LAMPIRAN A

PERHITUNGAN

A. Rasio mol antara minyak dan methanol

Rasio 1 : 9
Massa minyak = 100 gram
Mr minyak = 823,3514 gr/mol

𝑚 100
Mol minyak = = = 0,1214548248
𝑀𝑟 823,3514

1 : 9 = 0,1214548248 : x
X = 1,093093423 mol methanol

𝜌 metanol = 0,792 gr/ml

𝑀𝑟 × 𝑚𝑜𝑙
𝑉 metanol = 𝜌
32 × 1,093093423
= 0,792
= 44,17 ml

B. Kadar Asam Lemak Bebas (ALB)

1. Kadar ALB minyak goring sawit
Berat minyak = 3 gram
Volume etanol = 50 ml
Normalitas KOH = 0,08417 N
Volume KOH = 0,5 ml
𝑉𝐾𝑂𝐻 ×𝑁𝐾𝑂𝐻 ×𝑀𝑟𝑚𝑖𝑛𝑦𝑎𝑘
% ALB = 𝑏𝑒𝑟𝑎𝑡 𝑠𝑎𝑚𝑝𝑒𝑙 ×1000
0,5 ×0,08417 ×256
= 3 ×1000
= 0,36 %

2. Kadar ALB minyak goring sawit + 1% katalis KOH

Berat minyak = 3 gram
Volume etanol = 50 ml
Normalitas KOH = 0,08417 N
Volume KOH = 0,6 ml
𝑉𝐾𝑂𝐻 ×𝑁𝐾𝑂𝐻 ×𝑀𝑟𝑚𝑖𝑛𝑦𝑎𝑘
% ALB = 𝑏𝑒𝑟𝑎𝑡 𝑠𝑎𝑚𝑝𝑒𝑙 ×1000
0,6 ×0,08417 ×256
= 3 ×1000
= 0,43 %
3. Kadar ALB minyak goring sawit + 1,5% katalis KOH
Berat minyak = 3 gram
Volume etanol = 50 ml
Normalitas KOH = 0,08417 N
Volume KOH = 0,5 ml
𝑉𝐾𝑂𝐻 ×𝑁𝐾𝑂𝐻 ×𝑀𝑟𝑚𝑖𝑛𝑦𝑎𝑘
% ALB = 𝑏𝑒𝑟𝑎𝑡 𝑠𝑎𝑚𝑝𝑒𝑙 ×1000
0,5 ×0,08417 ×256
= 3 ×1000
= 0,36 %

4. Kadar ALB minyak goring sawit + 0,5% katalis KOH

Berat minyak = 3 gram
Volume etanol = 50 ml
Normalitas KOH = 0,08417 N
Volume KOH = 0,5 ml
𝑉𝐾𝑂𝐻 ×𝑁𝐾𝑂𝐻 ×𝑀𝑟𝑚𝑖𝑛𝑦𝑎𝑘
% ALB = 𝑏𝑒𝑟𝑎𝑡 𝑠𝑎𝑚𝑝𝑒𝑙 ×1000
0,5 ×0,08417 ×256
= 3 ×1000
= 0,36 %

C. Perbandingan Yield
1. Yield rasio 1 : 9 katalis 1 %
Produk Metil Ester = 95,97 gram
Reaktan = massa minyak + massa metanol
= 130,95264 gram
𝑝𝑟𝑜𝑑𝑢𝑘
Yield = 𝑟𝑒𝑎𝑘𝑡𝑎𝑛
× 100%
95,97
= 130,95264 × 100%
= 73,28 %

2. Yield rasio 1 : 9 katalis 1,5 %

Produk Metil Ester = 97,48 gram
Reaktan = massa minyak + massa metanol
= 132,46264gram
𝑝𝑟𝑜𝑑𝑢𝑘
Yield = × 100%
𝑟𝑒𝑎𝑘𝑡𝑎𝑛
97,48
= 132,46264 × 100%
= 73,59 %
 3. Yield rasio 1 : 9 katalis 0,5 %
Produk Metil Ester = 96,7 gram
Reaktan = massa minyak + massa metanol
= 131,68264 gram
𝑝𝑟𝑜𝑑𝑢𝑘
Yield = × 100%
𝑟𝑒𝑎𝑘𝑡𝑎𝑛
96,7
= 131,68264 × 100%
= 73,43 %

D. Neraca Massa

Metanol FAME
KOH (Katalis) Gliserol
Trigliserida
Metanol
Trigliserida KOH
Reaktor

1. Rasio 1 : 9, Katalis 1%
Mol TG produk (D) = Mol TG umpan (A) – r
Mol Metanol produk (E) = Mol metanol umpan (B) – 5r
Mol KOH produk (F) = Mol KOH umpan (C)
D + E + F = 0,6428
0,6428 = (A-r) + (B-9r) + C = A + B + C – 10r
r = 0,05897
a. Massa Komponen Umpan,
Triglliserida = 100,04 gram
Metanol = 44,17 gram
KOH = 1 gram
FAME = 0
Gliserol = 0
b. Massa Komponen Produk
Triglliserida = 51,6488 gram
Metanol = 17,99264 gram
KOH = 1 gram
 FAME = 95,97 gram
Gliserol = 21,14 gram
c. Mol Komponen Umpan
Triglliserida = 0,1217 mol
Metanol = 1,09309 mol
KOH = 0,01785 mol
FAME = 0
Gliserol = 0
Total = 1,2325 mol
d. Mol Komponen Produk
Triglliserida = 0,1217 mol – r = 0,06273 mol
Metanol = 1,093 mol – 9r = 0,56227 mol
KOH = 0,01785 mol
FAME = 0,3327 mol
Gliserol = 0,2297 mol
Total = 1,2052 mol

2. Rasio 1 : 9, Katalis 1,5%

Mol TG produk (D) = Mol TG umpan (A) – r
Mol Metanol produk (E) = Mol metanol umpan (B) – 5r
Mol KOH produk (F) = Mol KOH umpan (C)
D + E + F = 0,6055
0,6428 = (A-r) + (B-9r) + C = A + B + C – 10r
r = 0,0635
a. Massa Komponen Umpan,
Triglliserida = 100,16 gram
Metanol = 44,17 gram
KOH = 1,5 gram
FAME = 0
Gliserol = 0
b. Massa Komponen Produk
Triglliserida = 46,931 gram
Metanol = 44,17 gram
KOH = 1,5 gram
FAME = 95,97 gram
Gliserol = 21,14 gram
c. Mol Komponen Umpan
Triglliserida = 0,1215 mol
Metanol = 1,0930 mol
 KOH = 0,0267 mol
FAME = 0
Gliserol = 0
Total = 1,2312 mol
d. Mol Komponen Produk
Triglliserida = 0,1215 mol – r = 0,058 mol
Metanol = 1,093 mol – 9r = 0,5215 mol
KOH = 0,0267 mol
FAME = 0,3379 mol
Gliserol = 0,2692 mol
Total = 1,2133 mol

3. Rasio 1 : 9, Katalis 0,5%

Mol TG produk (D) = Mol TG umpan (A) – r
Mol Metanol produk (E) = Mol metanol umpan (B) – 5r
Mol KOH produk (F) = Mol KOH umpan (C)
D + E + F = 0,72144
0,72144 = (A-r) + (B-9r) + C = A + B + C – 10r
r = 0,0502
a. Massa Komponen Umpan,
Triglliserida = 100,09 gram
Metanol = 44,17 gram
KOH = 0,5 gram
FAME = 0
Gliserol = 0
b. Massa Komponen Produk
Triglliserida = 58,704 gram
Metanol = 44,17 gram
KOH = 0,5 gram
FAME = 96,7 gram
Gliserol = 12,8 gram
c. Mol Komponen Umpan
Triglliserida = 0,1215 mol
Metanol = 1,0930 mol
KOH = 0,00894 mol
FAME = 0
Gliserol = 0
Total = 1,2234 mol
d. Mol Komponen Produk
Triglliserida = 0,1215 mol – r = 0,0713 mol
Metanol = 1,093 mol – 9r = 0,6412 mol
KOH = 0,00894 mol
FAME = 0,3352 mol
Gliserol = 0,1391 mol
Total = 1,1957 mol
 LAMPIRAN B
DOKUMENTASI

Gambar B.1 sampel minyak Gambar B.2 Rangkaian Alat

goring sawit. transesterifikasi

Gambar B.3 Proses Gambar B.4 Hasil analisa

pemisahan biodiesel dengan kadar ALB
gliserol
Gambar B.5 Hasil biodiesel
dan gliserol