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Prediction
THERMODYNAMICS
Try to understand:
• Chemical thermodynamics
• Energy
Thermo -
• Temperature
• Heat
-dynamics
• Movement
• Work
Thermodynamics
• The study of temperature and heat and how it
relates to energy and work.
System Surroundings
System
Surroundings
Energy
• Capacity to do work.
• The ability to move or change something.
• It manifest as work or heat.
Internal Energy (E/U)
• Sum of the potential and kinetic energy of the
system.
• CANNOT BE MEASURED!
• Change in the internal energy of the system.
• Sum of Work and Heat
Heat (q)
• The transfer of energy between two bodies
that are different temperatures.
• The energy transferred between a system and
its surroundings as a result of a difference in
their temperatures.
Exothermic Process (-q)
• Heat transferred from the system to the
surroundings.
• FEEL WARM!
ΔU = q + w
Problem 1
ΔU = q + w
WORK
• In chemical system focuses mostly on
expansion or compression.
w = -PΔV
• Expansion Δ>0, w is negative
• Compression Δ<0, w is positive
Problem 2
ΔU = q - PΔV
Heat at constant Volume
(Isochoric Process)
Since it is at constant volume, ΔV = 0; no P-V
work.
ΔU = qv
Heat at constant Pressure
(Isobaric Process)
• Pressure exerted usually is atmospheric pressure.
• If the reaction results in a net increase in the
number of molecules of a gas. (expansion work)
• if the reaction consumes more gas molecules
than the initial (compression work)
• If the reaction produces the same amount of
molecules in the product and the reactant (no
work)
Heat at constant Pressure
(Isobaric Process)
ΔU = q - PΔV
Or
qp = ΔU + PΔV
Enthalpy
• The change in enthalpy equals the heat gained
or lost at constant pressure.
qp = ΔH
ΔH= ΔU + PΔV
Enthalpy
H = U + PV
ΔH= ΔU + Δ(PV )
Problem 4
Calculate the change in internal energy when a
gas at constant pressure of 1.23 atm reacts to
change the volume of a movable piston from
298mL to 479mL while releasing a heat of 456 J.
Problem 5
ΔH = Hfinal - Hfirst
ΔHrxn = Hproduct - Hreactant
Exothermic Process (heat out)