4.

22
a
nA (kmol/h)
0.10kmolH2/kmol
0.90kmolN2/kmol 100kg/h
nP (kmol / h)
0.20 kmolH2 / kmol
0.80 kmolN2 / kmol

nB (kmol/h)
0.50 kmolH2 / kmol
0.50 kmolN2 / kmol

MW = 0.20(2.016) + 0.80(28.012) = 22.8128 kg/mol

nP = (100 kg/h) * (kmol/22.813kg) = 4.383

Balance General = nA + nB = 4.383 ….(1)

Balance H2 = 0.10(nA) + 0.50(nB) = 0.20(4.38) = 0.876 ….(2)

Resolver (1) y (2) simultaneamente

nA + nB = 4.383
0.10(nA) + 0.50(nB) = 0.876

nA=3.289 nB=1.094

b nP= mP / 22.813

Balance General = nA + nB = mP / 22.813

Balance H2 = xA*nA + xB*nB = (xP*mP) / 22.813

nA = (mP*(xB-xP)) / (22.813*(xB-xA)) nB = (mP*(xP-xA)) / (22.813*(xB-xA))

c
NUM xA xB xP mP nA
1 0.10 0.50 0.10 100.00 4.3835
2 0.10 0.50 0.20 100.00 3.2876
3 0.10 0.50 0.30 100.00 2.1917
4 0.10 0.50 0.40 100.00 1.0959
5 0.10 0.50 0.50 100.00 0.0000
6 0.10 0.50 0.60 100.00 -1.0959
#DIV/0!
#DIV/0!
7 0.10 0.50 0.10 250.00 10.9587
8 0.10 0.50 0.20 250.00 8.2190
9 0.10 0.50 0.30 250.00 5.4793
10 0.10 0.50 0.40 250.00 2.7397
11 0.10 0.50 0.50 250.00 0.0000
12 0.10 0.50 0.60 250.00 -2.7397
B = (mP*(xP-xA)) / (22.813*(xB-xA))

nB
0.0000
1.0959
2.1917
3.2876
4.3835
 5.4793
#DIV/0!
#DIV/0!
0.0000
2.7397
5.4793
8.2190
10.9587
13.6983
a

Condensador
2 n1 [mol]
0.97 molB / mol
0.03 molT / mol

n1 [mol]
0.97 molB / mol

COLUMNA DE DESTILACION
100 mol 0.03 molT / mol
0.97 molB / mol
0.03 molT / mol

n4 [mol](45% de alimentacion de reboiler)

yB [ molB/ mol ]
1 - yB [ molB/ mol ]

Reboiler
n2 [ mol ]
zB [ molB/ mol ]
1 - zB [ molB/ mol ]

b Proceso General
Recuperacion 89.2% : 0.892(0.50)(100) = 0.97 n1
Balance general : 100 = n1 + n3
Balance B : 0.50(100) = 0.97 n1 + xBn3

Reboiler
Relacion de composición : (yB*(1 - yB))/(xB(1 - xB))
Porcentaje vaporizado : n4= 0.45*n2 ….(1)
Balance molar : n2= n3 + n4 ….(2)

resosolviendo (1) y (2) simultaneamente

n4= 0.45*n2 ….(1)

n2= n3 + n4 ….(2)
 Balance B : zB* n2 = xB*n3 + yB*n4

c B fraccion molar de la cola: xB = 0.100 molB / mol

Moles en la parte superior: n1 = 46.00 mol
Moles en el fondo: n3= 54.00 mol

Recuperación de tolueno : (((1-xB)*n3)/(0.50*100))*100%= ((1-0.10)54.02/0.50*100)*1

 Condensador

n1 [mol](89.2% en alimentacion)
0.97 molB / mol
0.03 molT / mol

on de reboiler)

n2 [ mol ]
Reboiler

xB [ molB/ mol ]
1 - xB [ molB/ mol ]
00%= ((1-0.10)54.02/0.50*100)*100% 97.236
1.00mol nA [mol CO]
0.20 mol CO/ mol nB [mol H2O]
0.10 mol CO2/ mol nC [mol CO2]
0.40 mol H2O/ mol nD [mol H2]
0.30 mol I/ mol nI [ mol I]

E= Grado de avance de la reaccion

nA = 0.20-E
nB = 0.40-E
nC = 0.10+E
nd = E
nI = 0.30
nT= 1.00 mol

Para equilibrio= yC*yD/yA*yB= (0.10+E)*E/(0.20-E)*(0.40-E)=0.0247EXP(4020/1123)

E= 0.110

T(K) y(H2) x(CO) x(CO2) Keq Keq*

1223 0.5 0.5 0 0.66103212 0.66103212
1123 0.5 0.5 0 0.88580823 0.88580823
1023 0.5 0.5 0 1.25692308 1.25692308
923 0.5 0.5 0 1.92400877 1.92400877
823 0.5 0.5 0 3.26616533 3.26616533
723 0.5 0.5 0 6.41868931 6.41868931
623 0.5 0.5 0 15.6691912 15.6691912
673 0.5 0.5 0 9.70170895 9.70170895
698 0.5 0.5 0 7.8331152 7.8331152
688 0.5 0.5 0 8.51706008 8.51706008
#DIV/0! #DIV/0!
1223 0.5 0.5 0 0.66103212 0.66103212
1223 0.5 0.5 0 0.66103212 0.66103212
1223 0.5 0.5 0 0.66103212 0.66103212
1223 0.5 0.5 0 0.66103212 0.66103212
1223 0.5 0.5 0 0.66103212 0.66103212
0.40-E)=0.0247EXP(4020/1123)

E y(H2)