HW 6.

4 – KEY

1. −q chocolate = +(qH2O)
= +(cH2O)(mH2O)(∆TH2O)
= + 1.00 cal (2225g) (58.9oC – 19.5oC)
g oC

= + 87700cal = + 87.7 kcal

+87.7 kcal 60.0 g = + 263 kcal

20.0 g cb

2. −q iron = +(qH2O)
(ciron)(miron)(∆Tiron) = (cH2O)(mH2O)(∆TH2O)
0.45 J (miron) (52oC – 1445oC) = + 4.18 J (25000g) (52oC – 21oC)
goC g oC
0.45 J (miron) (–1393) = + 4.18J (25000) (31)
g
(miron) = 5200 g = 5.2 kg

3. qH2O = (cH2O)(mH2O)(∆TH2O)
6000 cal = 1.00 cal (mH2O) (100oC – 22oC)
g oC
6000 cal = 78 cal (mH2O)
g
(mH2O) = 77 g = 77 mL

4. qH2O = (cH2O)(mH2O)(∆TH2O)
= 1.00 cal (1250g) (37oC – 0oC)
g oC

= 46000 cal = 46 kcal

 5. −q rxn = +(q sol’n)

= +(csol’n)(msol’n)(∆Tsol’n)

= + 0.995 cal (132.3 g) (28.7oC – 21.2oC)

goC

= + (0.995 cal) (132.3) (7.5)

= + 990 cal

−990 cal 111.1 g CaCl2 = − 15.0 kcal/mol CaCl2

7.33 g CaCl2 1 mol CaCl2

6. −q metal = +(qH2O)
(cmetal)(mmetal)(∆Tmetal) = (cH2O)(mH2O)(∆TH2O)

(cmetal)(21.7 g)(32.5oC – 100.0oC) = 1.00 cal (50.0 g)(32.5oC – 23.6oC)

g oC

(cmetal)(21.7 g)(–67.5oC) = +(1.00 cal)(50.0)(8.9)

(cmetal) = 0.30 cal

g oC

7. −q metal = +(qH2O)
(cmetal)(mmetal)(∆Tmetal) = (cH2O)(mH2O)(∆TH2O)

(cmetal)(5.05g)(23.83oC–100.0oC) = 1.00 cal (10.00g)(23.8oC–23.6oC)

g oC

(cmetal)(5.05 g)(–76.17oC) = +(1.00 cal)(10.00)(1.83)

(cmetal) = 0.0475 cal/g oC