TUGAS TERMODINAMIKA

Anggota Kelompok :
1.
2.
3.
4.
5.

Dede Hadi Widianto (03111003031)

Anissa Nurul Badriyah (03111003075)
Nova Amanda (03111003081)
Akhmad Ade Sucitro (03111003087)
Uwu Holifah A.F (03111003103)

CHAPTER 5
The Second Law of Thermodynamics
5.27. For a steady-flow procss at approximately atmospheric pressure, what is
the entropy change of the gas:
(a).
When 10 mol of SO2 is heated from 200 to 1,100oC?
(b).
When 12 mol of propane is heated from 250 to 1,200 oC
Answer :
Dengan menggunakan persamaan 5.14 didapatkan :
T

S
Cp ig dT
P
=
ln
R
R T
Po

( )

Dengan asumsi P = konstan , maka persamaan menjadi :

T

S
Cp ig dT
=
R
R T

.............. (1)

Dengan mensubstitusi persamaan 5.15 dengan persamaan 1 didapat :

[ (

S
D
=A ln + B . T o + C . T o2+ 2 2
R
T .To

() +12 )] ( 1)

................(2)

a. Berdasarkan tabel C.1 pada Appendix C, didapatkan nilai :

A
= 5,699
B
= 0,801 x 10-3
C
=0
D
= -1,015 x 105
Diketahui :
To = 473,15 K
T
= 1373,15 K

=
n

T 1373,15
=
=2,9021
T o 473,15

= 10 mol

Ditanya : Perubahan entropi ( S

Pembahasan :
Dengan persamaan (2) :

S
D
=A ln + B . T o + C . T o2+ 2 2
R
T .To

) ( )]

+1
( 1 )
2

S
1,015.10
3
=5,699 ln (2,9021)+ 0,801.10 .473,15+
2
2
R
2,9021 . 473,15

)(

)]

2,9021+1
( 2,90211 )
2

S
=6,0719+ [ 0,3790+ (0,0538 ) ( 1,9511 ) ] ( 1,9021 )
R

S
=6,5931
R

S=n . R . 6,5913

S=10 mol .8,314

J
J
.6,5913=548
mol . K
K

b. Berdasarkan tabel C.1 pada Appendix C, didapatkan data untuk

propana sebagai berikut :
A
= 1,213
B
= 28,785 x 10-3
C
= -8,824 x 10-6
D
=0

Diketahui :
To = 523,15 K
T
= 1473,15 K

T 1473,15
=
=2,8159
T o 523,15

=
n

= 12 mol

Ditanya : Perubahan entropi ( S

Pembahasan :

S
D
=A ln + B . T o + C . T o2+ 2 2
R
T .To

) ( )]

+1
( 1 )
2

)]

S
2,8159+1
=1,213 ln(2,8159)+ 28,785 .103 x 523,15+ ( 8,824 .106 )
(2,81591 )
R
2

S
=1,2558+ [ 15,0589 ] ( 1,8159 )
R

S
=2 0,555
R

S=n x R x 2 0.555

S=12mol x 8,314

J
J
x 2 0.555=2050,731
mol . K
K

5.43.Heat in the amount of 150 kJ is transferred directly from a hot reservoir at

TH = 550 K to two cooler reservoirs at T 1 = 350 K and T2 = 250 K. The
surroundings temperature is T0 = 300 K. If the heat transferred to the
reservoir at T1 is half that transferred to the reservoir at T2, calculate :
(a).
(b).

The entropy generation in kJ K-1

The lost work

Answer :
Diketahui :
QH

= -150 kJ

Q1
Q2
QH

= 50 kJ
= 100 kJ
= -150 kJ

TH
T1
T2

= 550 K
= 350 K
= 250 K
= 300 K

Pembahasan :
a. The entropy generation in kJ/K

S G=

Q H Q1 Q2
+ +
TH T1 T2

S G=

150 kJ 50 kJ 100 K
+
+
500 K 350 K 250 K

S G=0,2701

kJ
K

b. The lost work

W lost =T . S G

W lost =300 K .0,271

W lost =81.03 kJ

kJ
K