PROPERTIES OF GASES AND MIXTURES Prepared By-

A.K.PRADHAN

H (change
U (change in
Sl Index W.D (PdV) Heat transfer in enthalpy) P-V-T Relation
Process internal energy)
no n (reversible) in KJ (Q) in KJ in KJ
In KJ

1 P=C 0 𝑽𝟏 𝑽𝟐
=
𝑻𝟏 𝑻𝟐
P(vf-vi) mcp(Tf-Ti) mcv(Tf-Ti) mcp(Tf-Ti)
2 V=C ∞ 𝑷𝟏 𝑷𝟐
0 =
mcv(Tf-Ti) 𝑻𝟏 𝑻𝟐
mcv(Tf-Ti) mcp(Tf-Ti)
𝑽𝒇
3 T=C,PV=C 1 𝑷𝒊𝑽𝒊 ln 𝑽𝒊 0 0 𝑷 𝟏 𝑽𝟏 = 𝑷 𝟐 𝑽𝟐
𝑽𝒇
𝑷𝒊𝑽𝒊 ln 𝑽𝒊
4 𝑷𝑽𝜸 =C 𝜸 0
𝑷𝒊 𝑽𝒊 − 𝑷𝒇 𝑽𝒇
mcv(Tf-Ti) mcp(Tf-Ti)
𝜸−𝟏
5 PVn=C n 𝑷𝒊 𝑽𝒊 − 𝑷𝒇 𝑽𝒇 𝝂−𝒏
𝒏−𝟏 × 𝑾. 𝑫 mcv(Tf-Ti) mcp(Tf-Ti)
𝜸−𝟏

Cp-Cv=R
𝑪𝒑
𝑪𝑽
=𝜸