Chun dung dch Fe3+ bng EDTA

1. Nguyn tc:
a) Phn ng chun :
Fe3+ + H2Y2- FeY- + 2H+
FeY-( pH=2,5) = 1012,7.
Lu :
- Nu mun xc nh tng hm lng st trong dung dch, phi oxi ha Fe 2+
thnh Fe3+ (thng dng K2S2O8 hoc (NH4)2S2O8)
- Dung dch cn c [Fe3+] < 10-3M trnh s to kt ta Fe(OH)3.
- Cc phc Mn+ EDTA khc u km bn pH = 2,5 ( b). Ion Al 3+ cng
khng gy nh hng, v AlY- = 104,2 << FeY-)
- Phc FeY- c mu vng nht nn c nh hng n mu ca ch th im
cui chun .
b) Xc nh im cui:
Dng ch th phc kim loi, thng l axit salixylic (Sal) hoc sunfosalixylic
(SSal tt hn). Cn bng ch th:
H2Y2- + FeInd FeY- + HInd + H+
tm nho
khng mu
2. Thc nghim:
a) Ha cht:
- Dung dch chun EDTA 0,01M
- Dung dch NH3 (1:1): Ly 10mL dung dch NH3 m c, thm 10mL nc.
- Dung dch K2S2O8 2%
- Dung dch ch th salixylic hoc sunfosalixylic 5%.
- Dung dch m pH 2,5: Ly 10 mL Na2HPO4 0,2M + 90 mL axit xitric 0,1M.
b) Cch tin hnh:
- Ly 10mL mu, thm nc ct thch hp, thm 5 git dung dch K 2S2O8 2%.
Thm vi git ch th, sau thm tng git NH 3 cho n khi dung dch c
mu tm m nht (pH = 2 3).
- Thm 2mL dung dch m pH 2,5.
- Chun bng dung dch EDTA n khi dung dch mt mu tm (dung dch c
th c mu vng nht ca FeY-, ty thuc nng Fe3+ ban u)