 0 x = y (N.P.), x = 4y

x y = 4.
20. Let x, y and z are 2n, n2 1 & n2 +1. Let x = 2n, y = n2 1 and z = n2 +1. Option (A) : 2 does not divide x . Clearly 2 divides x. So option (A) is not true. Ex : 8, 15 and 17 are pythogorean triplet. 2 divides 8. Option (B) : 2 does not divide z(x + y) (n2 + 1)(2n + n2 1) which is an odd number so, 2 does not divides z(x + y). ) So, option (B) is true. Option (C) : 4 divides x + y + z Ex : 5, 12, 13 are the pythogorean triplet. Clearly 5 + 12 + 13 = 30, and 4 does not divides 30. )So, option (C) is not true. Option (D) : 8 divides x + y + z Ex : 8, 15, 17 are the pythogorean triplet. Clearly 8 + 15 + 17 = 40, and 8 divides 40. ) So, option (B) is true.
Pre-foundation Career Care Programmes (PCCP) Division

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PHYSICS
21. By work energy theorem, W = KK mgh wf = 0 wf = mgh

22.

E = 13.6

z2 n
2

= 13.6

4 = 54.4eV Ans (D) 1

2E
23.

E
V<L<<FB<M deflected in x direction (Ans.B)
P P1 I 45

P2

25.

90

By Malus's law, IN=<+Ocos245 initensity after P1

I 2 initensity after P2
I = Icos245 = I2 = 26. 27.

I1 I cos245 = !Ans : B" 2 4

Due to inertia ballon displace in the direction of motion of the bus. (D) As for hydrogen like atom

& 1 1 1# 6 R.z 2 $ ' 2! 2 $ ! P % n1 n2 "

So,

(Here z = 1, same for deuterium and hydrogen)

1 will be same for deuterium as that for hydrogen. P

KP & KV # $ ! % V "

28.

Bulk modulus, B = '

As in isothermal process, PV = K On differentiating, PdV + VdP = 0

KV KP 6' V P
' KP & Hence B = $ ' KP # ! =P % P "
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29. 30.

Q2 From brewsters law tan+ = Q 1

Cheaking dimensionally all the formula
Pg 2L / 6 [L]0 2 - 6 [L2 T ' 2 ] 27 1T .

and

Sg 2 [MLT ' 2 ] [L1T ' 2 ] / 60 * R [ML'3 ] . 0 [L] 1

1/ 2

= [L2T2]

(dimension of v2)

27S [M1L1T '2 ][L'1] 6 = [L2T2] PR [L][ML'3 ]

Only (A) option is correct dimensionally 33. As v & d depends on frame of referance but change in KE and hence heat does not depend.
V

34.

V>> 2gr

v x v
2 2v / vB = v0 01 ' c 1 . 2 vC = vo 01 ' 1 v/ c.

B C 2v

36.

2v

2 2v cos ; / VA = V0 01 ( c 1 . VA > VC > VB (Answer : C)

37.

By dalton's law of partion pressure.

KQ r2

(Ans : D)

38.

Ein = 0 Eout = Vin =

KQ KQ = const. Vout = R r X is for electric field versus distance graph Y is for potential versus distance graph Ans. is (B) kq
39. Enet = 2 Enet =

( x ( y 2 )3 / 2

[ x]

2kq x2

Pre-foundation Career Care Programmes (PCCP) Division

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CHEMISTRY
41. For weak acid [H+] = CT [H+] = 0.1 0.1 [H+] = 102 pH = log[H+] pH = log[102] pH = 2
O N O

42.

3 it has two donor side [O & N]

43.

H3O+ sp3 hybridisation, due to presence of 1 lp structure is trigonal pyramidal. (D) Ba > Ca > Mg > Be Solubility increases down the group due to increase of size of cation. C > Be > B > Li Zeff M I E M Dipole moment = e d
F Be =0 F

45.

46.

47.

48.

[NiCl4]2 is tetrahedral.

50.

mvr =

nh 27

where n = 1, 2, 3 -------

51.

(A) both valencies occupy by the same group.

52.

p-nitrophenol I & M

-o-nitrophenol I & M ( intramolecular H-bond)

m-nitrophenol I

CH2 O COR

CH2 OH + 3NaOH 3RCOONa + CH OH Salt of fatty acid CH2 OH glycerol

54.

(A) CH O COR
CH O COR

55.

(B) Branching M surface area L vanderwaals forces L<b.p. L

Pre-foundation Career Care Programmes (PCCP) Division

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56.

(C) Zn/NaOH 2 NO2

Zn/NaOH

N=N

58.

CH3 CH2 CH(OH) COOH

OH
59. (C)

COOH

[contains phenolic group]

60.

(B) stability of carbanions T

+ & M ( + & (M

PART-II (2 Mark) MATHEMATICS

81. ab = 2 (a + b)
a(b 1 6 ab 2 1 1 1 ( 6 a b 2

...... (i)

bc = 3( b + c)
b(c 1 6 bc 3 1 1 1 ( 6 b c 3

...... (ii)

ca = 4( c + a)
c(a 1 6 ca 4 1 1 1 ( 6 c a 4

...... (iii)

Add (i), (ii) and (iii)

& 1 1 1# 1 1 1 2$ ( ( ! 6 ( ( %a b c " 2 3 4
1 1 1 6(4(3 ( ( 6 a b c 24 1 1 1 13 ( ( 6 a b c 24

...... (iv)

From (i) and (iv) c = 24

Pre-foundation Career Care Programmes (PCCP) Division

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From (ii) and (iv)

a=

24 5

From (iii) and (iv) b=

24 7

So, value of 5a + 7b + c = 24 + 24 + 24 = 72. 82. x2 + ax + b = 0 T + U = a, TU = b x4 + ax3 + cx2 + dx + e = 0 Roots are T + U , T U , T + U and T U Sum of roots = a T + U<+ T U< T + U< T U<= a a = 0 8 T + U<= 0 Sum of roots taken two at a time = + c (T + U ) (T U ) + (T U ) (<T + U ) + (<T + U )(<T U ) + (<T U ) (T + U ) + (T + U ) (<T + U ) + (T U ) (<T + U ) = c 0 (<T + U )2 + 0 + 0 + 0 (T + U )2 = c 2(T U )2 = c 2[T2 + U 2 2TU ] = c 2[(T + U )2 2TU 2TU ] = c 2[ 4TU ] = c c = 8TU c = 8b V 0 Product of roots taken three at a time = d (T + U ) (T U ) (<T + U ) + (T + U ) (<T + U )(<T U ) + (<T U ) (T + U ) + (T + U ) (<T + U ) (<T + U ) (<T + U) = d 0+0+0+0=d d=0 Product of roots = e (T + U )(T U )(<T + U )(<T U ) = e e=0 So, c = 0 is the false statement

83.
y = 3x Q y = 2x P O

PQ = 5 Let point Q is (x, 3x)

Pre-foundation Career Care Programmes (PCCP) Division

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Given QP = 5 and QP W line 2x y = 0

2x ' 3 x 4 (1
x= 5 5

=5

Therefore point Q is ( 5 5 , 15 5 ) ) OQ = = =

H5 5 I ( H15 5 I

125 ( 1125 1250

= 25 2 ) In KOPQ OQ2 = OP2 + PQ2

H25 2 I

= OP2 + (5)2

1250 25 = OP2 OP2 = 1225 OP = 35 cm. 84. cot

B = 2

s(s ' b) (s ' c )(s ' c )

cot

s(s ' b) C = ( s ' a)(s ' b) 2

B C cot = 2 2
s(s ' b) (s ' a)(s ' c ) s(s ' c ) (s ' a)(s ' b)

cot

cot

B C cot = 2 2

s 2 (s ' b)(s ' c ) (s ' a)2 (s ' b)(s ' c ) s2 ( s ' a) 2

cot

B C cot = 2 2

cot

s B C cot = s'a 2 2

Given : b + c = 3a s=

a(b(c a ( 3a = = 2a. 2 2
2a 2a B C cot = = = 2. 2 a ' a a 2 2

cot

Pre-foundation Career Care Programmes (PCCP) Division

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85.

D F E

Given : AE = EF = FC = Let, Then,

AC 3

AB = BC = CD = DA = x AC =
2x

Let BE = a In KAEB

2x 2 ( x 2 ' a2 9 cos 45 = 2x 2 .x 3

11x 2 ' a2 9 1 = 2 2x 2 2 3

2x 2 11x 2 = a2 3 9 11x 2 2x 2 9 3 11x 2 ' 6 x 2 5x 2 = 9 9 5 x 3 5x . 3

a2 =

a2 =

a=

Similarily BF = a = In KBEF BE = BF =

5x 3

and

EF =

2x 3

Pre-foundation Career Care Programmes (PCCP) Division

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cos; =

BE 2 ( BF 2 ' EF 2 2BE * BF

5 x 2 5 x 2 2x 2 ( ' 9 9 9 cos; = 5x 5x 2* * 3 3

8x 2 9 cos; = 10 x 2 9

8 4 = . 10 5

) 86.
D

tan; =

3 . 4
x

2007

v = Volume of box = (2007 2x)2 x

dv = 2(2007 2x)( 2x) + (2007 2x)2 dx

= (2007 2x)[ 4x + 2007 2x] = (2007 2x) (2007 6x) For the maximum volume
dv =0 dx

(2007 2x)(2007 6x) = 0 x=

d2 v dx 2
2007 2007 or x = 6 2

= (2007 6x) ( 2) + (2007 2x) ( 6) = 4014 + 12x 12042 + 12x = 24x 16056

& d2 v # $ ! 2007 $ dx 2 ! 2007 = 24 16056 % "x6 6

6

= 8028 16056 < 0 ) Volume is maximum when x =

2007 669 = cm. 6 2

Pre-foundation Career Care Programmes (PCCP) Division

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87.

S = y2 4x S (0, 2) = 4, S (1/2, 5/2) = 25/4 2 = 17/4, S (5/2, 9/2) = 81/4 20/2 = 41/4 and S (1, 3) = 9 4 = 5 It is clear that (0, 2) is closest to parabola y2 = 4x.

88.

or 2 e I<0 J>0 2

e I<0 J<0

or 2

J<0

So, I and J can be both negative but not both positive. 89. |z1 z2 + z2 z3 + z3z1| = |z1z2z3|

1 1 1 ( ( z1 z 2 z 3
[! |z1| = |z2| = |z3| ]

= z1 ( z2 ( z3 = |z1 + z2 + z3|. 90. So, the angles will be 99, 108, ....., 153, 162 )<Sum of largest two angles = 153 + 162 = 315.

PHYSICS
91. Rotational inertia does not depend on speed so rotational inertia of the cylinder about its axis will be

1 MR2. 2
92. Air column is closed at one end, so fundamental frequency n=
v 330 6 = 125 Hz 4" 4 * 66 * 10 ' 2

!# n1 : n2 : n3 ....... = 1 : 3 : 5 ........... So, possible frequencies are 125, 375, 675, 875, 1125 (> 1kHz) So only possible frequenceies are 3. 93. Time period of pendulum on the surface of the earth T0 = 2p 27 " g ........(i)

At a depth d, So new time period, T = 27

d# & gN = g $ 1 ' ! R % "

and "N = "H1 ( T; I

1 # & d # "N "(1 ( T;) & ! = 27 = (1+ T;) (1 d/R) = $1 ( T; ! $1 ( 2 " % 2R " gN g(1 ' d / R) %

Pre-foundation Career Care Programmes (PCCP) Division

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94.

For first darkness, d sin; =<P 8 sin; =<

6 * 10 '7 2 * 10 ' 6

6 0.3 <; = 17

95.

In LC circuit time period, T = 27 Lc t=

T 7 LC = 4 2

96.

For insulated material capacity,

X0 A C = (d ' a ( a / X ) r
But of metal, Xr = 5 So, C = 97. Amax = g AY2 = g Amax =
g Y
2

X0 A (d ' a)

(block and piston remains together)

g 47 2 f 2
3

98.

z = 0, as P and E in same direction

dE 6 105 dZ
99. Inside the atom,

8<F = P

dE = 107 105 = 102 N dZ

Electric field due to +v charge , E(r) =

ze r r3

kz e r2

Due to ve charge, E(r) = K

ze & 1 r # $ 2 ' 3! 4 7X 0 % r R "

So, E(r) =

r<R

For out side atom Qnet = 0 E(r) = 0 r>R 100. KQ = cPKT

&f # &f # = $ ( 1! RKT = $ ( 1! PKV 2 2 % " % "

&f # KQ 10.61 $ ( 1! = 6 2 PdV % " 1.01* 10 5 * 3 * 10 ' 5

f = 4.3 So, gas is a mixture of mono and diatomic molecules.

Pre-foundation Career Care Programmes (PCCP) Division

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CHEMISTRY
101.
CH2 = CH CH CH2 CH3 Br
Br2

* * CH2 CH CH CH2 CH3 Br Br Br

CH2Br H C Br H C Br CH2 CH3

/////////////////////////

CH2Br Br C H Br C H CH2 CH3

CH2Br H C Br Br C H CH2CH3

/////////////////////////

CH2Br Br C H H C Br CH2CH3

102.
V

according to above graph P T V This contradict the Boyles law 103. ! Molarity of acetic acid = 0.1 M [Suppose volume of acetic acid = x] ) no. of millimoles present in x ml of acetic acid = 0.1x ! Molarity of sodium acetate = 0.2 ) no. of millimoles present in 10 ml of sodium acetate = 0.2 10 = 2 [Salt] pH = pKa + log [ Acid]

2 4.91 = 4.76 + log 10 ( x 0.1x 10 ( x 2 0.15 = log 0.1x

0.15 = log20 logx 0.15 = 1.3010 logx logx = 1.151 x = antilog (1.151) x = 14.16 ml x Z 14.2 ml

[ ! total volume = (10 + x) ml]

Pre-foundation Career Care Programmes (PCCP) Division

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104.

[3 BaSO3 + H2O Ba(OH)2 + SO2 [ (White ppt.)

[3 BaSO4 + H2O Ba(OH)2 + SO3 [ (White ppt.) BaSO3 is soluble in dil HCl but BaSO4 is not soluble in dil HCl . After filteration , filtrate contains BaSO3

[3 2HBr + O Br2 + H2 O [ (Bromine water)

[3 BaSO4 BaSO3 + O [ White ppt

1
105. PT

V according to question given potential energy = kinetic energy 1 eV = mv2 ----- (1) 2 P2 eV = [! P = mv] 2m h2 h eV = 2 [) p = ] P P 2m 2 h P2 = 2meV h P= 2meV ! e, m, h are constants 1 so P \ V
Kb = 0.52 k Kg mol1 (given) KTb = 0.052 K (given) m = given ) KT b =

106.

1000 K b w 0 mW KTb * m w0 = 1000K W b

---------------- (i)

It means we can calculate

Relative lowering of vapour pressure of water 8

Po Ps w M = 0 ------(ii) Po W m

M = molecular mass of water = 18 m = given

w0 = by equation (i) W so we can calculate relative lowering of V.P. of water by equation (ii) n ST V But V is unknown, so we cant find out the value of osmotic pressure.
osmotic pressure 7 =

1000 K f w o mW But value of Kf is not given so we cant calculate the magnitude of freezing point depression.
freezing point depression KTf =
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107.

Test of Nitrogen Organic compound Fused with Na + FeSO4 + FeCl3 Test of sulphur Organic compound fused with Na + sodium nitroprusside

no ppt. observed

Nitrogen absent

violet S present colour observed Thus according to question organic compound contains sulphur only.

NH2
108.

(CH3CO)2O CH3 (I)

NHCOCH3 Br2/CH3COOH

NH COCH3

CH3

CH3

Br (II) H2O/H+ NH2

CH3 Br (III)

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