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Chemistry
CHEMISTRY
21998
_____________________
RAJASTHAN P.E.T.
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(3) linear
(4) tetrahedral
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(1) 6, 6
(2) 4, 6
(3) 6, 8
(4) 8, 8
(4) 22.8 M
(3) Refrigerant
(4) Antipyretic
(3) 6 gm
(3) 8
(4) 7
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34. For the reaction 2A C + D the value of equilibrium constant is 1 x 10-3 . If [C] = 1.2 x 10-3 M,
[D] = 3.8 x 10-6 M the value of [A] will be :
(2) 3.6 x 10-9 M
(1) 5.2 x 10-6 M
-3
(3) 2.1 x 10 M
(4) 4.8 x 10-12 M
35. Which of the following does not obey the octet rule :
(1) PCI3
(2) SF6 (3) SO2
(4) OF2
36. Mustard gas is found from :
(1) C2H4 & H2SO4
(2) C2H4 & H2S
(3) C2H4 & S2C12
(4) C2H4 & CH3SH
37. The most reactive metal is :
(1) Li
(2) Au
(3) F
(4) Pt
(3) Ag
(4) Mg
43. If the ionization constant of CH3COOH is 1.8 x 105, the degree of ionization of 0.01 M
CH3COOh will be :
(1) 1.8 x 10-7
(2) 1.8
(3) 4.2 x 10-2
(4) 42.4 x 10-5
44. If the price of Nac1 sugar are 2 and 14 rupees per kg. then the price of 1 mole NaC1 and 1
mole sugar will be :
(1) 7 Rs.
(2) different
(3) equal
(4) 28 Rs.
45. In which of the following there are minimum nos. of molecule :
(1) 2 gm. H2
(2) 8 gm. O2 (3) 16 gm. CO2
(4) 4 gm. N2
46. In which of the following central atom uses sp2 hybrid orbitals :
(1) SbH3
(2) NH3
(3) PH3
(4) +CH3
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(4) NO+
(4) +4
(4) Kr
(3) CN-
(4) O2-
(3) n = 0
(4) n = 0, = 0
59. The dipole moment of BF3 is zero. Which of the following 6 bond orbitals are used by B :
(1) sp2
(2) sp
(3) sp3
(4) none of these
60. Which of the following have acidic hydrogen :
(1) C2H4
(2) C2H2
(3) C2H6
(4) None of these
61. In which of the following molecule C-C bond is largest :
(1) Benzene
(2) Ethene
(3) Ethane
(4) Ethyne
62. The set of four quantum number of e0 of 4-d will be :
(1) 3, 2, 0 + (2) 4, 2, 0, +
(3) 4, 1, 0, + (4) 4, 3, 0, +
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H
Between C(1) and C(2) is formed by hybrid orbitals of :
(1) sp & sp2
(2) sp & sp3 (3) sp & sp
(4) sp2-sp2
66. The dipole moment of CCl4 is zero, because of :
(1) equal electron affinity of C, and Cl
(2) equal size of C and Cl
(3) regular size of C and Cl
(4) planar structure
67. The number of moles of H2 at 500 cm.3 volume, 700 mm. pressure and 3000 K temperature
will be:
(1) 0.203x10-2 moles
(2) 20.x10-3 moles
(3) 20.3x10-2 moles
(4) 2.03 x 10-7 moles
68.Which of the following has electronic configuration as 4f1-145s25p65d16s2 :
(1) Representative elements
(2) Transition elements
(3) Lanthanides
(4) Actinides
69. The wave number of hydrogen atom in Lymen series is 82, 200 cm.-1. The electron
goes from :
(1) III orbit to II
(2) II orbit to I
(3) IV orbit to III
(4) none of these
70. Teflen is a polymer of :
(1) PVC
(2) Tetrafluro ethane (3) Tetra fluro ethane (4) C2H4
71. In which of the following s character is maximum :
(1) C6H6
(2) H2H6
(3) C2H4
(4) C2H2
72. Benzene hexachloride is found by :
(1) Addition
(2) Elimination
(3) Substitution reaction
73. Alkane is found by :
(1) Reaction by alky l halide
(2) Wurtz reaction
(3) Grignard reagent
(4) All these
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74. The first inert gas compound invented was :
(1) KrF6
(2) XeF6
(3) XeF2
(4) XePtF6
79. In which of the following nos. of primary carbon atoms are maximum :
(1) is pentane
(2) iso-octane
(3) neopentane
(4) all of these
80. Na2 S2O3 is used in photography because :
(1) It is a compound of sulphur
(2) It reacts with Ag Br to form sodium silver thisulphate
(3) It is an antichlor reagent
(4) none of these
81. Borax is found in :
(1) Punjab
(2) Rajasthan
(3) Utterpradesh
(4) Delhi
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(2) F.C.R.
(3) Wurtz reaction
(4) Markownikoffs rule
87. The frequency of wave of 4000 wave. Length will be :
(1) 7.5 x 02s-1
(2) 75 x 1010s-1
(3) 7.5 x 1014 (4) 0.75 x 102s-1
88. The oxidation no. of C in CO2 is :
(1) +1
(2) +2
(3) +4
(4) 0
89. H2O2 is :
(1) strong oxidizing agent and weak reducing agent
(2) neigther oxidizing agent nor reducing agent
(3) only reducing agent
(4) only oxidizing agent
90. Which element have maximum oxidation states :
(1) Sc
(2) Zn
(3) B
(4) Mn
91. Carborundum is :
(1) SiB
(2) SiC
(4) CO2
(3) SiO2
(3) Neutral
(4) Basic
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(4) Bauxite
99. Which of the following gives rod colour precipitate with sodium cupritartaarate :
(1) CH3COOH
(2) CH3COCH (3) CH3COC2H5
(4) CH3CHO
100. Which of the following are present in picric acid :
(1) NO2 group
(2) OH and NO2 group
(3) NO2 and COOH groups
(4) OH group
1.(3)
12.(4)
23.(3)
34.(3)
45.(4)
56.(1)
67.(4)
78.(3)
89.(1)
100.(2)
2.(1)
13.(3)
24.(3)
35.(2)
46.(4)
57.(3)
68.(3)
79.(2)
90.(4)
3.(1)
14.(3)
25.(3)
36.(3)
47.(3)
58.(2)
69.(2)
80.(2)
91.(2)
4.(4)
15.(4)
26.(1)
37.(1)
48.(3)
59.(1)
70.(3)
81.(3)
92.(3)
ANSWER SHEET
5.(3) 6.(1) 7.(3)
16.(2) 17.(4) 18.(2)
27.(1) 28.(2) 29.(1)
38.(1) 39.(4) 40.(3)
49.(1) 50.(3) 51.(4)
60.(2) 61.(3) 62.(2)
71.(4) 72.(1) 73.(4)
82.(4) 83.(3) 84.(4)
93.(3) 94.(1) 95.(2)
8.(3)
19.(1)
30.(3)
41.(3)
52.(1)
63.(3)
74.(4)
85.(2)
96.(1)
9.(4)
20.(1)
31.(1)
42.(1)
53.(3)
64.(4)
75.(1)
86.(2)
97.(2)
10.(4)
21.(1)
32.(3)
43.(3)
54.(1)
65.(1)
76.(1)
87.(3)
98.(1)
11.(2)
22.(2)
33.(2)
44.(2)
55.(3)
66.(3)
77.(1)
88.(2)
99.(4)