Some possibly useful equations: F j = FA0 (Θ j + υ j X )

x
(1 + εx )2 dx FT = FT 0 + δFA0 X
∫0 (1 − x )2
ε = y A0δ
= 2ε (1 + ε ) ln(1 − x ) + ε 2 x +
(1 + ε ) x
2

v = v0 (1 + εX )
P0 T
1− x P T0
Fj Θ j + υ j X P T0
dN A
= rAV Cj = = C A0
dt v 1 + εX P0 T
X
dX ΘI P T0
t = N A0 ∫ C I = C A0
0
− rAV (1 + εX ) P0 T
F j T0 P
FA = FA0 − FA0 X C j = CT 0
FT T P0
FA0 X V
V= τ=
(− rA )exit v0
− rA0V
dF Da =
rA = A FA0
dV
Da1
FA 0
dFA X=
V= ∫ − rA
1 + Da1
FA 1 1
X =1− =1−
(1 + Da1 ) (1 + τk )n
X n
dX
V = FA0 ∫
0
− rA 1 + 2 Da2 − 1 + 4 Da 2
X=
2 Da2
rA r r r
− =− B = C = D Da2
a b c d X=
1 + Da2

KC =
kB
Da 2 = 2ε (1 + ε )ln (1 − X ) + ε 2
X+
(1+ ε ) X
2

k−B 1− X
ΔH Rx ⎛ 1 1 ⎞
⎜ − ⎟ C A0 ⎧ − (1+τk ) ⎫
t

K C (T ) = K C (T0 )e
R ⎜⎝ T0 T ⎟⎠ CA = ⎨1 − e
τ
⎬
1 + τk ⎩ ⎭
k(T ) = Ae − E / RT τ
t S = 4.6
1 + τk
b c d
A+ B= C+ D ⎛ dC ⎞
a a a ln⎜ − A ⎟ = ln k A + α ln C A
⎝ dt ⎠
⎛c d b ⎞ xn
δ =⎜ + − − 1⎟ dy
⎝a a a ⎠ y n − y1 = ∫ dx dx
x1

⎛ dC A ⎞ − 3C A0 + 4C A1 − C A 2
⎜ ⎟ =
2Δt
= C A0 (Θ j + υ j X ) ⎝ dt ⎠ t = 0
Nj
Cj =
⎛ dC A ⎞
[ ]
V 1
N T = N T 0 + δN A0 X ⎜ ⎟ = C A( i +1) − C A(i −1)
⎝ dt ⎠ ti 2Δt

V = V0 (1 + εX )
T P0 ⎛ dC A ⎞
⎜ ⎟ =
1
[
C A( N − 2 ) − 4C A( N −1) + 3C A( N ) ]
T0 P ⎝ dt ⎠ t N 2Δt
σ2 =
s2 N
(r − r )
= ∑ im ic
2
β0 =
G ⎛ 1 − φ ⎞ ⎡150(1 − φ )μ
⎜⎜ 3 ⎟⎟ ⎢
⎤
+ 1.75G ⎥
N − K i =1 N − K ρ0 g c D p ⎝ φ ⎠ ⎢⎣ Dp ⎥⎦

t1/ n =
1
k (α − 1)C A0
α −1
(
nα −1 − 1 ) dP
dW
=−
α T P0
2 T0 P / P0
(1 + εX )
2β0
α=
k cat (Et )(S ) Ac ρ c (1 − φ )P0
− rS =
(S ) + K M P ⎛ 2β 0 z ⎞
= ⎜1 − ⎟
1/ 2

1 1 K 1 P0 ⎜⎝ P0 ⎟⎠
= + M
− rS Vmax Vmax (S ) W
x A2
dX A
(S ) = FA0
= ∫ − rA′
1
(S ) + KM x A1

− rS Vmax Vmax
− rS − rA′ = a(t )k (T ) f (C A , CB , ........ )
− rS = Vmax − K M
(S )
= p[a(t )] kd (T )h(C A , CB , ... )
da
rd = −
Q& − W& S + FA0 ∑ Θ i C Pi (Ti 0 − T ) dt

[ ]
1 1
a= =
− FA0 X ΔH Rx
0
(TR ) + ΔC P (T − TR ) = 0 1 + CCp A pt np + 1

T=
XΔC PTR + ∑ Θ i C PiTi 0 − X ΔH [ 0
Rx (TR )] a = e −α 1C C
XΔC P + ∑ Θ i C Pi a=
1
1 + α 2CC
dT Ua(Ta − T ) + rA (ΔH Rx )
=
dV FA0 (∑ Θ i C Pi + ΔC P X )
CC = At n 0.5 < n < 1
dTa Ua(T − Ta )
=
dV m& c C Pc ⎡ E A − nE A + E d ⎛1 1 ⎞⎤

Ua(T − Ta )
⎢ ⎜⎜ − ⎟⎟ ⎥
⎢⎣ ⎠ ⎥⎦
1− e ⎝ T T0
R
dTa
=− t=
dV m& c C Pc kd 0 (1 − n + Ed E A )
UA(Ta − T ) / FA0 + ∑ Θ i C Pi (Ti 0 − T )
X EB =
ΔH Rx
0
(TR ) + ΔC P (T − TR ) t=
W
Us

kC 2 U ⎛ − dW ⎞
k
X
= A 0 s ⎜1 − e U s ⎟
K A PACt
C A• S =
1 + K A PA 1− X FA0 kd ⎜ ⎟
⎝ ⎠

Rate =
(kinetic factor )(driving - force group) kC A2 0W
Da2 =
adsorption group FA0

dP
=−
G ⎛ 1 − φ ⎞ ⎡150(1 − φ )μ
⎜⎜ 3 ⎟⎟ ⎢
⎤
+ 1.75G ⎥ X=
(
Da2 1 − e − λ )
dz ρg c D p ⎝ φ ⎠ ⎣⎢ Dp ⎦⎥
(
λ + Da2 1 − e − λ )
dTs ha~ (T − T )
dP G ⎛ 1 − φ ⎞ ⎡150(1 − φ )μ ⎤ P TF If T ≠ Ts =− P s
=− ⎜⎜ 3 ⎟⎟ ⎢ + 1.75G ⎥ 0 T dW U sC p s
dz ρ 0 g c D p ⎝ φ ⎠ ⎣⎢ Dp ⎦⎥ PT0 FT 0
dT dT Ua~ (T − T ) + (rA′ )(ΔH Rx )
If T = Ts = s = W a
dP P TF
= −β0 0 T dW dW U sCPs + ∑ FiC pi
dz PT0 FT 0