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CHE 325 Module One PDF
CHE 325 Module One PDF
Engineering
Thermodynamics I
CHE 325
(3 Units)
Mode of Grading
Assignments/Tests = 30 marks
Examination = 70 marks
Module
1: INTRODUCTION
• Basic definitions, aim and scope.
• PVT system, path dependency.
INTRODUCTION:
State:
Condition/position of a system
due to change in properties
INTRODUCTION
Process: a series of changes experience by a
system from one state to another.
The path of successive states through which
a system passes when change from one
state to another.
Reversible Process: a system undergoes
reversible process when it is restored to its
initial state following same manner.
INTRODUCTION
Cyclic process: a system undergoes
thermodynamic cyclic process when it is restored
to its initial state.
V
Example 1
As shown in the figure, water which
circulates between a storage tank
and a solar collector is used for
domestic purposes. Identify
locations on the system boundary
where the system interacts with the
surroundings and describe events
that occur within the system, if the
system is
[a] solar collector
[b] solar collector, storage tank and
connecting pipes.
Solution
[a] The system (solar collector) is
an open system.
Warm water enters the system at
the base through the pump.
The water is heated up as a result
of heat radiation through the
surface of the system.
Hot water leaves the system at the
top.
Pressure exerted on the system
through the pump makes upflow
of water possible.
Solution
[b] The system consisting of the solar
collector, the tank and pipes is an open
system.
Cold water enters the tank at the base and
get warm on mixing with hot water inside
the tank.
There is interaction between the
surroundings, surface of the tank, water
inside the tank.
Warm water entering solar collector
interacts with the surroundings at the
surface of the collector and becomes hot
water.
Hot water in the tank leaves the tank the
moment the water level rises to the top.
Example 2
The table below lists temperatures and specific volumes of water
vapor at two different pressures
p = 1.0 MPa p = 1.5 MPa
T (⁰C) v (m³/kg) T (⁰C) v (m³/kg)
200 0.2060 200 0.1325
240 0.2275 240 0.1483
280 0.2480 280 0.1627
Slope =
𝑇 −240
0.1555 −0.1483
280 −240
=
0.1627 −0.1483
⟹
T = 260ºC
Solution
[c] At T = 220 ⁰C and p = 1.4 MPa, the specific volume
falls between 1.0 and 1.5 MPa and T = 220 ⁰C btw 200
and 240⁰C. Hence, double interpolation is required.
At 220 ⁰C, v at each pressure is the average over the
interval
0.2060 + 0.2275
At 1.0MPa, 220⁰C; v= = 0.21675 m³/kg
2
0.1325 + 0.1483
At 1.5MPa, 220⁰C; v= = 0.1404 m³/kg
2
so as calculated in [a]
𝑣 −0.1404 0.21675 −0.1404
= ⟹ v = 0.15567 m³/kg
1.5 −1.4 1.5 −1.0
Assignment
1. Over a limited temperature range , the relation between
electrical resistance R and temperature T for a resistance
temperature detector is
𝑅 = 𝑅0 [1 + 𝛼(𝑇 − 𝑇0 )]
where 𝑅0 is the resistance, in ohms (Ώ), measured at
reference temperature 𝑇0 (⁰C) and 𝛼 is a material constant
with units of (⁰C)−1 . The following data are obtained for a
particular resistance thermometer.
𝑇0 (⁰C) 𝑅 (Ώ)
Test 1 (𝑇0 ) 0 𝑅0 = 51.39
Test 2 91 51.72